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d. Penerbit : Departemen Teknik Kimia Undip e. DOI artikel (jika ada) : https://doi.org/10.14710/reaktor.20.3.150

-158

f. Alamat web Jurnal : https://ejournal.undip.ac.id/index.php/re aktor/article/view/33469/18105

g. Terindeks di Scimagojr/Thomson Reuter ISI Knowledge atau di SINTA Kategori Publikasi Jurnal

Ilmiah

: Jurnal Ilmiah Internasional / Internasional bereputasi (beri pada kategori yang

tepat)

Jurnal Ilmiah Nasional Terakreditasi SK No.: 60/E/KPT/2016 dengan p- ISSN No. 0852-0798 (printed version) and e-ISSN No. 2407-5973 (electronic version)

Jurnal Ilmiah Nasional terindeks di DOAJ, IPI, SINTA Hasil Penilaian Peer Review :

Komponen Yang Dinilai

Nilai Maksimal Jurnal Ilmiah

Nilai Akhir Yang Diperoleh Internasional/

Internasional bereputasi**

Nasional

Terakreditasi Nasional***

a. Kelengkapan unsur isi artikel (10%) 2,50 2,50

b. Ruang lingkup dan kedalaman pembahasan (30%)

7,50 6,50

c. Kecukupan dan kemutahiran data/informasi dan metodologi (30%)

7,50 6,50

d. Kelengkapan unsur dan terbitan/jurnal (30%) 7,50 6,00

Total = (100%) 25,00 21,50

Nilai Pengusul = 21,50 x 0,60 =12,90

Catatan Penilaian Artikel oleh Reviewer:

1. Kesesuaian dan kelengkapan unsur isi jurnal:

Artikel tersaji dengan lengkap, tata penulisan sesuai dengan format jurnal. Artikel ditulis lengkap sesuai dengan template jurnal Reaktor, terdiri dari abstract, introduction, experimental, results and discussions, conclusions, acknowledgments serta references.

2. Ruang lingkup dan kedalaman pembahasan:

Topik dan materi sesuai dengan ruang lingkup jurnal yang bersangkutan, yaitu dalam bidang Teknik Kimia. Kebaruan artikel ini membahas tentang aplikasi glyoxal acrylamide pada modifikasi kappa-karagenan sebagai superabsorbent polymer untuk system pengaturan pelepasan obat povidone iodine. Pembahasan dilakukan cukup baik dengan merujuk atau membandingkannya dengan peneliti-peneliti sebelumnya dan dilengkapi 8 figure dan 1 table. Sitasi dalam pembahasan sebanyak 24 artikel atau 63,15%.

3. Kecukupan dan kemutakhiran data/informasi dan metodologi:

Kemutakhiran data/informasi yang berasal dari referensi 10 tahun terakhir dari jurnal, sebanyak 26 dari 38 pustaka, atau 68,42 %.

Metodologi lengkap dan terstruktur, instrumen-instrumen pengukur yang dipakai cukup memadai.

4. Kelengkapan unsur dan kualitas terbitan

Jurnal “Reaktor” adalah jurnal Nasional Terakreditasi DIKTI, SK No. : 60/E/KPT/2016; ISSN : p- 0852-0798. e- ISSN : 2407- 5973. PENERBIT :Departemen Teknik Kimia FT. UNDIP, Semarang. dengan subject Area : Teknik Kimia. Nilai similaritas artikel berdasarkan Turnitin adalah 10%, sehingga orisinalitas artikel baik.

Semarang, Reviewer 1

Prof. Ir. Didi Dwi Anggoro, M.Eng., PhD NIP. 196711141993031001

Unit kerja : Fakultas Teknik Universitas Diponegoro

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Lampiran : 2 (dua) lembar

Perihal : Pemberitahuan Akreditasi Terbitan Berkala Ilmiah Tahun 2016

Kepada Yth.

1. Pimpinan Perguruan Tinggi

2. Koordinator Kopertis Wilayah I s.d. XIV 3. Ketua Himpunan Profesi

4. Pengelola Terbitan Berkala Ilmiah di Litbang di seluruh Indonesia

Sehubungan dengan hasil Akreditasi Berkala Ilmiah Elektronik Periode II Tahun 2016 dan telah diterbitkannya Surat Keputusan Direktur Jenderal Penguatan Riset dan Pengembangan Kementerian Riset, Teknologi, dan Pendidikan Tinggi Nomor 60/E/KPT/2016, tanggal 13 November 2016, dengan hormat bersama ini kami sampaikan hasil akreditasi sebagaimana terlampir.

Bagi Terbitan Berkala Ilmiah yang terakreditasi akan kami sampaikan Sertifikat Akreditasi dan diwajibkan mencantumkan masa berlaku akreditasi dengan menuliskan tanggal penetapan dan tanggal akhir masa berlaku tersebut di laman dan atau halaman muka terbitan berkala ilmiah.

