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Alkaline Earth Metals. Boron Family. Sifat Logam

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Tabel

Tabel

Periodik

Periodik

Unsur

Unsur

Merupakan referensi kimia

Susunan unsur-unsur dengan informasi dasar

TABEL PERIODIK

• Dmitri Mendeleev, 1869: pengaturan unsur-unsur

yang diketahui dalam bentuk tabel periodik,

sebelum ada detail struktur atom.

– Berdasar: sifak fisik dan kimia unsur – Sifat kimia unsur meningkat secara periodik – Digolongkan berdasar massa atom

– Prediksi unknown elements: ada posisi kosong bila unsurnya tidak sesuai dgn yg diatas dan dibawah

– Saat unknown elements ditemukan, sifat-sifatnya mendekati yg diprediksi.

Tabel periodik

:

penyusunan unsur-unsur yang mana unsur-unsur

tersebut dipisahkan menjadi grup-grup berdasarkan

set pengulangan sifat-sifatnya.

-disusun berdasar kenaikan nomor atom

-terdiri dari deretan (periode) dan kolom (grup)

unsur-unsur

mempermudah dalam membandingkan sifat

unsur yg satu dengan yang lainnya.

• Hukum berkala: sifat-sifat kimia dan fisika unsur-unsur merupakan fungsi berkala dari nomor atomnya.

• Periodisitas kimia tidak berhubungan dengan massa atom, namun berhubungan dgn jumlah protonnya.

• Perilaku kimiawi unsur ditentukan oleh konfigurasi elektronnya • Tingkatan energi terkuantisasi sesuai lapisan elektron disekitar inti. • Tiap deretan (periode)diawali dgn kulit elektron terluar yang baru. – ditandai dengan kulit (n) sama⇒1 deretan dlm sistem periodik • Kolom dalam sistem periodik: grup, mengandung unsur-unsur yg

memiliki sifat kimia dan fisik yg serupa.

– diidentifikasi dari jumlah elektronnya pada kulit terluar, kecuali He

Periodisitas

• Menampilkan informasi:

• Nomor atom

• Simbol

• Massa atom

• Jumlah elektron valensi

• Wujud zat pd suhu kamar

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Sifat Logam

Logam

: unsur-unsur yg umumnya padatan pada

suhu kamar. Paling banyak diantaranya adalah

logam.

Non-logam

: unsur-unsur pada pojok kanan atas

tabel periodik.

Metalloid

: unsur-unsur yang berada pada batas

diagonal antara logam dan non-logam. Sifat

kimia-fisiknya merupakan intermediet logam dan

non-logam.

Detail sifat2.

Alkali Metals

• The alkali family is found in the first column of the periodic table. • Atoms of the alkali metals have a single electron in their outermost level, in other words, 1 valence electron.

• They are shiny, have the consistency of clay, and are easily cut with a knife.

• They are the most reactive metals.

• They react violently with water.

• They are always bonded with another element.

Alkaline Earth Metals

• They are never found uncombined in nature.

• They have two valence electrons.

• Alkaline earth metals include magnesium

and calcium, among others.

Transition Metals

• Transition Elements include those elements in the B families. • These are the metals you are probably most familiar: copper, tin,

zinc, iron, nickel, gold, and silver.

• They are good conductors of heat and electricity. • The compounds of transition metals are usually brightly colored and are often used to color paints. • Transition elements have 1 or 2 valence electrons,

which they lose when they form bonds with other atoms. Some transition elements can lose electrons in their next-to-outermost level.

• Transition elements have properties similar to one another and to other metals, but their properties do not fit in with those of any other family.

• Many transition metals combine chemically with oxygen to

Boron Family

• The Boron Family is named

after the first element in the

family.

• Atoms in this family have 3

valence electrons.

• This family includes a

metalloid (boron), and the

rest are metals.

• This family includes the

most abundant metal in the

earth’s crust (aluminum).

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Carbon Family

• Atoms of this family have 4

valence electrons.

• This family includes a

non-metal (carbon), non-metalloids, and

metals.

• The element carbon is called

the “basis of life.” There is an

entire branch of chemistry

devoted to carbon compounds

called organic chemistry.

