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(2)

THE SIMULATION OF WATER OUALITY

IN THE

WAIKATO AND TARAWERA RIVERS

A rh.esi.s subnitted in ;.:':ial fuLfitreit fcr the degree of Dcctor of Ph:10scphy, at t:-.e University of Auckland.

February

1975.

Jarnes Christopher Rutherford

B.E.

(Hons).
(3)

ABSTRACT

Th,e calre,es aqd

effeets of

watelr

pollutior:r

a're

Listed

and

tlre

neehanisms

of

staeart sel-tr-ry,unifioation

des.oribed,

The paraneters

for

whleh nathena,tical,

rneidielj.E have been de,v,e].oped a:ne deecr.ib€d and the .suec€s,s

of the

variOus p,nevious s@de'Is f,oF

paedicting

thern

ts discussed.

Tlre eqr.ratiorls governing ta-e

eoncentretlen

of

dicqotved oxy€e,n Ln

a

pol,J.uted '*aterway

are

devElop,ed End h rtrev,j.ew :i.,s nEde

of

tlii€ vani.o,ue

f,inite

dif,fenenee seheFyeg w,biclr ane

avallable

fo_1.

sotrv-ing then.

Models

are

deveLo5red

f,or pnedicting

diesolued px,ygen co$reentnations

in

two proll.,gted l{ew Z,ea1snd

riveFs, th€

ttaLkato a.n:d

the Tapawena. I*

tra,s f,,ound

that

the, -lhatdel. tis,ed, pr"evious,ly i.n

other

tdaterway6 rdere

not

ad€gtrate

fof; eith€F

o,f thes€

rivqne.

The nodel

of

the I{.ai}ato R.iven use,s

the

$elt+kRown S reeter-Fhelps:

cquatLon

tq

nnedel thef

exgrtion of

6OD

but

ineludes

the effeets

o.f

the

rnaerioeh)rt€

afid phy:l6,pLankton couuauni*ies on

th€

eonce,ntr.atlgn

of

dissolved roJy'geqd The

nodeL

of

ttre,tarasrer.a Riveq uses

t-te

!{onod equariohs Ge

gredict

rh€ concent-latlons

of

aeti've bi.6mass

in the

ipgrous p'unlee se-dinentg pn

the

Five,lr rbed

j

,Eird. suceess.ftlllll

aecountB

fo.r thq high

r.ate <lf .ox5rge*r uptake whielir has been

observed.

The way ;ln whietl these ,node.ls could

pro,fitabty

be developgd

is also

di.seuss,ed.
(4)

ACK NOWLED GEMENTS

There atrs serae,$al p€op],e w-lrro have made ualo,r

eontributions to the

sork de,eeribed i.ri

thi.s thesi:s,.

Mess)os

J.S. I{ietsen,

B.H-

PyIe,

rI .W.. Nagels and

G,€.

Bnyers, lilater QU4J.itJ L4bo.:tnatoryn

l4inist?y

,of [.lcr,fte, liahiilLtori, ltessns 6.T.. Ridal.tr and 8..

eaelisle,

gtraikato Val.ley

Authofity

Ha.lLiltont

Dr.:H.E.IJ. [6ylLor,, Auclrlatrd fiqgf.onatr

Autho!'ity,

,rqsk],and, H:o F..

toFe,

Steven and

Fitzdaulliee

L€di Auekla:ndn Dre

B.!.

Ooff,ey, I'les Zcralrand

Electr.ieity

Depantaentn HerqiLtorrr, D'

g

J,f,t;A. Btroiwt 6nd

t'l.rl.

Sitrvesten, afld l.tiss

C,

Lan, Botany DeFart$erti Uni.versity' of, A.ueklan4,

l{r F,a. Leighton,

l{ew, Zealand Co;-operative

Dairy

Conpan5r

Ltd"

ruatAngl, lfi:, C.F. Densread, lt€.at Res6ancb

Institu-t€, llanilton,

nelUbers

of

the

Teehntcgl Gonqri-ttae, tf,aikata Rl.va:r Resowoe.s FFojeqt, Dn

!.l.J. l,titchell"

Tasm44 .FuLg aad FaEer Oonpa$gr Kawerau, and ntrrmerrous Otlrers"

f

wquld

liRe tg

e,raplae$s

ny sincere

thariks

to

my supervisorrr

Dtr

l{-.I.