Atas perhatian dan kerja sama yang baik, kami ucapkan terima kasih.

Direktur Pengelolaan Kekayaan Intelektual

Tembusan:

Direktur Jenderal Penguatan Riset dan Pengembangan

ttd

Sadjuga

NIP. 195901171986111001

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KEMENTERIAN RISET, TEKNOLOGI, DAN PENDIDIKAN TINGGI DIREKTORAT JENDERAL PENGUATAN RISET

DAN PENGEMBANGAN

Jl. M.H. Thamrin No. 8, Jakarta 10340 – Gedung II BPPT, Lantai 20 Telepon (021) 316-9778. Faksimili (021) 310 1728, 310 2368

Homepage : www.ristekdikti.go.id

LAMPIRAN

KEPUTUSAN DIREKTUR JENDERAL PENGUATAN RISET DAN PENGEMBANGAN KEMENTERIAN RISET, TEKNOLOGI, DAN PENDIDIKAN TINGGI

NOMOR 60/E/KPT/2016

TENTANG HASIL AKREDITASI TERBITAN BERKALA ILMIAH ELEKTRONIK PERIODE II TAHUN 2016

Bidang Ilmu No Nama Jurnal ISSN Penerbit Peringkat

Ekonomi 1 Jurnal Manajemen Teknologi

2089-7928 Unit Penelitian dan Pengetahuan, Sekolah Bisnis dan Manajemen Institut Teknologi Bandung

Terakreditasi B

Humaniora 1 Dinamika Ilmu 2442-9651 Institut Agama Islam Negeri Samarinda

Terakreditasi B 2 Jurnal

Sosioteknologi

2443-258X Kelompok Keahlian Ilmu Kemanusiaan Fakultas Seni Rupa dan Desain Institut Teknologi Bandung

Terakreditasi B

3 Masyarakat, Kebudayaan dan Politik

2528-6013 Fakultas Ilmu Sosial dan Ilmu Politik Universitas Airlangga

Terakreditasi B

4 Wacana, Jurnal Ilmu Pengetahuan Budaya

2407-6899 Fakultas Ilmu Pengetahuan Budaya Universitas

Indonesia

Terakreditasi B

Kesehatan 1 Acta Medica Indonesiana

2338-2732 Perhimpunan Dokter Spesialis Penyakit Dalam Indonesia

Terakreditasi B

2 Nurse Media Journal of Nursing

2406-8799 Departemen Keperawatan, Fakultas Kedokteran, Universitas Diponegoro

Terakreditasi B

MIPA 1 ALCHEMY Jurnal

Penelitian Kimia

1412-4092 Universitas Sebelas Maret Terakreditasi B Pendidikan 1 Journal of

Education and Learning

2302-9277 Universitas Ahmad Dahlan bekerjasama dengan IAES Indonesia Section

Terakreditasi B

Pertanian 1 AGRIVITA Journal of Agricultural Science

2477-8516 Fakultas Pertanian Universitas Brawijaya berafiliasi dengan Perhimpunan Agronomi Indonesia (PERAGI)

Terakreditasi B

2 Journal of Degraded and Mining Lands Management

2502-2458 Fakultas Pertanian, Universitas Brawijaya, Malang

Terakreditasi B

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Pertanian

Indonesian Tropical Animal Agriculture

Ilmu Pertanian Universitas Diponegoro dan Indonesian Society of Animal

Agriculture (ISAA) 4 Journal of Tropical

Life Science

2527-4376 Universitas Brawijaya Terakreditasi B 5 Jurnal Pengelolaan

Sumberdaya Alam dan Lingkungan

2460-5824 Pusat Penelitian Lingkungan Hidup, Institut Pertanian Bogor

Terakreditasi B

Rekayasa 1 Bulletin of Electrical Engineering and Informatics

2302-9285 Universitas Ahmad Dahlan Terakreditasi B

2 Communication and Information Technology Journal

2460-7010 Universitas Bina Nusantara Terakreditasi B

3 International Journal of

Renewable Energy Development (IJRED)

2252-4940 Universitas Diponegoro Terakreditasi B

4 Journal of Engineering and Technological Sciences

2338-5502 ITB Journal Publisher Terakreditasi B

5 Jurnal Ilmu Komputer dan Informasi

2502-9274 Fakultas Ilmu Komputer Universitas Indonesia

Terakreditasi B

6 Reaktor 2407-5973 Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro Semarang

Terakreditasi B

7 Tataloka 2356-0266 Universitas Diponegoro Terakreditasi B

Ditetapkan di Jakarta

pada tanggal 13 November 2016

DIREKTUR JENDERAL PENGUATAN RISET DAN PENGEMBANGAN

ttd

MUHAMMAD DIMYATI

NIP 19591217 198402 1001

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Acredited:

p-ISSN 0852 – 0798

SK No.: 60/E/KPT/2016

e-ISSN 2407 – 5973

Volume 20 Number 3 September 2020

Reaktor Vol.20 No.3 Page: 109-159 Semarang

September 2020 p-ISSN

0852-0798

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Reaktor, Vol. 20 No. 3, September Year 2020

