Glycerol ScienceLabs

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H e a l t h H e a l t h F i r e F i r e

R e a c t i v i t y R e a c t i v i t y P e r s o n a l P e r s o n a l P r o t e c t i o n P r o t e c t i o n

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Material Safety Data Sheet Material Safety Data Sheet

Glycerin MSDS Glycerin MSDS

Section 1: Chemical Product and Company Identification Section 1: Chemical Product and Company Identification

Product Name:

Product Name: Glycerin Glycerin Catalog Codes:

Catalog Codes: SLG1171, SLG1894, SLG1111, SLG1615 SLG1171, SLG1894, SLG1111, SLG1615 CAS#:

CAS#: 56-81-5 56-81-5 RTECS:

RTECS: MA8050000 MA8050000 TSCA:

TSCA: TSCA 8(b) inventory: Glycerin TSCA 8(b) inventory: Glycerin CI#:

CI#: Not available. Not available.

Synonym:

Synonym: 1,2,3-Propanetriol; 1,2,3-Propanetriol; GlycerolGlycerol Chemical Name:

Chemical Name: Glycerin Glycerin Chemical Formula:

Chemical Formula: C3H5(OH)3 C3H5(OH)3

Contact Information:

Sciencelab.com, Inc.

14025 Smith Rd.

Houston, Texas 77396 Houston, Texas 77396 US Sales:

US Sales:1-800-901-72471-800-901-7247 International Sales:

International Sales:1-281-441-44001-281-441-4400 Order Online:

Order Online: ScienceLab.comScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300 1-800-424-9300

International CHEMTREC, call:

International CHEMTREC, call: 1-703-527-3887 1-703-527-3887 For non-emergency assistance, call:

For non-emergency assistance, call: 1-281-441-4400 1-281-441-4400

Section 2: Composition and Information on Ingredients Section 2: Composition and Information on Ingredients

Composition:

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Gllyycceerriinn 5566--8811--55 110000

Toxicological Data on Ingredients:

Toxicological Data on Ingredients: Glycerin: ORAL (LD50): Acute: 12600 Glycerin: ORAL (LD50): Acute: 12600 mg/kg [Rat]. 4090 mg/kg [Mouse]. DERMALmg/kg [Rat]. 4090 mg/kg [Mouse]. DERMAL (LD50): Acute: 10000 mg/kg [Rabbit]. MIST(LC50): Acute: >570 mg/m 1 hours [Rat].

(LD50): Acute: 10000 mg/kg [Rabbit]. MIST(LC50): Acute: >570 mg/m 1 hours [Rat].

Section 3: Hazards Identification Section 3: Hazards Identification

Potential Acute Health Effects:

Potential Acute Health Effects: Slightly hazardous in Slightly hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), ofcase of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation.

ingestion, of inhalation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys. Repeated or prolonged exposure to the DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys. Repeated or prolonged exposure to the substance can produce target organs damage.

substance can produce target organs damage.

Section 4: First Aid Measures Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses.

Check for and remove any contact lenses. In case of contact, immediately flush eyes wiIn case of contact, immediately flush eyes with plenty of water for at least th plenty of water for at least 1515 minutes. Cold water may be used.

minutes. Cold water may be used. Get medical attention if irritation occurs.Get medical attention if irritation occurs.

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Skin Contact:

Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used.

may be used.

Serious Skin Contact:

Serious Skin Contact: Not available. Not available.

Inhalation:

If inhaled, remove to fresh air. If not

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicaldifficult, give oxygen. Get medical attention immediately.

attention immediately.

Serious Inhalation:

Serious Inhalation: Not available. Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as

person. Loosen tight clothing such as a collar, tie, belt or a collar, tie, belt or waistband. Get medical attention if symptoms appear.waistband. Get medical attention if symptoms appear.

Serious Ingestion:

Serious Ingestion: Not available. Not available.

Section 5: Fire and Explosion Data Section 5: Fire and Explosion Data

Flammability of the Product:

Flammability of the Product: May be combustible at hi May be combustible at high temperature.gh temperature.

Auto-Ignition Temperature:

370°

370°C (698°C (698°F)(NFPA Fire Protection F)(NFPA Fire Protection Guide to Hazardous Guide to Hazardous Materials, 13th ed., 2002; Materials, 13th ed., 2002; NIOSH ICSC, 2001; NIOSH ICSC, 2001; CHRIS, 2001) 392 CHRIS, 2001) 392 CC (739 F) (Lewis, 1997)

(739 F) (Lewis, 1997) Flash Points:

Flash Points:

CLOSE

CLOSED CUP: 160°D CUP: 160°C (320°C (320°F). (ChemicF). (Chemical Hazard Resal Hazard Response Inforponse Information Systmation System, 2001; Lewisem, 2001; Lewis, 1997). OPEN CUP, 1997). OPEN CUP: 177°: 177°CC (350.6°