Or8.u11luern., r.tho }ra.s given ne

a

co-nsiderable ano,unt

of

},lelp and. guidattee..

thtrough.o,ut.

the Droiectr

:alld

in the

pr€pa,ratien

of thie

scniBt.

I

worlld

also

Ii-ke

tp

thank ury mothen and

ny sisten, fon thgiF

rassistgr.lo€

r{th

proof, r€adlngn ray wif,er. Susanl

folr,her

errt}ruaiasn and support thtougltout the ppoJectt a-nd

to

lfarnie Lolrg

fot the

enduotis

task

she performe.d

in ttrping

the nanusesipt.

I

weu.ld

likp tg

e4pr.ess my €rFatitude

to the

f,asna.n Fulp and Faperi cotipanyt Kireerau,

tlie

llew Zealah(t Co-;0.peiative Daitsy Company, l,tatangir dnd

the

Auar(land

Farners.r freea:lng Conpa4y, AuckLand, whq h.ave gtven ne aeeess

to their files, I

q4

also

deePtry {-ndebted

te the riinisEry of

Worts en4 9evelopraent, ,b}

ttttorn

I

harie baen eraployed f.sr -the

last

eightee,n mom-ths n

for

araking

it

possi-bIe fon

!tre

tE

e.e-rilpil,Ft9

the

wqrrk dEsenibed

in this, thesis at the

t:lrlivers-.1-ty gf, Aucklald.

I

a'[

als6

gratefutr

to the

trln,iverslty of, Aucklan'd

f,or

allowLng me paiat-time statrrE urLng

thiF

p€niod aRd

to the Un,iversitf

Olrants Co,rulitte€

tror the flnancial

as.s:lstqnge

of a

post-gSadg4te pehol,a:rghip betr.r€.en Marah 1972 a,nd

*lullt

1.973.
(5)

TABLE OF CONTENTS

Fage No, trIIf,ROEUCTI.ON

CtsAFTSR

1

PO'LLUTION AND I{ATER I'AE

1.1, Follutiorr

and

the

Gerteral Fubli.e

X.

2

lf,at€r Use

1. ?.

1

Done,s,tic Supply

7..2.2 Agnlcultural

Supply 1. ?.

3 Industrlel

lJ-se

L.2.4

Reereatior,r

:1.2..5

G,eneration o.f

El.e.ctricity 1.2.6

Eisposa.l od Waste Maittef

1.3

Typ€s

of

Pollutants

1. 3

.1

Fhysieal P-ollut.rntg

1,. 3.

2

Chen.iea.i_ Poll.uta,nts 1.3.

A Eiological

PoLltrtsnt-s

l.jlr

lfu.tef Qua.lity Letgislation

1.5

lletherdatical Hod.elling

of

l{ateF Quality

1.

5.1

Intr,'o.d.uet'ion

1.5.2

Parametetas

of

Wdter

Quality

MOdelE

I.5.3

Lin{.tatione

,ot

Mathenatieatr l{odels qtAPrER

2

['lEeI{4NISHs AND }{EA$'rilREf{ {T

or

P0LLUTISN

2.L

Intnoduction

l2

2'.2 Dilrrrtion,

Dispersion, arnd

Adveetiori

12

. Z.g

Oxygen

Deptetion

13

2.3.

I

Intnoduction

2.9,2

Oxygen De:na,nd

of Polluted

Waten

2.3.3

oxygen Uptake

in tlrc

l{atenray

2.3r.rt

Oxygen Pnoduction and eonsump€.ion by Aquatic ?-lan:ts

2.1+

Kin,etics

of

P.eDulafion rghan.geE

in

FolLuted

t$aten

19

2.4.1

Intnoduct.ion

' 2.$.?

Exogerrogs Ms:taboLlsrn

of

Baetefie-

?.4.3

Endogenous Hetabolisn

of

Seqteria

' 2..4r.4

Pnedatlorl

by

F:rotozoa

2.b..5

oxygen Uptalae

la

Co:nplex Systene

2

.5

!4ierobial rContaminatioo and Self-Funif

ieat:lon

22

e.S.1

Inttroduet:lon

2.5.Z

Tndieaton 0rganigns

2.5.3

Mierrob:ial

Self-Purlfieatlon.

