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RSCE-SOMCHE 2008 67 Edited by Daud et al.

SYNTHESIS AND CHARACTERIZATION OF

STARCH-CHITOSAN COMPOSITES

Emma S1; Natalia S1.; Tokok A2; Wulandari1, Kenfat1

1

Chemical Engineering Department,University of Surabaya, Indonesia 2 Departement of Chemistry, University of Airlangga, Indonesia

Email : [email protected]

Keywords: biodegradable plastic; mechanical properties; swelling

ABSTRACT

In this experiment, the composites based on chitosan-starch were synthesized at different weight ratios (3/7, 4/6, 5/5, 6/4, 7/3, 8/2, 9/1) by using 4 %v of glycerol as plasticizer. The influence of composition and the degree of deacetylation of chitosan on the properties of starch-chitosan composites film were studied. The films were observed on the aspect of mechanical characteristic, and % swelling, and biodegradability. Tensile strength of the composite films first increased and then decreased with chitosan addition. Otherwise, the addition of chitosan increased the elasticity of film and decreased % swelling. Films made of chitosan with the higher degree of deacetylation were found to have higher tensile strength and elongation in a tensile test.

INTRODUCTION

In recent years, the increasing environmental consciousness has been directing attention to utilizing of biodegradable resins to packaging containers for foods and commodities. After disposal, containers made of biodegradable resins can be decomposed by bacteria and return to soil even buried in landfill or left to stand under environmental condition. In present invention provides natural sources such as starch, chitosan, etc as biopolymer used in biodegradable film packaging application.

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