Risalah Data Keselamatan Safety data sheet

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Safety data sheet

Mukasurat (Page): 1/19 BASF Risalah Data Keselamatan (BASF Safety data sheet)

Tarikh / Disemak (Date / Revised): 06.06.2017 Versi (Version): 2.0 Produk (Product): Irganox® 1035

(30141931/SDS_GEN_MY/MS) Tarikh cetakan (Date of print) 07.06.2017

1. Pengenalan bahan kimia dan pembekal

Irganox® 1035

Nama bahan kimia: Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 1,1'-(thiodi-2,1- ethanediyl) ester

Nombor CAS: 41484-35-9 Kegunaan: penstabil

Syarikat:

BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U8

40150 Shah Alam, Selangor, MALAYSIA Nombor Telefon: +60 3 5628-3888 Nombor Telefax: +60 3 5628-3777 Maklumat kecemasan:

Nombor Kecemasan Antarabangsa Nombor Telefon: +49 180 2273-112

2. Pengenalan Bahaya

Pengelasan bahan dan campuran:

Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini.

Unsur label dan pernyataan berjaga-jaga:

Produk tidak memerlukan label amaran bahaya menurut kriteria GHS . Bahaya lain yang tidak menyebabkan pengelasan:

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Produk di bawah keadaan tertentu boleh mengakibatkan letupan debu.

3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia

Keadaan kimia

Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, thiodi-2,1-ethanediyl ester Nombor CAS: 41484-35-9

4. Langkah-Langkah Pertolongan Cemas

Nasihat am:

Tanggalkan pakaian yang tercemar.

Jika tersedut:

Tenangkan pesakit, alihkan ke tempat berudara bersih, dapatkan rawatan perubatan.

Apabila terkena kulit:

Basuh bersih-bersih dengan sabun dan air.

Apabila terkena mata:

Basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air sambil membuka mata.

Nota kepada doktor:

Gejala: Gejala dan kesan terpenting yang diketahui diterangkan didalam label (lihat bahagian 2) dan/atau bahagian 11.

Gejala dan kesan penting selanjutnya tidak diketahui setakat ini.

Nota kepada doktor:

Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui.

5. Langkah-Langkah Pemadaman Kebakaran

Bahan pemadam yang sesuai:

serbuk kering, busa

Alat memadam yang tidak sesuai untuk tujuan keselamatan:

karbon dioksida Maklumat tambahan:

Elakkan daripada memusarkan bahan/produk kerana bahaya letupan debu.

Bahaya tertentu:

wap yang merbahaya

Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran.

Peralatan perlindungan khusus:

Gunakan alat pernafasan serba lengkap.

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Maklumat lanjut:

Tahap risiko ditentukan oleh bahan yang terbakar dan keadaan kebakaran. Air pemadam api yang tercemar mestilah dilupuskan mengikut peraturan rasmi.

6. Langkah-Langkah Pelepasan Tidak Sengaja

Langkah pencegahan diri:

Elakkan pembentukan debu. Gunakan pakaian pelindung diri.

Langkah berjaga-jaga untuk alam sekitar:

Bendung air yang tercemar/air yang digunakan untuk memadam kebakaran. Jangan lepaskan ke dalam parit/air permukaan/air tanah.

Kaedah pembersihan atau penyerapan:

Bagi sejumlah kecil: Kutip dengan alat yang sesuai dan lupuskan.

Bagi sejumlah besar: Bendung dengan bahan pengikat debu dan lupuskan.

Elakkan pertambahan debu.

7. Pengendalian dan Penyimpanan;

Pengendalian

Pernafasan mestilah dilindungi apabila produk dalam jumlah yang banyak disiring tanpa pengalihudaraan ekzos setempat.

Perlindungan terhadap kebakaran dan letupan:

Elakkan pembentukan debu. Ambil langkah berjaga-jaga terhadap luahan statik.

Kelas letupan debu: Kelas letupan habuk 2 (Nilai-Kst 200 sehingga 300 barm s-1).

Penyimpanan

Maklumat lanjut tentang keadaan penyimpanan: Simpan hanya dalam bekas asal sahaja. Pastikan bekas sentiasa ditutup rapat dan kering. Simpan bekas di tempat yang mempunyai pengalihan udara yang baik.

8. Kawalan pendedahan dan perlindungan diri

Komponen dengan parameter kawalan tempat kerja

Nilai had debu yang biasa hendaklah dipatuhi.