(6)

I

'

Fage l{o.

e$AFTER

3

HATI{EI{ATXCAL I{CiDSLS 0F trATEn QUAl"ltY

3.

tr

Kineti.ee ,of Oxygen

Uptake

?5

3.l,L

F:i-t,st Orden Models

3,1.2

Seeend Onden Models 3. 1..

3, the

llonsd Eqr,rations

3.l..ir

Frotoz,cal

Aetivi.ty . 3.1,5

End-oge.no-us Hetabo,li.sm

g.2

The Transpoi3t

Egu,Eti.on

3r0

3.3

The

Potlutioa fquatiorts

32

3.3.L

BOD=DO Equations

,3.

3.2

Secand OederF Equatloas

3.3.3,

Bo'und,ary and

ltiitial

&rnd.itior.re

3.4,

The 0perr ctlierinel Floir

Eg.uations

3s

3.

5 Estination of the

Rate

of tongitudinel Diepensirin

36

3. S.

t

Inli.lpduetio,n

3.5"'2 Fredictioq of the

Rate

of

Dis,persion

3.5.,3,

P-as,slb,Le trna<reurEcies

in the

l{ethocl

3.6

Estirnation of,

the

Sate

of

Reaeration

CInAFTER

4

SOLUTION 0,F THE POLI!UTI0!{ EQUATTOUS

t{.1

Introduation

4.2

Efirors Ag:goelated.$rith

the

NunerriEal

Solution of

ttre FoJrl.uti'on Eguation.s

r+.5,

Nunerroie+L ,S-olu,tien of,

the

TFenspoi't Eqg-atrlon

11,3..1

6.iaple

Explielt

l{ethod

tt.3.2 Inplicit

Methods

tt

.3.3

Lax=tlendroff

fype

lilethods

tr.s.,$

A General Sesc:riptiori

of

t-b€ A-cqqracy aad UsefuLne.s;s

of the

Numerie.al Pietldde

4.r!t

!e^slE' F:rob,lelne

u.f+.1

Introducti.on

r+.tl

.A Anaiytieal

SolutXorrs

to

t-!ie

test

Pnoblens

l+.tt.3

Results and Cbtncl.trsl,ons

4.5

SoLution of, t.he Tr,ansport Equation

in a

Non-Uriiforn

'

Chann,el

l|'.6

SioLuttion

of tlre

Po,!!-utl6n Equation$

b.6.1 Explicit

Uethods

11.6,2

Trdo-Step !{ethods.

4.6.3 Iu5rli;cit

Methods

!+.,6"

rt

Diqe-uesion

4.7

sol-utieNr o.f

the

G,radua}ly V.atying H[Otr gqiuetion

CHAPTER,

5,

DESCNIPtrION OF T.T.IE IIIAIKATO RIVER

5,1

Desoeip.tion

af the

eatc iuent 6e

5.2

Ercletlng Sater

Qrlality ia the

U.p:per lCaikato River

and

La-kes

67

- 9,3 Exleting

Slaten gualtt5r

in the

Lower" lrlaLkato

f,ive!

5.3.1

Ssui^see

of

Fotr,tutJ.on

5.i.2

ltleagu.rement

of

glater Quattty 5. 3.

g

;ELsEorlved Oxy:gen

5.3.4

Biocbenical Oxygen Denand

40

$,1

'50

6,8 5s

(7)

Faee_ No.

C'IiAPTER

5

(c<intinued)

5.3..5

Fa,ecal B'aster:la

5.3.6

Aquatic

Plant Life

9.3,? !/ater

Tenp.erature and othen Faragneters

5.4

,

I|3rdnaulie Charae€eristieg

5.4.1

Riven

flofi -

5 .4

.2

Tributar.i:es

5,t+.3

Chaonel CharasteF(stics

CTTAFTER

6

A WATER QTIALITY HODEL FOR TIIE WAIKIITO R TE8

6.1 Paranete.rxs,llode}led

?8

6.2

llydrauli.e Eata Req-uirred

bJ the l{odel

15

6.2.1

Titre

of Travel

Predictions

6.

