L Berdoalah
terlebih dahulu sebelum anda mengerjakan !
2' Bacalah seluruh soal untuk memahami maksud soal, sebelum dijawab !
^ ^
1. fung.u.n
lupa tuliskan nim, nama, dan tanda tangan anda, sebelum menjawab soal!
ly
4. Jawablah
pertanyaan
dengan singkat dan jelas ! (untuk soal essay / isian)
Pilihlah.jawaban
yang paling tepat
5. Kerjakanlah soal yang anda anggap lebih mudah dahulu, dan tuliskan iawaban dilembar iawaban
yang telah disediakan
!
6. Jawaban
harus ditulis dengan tulisan yang jelas dan mudah dibaca, dan tidak diperbolehkan
kerja sama !
7. Koreksilah jawaban sebelum dikumpulkan !
JAWAPLAH DENGAN CERMAT. JELAS & TEPAT!
1. Jelaskan
hal-hal apa saja yang harus ada dalam sebuah
MSDS? Dan siapa saja pengguna
MSDS?
2. Jelaskan
mekanisme
toksisitas pestisida diazinon?
i
3. Jelaskan
diazinon?
peran masyarakat awam dalam penanganan kasus keracunan pestisida
4. Jelaskan
dampa(pestisdia
diazinon bagi lingkungan?
DIAZINON
AG6OO
WBC
TERIAL SAFETY DATA SHEET
FOR CHEMICAL EMERGENCY,
SPILL, LEAK, FIRE, EXPOSIJRE
OR ACCIDENT'CALL CHEMTREC
- DAY OR NIGHT 1-800'424-9300
F O R M U L A T E D F O R :
L O V E L A N D P R O D U C T S ' IN C
P O B o x 1 2 8 6 ' G r e e l e Y , C O 8 0 6 3 2 - 1 2 8 6
24-Hour Emergency Phone: 1 -800-424-9300 M e d i c a l E m e r g e n c i e s : 1 - 8 0 0 - 3 0 1 - 7 9 7 6 U.S. Coast Guard National Response Center: 1-800-424-8802 P R o D U C T N A M E : D | A Z I N o N A G 6 0 0 W A T E R - B A S E D C O N C E N T R A T E I N S E C T I C | D E
C H E M | C A L N A M E : o , u o n o n ' ( o - o . d i e t h y | o - ( 2 - i s o p r o p y l - 6 - r r e t h - r 1 - 4 . p y r i m i d i n y l )
p h o s p h o r o t h i o a t e ) C H g V r f C A l F A M I L Y : O r g a n o p h o s p h a t e l n s e c t i c i d e
EPA REG. NO.:
66222-103-34704
M S D S
N u m b e r "
6 6 2 2 2 1
0 3 - 0 7 ' t P l
M S D S R e v i s i o n s : S e c : i c - ' 3 D a t e O f l s s u e : 1 0 / 1 5 / 0 7Superqgdes:
09/03/04
ffiRDS rDENTlFtcATloN
suM
MARY
K E E P O U T O F R E A C H O F c H I L D R E N - CAUTION - Harrnful i f s r " a l l o " ' e o in h a l e d c r a b s o r b e d t h r o u q h s K r n skin, eyes or clothing. Avold breathing vapor or spray mrst Avord contarrination of food and feed Food utenstts should not be used for food purposes after use in measurtng pesticides Keep out of reach of domestic
anlmals livestock. Do not contaminate ornamental fishponds
T h i s o r o d u c t i s a n o f f - w h r t e l i q u i d w i t h s l i g h t s u l f u r - l i k e o d o r
C a u s e s e y c i r r i t a t i o n A v o i d c o n l a o t w l t n s u c h a s t a b l e s p o o n s a n d m e a s u r l n g c u p s D o n o t u s e o n h u m a n s ' h o u s e h o l d p e t s o r
3 . C O M P O S l r l o N , I N F O R M f i T I O N O X I I g I E D I E N T S
C h e m i c a l In o r e d i e n t s : D i a z i n o n
l n e r l I n g r e d i e n t s
Percentaqe bv Weiqht:
56 00
44 00
C A S N o . 3 3 3 - 4 1 - 5
T L V ( U n i t s l O O 1 m g / m : ' ( S k i n )
T h i s p r o d u c t i s h a z a r d o u s a c c o r d i n g t o t h e o S H A H a z a r d c o m m u n i c a t i o n s t a n d a r d ( 2 9 C F R 1 9 1 0 1 2 0 0 )
+ TIRST
AID MEASURES
l f s w a l l o w e d : l f i n e y e s : l f i n h a l e d :
l f o n s k i n o r c l o t h i n g :
call a poison control ccntor or doctor irnrnodiatcly for troatrncnt advice. Havc pcrsorr sip a glass of water tf able to swallow D o n o t i n d u c e v o m i t i n g u n l e s s io l d to d o s o b y a p o i s o n c o n t r o l c c n t c r o r d o o t o r ' D o n o t g i v e a n y t h i n g b y m o u t h to a n
nutes Removc contact lenses' if present' after the first 5 ' or doctor for treatmcnt advlce
an ambulance, then give artificial respiration, preferably er treatment advice
p l e n t y o f w a t e r fo r 1 5 - 2 0 m i n u t e s C a l l a p o i s o n c o n t r o l c e n t e r o r d o c t o r fo r t r e a t m e n t a o v l c e