EDITORIAL BOARDS

Editor in Chief

Prof. Dr. Andri Cahyo Kumoro (ScopusID: 22980375000)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

International Editorial Board

Dr. Pablo Fuciños (ScopusID: 6506552780)

International Iberian Nanotechnology Laboratory, Braga, Portugal

Dr. Jose Antonio Vazquez (ScopusID: 23107698900) Marine Research Institute IIM-CSIS Spain, Spain

Dr. Mark Leaper (ScopusID: 6602515825)

Department of Chemical Engineering, Loughborough University, Loughborough, United Kingdom

Dr. Qingchun Yuan (ScopusID: 12792448300)

Aston University, Aston Materials Centre, Birmingham, United Kingdom

Dr. Oki Muraza (ScopusID: 22433275900)

CENT & Department of Chemical Engineering, King Fahd University of Petroleum and Minerals (KFUPM), PO Box 5040 Dhahran 31261 KSA, Saudi Arabia

Dr. Ivan Salmeron (ScopusID: 43861832300)

Universidad Autonoma de Chihuahua, Graduate Program in Food Science and Technology, Chihuahua, Mexico, Mexico

Prof. Dr. Ahmad bin Jusoh (ScopusID: 57202652904)

Faculty of Science and Technology, Universiti Malaysia Terengganu, Malaysia, Malaysia

Dr. Suryadi Ismadji (ScopusID: 10039423500)

Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114 Indonesia, Indonesia

Dr. Made Tri Ari Penia Kresnowati (ScopusID: 8639247200)

Department of Chemical Engineering, Bandung Institute of Technology (ITB), Indonesia

Dr. Muhammad Dani Supardan (ScopusID: 6506563268)

Department of Chemical Engineering University of Syiah Kuala, Indonesia

Prof. Dr. Widayat Widayat (ScopusID: 36715625400)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

Dr. Nita Aryanti (ScopusID: 25639393400)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

Dr. Dyah Hesti Wardhani (ScopusID: 24075014500)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

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Associate Editors

Dr. Dessy Ariyanti (ScopusID: 556433413700)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

Dr. Aprilina Purbasari (ScopusID: 55786077900)

Department of Chemical Engineering, Diponegoro University, Semarang, Indonesia

Publisher :

Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Semarang, Indonesia

Jl. Prof. Soedarto, SH., Tembalang, Semarang, 50275 Telp. (024) 7460058; Fax. (024) 76480675

[email protected]

Reaktor is published 4 (four) times a year. The editors receive scientific papers on research laboratory, review paper, simulation and problem solving in industries that related to the field of Chemical Engineering.

The submitted manuscript will be reviewed by reviewers to assess the substance of the feasibility and technical writing. Registration system/Submission article already using Online system with website address is http://ejournal.undip.ac.id/index.php/reaktor/

Every paper pubished in Reaktor journal has been proof reading.

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Reaktor, Vol. 20 No. 3, September Year 2020

TABLE OF CONTENTS

Effect of Acid Concentration on the Activation of Bayah Natural Zeolite for Palm Kernel Shell Pyrolysis Application

109-116 Endang Suhendi, Andre Wibowo, Tia Lestari, and Teguh Kurniawan

Mathematical Modeling for Determination of Correlation Between Current Density and Dissolved Oxygen in Yeast Microbial Fuel Cell-Based Biosensor

117-121 Marcelinus Christwardana, Linda Aliffia Yoshi

Solely Cellulose-based Adsorbent Derived from Oil Palm Empty Fruit Bunches for Dye Removal

122-128 Athanasia Amanda Septevani, Farhan Riza Afandi, Yulianti Sampora, Yenni Apriliani Devy,

Aisah Resti Amelia, Melati Septiyanti, Dian Burhani

Comparative Analysis Between PI Conventional and Cascade Control in Heater-PFR- Series

129-137 Dedy Kristanto, and Yulius Deddy Hermawan

Kinetic Study of Kapok Seed Oil Esterification Using BMIM-PF6 Catalyst 138-149 Bagus Agang Sudrajat, Widayat, Ngurah Widiantara, Hantoro Satriadi, Maria Siahaan, Wira

Pinem

Application of Glyoxal Acrylamide Modified Κ-Carrageenan as a Superabsorbent Polymer in Drug Delivery System