!.2

Goef

ficient qf

l.otrgttudi.-nar DisPqrs:ion

6.3

Data on

th€ PallutloB So.urc€s

80

6.

9,'J

Domestic ise$age

6r.3

.;?

Da.i.ry f.'aqtory

Efftu€nt

6.3.3 Abattoir

and l"r.eezing

liorks Effluent

6 ! 3 .

r{

Agrie. un

tlrr,al

Ef

flqeot

and Fasture Ru,noff

6.lr

Bate

ebeffioients for the l-{odel

g'P

6.

$.1,

EOD E:certiOn Rhte

6.ft.z .

BeaeFation Rate

6 .4 r

5

O4ige-n Prroduetion and Consunption by

{quatic

PlaEt€

6.!r,r+

Ef,fects

of

Sur.rlight

IntensitJr

aiid

['l*tef -_

'Feurpq'natune oril ,Or$f,gan Produetion and Consumption Rates

cIiaPrER

7

PREDICTIoIfS OF T,JATER QUALIty IH THE r{ArKATo RMR

'l.L

Cornputation

Procedunes 190

I

1.1"1

Des'cr{pti.on

of the

Mathenatieal l4odeL 7.1

.2

.Discr*ssion

of

t-he flethods usied t@ FF.edlct,

,Eiseol.ved Oxy, ge-n Ooncentratlons

7.?

?-r:'edieti.sn$,

of

E'*'is,ti.nB Conce'ltrnatlsns

of

Dib€olved

Oxygen

lq1

7.2.L

Pe:riod

of

Sunner Low Flort

7,?"2

Peried

df

Peak Daiklr Produetion

7.3 Prediction of

Changes

in the

Concentrations

of

Dissolved

Or.Jrg-ed

1,13

7.3.1 Effects of

Increasing F,opulation and X,ndustry

7.3t2

Ef,feote

of

Dischange

of

,Co'elirlg Eatejr-

7,4 Csnclnqlgn€

12q

_

7. !l .

L

Mo€e].

flor

D:Lesolved Oxygen

'1,.t,2

Steps Neo€ssany

to

Maintain Eigh Coneentratlo&s

of

Dissolved Or.ygen.

? "

lt.3

Suggeoti;ons

for

Furthen l{srih

-

T

-S Predictioh of

Rateo

of

Fnush.i.ng

of Pollutan.t€

L2'7

7.5 .

I

fntnoduc'tion

'?

.6,2

Nume:rieal ltethodc

7,5.8

nesultE

?.5.4

Dissussion and Propqsed llonk
(8)

CHAPTER, 8 S'IMIIIATION 0F I.IATER QUALITY

IN

THE TARA{,IERA nrPEfl trnt-?odrletiion,

Hydrau.Lie Character.lstics

8 . ?,

1

R.lver Flow

8.2.12

'f,he Riven Bed

8.1.,3

Lo,ngitud:lnaL Disperslon

8.2.4

Rate sf, Reaepati6n

8

-3;

Th,e t{eo=hanis.ms

of

oxygen

tJptake

136

8.4

Uathe&atioal. ModeL

of

Di.sso.ve{ Oxy,gen

Go.neentna,tion

13?

I .4 r

1

In.trFoduet iorj

8.4.?

Model ,ef

the River

Bad

8.$!3

.Eguatioas €ovot'niag

the

Coneentr*tio,n sf, Dissol,ved 0xygen

Pqge Nq.

13s L3?

l4I

lq6

$a

1s,tr

1.5.5

156

158

183

18lt 185

1E ,8.1

a.2

8.5

The

Fplluting

[.oed

9.s.1

chortric-al c-onstituen_ts o,f

pulp MlIl Effluant 8.5.2 Estination of

Rate Parametens

8,5.3

Erstii'nation

sf

Rates

sf

Additi.on

L 5.4

.Pii.6to,zoal .Aetivi.ty

8,5,,5

Endogenor:rs HetaboJ.ls.lo

9.6

Reer.lXts .and DiserlssLen

8.8.f

. Dinensions

of the

Sedisrent Layerns I

.6.2

Rates

of

Di€pers i.oir

9.8.3 laitial

Concenrration

of

giorlras,s

$.6.+ Effects sf

protozoa

d.8.S

Eff,eicte o.f Endogerou,s Hetabolisr[

8.€.'6r

eompari.son

of the

One and Twos8u$.stnate. lttgdeJs

8.T

Concl.us:loRs

8.8

SuggestJ"ons

fbr

Fupth€r ifork

EEAPTIR

9

S['r+tARY AND COI{CLUSIOIi}S

S.l,

$unErary: and Conelusigns.

