LABORATORIUM TEKNIK PENGUJIAN KUALITAS LINGKUNGAN

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KEMENTERIAN PENDIDIKAN DAN KEBUDAYAAN UNIVERSITAS SYIAH KUALA

FAKULTAS TEKNIK JURUSAN TEKNIK KIMIA

LABORATORIUM TEKNIK PENGUJIAN KUALITAS LINGKUNGAN

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Chromatogram Ekstrak Asam Gelugur D:\Data\2023.09.26 Ekstrak Asam Gelugur.qgd

min (Normalized)

10.0 20.0 26.

TIC

4.829 5.056 5.325 6.100 6.435 7.242 7.842 8.188 8.608 8.880 9.286 9.578 9.7669.872 10.390 10.81510.982 11.212 11.62611.847 12.400 12.570 12.858 13.38113.539 13.702 14.585 14.814 15.423 15.698 16.334 17.500 19.060 19.696 20.521 20.983 21.208 21.825 22.94623.136 23.521 23.729 24.688

Sample Information Analyzed by : Karina

Analyzed : 9/26/2023 12:04:02 PM Sample Type : Unknown

Level # : 1

Sample Name : Ekstrak Asam Gelugur Sample ID : Asam Gelugur_HCA IS Amount : [1]=1

Sample Amount : 1 Dilution Factor : 1

Vial # : 2

Injection Volume : 1.00

Data File : D:\Data\2023.09.26 Ekstrak Asam Gelugur.qgd Org Data File : D:\Data\2023.09.26 Ekstrak Asam Gelugur.qgd Method File : D:\Method\RTX-5MS\Ekstrak_DBB.S.qgm Org Method File : D:\Method\RTX-5MS\Ekstrak_DBB.S.qgm Report File : D:\Format Report RTX.qgr

Tuning File : C:\GCMSsolution\System\Tune1\Tuning.qgt Modified by : Admin

Modified : 9/27/2023 11:50:43 AM

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Peak Report TIC

Peak# R.Time Area Area% Height Height% A/H Name

1 4.829 13181230 0.45 2730029 0.67 4.83 Acetic acid

2 5.056 7566274 0.26 5380533 1.32 1.41 2-Propanone, 1-hydroxy-

3 5.325 18249237 0.62 1399156 0.34 13.04 Acetic acid, hydroxy-, methyl ester (CAS) M 4 6.100 41500126 1.41 3462019 0.85 11.99 2-Furancarboxaldehyde (CAS) Furfural 5 6.435 245560514 8.32 27098989 6.65 9.06 Furfural

6 7.242 10825406 0.37 1920854 0.47 5.64 2-Propanone, 1-(acetyloxy)- 7 7.842 46631354 1.58 9522366 2.34 4.90 Butyraldehydic acid, methyl ester 8 8.188 93583702 3.17 11601787 2.85 8.07 2(5H)-Furanone

9 8.608 51791554 1.75 11525904 2.83 4.49 2-Furancarboxaldehyde, 5-methyl- (CAS) 5 10 8.880 26595767 0.90 5003472 1.23 5.32 .beta.-Myrcene

11 9.286 28067428 0.95 11879073 2.92 2.36 Valeric acid, 2-ethoxyethyl ester 12 9.578 53474562 1.81 16690137 4.10 3.20 Dimethyl fumarate

13 9.766 5994768 0.20 2805272 0.69 2.14 Butanedioic acid, dimethyl ester 14 9.872 16260667 0.55 5943007 1.46 2.74 1,3,6-Octatriene, 3,7-dimethyl-, (Z)- 15 10.390 34588141 1.17 9765019 2.40 3.54 2(3H)-Furanone, 5-ethoxydihydro- 16 10.815 43505888 1.47 10035115 2.46 4.34 Butanedioic acid, methylene-, dimethyl este 17 10.982 5774684 0.20 1964428 0.48 2.94 Dimethyl ethylidenemalonate

18 11.212 66103761 2.24 10174219 2.50 6.50 Azeleonitrile

19 11.626 371553906 12.59 29151917 7.16 12.75 3-Acetoxy-3-hydroxypropionic acid, methy 20 11.847 64296345 2.18 13240811 3.25 4.86 HEPTA-2,4-DIENOIC ACID METHYL ES 21 12.400 38230044 1.30 5651081 1.39 6.77 Dimethyl dl-malate

22 12.570 73677141 2.50 12441186 3.05 5.92 2-CHLORMETHYLCYCLOPROPANCAR 23 12.858 46203818 1.57 6555710 1.61 7.05 2-Furancarboxaldehyde, 5-(ethoxymethyl)- 24 13.381 104604604 3.54 11048537 2.71 9.47 5-Hydroxymethylfurfural

25 13.539 3054686 0.10 1141580 0.28 2.68 .alpha.-d-Lyxofuranose, cyclic 2,3-(ethylbor 26 13.702 9112083 0.31 2362796 0.58 3.86 4-Bromo-2-methylpent-2-enoic acid, methy 27 14.585 16285430 0.55 2789656 0.68 5.84 3-Furancarboxylic acid, 4-butyltetrahydro-2 28 14.814 14677461 0.50 4484221 1.10 3.27 Dimethyl 1,4-cyclohexadiene-1,2-dicarboxy 29 15.423 30039782 1.02 3872818 0.95 7.76 DL-Proline, 5-oxo-, methyl ester