(350.6°F) (Budavari, 2000; F) (Budavari, 2000; Chemical Response Information System, 2001; Chemical Response Information System, 2001; NIOSH ICSC, 2001) NIOSH ICSC, 2001) OPEN CUP: OPEN CUP: 199 C(390 F)199 C(390 F) (National Fire Protection Association, Fire Protection G

(National Fire Protection Association, Fire Protection Guide to Hazardous Materials, 13 ed., 2002)uide to Hazardous Materials, 13 ed., 2002) Flammable Limits:

Flammable Limits: LOWER: 0.9% LOWER: 0.9%

Products of Combustion:

Products of Combustion: These products are carbon oxides These products are carbon oxides (CO, CO2), irritating and toxic fumes.(CO, CO2), irritating and toxic fumes.

Fire Hazards in Presence of Various Substances:

Slightly flammable to flammable in

Slightly flammable to flammable in presence of open flames and sparks, of heat, presence of open flames and sparks, of heat, of oxidizing materials. Non-flammable inof oxidizing materials. Non-flammable in presence of shocks.

presence of shocks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Explosive in presence of oxidizing materials.

presence of static discharge: Not available. Explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards:

Special Remarks on Fire Hazards: Not available. Not available.

Special Remarks on Explosion Hazards:

Glycerin is incompatible with

Glycerin is incompatible with strong oxidizers such as chromium trioxide, potassium chlorate, or strong oxidizers such as chromium trioxide, potassium chlorate, or potassium permanganate andpotassium permanganate and may explode on contact with these

may explode on contact with these compounds. Explosive glyceryl nitrate is formed from a compounds. Explosive glyceryl nitrate is formed from a mixture of glycerin and nitric andmixture of glycerin and nitric and sulfuric acids. Perchloric acid , lead oxide + glycerin form perchloric esters which may be explosive. Glycerin and chlorine may sulfuric acids. Perchloric acid , lead oxide + glycerin form perchloric esters which may be explosive. Glycerin and chlorine may explode if heated and confined.

explode if heated and confined.

Section 6: Accidental Release Measures Section 6: Accidental Release Measures

Small Spill:

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.

requirements.

Large Spill:

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Stop leak if without risk. If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal Stop leak if without risk. If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is in its liquid form: Do not get water inside container. Absorb with an inert material and put the spilled container. If the product is in its liquid form: Do not get water inside container. Absorb with an inert material and put the spilled material in an appropriate waste disposal.

material in an appropriate waste disposal. Do not touch spilled Do not touch spilled material. Use water spray to reduce vapors. Prevent entry imaterial. Use water spray to reduce vapors. Prevent entry intonto sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on

cleaning by spreading water on the contaminated surface and allow to the contaminated surface and allow to evacuate through the sanitary system. Be careful thatevacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice

breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show theimmediately and show the container or the label. Keep away from incompatibles such as oxidizing agents.

container or the label. Keep away from incompatibles such as oxidizing agents.

Storage:

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic

Section 8: Exposure Controls/Personal Protection Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors controls to keep the airborne concentrations of vapors below their respectivebelow their respective threshold limit value. Ensure that eyewash

threshold limit value. Ensure that eyewash stations and safety showers are proximal to the stations and safety showers are proximal to the work-station location.work-station location.

Personal Protection:

Safety glasses. Lab coat. Vapor respirator. Be sure

Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

product.

Exposure Limits:

TWA: 10 (mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation

TWA: 10 (mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation Total. TWA: 15 (mg/m3) from OSHA (PEL) [UnitedTotal. TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total. TWA: 10 STEL: 20

States] Inhalation Total. TWA: 10 STEL: 20 (mg/m3) [Canada] TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation(mg/m3) [Canada] TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.Consult local authorities for acceptable exposure l

Respirable.Consult local authorities for acceptable exposure limits.imits.

Section 9: Physical and Chemical Properties Section 9: Physical and Chemical Properties

Physical state and appearance:

Physical state and appearance: Liquid. (Viscous (Syrupy) liquid.) Liquid. (Viscous (Syrupy) liquid.) Odor:

Odor: Mild Mild Taste:

Taste: Sweet. Sweet.

Molecular Weight:

Molecular Weight: 92.09 g/mole 92.09 g/mole Color:

Color: Clear Colorless. Clear Colorless.

pH (1% soln/water):

pH (1% soln/water): Not available. Not available.

Boiling Point:

Boiling Point: 290°C (554°F) 290°C (554°F) Melting Point:

Melting Point: 19°C (66.2°F) 19°C (66.2°F) Critical Temperature:

Critical Temperature: Not available. Not available.