9..2

Sug8es.tions

fori

FuFttr€r l{ork

APSENETX

r

AFPENDIX 2

d,FPENOTX 9

AFFIX'|-DIX q.

APPENDIX 5

AtFEREIfCES

E€tiln€tioo

of

'luongitrldlnal D,ii spe:'s,.ion,Coef f,

ieisnts Detailed

De'script:i.on

of the

,t{unenical Sol.ut:isus

to

tb,e Te,slt Prerblems

Rate.g

of

Qxyg.en Frolduotl.on by Helos.i)ia Epecies

Ffedic-lion

of,

gtege arrd Me:an VeXocitll in: t-he Wai]<atE

l,iver

1?9

ExPerlurents on 0xygen lJptake

in the

Tarallera Rirren, 1c€5
(9)

LIST OF FIGURES

CHAPTER

4

Page No'

r+.1

Computational- Net f

or the

t,ax-i{endrof

f

Two-Step

Scheme

r+5

4.2

Conputational Net

fon the

Cnowley Two-Step

Scheme

47

CHAFTER 5

5.1

Hap

of the Locality of the

Viaikato

Riven

64

5.2

Seasonal Vaniation

of

tlaten TemDerature

in the

Waikato

River.

75

CHAPTER 6

6.1

Diurnal- Vaniation

of Effluent

Flow and Composition

fron

a

Septic Tank

in Hamilton

82

6.2

Seasonal- Va::iation

of

Production

at

Te Rapa and

Taupiri

Dairy

Factonies

83

6.3 Diurnal Variation of Effluent

Flow from

the

Horotiu

Abattoin

87

6.1+ Correlation

between

Effluent

Flow and Pnoduction

at

the

Horotiu

Abattoir

88

6.5

SeasonaL

Variation of

Production

at the Horotiu Abattoir

89

6.6 Algal

Counts

at

Tuakau

Bridge, 1971-1973

95

6.7 Algal

Counts

at the

Road Enidges,

19?4

96

6.8

Assur:led

Diurnal

Vaniation

of

tlxygcn Pncduction and

Consunption by Aquatic

Plants

99

CHAPTER 7

7,1 Daily

Average Dissolved Oxygea Concentrations Predicted Using

Three

Dif.ferent

Values

for

BOD Decay

Rate

102

?.2

Predicted Diunnal

Variations in

Dissolved Oxygen and BODU

concentrations

104

7.3

Predicted Dissolved Oxygen Concentrations

including the Effect

of Hacrophytes

105

7.4

Predicted Dissolved Oxygen Ccncentrations

including the

Effects

of a Uniforn

concentration

of

Phy-topl-ankton, 5

Bgl1

1071

7.5

Predicted Dissolved Oxygen Concentrations Incl,uding

the

Effects

of

an Increasing Concentration

of

Fhytoplanktont 5-10

ngll

109

?.6

Predicted Dissolved oxygen Concentrations

Includiig

the

Effects of

an Increasing Coneentration

of

PhytoPlankton

7.s -

15

ngl1.

110

?,7

Pnedicted Dissolved oxygen Concentrations Assuming

that

the

PhytopLankton

are active only in the

Euphotic Zoner

l

metre

deep

111

7.8

A Comparison Between 0bserved and Predicted Dissolved Oxygen

Concentrations

during the

Period

of

Peak

Dairy

Production

7.9

A Compar"ison

of

Predicted Dissolved Oxygen Concentrations

during

Surnmen Low Flow

Periods,

1975 and

1985 Utl 7.10

Dissolved Oxygen Coneentrations Predicted Assuming

that

the

Disehar:ge

of

Chlorinated

Effluent

from Hamilton Severely

Damages Phytoplankton

Populations

LL7

7.lL

A Comparrison

of

Dissolved Oxygen Concentnations Predicted

.