F o R A M E D I C A L E M E R G E N C Y I N V O L V I N G T H I S P R O D U C T C A L L : 1 - 8 0 0 . 3 0 1 - 7 9 7 6 . H A V C c e n t e r o r < l o c t o r o r g o i n g f o r t r e a t m e n t
t h e p r o d u c t c o n t a i n e r o r l a b e l w i t h y o u w h e n c a l l i n g a p o i s o n c o n t r o l
ilr
r ne r tc HTt
N G M EAS
u RES
FLASH POINT ('F/Test Method): F L A M M A B L E L I M I T S (L F L & U F L ) : E X T I N G U I S H I N G M E D I A :
H A Z A R D O U S C O M B U S T I O N P R O D U C T S : S P E C I A L F I R E F I G H T I N G P R O C E D U R E S : U N U S U A L F I R E A N D E X P L O S I O N H M A R D S :
2 2 o o F t 1 M S c c ( P M c c ) N o n e e s t a b l i s h e d
T h i s o r o d u c t i s w a t e r . b a s e d ; U s e m e d i u m a p p r o p n a t e t o s u r r o u n d i n g f i r e D r y c h e m i c a l , c a r b o n d i o x i d e , foam, water sPraY or fog.
T h e r m a l d e c o m p o s r t l o n p r o d u c t s i n c l u d e , b u t a r e n o t l t m i t e d t o , v a r i o u s a l i p h a t i c o r g a n o p h o s p h a t e s ' s u b s t i t u t e d p y r , n rd r n c s a n d h y d r o g c n c y a n l d c
-wear self_contarned breathing app"urutri with full proteclive clothing Fight fire from upwind and keep a l l n o n - e s s e n t t a l p e r s o n n e l o u t o [ a r e a
l f w a t e r is u s e d t o f i g h t li r e o r c o o l c o n t a i n e r s , d i k c t o p r e v e n t ru n o f f c o n t a m i n a t i o n o f m u n i c i p a l sewers and waterways
TERIAL
SAFETY
DATA SHEET
DIAZINON
AG6OO
WBC
S T E P S T O B E T A K E N I F M A T E R I A L IS R E L E A S E D O R S P I L L E D :
Wear chemical safety glasses with side shields or chemical goggles, rubber gloves, rubber boots, long-sleeved shirt, long pants, head covering, and a NIOSH-approved pesticide respirator or air-supplied respirator'
Fc.:r small spills, absorb wrth an absorbent material such as pet litter Sweep up and place in an approved chemical container for proper disposal. Check local, state and federal regulations for proper disposal. For large spills. contain liquid by diking the area, keep product out of water supplies lf possible use a pump to pick up liquid, th-en use absorbent material to abso6 any residual liquid. Place both in an approved container. Flush the area with a household bleach and water mixture (1:'l) and then absorb the liquid as descnbed in small spills
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water
Wash hands before eating, drinking. chewirp gum using tobacco or using the toilet Remove clothing immediately if pesticide gets inside. Then wash tn-oroughtyind put on-ctean clothing. Remove PPE after handling this product Wash the outside of lloves before removing. As s6n as possible, wash thoroughly and change into clean clothing. Do not use, pour, spill or store near heat or open flame
lf freezing occurs, place the product in a warm room 168oF/20oC or above) and allow to thaw Roll or shake container frequenily until thawing is complete Do not contaminate water, food or feed by storage or disposal
p e r s o n a l p r o t e c t i v e Equipment: Mixers, loaders, applicators and other handlers using engineering controls mustwear: long sleeved shirt and ng, and chemical resistant apron if mixing or loading. Handlers performing eering controls are not feasible must wear: coveralls over long sleeved 'ear plus socks, chemical resistant apron if exposed to concentrate, and a ; t e r w r t h a n y R , P , o r H E p r e f i l t e r . F o l l o w m a n u f a c t u r e r ' s i n s t r u c t i o n s f o r c l e a n i n g l t a n d h o t w a t e r . K e e p a n d w a s h P P E s e p a r a t e l y f r o m o t h e r la u n d r y . D i s c a r d
c o n t a m i n a t e d w i t h t h i s p r o d u c t ' s c o n c e n t r a t e D o n o t r e u s e th e m H A N D L I N G :