30 15.698 248057910 8.40 24815118 6.09 10.00 Dimethyl 1,4-cyclohexadiene-1,2-dicarboxy 31 16.334 442233016 14.98 24467965 6.01 18.07 Citric acid, trimethyl ester

32 17.500 45468055 1.54 4287194 1.05 10.61 Dodecanoic acid 33 19.060 28965544 0.98 5344658 1.31 5.42 Methyl tetradecanoate 34 19.696 9005494 0.31 1435250 0.35 6.27 Tetradecanoic acid

35 20.521 8604116 0.29 2581960 0.63 3.33 1,2,4-Benzenetricarboxylic acid, trimethyl e 36 20.983 5604956 0.19 1348829 0.33 4.16 9-Hexadecenoic acid, methyl ester, (Z)- 37 21.208 96721281 3.28 28268598 6.94 3.42 Hexadecanoic acid, methyl ester (CAS) Met 38 21.825 72437501 2.45 8906221 2.19 8.13 9-Octadecenoic acid (Z)- (CAS) Oleic acid 39 22.946 200656430 6.80 27245967 6.69 7.36 9-Octadecenoic acid, methyl ester, (E)- 40 23.136 32208799 1.09 10719122 2.63 3.00 Methyl stearate

41 23.521 139487242 4.73 14723806 3.61 9.47 Oleic Acid

KEMENTERIAN PENDIDIKAN DAN KEBUDAYAAN UNIVERSITAS SYIAH KUALA

FAKULTAS TEKNIK JURUSAN TEKNIK KIMIA

LABORATORIUM TEKNIK PENGUJIAN KUALITAS LINGKUNGAN

Sample Information Analyzed by : Karina

Analyzed : 9/26/2023 12:04:02 PM Sample Type : Unknown

Level # : 1

Sample Name : Ekstrak Asam Gelugur Sample ID : Asam Gelugur_HCA IS Amount : [1]=1

Sample Amount : 1 Dilution Factor : 1

Vial # : 2

Injection Volume : 1.00

Data File : D:\Data\2023.09.26 Ekstrak Asam Gelugur.qgd Org Data File : D:\Data\2023.09.26 Ekstrak Asam Gelugur.qgd Method File : D:\Method\RTX-5MS\Ekstrak_DBB.S.qgm Org Method File : D:\Method\RTX-5MS\Ekstrak_DBB.S.qgm Report File : D:\Format Report RTX.qgr

Tuning File : C:\GCMSsolution\System\Tune1\Tuning.qgt Modified by : Admin

Modified : 9/27/2023 11:50:43 AM

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Peak# R.Time Area Area% Height Height% A/H Name

42 23.729 25397087 0.86 6837864 1.68 3.71 9,12-Octadecadienoic acid (Z,Z)-, methyl es 43 24.688 16181025 0.55 4702135 1.15 3.44 Hexadecanoic acid, 1-(hydroxymethyl)-1,2-

2952018819 100.00 407326379 100.00

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KEMENTERIAN PENDIDIKAN DAN KEBUDAYAAN UNIVERSITAS SYIAH KUALA

FAKULTAS TEKNIK JURUSAN TEKNIK KIMIA

LABORATORIUM TEKNIK PENGUJIAN KUALITAS LINGKUNGAN

Method [Shimadzu GCMS-QP2010 Ultra]

Carrier gas : Helium Column : Rtx-5MS

===== Analytical Line 1 =====

[AOC-20i+s]

# of Rinses with Presolvent :3

# of Rinses with Solvent(post) :3

# of Rinses with Sample :3 Plunger Speed(Suction) :High Viscosity Comp. Time :0.2 sec Plunger Speed(Injection) :High Syringe Insertion Speed :High

Injection Mode :Normal

Pumping Times :5

Inj. Port Dwell Time :0.3 sec

Terminal Air Gap :No

Plunger Washing Speed :High

Washing Volume :8uL

Syringe Suction Position :0.0 mm Syringe Injection Position :0.0 mm

Solvent Selection :All A,B,C

[GC-2010]

Column Oven Temp. :31.0 °C Injection Temp. :270.00 °C Injection Mode :Splitless

Sampling Time :1.00 min

Flow Control Mode :Linear Velocity

Pressure :60.0 kPa

Total Flow :47.2 mL/min

Column Flow :1.20 mL/min

Linear Velocity :39.3 cm/sec

Purge Flow :10.0 mL/min

Split Ratio :30.0

High Pressure Injection :OFF Carrier Gas Saver :OFF Oven Temp. Program

Rate Temperature(°C) Hold Time(min)

- 31.0 2.00

10.00 300.0 5.00

< Ready Check Heat Unit >

Column Oven : Yes

SPL1 : Yes

MS : Yes

< Ready Check Detector(FTD) >

< Ready Check Baseline Drift >

< Ready Check Injection Flow >

SPL1 Carrier : Yes SPL1 Purge : Yes

< Ready Check APC Flow >

< Ready Check Detector APC Flow >

External Wait :No

Equilibrium Time :3.0 min [GC Program]

[GCMS-QP2010 Ultra]

IonSourceTemp :200.00 °C Interface Temp. :270.00 °C Solvent Cut Time :2.50 min Detector Gain Mode :Absolute Detector Gain :0.95 kV

Threshold :0

[MS Table]

--Group 1 - Event 1--

Start Time :3.00min

End Time :33.00min

ACQ Mode :Scan

Event Time :0.30sec

Scan Speed :2000

Start m/z :35.00

End m/z :600.00

Sample Inlet Unit :GC [MS Program]

Use MS Program :OFF