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Peralatan perlindungan peribadi Perlindungan pernafasan:

Perlindungan pernafasan yang sesuai bagi kepekatan yang rendah atau kesan jangka pendek:

Penapis zarah jenis kecekapan sederhana untuk zarah pepejal dan cecair (misalnya EN 143 atau 149, Jenis P2 atau FFP2)

Perlindungan tangan:

Sarung tangan keselamatan kalis bahan kimia.

Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374):

misalnya getah nitril (0.4 mm), getah kloroprena (0.5 mm), polivinilklorida (0.7 mm) dan lain-lain.

Nota tambahan : Spesifikasi adalah berdasarkan ujian –ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian.

Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai.

Perlindungan mata:

Kaca mata keselamatan dengan perlindungan sisi.

Perlindungan badan:

Perlindungan badan mestilah dipilih berdasarkan tahap aktiviti dan pendedahan.

Langkah kebersihan dan keselamatan am:

Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Disyorkan memakai pakaian kerja yang tertutup. Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik.

9. Sifat Fizikal dan Kimia

Bentuk: serbuk, berbutir

Warna: putih hingga warna krim

Bau: tidak berbau

Ambang bau: Tiada maklumat berkaitan diperoleh.

nilai pH: 8.0

(1 %(m), 20 - 25 °C) (sebagai ampaian) pKA: 12

(25 °C)

(dikira)

takat lebur: 68.2 °C (diukur)

Suhu didih:

Tidak boleh digunakan

takat mengurai: > 300 °C (diukur)

Takat kilat: 140 °C (DIN EN 22719; ISO 2719)

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Tahap penyejatan:

Produk ini adalah pepejal tidak meruap

Kemudahbakaran (pepejal/gas): tidak sangat mudah terbakar

(Peraturan 440/2008/EC, A.10) Had letupan bawah:

Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal.

Had letupan atas:

Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal.

Suhu pencucuhan: 380 °C

pencucuhan sendiri: Tidak swacucuh. Jenis ujian: Swanyalaan spontan pada suhu bilik.

Tidak boleh digunakan Jenis ujian: Pencucuhan sendiri pada suhu tinggi.

Kebolehan swapemanasan sendiri: Ia bukanlah bahan yang mampu pemanasan spontan.

Bahaya letupan: tidak mudah meletup

Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: < 0.000001 Pa

(20 °C)

(diukur)

Kepekatan: 1.0 g/cm3

(20 °C)

(piknometer) Ketumpatan pukal: 540 - 680 kg/m3

Keterlarutan dalam air:

< 0.001 g/l (20 °C)

Pekali petakan n-oktanol/air (log Pow): 10 (25 °C)

(dikira) Penjerapan/air-tanah: KOC: 321000000; log KOC: 8.5 (dikira) Tegangan permukaan:

Tidak boleh digunakan Kelikatan, dinamik:

tidak ditentukan

Jisim molar: 642.94 g/mol Maklumat lain:

Jika perlu, maklumat tentang parameter fizikal and kimia ada dinyatakan didalam bahagian ini.

10. Kestabilan dan Kereaktifan

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Keadaan yang perlu dielakkan:

Elakkan pembentukan debu. Elakkan pengumpulan debu. Jauhkan dari semua sumber pencucuhan:

haba, percikan api, nyalaan terbuka. Elakkan cas elektrostatik.

Bahan yang perlu dielakkan:

asid kuat, bes kuat, agen pengoksida yang kuat Kakisan kepada

logam:

Kesan mengakis pada logam tidak dijangka.

Tindak balas berbahaya:

Produk mungkin mengandungi debu halus boleh meletup atau debu tersebut mungkin dihasilkan melalui geseran semasa diangkut atau dipindah.

Bahan penguraian berbahaya:

Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

11. Maklumat Toksikologi

Ketoksikan akut

Penilaian ketoksikan akut:

Tidak toksik selepas sekali ditelan. Tidak toksik selepas sekali terkena kulit Data eksperimen/dikira:

LD50 tikus (melalui mulut): 5,000 mg/kg (Garispanduan OECD 401) (melalui penyedutan):Tiada data diperoleh.

LD50 tikus (dermal): 2,000 mg/kg (Garispanduan OECD 402)

Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Tiada kematian diperhatikan

Kerengsaan

Data eksperimen/dikira:

Kakisan/Kerengsaan kulit arnab: tidak merengsa

Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama.

Kerosakkan/kerengsaan mata yang serius arnab: tidak merengsa (Garispanduan OECD 405) Pemekaan pernafasan/kulit

Penilaian pemekaan:

Kesan pemekaan kulit tidak diperhatikan dalam kajian haiwan.