S T O R A G E :
EXPOSURE
C
/ EERSONAL
PROTECTION
E N G T N E E R I N G
C O N T R O L S :
RESPIRATORY
PROTECTION
:
EYE PROTECTION:
SKIN PROTECTION:
C h e m i c a l g o g g l e s o r s h i e l d e d s a f e t y g l a s s e s
W e a r p r o t e c t i v e c l o t h i n g : l o n g - s l e e v e d s h i r t s a n d p a n t s ,
O S H A P E L 8 h r T W A D i a z i n o n n o t l i s t e d
When handlers
use closed
systems,
enclosed
cabs,
or aircraft
in a manner
that meets
with requirements
listed
in the
Worker
Protection
Standard
iWpS) tor agricultural
pesticides
[40 CFR 170 240(d)(4-6)],
the handler
PPE
requirements
may be reduced
or modified
as specifred
in the WPS
Noi normally
required,
if vapors
or mists
exceed
acceptable
levels,
wear
a NIOSH
approved
pesticide
respirator
shoes
with socks Wear
chemical-resistant
gloves
ACGIH
TLV.TWA
o 0'1
mg/m3
(Skin)
9. PHYSICAL
AND CHEMICAL
PROPERTIES
APPEARANCE AND ODOR: Off-white liquid with sltght sulfur-like odor
s p E c t F t c G R A v l w ( w a t e r = 1 ) : 1 . 0 7 g / m l B U L K D E N S I T Y : 8 9 3 l b s / g a l . V A P O R p R E S S U R E : < 0 1 m m H g @ 2 5 " C B O I L I N G P O I N T : N o t e s t a b l i s h e d PERCENT VOLATILE (by volumel: t 30% EVAPORATION RATE: Not established Note: These physical data are typical values based on material tested but may vary from sample to sample
typicai vatues should not be construed as a guaranteed analysis of any specific lot or as specification items
S O L U B I L I T Y : S l i g h t p H : 7 - 8 ( 1 % s o l u t i o n )
STABILITY: Stable
INCOMPATIBILITY: Strong bases, acids, and oxidizers
CONDITIONS TO AVOID: Excessive heat and tgnition sources
HAZARDOUS DECOMpOSITION pRODUCTS: Thermat decomposition - aliphatic organophosphates, substituted pyrimidines, and hydrogen cyanide
HAZARDOUS POLYMERIZATION: Will not occur
Acute Oral LD5s (rat): 1600 mg/kg Eye lrritation (rabbit): Causes irritalion l n h a l a t i o n L C 5 e ( r a t ) : > 2 , 5 m g / L ( 4 h r )
C a r c i n o g e n i c P o t e n t i a l : N o n e li s t e d in O S H A , N T P , I A R C o r A C G I H
Acute Dermal LDm (rabbit): > 2020 mg/kg Skin lrritation (rabbit): Non-irritating
S k i n S e n s i t i z a t i o n ( G u i n e a P i g ) : N o t a s e n s i t i z e r
Summarv of Effects: Drazinon is highly toxic to birds, lish, and other wildlife Avoid exposure to waterfowl Keep out of lakes' streams' ponds, tidal
",*ches, a"d est,.laries. Do not apply direcfly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark
Drift and runoff may be hazardous to aquatii organisms in neighboring areas. Shrimp and crab may be killed at application rates on the product label. Do not apply this pioduct where fish, shrimp, crJb, and other aquatic life are important resources. Do not contaminate water by cleaning of equipment or disposal of lquipment wash waters. Highly toxic to bees exposed to direct treatment or to residues on blooming crops or weeds Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the trealment area
E c o - A c u t e T o x i c i t y
R a i n b o w T r o u t B l u e g i l l S u n f i s h
B o b w h i t e O r a l L D 5 s : 5 2 m g / k g M a l l a r d O r a l L D 5 e : 1 4 4 m g / k g B o b w h i t e 8 - d a y D i e t a r y L C 5 s : 2 3 5 p p m M a l l a r d 8 - d a y D i e t a r y L C 5 e : 3 3 p p m A I
TERIAL
SAFETY
DATA SHEET
DIAZINON
AG6OO
WBC
D a p h n i a M a g n a
4 8 H R L C s o 0 O 0 1 1 m g A l / L
E c o - C h r o n i c T o x i c i t y
D i a z i n o n : F i s h ( F a t h e a d m i n n o w ) E a r l y L i f e S t a g e M A T C > 0 0 9 2 a n d < 0 1 7 m g / L I n v e r t e b r a t e ( D a p h n i a M a g n a ) Life Cycle MATC >0 00017 and <0 00032 mg/L M a l l a r d R e p r o d u c t i o n N O E C 1 0 p p m ( C h E i n h i b i t i o n . 5 ppm)
B o b w h i t e R e p r o d u c t i o n N O E C 4 0 p p m ( C h E in h i b i t i o n < 10 ppm) 96 HR LC5!