Assulning

that the

Discharge

cf

Cooling Water

at

Huntly

Affects

the

Phytoplankton Populations

in Different ways

119

7.L2

Dissolved Oxygen and BOD Concentrations Predicted Assurning

that

the

Dischange

of

Cooling Water

at

Huntly Causes Severe Damage

to the

Phytoplankton

Populations

12L
(10)

Page No.

7.L3 Pollutant

Concentrations

after the

Reled,se

of a

Slug Load

fron Fainfield Eridge

128

7.L4

PolLutant Concentrations Passing

the

Proposed

Intake

Site Following

the

Discharge

of a

Stug Load

at a

llumber

of

Different Loeaticns

129

7.15

Tirne

fon

which

the Pollutant

Concentration

at the

Proposed

Intake is

above

the

Detection

Limit.

130

CHAPTER 8

8.1

ltap

of the Locality of the

Tarawena

Riven

133

8.2

Predicted FIow Ccnditions and Rate

of

Sediment

TransDort

135

8.3

Dime.nsions

of the

Sediment

Layens

139

8.4 Effects of

Variati.ons

of the

Dirnensions

of the

Sediment Layens on Pnedicted Dissolved Oxygen Concentrations, One Substrate

MoCeL

147

8.5 Effects of Variations of the Initial

Concentration

of

Baeteria on Predicted Dissolved oxygen Concentratj.ons, One Substrate

Model

147

8.6 Effects of

Var"iations

of the

Dinensions

of the

Sediment Layens

on Pr^edicted Dissolved oxygen Concentrations, T..-ro Substrate

HodeJ., Simultanecus Substrate

Assi:nilation

lqg

8.7 Effects of

Var:iations

of the Initial

Concentration

of

Bacteria,

on ?redicted Dissolved oxygen Concentrations, Two Substrate

Hodel, Sinultaneous Substrate

Assinilation

1\9

8.8 Effects of Variations of the

firnensions

of the

Sediment layers

on Predicted Dissolved Oxygen Concentrations, Two Substrate

Mo<iel, Sequential Substrate

AssiniLation

l'51

8.9 Effects of

Vaniations

of the Initial

Concentration

of

Eactenia

on ?redicted Dissolved 0xygen Concentrations, Tvro Substrate

Hodel, Sequential Substrate

Assinilation

151

8.1C

Comparison

of

Predicted

Dissolvei

Cxygen Concentrations, Two

Substrate

llodels,

Simultaneous and Sequential Substnate

Assinilation

1S3

8.11

Conparison

of

Predicted Dissolved Oxygen Concentrations, Trro

Substr"ate Models,

at

two

Different

Flow

Rates

153

APPENDIX 1

- A1.1. Definition

Sketch

of the Variables

Used

to

Evaluate

the Integral in

(3.31)

41,2 Longitudinal

Dispersion

Coefficients in the

Lowen hlaikato

Riven

151

APPENDIX 2

42.1

Nurae:rical and Anal5rtieal Solutj.ons

to the

Advection

of a

Sl.ug'

in a

Uniforrn

Channel

L68

}.2.2

Numerical and Analytical-

Solutions to the

Advection and

Dispersion

of a

Slug

in a

Unifor:m

Channel

171

42.3

Numerical and AnalyticaL

solutions to the

Advection

of

a

Pollutant

below

a Sinusoidally

Varying Source

in a Uniforn Channel

l'73

A2.r+

Numerical and

Analytical Solutions to the

Advection and Dispersion

of a Pollutant

below

a Sinusoidally

Varying Source

in a

Unifonrn

channer

176

APPENDIX 3

A3.L Definition

Sketch

of the

Channel

Characteristics

180

43,2

Conparison

of the

Observed. and preCicted Ratings

at

Several

Sites

on

the

Lol;erl' Waikato

River.

181
(11)

LIST OF TABLES

Page No.

CHAPTER 5

5.L

Areas unden

Cultivation

ano Stocking Areas

in the

Waikato

Valley

66

5.2

Population j.n

t}e

Waikato

Valley, 1956-1976

67

5.3

Sewage Treatment Systems

in the

l.laikato

Valley, 1955-1974

68

5.k

Dair.y Factories

in the

Waikato

Val1ey

?o.