Specific Gravity:

Specific Gravity: 1.2636 (Water = 1) 1.2636 (Water = 1) Vapor Pressure:

Vapor Pressure: 0 kPa (@ 20°C) 0 kPa (@ 20°C) Vapor Density:

Vapor Density: 3.17 (Air = 1) 3.17 (Air = 1)

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Volatility:

Volatility: Not available. Not available.

Odor Threshold:

Odor Threshold: Not available. Not available.

Water/Oil Dist. Coeff.:

Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -1.8 The product is more soluble in water; log(oil/water) = -1.8 Ionicity (in Water):

Ionicity (in Water): Not available. Not available.

Dispersion Properties:

Dispersion Properties: See solubility in water, acetone. See solubility in water, acetone.

Solubility:

Miscible in cold water, hot water and alcohol. Partially soluble in acetone. Very slightly soluble in diethyl ether (ethyl ether).

Limited solubility in ethyl

Limited solubility in ethyl acetate. Insoluble in carbon tetrachloride, benzene, chloroform, petroleum ethers, and oilsacetate. Insoluble in carbon tetrachloride, benzene, chloroform, petroleum ethers, and oils

Section 10: Stability and Reactivity Data Section 10: Stability and Reactivity Data

Stability:

Stability: The product is stable. The product is stable.

Instability Temperature:

Instability Temperature: Not available. Not available.

Conditions of Instability:

Conditions of Instability: Avoid contact with incompatible Avoid contact with incompatible materials, excess heat and ignition, sources, moisture.materials, excess heat and ignition, sources, moisture.

Incompatibility with various substances:

Incompatibility with various substances: Highly reactive with oxidizing agents. Highly reactive with oxidizing agents.

Corrosivity:

Corrosivity: Non-corrosive in presence of glass. Non-corrosive in presence of glass.

Special Remarks on Reactivity:

Hygroscopic. Glycerin is incompatible wi

Hygroscopic. Glycerin is incompatible with strong oxidizers such as chromium trioxide, potassium chlorate, or th strong oxidizers such as chromium trioxide, potassium chlorate, or potassiumpotassium permanganate. Glycerin may react violently with acetic anhydride, aniline and nitrobenzene, chromic oxide, lead oxide and permanganate. Glycerin may react violently with acetic anhydride, aniline and nitrobenzene, chromic oxide, lead oxide and fluorine, phosphorous triiodide, ethylene oxide and

fluorine, phosphorous triiodide, ethylene oxide and heat, silver perchlorate, sodium peroxide, sodium hydride.heat, silver perchlorate, sodium peroxide, sodium hydride.

Special Remarks on Corrosivity:

Special Remarks on Corrosivity: Not available. Not available.

Polymerization:

Polymerization: Will not occur. Will not occur.

Section 11: Toxicological Information Section 11: Toxicological Information

Routes of Entry:

Routes of Entry: Absorbed through skin. Eye contact. Absorbed through skin. Eye contact.

Toxicity to Animals:

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 4090 mg/kg [Mouse]. Acute dermal toxicity (LD50): 10000 mg/kg

toxicity (LD50): 4090 mg/kg [Mouse]. Acute dermal toxicity (LD50): 10000 mg/kg [Rabbit]. Acute toxicity of the mist (LC50):[Rabbit]. Acute toxicity of the mist (LC50):

>570 mg/m3 1 hours [Rat].

Chronic Effects on Humans:

Chronic Effects on Humans: May cause damage to the following organs: kidneys. May cause damage to the following organs: kidneys.

Other Toxic Effects on Humans:

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals:

TDL (rat) - Route: Oral; Dose: 100

TDL (rat) - Route: Oral; Dose: 100 mg/kg 1 day prior to mating. TDL mg/kg 1 day prior to mating. TDL (human) - Route: Oral; Dose: 1428 mg/kg(human) - Route: Oral; Dose: 1428 mg/kg Special Remarks on Chronic Effects on Humans:

Special Remarks on Chronic Effects on Humans:

Glycerin is transferred across the plancenta in

Glycerin is transferred across the plancenta in small amounts. May cause adverse reproductive effects based on animalsmall amounts. May cause adverse reproductive effects based on animal data (Paternal Effects (Rat): Spermatogenesis (including genetic material, sperm morphology, motility, and

data (Paternal Effects (Rat): Spermatogenesis (including genetic material, sperm morphology, motility, and count), Testes,count), Testes, epididymis, sperm duct). May affect genetic material.

epididymis, sperm duct). May affect genetic material.