Nitrogen Family

• The nitrogen family is named after the element that makes up 78% of our atmosphere. • This family includes

non-metals, metalloids, and metals. • Atoms in the nitrogen family

have 5 valence electrons. They tend to share electrons when they bond.

• Other elements in this family are phosphorus, arsenic, antimony, and bismuth.

Oxygen Family

• Atoms of this family have 6

valence electrons.

• Most elements in this family

share electrons when

forming compounds.

• Oxygen is the most

abundant element in the

earth’s crust. It is extremely

active and combines with

almost all elements.

Halogen Family

• The elements in this

family are fluorine,

chlorine, bromine,

iodine, and astatine.

• Halogens have 7 valence

electrons, which explains

why they are the most

active non-metals. They

are never found free in

nature.

Halogen atoms only need to gain 1 electron to fill their outermost energy level. They react with alkali metals to form salts.

Noble Gases

• Noble Gases are colorless gases that are extremely un-reactive. • One important property of the noble gases is their inactivity.

They are inactive because their outermost energy level is full. • Because they do not readily combine with other elements to

form compounds, the noble gases are called inert. • All have complete octets: stability.

• The family of noble gases includes helium, neon, argon, krypton, xenon, and radon.

• All the noble gases are found in small amounts in the earth's atmosphere.

Rare Earth Elements

• The thirty rare earth

elements are composed

of the lanthanide and

actinide series.

• One element of the

lanthanide series and

most of the elements in

the actinide series are

called trans-uranium,

which means synthetic

or man-made.

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Atomic Radii Properties

Ionic Radii

The ionic radius of each ion is the portion of the distance between the nuclei occupied by that ion

Cationsare smaller than the atoms from which they are formed - the nucleus attractsthe remaining electrons more strongly

Anionsare larger than the atoms

from which they are formed - the greater number of electrons repelmore strongly

Ionization Energy

Ionization energyis the energy required to remove an electron

from a ground stateatom in the gaseous state

Electron Affinity

Electron affinityis the energy change that occurs when an electron is addedto a gaseous atom

Electron affinities are expressed as negative because the process is exothermic

A Summary of Periodic Trends

• Jumlah elektron valensi

– Meningkat dalam 1 periode (kiri ke kanan) – Sama jika dalam satu gol.

• Ukuran atom

– Menurun dalam 1 periode – Meningkat dalam 1 gol. (atas ke bawah)

• Energi ionisasi

– Meningkat dalam 1 periode – Menurun dalam 1 gol.

• Afinitas elektron

– Meningkat dalam 1 periode – Menurun dalam 1 gol.

• Elektronegativitas

– Meningkat dalam 1 periode – Menurun dalam 1 gol.

• Ukuran ion

– Menurun dalam 1 periode – Meningkat dalam 1 gol.

• Sifat logam

– Menurun dalam 1 periode

R

I

N

G

K

A

S

A

N

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ATOMIC STRUCTURE

ATOMIC STRUCTURE

the number of protons in an atom

the number of protons and neutrons in an atom

He

He

2

2

4

4

Atomic mass Atomic number

number of electrons = number of protons

ATOMIC STRUCTURE

ATOMIC STRUCTURE

Electrons are arranged in Energy Levels or Shells

around the nucleus of an atom.

first shell

a maximum of

2

electrons

second shell

a maximum of

8

electrons

third shell

a maximum of

8

electrons

ATOMIC STRUCTURE

ATOMIC STRUCTURE

There are two ways to represent the atomic structure of

an element or compound;

1.

Electronic Configuration

2.

Dot & Cross Diagrams

ELECTRONIC CONFIGURATION

ELECTRONIC CONFIGURATION

With electronic configuration elements are represented

numerically

by the number of electrons in their shells

and number of shells. For example;

N

Nitrogen

7 14

2 in 1

st

shell

5 in 2

nd

shell

configuration = 2 , 5

2

+

5 = 7

ELECTRONIC CONFIGURATION

ELECTRONIC CONFIGURATION

Write the electronic configuration for the following

elements;

Ca

O

Cl

Si

Na

20 40 11 23 8 17 16 35 14 28

B

11 5 a) b) c) d) e) f)

Gambar

Tabel Periodik Periodik Unsur Unsur

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