5.5

l'tajon Tnibutanies

of the

Lor*er 'rlaikato

River

76

CHAPTER, 6

6.

L Effluent

Volune and BOD Load from

a

Septic Tank

in Hamilton

81

6.2

Volurne and Cornposition

of Efftuent

Associated

with

the

Manufacture

of

Various

Dairy Products

86

5.3

Composition

of Effluent

frorn

the

AFFCo Works

liorotiu, 1970-19?3

86

6.r.1

BOD Exertion Rate j.n Sarnples

of

Waikato River

!'later

91

6.5

Rates

of

0xygen Pr.oduction and Consumption by Macnophytes,

after

Sculthor:pe

93

6.6

Areas

of the

Predominant Species

of

Hacrophytes

in the

Waikato

River, 1969-?3

9r+

6.7

Rates

of

Oxygen Production and Consumption by

Phytoplankton

98

CHAPTER 7

?.1 Effluent

Loads,

Tributary

Flow and Conposition Used

to Predict

103

Dissolved Oxygen Concentrations

during a

Current February Low

Flow

period

103

7.2 Effluent

Loads,

Tributary

Flow and Composition Used

to

Predict Dissolved Oxygen Concentrations

during a

Current Cctober Low

-_'

Flow

peniod

113

7.3

EffLuent Loads,

Tributary

FIo', and Composition Used

to

Predict Dissolved Oxygen Concentrations ciuring

a

Februar.y Low FIow

Period

in 198r+

116

CTNPTER

8

'

8.1

Chemieal Conposition

of

pulp

llill Effluent

1r+2

8.2

Rate Parameters Used

to Predict

Dissoh,ed Oxygen

Concentrations

145

APPENDIX ].

AL.L

Predi.cted

Longitudinal

Dispersion

Coefficients in the

Waikato

Riven

160

AL.z

Published

Longitudinal

Di.spersion

Coefficients

162

A1.3

Fublished

Lateral

Dispersion

Coefficients

162

APPENDIX 3

A3.1 Friction Coefficients in the

Vlaikato

Riven

183

APPENDTX

Aq.1

'{ Rates

of

Oxygen Production Estimated using Magadzats

data

from

Lake

Karapino

184

Att.2

Rates

of

Oxygen Froduction Estimated using .Iavornicky and

'

Kornarkovat

s data

184

A4.3

Dimensions

of the

Thnee Predonlinant Species

of Diatoms

185

APPENDIX 5

A5.1

Rate

of

Deoxygenetion

of

Surface Waters of,

the Tar-.era Rive::

187

A5.2

Deoxygenating

Activity of

Sanples

of

Purnice

fron the

Tarauera

River

187
(12)

NOTATION

S{E8!|[|trIIC ANE C0MFUTATtr0NAL PARAIIETERS

A(xot)

ehanrrel a,rea

[i{l ar ,,crd

tridi.agona). o.oef,fioie,nt nat}irilc and

its

eomp-o'nent vector3s

b(xry)

channel

Fidth

d(a)

ahrartnel depth

drt

drfunensj.orrs

of the

s€dirDg.rt laye!.3

ErFrF longitudinal

dLspe:rs,ion coefficLents

t oF

nrrrmerica.l- crr pd.eudo-dispeis,ion boe.ff:ioientreofi^Ect€A cOeffioierrt

E giravitetional

aoceleratj.on

hod

dineneilotris e,f

the

sed:irnerrt lpyers

J;n

slraee and

tine indiciee in finlt€

diiffe,Tence

notation k.rkt

non-di&ensionatr disBersion cOefftcients

K(xty)

.eharrnpl conyeJance

n

l..lanning

friction

eoeff,:i.c.lent

Q(xrt)

ehannef, df.soharge

g(xrtt)

l,etoraL lnf-low

per rrnlt

l.ength o,f, ohannell

$(x:ry)

ohannel hydi'aullrc nadiu€

SI

sr!il <rf, eddy lo,sses

TfCl transport

opeinator

f,(xrt)

wate:. tedpeiFature

t tiae

u(x,yrAnt)

:lnstantanecus vetro.e.lty

U(xrt),V(x,tlrlf(x"t)

€roes-rse€tional average

veloeltiee

ut(rt' r.Zrt) differetrce

betrre€n ine.,taita'neous a$a.!re-'d'n veLoelt-y ilr

(xrsr:t)

6epth elrepaged:

velocitlr

diff,qrenee

'rsy

>z

Eu,le:ntan di€paaccneflte, -y

veriti.ealr ,(

down,Ett'ea!0

V6(x)

alrelage d"pth

z(x)

eharlnel bed

elevation,,

abolre datur.

o(x:t)

,

$(x't )

vsloeJ.tsr coBff,icients

AxoAt .