Data eksperimen/dikira:

Ujian pemaksimum tikus kasturi marmut: Tidak memeka (Garispanduan OECD 406) Kemutagenan sel germa

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Penilaian kemutagenan:

Bahan tidak mutagen dalam bakteria. Bahan tidak mutagen dalam ujian dengan mamalia. Bahan tidak mutagen dalam kultur sel mamalia. Produk belum diuji sepenuhnya. Pernyataan diambil sebahagiannya daripada produk yang mempunyai struktur dan komposisi yang sama.

Kekarsinogenan Penilaian kekarsinogenan:

Berdasarkan bahan kandungannya, tidak disyakki terdapat kesan karsinogen pada manusia.

Ketoksikan pembiakan Penilaian ketoksikan pembiakan:

Kajian ke atas haiwan tidak memberikan petunjuk kepada kesan kelemahan Produk belum diuji.

Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama.

Ketoksikan perkembangan Penilaian keteratogenan:

Kajian haiwan tidak menunjukkan kesan yang menjejaskan kesuburan pada dos yang tidak toksik kepada haiwan induk. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama.

Ketoksikan khusus organ sasaran (sekali pendedahan):

Penilaian sekali STOT:

Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan.

Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang)

Penilaian ketoksikan dos berulang:

Kesan adaptif diperhatikan selepas pendedahan berulang-ulang didalam ujian haiwan.

Bahaya penyedutan

Tiada bahaya penyedutan dijangka.

12. Maklumat Ekologi

Keekotoksikan

Penilaian ketoksikan akuatik:

Ada kemungkinan besar produk tidak memudaratkan organisma akuatik secara akut. Tiada kesan toksik dalam julat keterlarutan. Perencatan aktiviti degradasi di dalam enap cemar yang diaktifkan tidak dijangka akan berlaku semasa bahan berkepekatan rendah dimasukkan kedalam loji rawatan biologi.

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Ketoksikan kepada ikan:

LC50 (96 h) > 57 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, statik)

Keterlarutan produk adalah rendah dalam medium ujian. Larutan akueus disediakan dengan pelarut telah diuji. Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan.

Penyataan kesan toksik berkaitan dengan kepekatan yang ditentukan secara analisis.

Invertebrat air:

EC50 (48 h) > 100 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 1, statik)

Produk mempunyai keterlarutan yang rendah dalam medium ujian. Larutan Ujian kepekatan had sahaja (ujian HAD). Perincian kesan toksik berkaitan dengan kepekatan nominal.

Tumbuhan akuatik:

EC50 (72 h) > 100 mg/l, Desmodesmus subspicatus (Garispanduan OECD 201, statik)

Produk mempunyai keterlarutan yang rendah dalam medium ujian. Larutan Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan. Perincian kesan toksik berkaitan dengan kepekatan nominal.

Tiada kesan kepekatan yang diperhatikan (72 h) 100 mg/l, Desmodesmus subspicatus (Garispanduan OECD 201, statik)

Produk mempunyai keterlarutan yang rendah dalam medium ujian. Larutan Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan. Perincian kesan toksik berkaitan dengan kepekatan nominal.

Mikroorganisma/Kesan ke atas enap cemar diaktifkan:

EC20 (3 h) > 100 mg/l, Enap cemar diaktifkan, domestik (Garispanduan OECD 209, statik) Ujian kepekatan had sahaja (ujian HAD). Perincian kesan toksik berkaitan dengan kepekatan nominal.

Ketoksikan kronik kepada invertebrata akuatik:

Tiada kesan kepekatan yang diperhatikan (21 hari), > 10 mg/l, Daphnia magna (Garispanduan OECD 211, semistatik)

Keterlarutan produk adalah rendah dalam medium ujian. Eluat telah diuji. Perincian kesan toksik berkaitan dengan kepekatan nominal. Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan.

Mobiliti

Penilaian pengangkutan di antara bahagian di persekitaran:

Penjerapan kepada fasa tanah pejal dijangka Keterusan dan boleh keterdegradasikan Maklumat penyingkiran:

7 % Pembentukan CO2 relatif kepada nilai teori (28 hari) (OECD 301B; ISO 9439; 92/69/EEC, C.4- C) (aerobik, enap cemar diaktifkan, domestik, tidak disesuaikan)

Penilaian kestabilan dalam air:

Tiada data diperoleh.

Potensi Biotumpukan Penilaian potensi bioakumilasi:

Akumulasi yang ketara dalam organisma tidak dijangka.