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects: Low hazard for

Acute Potential Health Effects: Low hazard for normal industrial handling or normal normal industrial handling or normal workplace conditions. Skin: May causeworkplace conditions. Skin: May cause skin irritation. May be absorbed through skin

skin irritation. May be absorbed through skin Eyes: May cause eye irritation with Eyes: May cause eye irritation with stinging, redness, burning sensation,stinging, redness, burning sensation, and tearing, but no eye i

and tearing, but no eye injury. Ingestion: Low hazard. Low toxicity except winjury. Ingestion: Low hazard. Low toxicity except with very large doses. When large th very large doses. When large doses aredoses are ingested, it can cause gastrointestinal tract irritation with

ingested, it can cause gastrointestinal tract irritation with thirst (dehydration), nausea or vomiting diarrhea. It may alsothirst (dehydration), nausea or vomiting diarrhea. It may also affect behavior/central nervous system/nervous system (central nervous system depression, general anesthetic, headache, affect behavior/central nervous system/nervous system (central nervous system depression, general anesthetic, headache, dizziness, confusion, insomnia, toxic psychosis, muscle weakness, paralysisconvulsions), urinary

dizziness, confusion, insomnia, toxic psychosis, muscle weakness, paralysisconvulsions), urinary system/kidneys(renal failure,system/kidneys(renal failure,

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hemoglobinuria), cardiovascular system (cardiac arrhythmias), liver. It may also cause elevated

hemoglobinuria), cardiovascular system (cardiac arrhythmias), liver. It may also cause elevated blood sugar. Inhalation:blood sugar. Inhalation:

Due to low vapor

Due to low vapor pressure, inhalation of the vapors at room temperature is unlpressure, inhalation of the vapors at room temperature is unlikely. Inhalation of mist may cause respiratoryikely. Inhalation of mist may cause respiratory tract irritation. Chronic Potential Health Effects: Ingestion: Prolonged or

tract irritation. Chronic Potential Health Effects: Ingestion: Prolonged or repeated ingestion may affect the blood(hemolysis,repeated ingestion may affect the blood(hemolysis, changes in white blood

changes in white blood cell count), endocrine system (changes in adrenal cell count), endocrine system (changes in adrenal weight), respiratory system, and may cause kidneyweight), respiratory system, and may cause kidney injury.

injury.

Section 12: Ecological Information Section 12: Ecological Information

Ecotoxicity:

Ecotoxicity: Ecotoxicity in water (LC50): 58.5 ppm Ecotoxicity in water (LC50): 58.5 ppm 96 hours [Trout].96 hours [Trout].

BOD5 and COD:

BOD5 and COD: Not available. Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not l

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.ikely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation:

Toxicity of the Products of Biodegradation: The products of degradation are The products of degradation are less toxic than the product itself.less toxic than the product itself.

Special Remarks on the Products of Biodegradation:

Special Remarks on the Products of Biodegradation: Not available. Not available.

Section 13: Disposal Considerations Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in

Waste must be disposed of in accordance with federal, state and local accordance with federal, state and local environmental control regulations.environmental control regulations.

Section 14: Transport Information Section 14: Transport Information

DOT Classification:

DOT Classification: Not a DOT controlled material (United States). Not a DOT controlled material (United States).

Identification:

Identification: Not applicable. Not applicable.

Special Provisions for Transport:

Special Provisions for Transport: Not applicable. Not applicable.

Section 15: Other Regulatory Information Section 15: Other Regulatory Information

Federal and State Regulations:

Illinois toxic substances disclosure to employee act: Glycerin Rhode Island RTK hazardous substances: Glycerin Pennsylvania Illinois toxic substances disclosure to employee act: Glycerin Rhode Island RTK hazardous substances: Glycerin Pennsylvania RTK: Glycerin Minnesota: Glycerin Massachusetts RTK: Glycerin Tennessee - Hazardous Right to Know: Glycerin TSCA 8(b) RTK: Glycerin Minnesota: Glycerin Massachusetts RTK: Glycerin Tennessee - Hazardous Right to Know: Glycerin TSCA 8(b) inventory: Glycerin

inventory: Glycerin Other Regulations:

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):

WHMIS (Canada): Not controlled under WHMIS (Canada). Not controlled under WHMIS (Canada).

DSCL (EEC):

Not available S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard:

Health Hazard: 1 1 Fire Hazard:

Fire Hazard: 1 1 Reactivity:

Reactivity: 0 0

Personal Protection:

Personal Protection: g g

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National Fire Protection Association (U.S.A.):

Health:

Health: 1 1 Flammability:

Flammability: 1 1 Reactivity:

Reactivity: 0 0 Specific hazard:

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Vapor respirator. Be sure

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorto use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Safety glasses.

when ventilation is inadequate. Safety glasses.

Section 16: Other Information Section 16: Other Information

References:

References: Not available. Not available.

Other Special Considerations:

Other Special Considerations: Not available. Not available.

Created:

Created: 10/10/2005 08:38 PM 10/10/2005 08:38 PM Last Updated:

Last Updated: 11/06/2008 12:00 PM 11/06/2008 12:00 PM

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has been advised of the possibility of such damages.