Eedh EXze and

tirne

Etep

in fiaite

Etiff,erence

notation

e latefaL

addy

diffusivity

lrlr tise

'and .epace dlff.erenci.og pairameters

P

advection pa'rAaeteir, U AtlAx

o

dispension pa?amster, E At/Axz

E

tag-rangian displaeenent

variable

ru\TER QUAL]TV FARASETERS BrBn

9gtB6. . .

c,irEi,..

DtD*

k1

k, plpt

S,8n 'onFrYrd

.

GrCrDrF

11K 1l

$rvnt

$rPr.ulrX 0(c l'

eoneentration of, heterotrotrlhie bactenia

pdll.utant

esneent-tration

i.nitial,qoncentratiotns

eolrcentfations

in tnibutary

in'flo;ws

diss€ v€d oxygen coneeltt'?atioa'gat.qration eonoentlatLpn

BOD decay

fate

nea€ratioft nate

eonoentr?atibn

of

g.rotoa-oa concentration

of

substrate

aubstrate a

sslnila lion/bastcr !a

gnowth para&€ters

bacteria

eons umpt :LoD /p.r'otozoa gngwth Par*meterf g

bacteria decline

parametePs Ilrotozoa dee,lir

e

lEnaret€rs

atop

funetionc

biological rate

oper€to-r
(13)

BIOLOGICAL TERMS

aerobic occurring in the

Pnescence of

'

making use

of

oxygen

aLgae

conmon name

for a

wide nange

of aquatic

plants

anaerobic

occunring

in the

absence

of, without

making use

of

oxygen

bactenia prirnitive nicro-organisns,

abundant

in

erater and

the soil benthic inhabiting the

sedi.nents on

the

bed

of a

wateruay

biota total

PoPulation

of

animals and

plants in a locality

coliform a type of

bactenia cornmonly found

in the digestive

systems

of

nammalst

and

also

found

in the soil

enzJrme catalyst

neleased by an organism, conmonly

to

incnease

the rate of

br.eakdown

of a

substrate

endogenous utilization of

food stored

within the cell

netabo].ism

epiphyte a

pLant which adheres

to Parts of

another largen

plant

e.utr:ophic

enniched

with nutrients,

capable

of

suppor"ting extensive

plant

and animal populations

exogenous utilization of

food obtained fFom outside

the cell

netabolisn

heterotrophic obtaining

noupishment frorn organic Substancesr

Parasitic

on saproPhytic

indicaton bacteria typically of enteric origin

whose pnesence

in large

nunrbens

in bacteria in

waterway

indicates recent

sewage contamination

lysis celL

r.upture

following starvation

maerophytes

I'ooted vascular

aquatic plants'

water weed

nutnient inorganic

compound nequined by

plants for the

synthesis

of

carbohydrate and protein

oligotnophic deficient in

one or' rnone

nutrients,

incapable

of

suPPorting extensive

plant

and animal populations

periphyton plants or

anirnals

adhering to parts of

rooted

aquatic plants

photcnespiration respiration

which occurs

in sunlight, at a higher rate than in the

dark

photosynthesis

process whe:reby

plants

manufactune carbohydrate fnom

inorganic

conpounds

in the presence of sunlight,

oxygen being neleased as

a

by-product

phytoplankton plant plankton,

smal1

plants

which

d:rift gtith the

surrounding water

protozoa uni-cellular or non-cellular

anirnals which

often

feed on bactenia

substrate

source

of

nourishment

for

heterotroPhic organisms

turbidity

absorbance

of light

by suspended

natter, usually over a

wide nange

of

wavelengths

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