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Potensi Biotumpukan:

Faktor Kebiopekatan: <= 12 (56 hari), Cyprinus carpio (Garispanduan OECD 305 C)

Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Berdasarkan berat bukti, sebatian tidak akan bioakumulasi.

13. Maklumat Pelupusan

Mestilah dibuang atau dibakar mengikut peraturan tempatan.

Pembungkusan tercemar:

Bungkusan yang tidak tercemar boleh diguna semula.

Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya.

14. Maklumat Pengangkutan

Pengangkutan domestik:

Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan

Pengangkutan laut IMDG

Pengangkutan udara IATA/ICAO

Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC

Peraturan: Tidak dinilai

Penghantaran yang diluluskan:

Tidak dinilai Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai

15. Maklumat Pengawalseliaan

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16. Maklumat lain

Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya.

Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

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1. Identification of the chemical and of the supplier

Irganox® 1035

Chemical name: Thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]

CAS Number: 41484-35-9 Use: stabilizer

Company:

BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U8

40150 Shah Alam, Selangor, MALAYSIA Telephone: +60 3 5628-3888

Telefax number: +60 3 5628-3777 Emergency information:

International emergency number:

Telephone: +49 180 2273-112

2. Hazard identification

Classification of the substance and mixture:

No need for classification according to GHS criteria for this product.

Label elements and precautionary statement:

The product does not require a hazard warning label in accordance with GHS criteria.

Other hazards which do not result in classification:

The product is under certain conditions capable of dust explosion.

3. Composition/information on ingredients

Chemical nature

Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, thiodi-2,1-ethanediyl ester CAS Number: 41484-35-9

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4. First-Aid Measures

General advice:

Remove contaminated clothing.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

Note to physician:

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.

Further important symptoms and effects are so far not known.

Note to physician:

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire-Fighting Measures

Suitable extinguishing media:

dry powder, foam

Unsuitable extinguishing media for safety reasons:

carbon dioxide

Additional information:

Avoid whirling up the material/product because of the danger of dust explosion.

Specific hazards:

harmful vapours

Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:

The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions:

Avoid dust formation. Use personal protective clothing.

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Environmental precautions:

Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up or taking up:

For small amounts: Pick up with suitable appliance and dispose of.

For large amounts: Contain with dust binding material and dispose of.

Avoid raising dust.

7. Handling and Storage

Handling

Breathing must be protected when large quantities are decanted without local exhaust ventilation.

Protection against fire and explosion:

Avoid dust formation. Take precautionary measures against static discharges.

Dust explosion class: Dust explosion class 2 (Kst-value 200 up to 300 bar m s-1).

Storage

Further information on storage conditions: Keep only in the original container. Keep container tightly closed and dry. Keep container in a well-ventilated place.

8. Exposure controls and personal protection

Components with occupational exposure limits

The nuisance dust limit value is to be kept.

Personal protective equipment Respiratory protection:

Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection:

Chemical resistant protective gloves

Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.

temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Manufacturer's directions for use should be observed because of great diversity of types.

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Eye protection:

Safety glasses with side-shields.

Body protection:

Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Form: powder, granules

Colour: white to cream

Odour: odourless

Odour threshold: No applicable information available.

pH value: 8.0

(1 %(m), 20 - 25 °C) (as suspension) pKA: 12

(25 °C)

(calculated)

Melting point: 68.2 °C (measured)

boiling temperature:

not applicable

decomposition point: > 300 °C (measured)

Flash point: 140 °C (DIN EN 22719; ISO 2719)

Evaporation rate:

The product is a non-volatile solid.

Flammability (solid/gas): not highly flammable (Regulation 440/2008/EC, A.10)

Lower explosion limit:

For solids not relevant for classification and labelling.

Upper explosion limit:

For solids not relevant for classification and labelling.

Ignition temperature: 380 °C

Self ignition: not self-igniting Test type: Spontaneous self- ignition at room-temperature.

not applicable Test type: Self-ignition at high

temperatures.

Self heating ability: It is not a substance capable of spontaneous heating.

Explosion hazard: not explosive

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Fire promoting properties: not fire-propagating Vapour pressure: < 0.000001 Pa

(20 °C)

(measured)

Density: 1.0 g/cm3

(20 °C)

(pyknometer) Bulk density: 540 - 680 kg/m3

Solubility in water:

< 0.001 g/l (20 °C)

Partitioning coefficient n-octanol/water (log Pow): 10 (25 °C)

(calculated) Adsorption/water - soil: KOC: 321000000; log KOC: 8.5 (calculated) Surface tension:

not applicable Viscosity, dynamic:

not determined

Molar mass: 642.94 g/mol Other Information:

If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid:

Avoid dust formation. Avoid deposition of dust. Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static charge.