1 8 m g A l / L 0 2 1 m g A l / L
1 3 . D I S P O S A L C O N S I D E R A T I O N S
Do not reuse product container Plastic: Triple rinse (or equivalent), then offer for recycling at an ACRC site (go to bltp_llrywweercey_S!,C !,!d for l o c a t i o n s ) o r b y r e c o n d i t i o n i n g , o r p u n c t u r e a n d d i s p o s e o f i n a s a n i t a r y l a n d f i l l , o r , i n c i n e r a t i o n , o r , i f a l l o w e d b y s t a t e a n d l o c a l a u t h o r i t i e s , b y b u r n i n g l f b u r n e d , s t a y o u t o f s m o k e P e s t i c i d e w a s t e s a r e t o x r c l m p r o p e r d i s p o s a l o f e x c e s s p e s t i c i d e , s p r a y m i x t u r e , o r r i n s a t e is a v i o l a t i o n o f F e d e r a l la w D o not contaminate water, food or feed by storage or disposa.
14. TRANSPORT
INFORMATION
D O T S h i p p i n g D e s c r i p t i o n : R Q E N V I R O N M E N T A L L Y H A Z A R D O U S S U B S T A N C E , L | Q U l D , N O S , 9 UN3082. ilt (D|AZINON) I V A R | N E P O L L U T A N T E R G G U I D E 1 7 1
U . S S u r f a c e F r e i g h t C l a s s i f i o a t i o n : I N S E C T I C I D E S , I N S E C T R E P E L L E N T S N O I O T H E R T H A N P O I S O N ( N M F C 1 0 2 1 2 0 , C L A S S : 6 0 ) C o n s u l t a p p r o p r i a t e I C A O / I A T A a n d I M D G r e g u l a t i o n s f o r s h i p m e n t r e q u i r e m e n t s in the Air and Maritime shipping modes.
15. REGULATORY
INFORMATION
N F P A & H M I S H a z a r d R a t i n g s :
' ,
SARA Hazard Notifi cation/Reporting SARA Title lll Hazard Category:
Reportable Quantity (RQ) under U.S. S A R A , T i t l e ll l , S e c t i o n 3 1 3 : D i a z i n o n RCRA Waste Code: Not listed C A P r o p o s i t i o n 6 5 : N o t l i s t e d
N F P A 1 H e a l t h 1 F l a m m a b i l i t y 0 I n s t a b i l i t y
l m m e d i a t e D e l a y e d
0 L e a s t 1 S h g h t 2 Moderate 3 H t g h 4 Severe
HI\4IS 1 H e a l t h 1 F l a m m a b i l i t y 0 Reactivity H P P E
Y Y
Frre
Reactive
N N
S u d d o n R e l e a s e o f P r e s s u r e N
CERCLA:
Diazinon
(CAS:
333a1-5)
(CAS:
333-41-5)
56 0%
'l pound
16. OTHER INFORMATION
MSOS STATUS: Section 16 revised
PREPARED BY: Registrations and Regulatory Affairs
Th6 product is a RESTRICTED USE PESTICIDE due to Avian and Aquatic Toxicity
R E V I E W E D B Y : E n v i r o n m e n t a l i R e q u l a t o r v S e r v i c e s
Disclaimer and Limitation of Liability: This data sheet was developed from information on the constituent materials ic1entified herein and does nor relate to the use of such materials in combination with any other material or process No warranty is expressed or implied with respect to the c o m p l e t e n e s s o r o n g o l n g a c c u r a c y o f t h e i n f o r m a t i o n c o n t a i n e d i n t h i s d a t a s h e e t , a n d L O V E L A N D P R O D U C T S , l n c d i s c l a i m s a l l l i a b i l i t y f o r r e l i a n c e o n such information This data sheet is not a guarantee of safety Users are responsible for ensuring that they have all current information necessary ro safely use the product described by this data sheet for their specific purpose