Substances to avoid:

strong acids, strong bases, strong oxidizing agents

Corrosion to metals: Corrosive effects to metal are not anticipated.

Hazardous reactions:

The product may contain explosive fine dust or such dust may be produced by abrasion during transport or product transfer.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

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Experimental/calculated data:

LD50 rat (oral): 5,000 mg/kg (OECD Guideline 401) (by inhalation):No data available.

LD50 rat (dermal): 2,000 mg/kg (OECD Guideline 402)

The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. No mortality was observed.

Irritation

Skin corrosion/irritation rabbit: non-irritant (similar to OECD guideline 404)

The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization

Assessment of sensitization:

Skin sensitizing effects were not observed in animal studies.

Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406) Germ cell mutagenicity

Assessment of mutagenicity:

The substance was not mutagenic in bacteria. The substance was not mutagenic in a test with mammals. The substance was not mutagenic in mammalian cell culture. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition.

Carcinogenicity

Assessment of carcinogenicity:

Based on the ingredients there is no suspicion of a carcinogenic effect in humans.

Reproductive toxicity

Assessment of reproduction toxicity:

Animal studies gave no indication of a fertility impairing effect at doses which were not toxic to the parental animals. The product has not been tested. The statement has been derived from

substances/products of a similar structure or composition.

Developmental toxicity Assessment of teratogenicity:

Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. The product has not been tested. The statement has been derived from

substances/products of a similar structure or composition.

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Specific target organ toxicity (single exposure):

Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:

Adaptive effects were observed after repeated exposure in animal studies.

Aspiration hazard

No aspiration hazard expected.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:

There is a high probability that the product is not acutely harmful to aquatic organisms. No toxic effects occur within the range of solubility. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.

Toxicity to fish:

LC50 (96 h) > 57 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, static)

The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Limit concentration test only (LIMIT test). No toxic effects occur within the range of solubility. The statement of the toxic effect relates to the analytically determined concentration.

Aquatic invertebrates:

EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

The product has low solubility in the test medium. A saturated solution has been tested. Limit

concentration test only (LIMIT test). The details of the toxic effect relate to the nominal concentration.

Aquatic plants:

EC50 (72 h) > 100 mg/l, Desmodesmus subspicatus (OECD Guideline 201, static)

concentration test only (LIMIT test). No toxic effects occur within the range of solubility. The details of the toxic effect relate to the nominal concentration.

No observed effect concentration (72 h) 100 mg/l, Desmodesmus subspicatus (OECD Guideline 201, static)

concentration test only (LIMIT test). No toxic effects occur within the range of solubility. The details of the toxic effect relate to the nominal concentration.

Microorganisms/Effect on activated sludge:

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EC20 (3 h) > 100 mg/l, activated sludge, domestic (OECD Guideline 209, static)

Limit concentration test only (LIMIT test). The details of the toxic effect relate to the nominal concentration.

Chronic toxicity to aquatic invertebrates:

No observed effect concentration (21 d), > 10 mg/l, Daphnia magna (OECD Guideline 211, semistatic)

The product has low solubility in the test medium. An eluate has been tested. The details of the toxic effect relate to the nominal concentration. Limit concentration test only (LIMIT test). No toxic effects occur within the range of solubility.

Mobility

Assessment transport between environmental compartments:

Adsorption to solid soil phase is expected.

Persistence and degradability Elimination information:

7 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4- C) (aerobic, activated sludge, domestic, non-adapted)

Assessment of stability in water:

No data available.

Bioaccumulation potential

Assessment bioaccumulation potential:

Significant accumulation in organisms is not to be expected.

Bioaccumulation potential:

Bioconcentration factor: <= 12 (56 d), Cyprinus carpio (OECD Guideline 305 C)

The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Based on a weight of evidence, the compound will not

bioaccumulate.

13. Disposal Considerations

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:

Uncontaminated packaging can be re-used.

Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14. Transport Information

Domestic transport:

Not classified as a dangerous good under transport regulations

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Sea transport IMDG

Air transport IATA/ICAO

Transport in bulk according to Annex II of MARPOL and the IBC Code

Regulation: Not evaluated

Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated

Ship Type: Not evaluated

15. Regulatory Information

16. Other Information

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the

corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.