150-158 Aji Prasetyaningrum, Al Farrel A. Raemas, Nur Rokhati, Bakti Jos

Erratum to: Evaluation Performance of Pneumatic Dryer for Cassava Starch [18 (4): 216- 223]

159-159 Reaktor Editorial

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150

p-ISSN 0852 – 0798 e-ISSN 2407 – 5973

Acredited: SK No.: 60/E/KPT/2016

Website: http://ejournal.undip.ac.id/index.php/reaktor/

Reaktor, Vol. 20 No. 3, September Year 2020, pp. 150-158

Application of Glyoxal Acrylamide Modified Κ-Carrageenan as A Superabsorbent Polymer in Drug Delivery System

Aji Prasetyaningrum

1,*)

, Al Farrel A. Raemas

1)

, Nur Rokhati

1,2)

, Bakti Jos

1)

1) Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Jl. Prof. Soedarto SH Tembalang Semarang

2) Laboratorium Mer-C, UPT Laboratorium Terpadu Universitas Diponegoro Jl. Prof. Soedarto SH Tembalang Semarang

*)Corresponding author: [email protected] (Received: June 18, 2020; Accepted: September 25, 2020)

Abstract

The hydrogel is superabsorbent polymers (SAP) that are biodegradable and can be obtained from polysaccharides, lipids, and proteins. Polysaccharides include cellulose, starch and their derivatives, seaweed extracts such as carrageenan, alginate, pectin, and chitosan. Carrageenan is the result of the extraction of red seaweed sap with an alkaline solution. The main objective of this study was to simultaneously increase the strength and properties of κ- carrageenan SAP film with the addition of glyoxal and acrylamide as crosslinkers. The addition of acrylamide (variated from 1 to 7 % b/v) into the κ-Carrageenan based SAP hydrogel compound and the presence of glyoxal as crosslink agent (variated from 0 to 1,0 % v/v). The physical properties of the SAP films were analyze using swelling degree and tensile strength. The structural and morphological properties of composite films were analyzed using Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM). In addition, the effect of pHs on the releasing drug Poly(vinylpyrrolidone)-Iodine was investigated. This research shows that the addition of acrylamide and glyoxal can improve the physical properties of the modified κ-carrageenan film. Characterization using SEM shows that the addition of glyoxal causes the formation of tissue fibers in SAP. FTIR spectra indicated the formation of cross bonds in modified SAP film at 3294.42 cm-1 (carboxylic acid). The treatment under alkaline conditions will increase drug release ability.

Keywords: κ-carrageenan; hydrogels; acrylamide; glyoxal; drug delivery

How to Cite This Article: Prasetyaningrum, A., Raemas, A.F.A., Rokhati, N., Jos, B. (2020), Application of Glyoxal Acrylamide Modified Κ-Carrageenan as A Superabsorbent Polymer in Drug Delivery System, Reaktor, 20(3), 150- 158, https://doi.org/10.14710/reaktor.20.3.150-158

INTRODUCTION

The modification of polysaccharide as a biopolymer is a new method for the production of biomaterials. Superabsorbent polymer (SAP) has a three-dimensional polymer network that has a lot of water and usually used as carriers for therapeutic

agents in drug administration and as scaffolds for tissue modification. Various natural and synthetic polymer developments have used hydrogels as tissue breakers. (Calo, et al. 2014; Ni, et al. 2017; Graulus, et al. 2015). Several previous studies reported the use of natural polysaccharides such as carrageenan as an

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109

Reaktor, Vol. 20 No. 3, September Year 2020, pp. 109-116

Effect of Acid Concentration on the Activation of Bayah Natural Zeolite for Palm Kernel Shell Pyrolysis Application

Endang Suhendi

*)

, Andre Wibowo, Tia Lestari, and Teguh Kurniawan

Department of Chemical Engineering, Faculty of Engineering, Sultan Ageng Tirtayasa University Jl. Raya Jendral Sudirman KM.3, Cilegon, Banten

*)Corresponding author: [email protected] (Received : January 01, 2020; Accepted: August 03, 2020)

Abstract

Bio-oil is the main product in the pyrolysis process which is expected to be a liquid fuel replacement solution. But the resulting bio-oil cannot be directly used because of high oxygenated compounds, high viscosity, corrosive, and unstable. Addition of activated natural zeolite catalyst to the pyrolysis process is expected to improve the quality of bio-oil to be used as a renewable liquid fuel. The research aims to determine the influence of acid concentrations on zeolite modification to the characteristics of pyrolysis products. Result of catalyst characterization indicates that zeolite activation using acid will increase Si/Al ratio as well as open the surface of previously hindered zeolite. The yield of char produced in this study tends not to undergo significant changes between the catalytic and noncatalytic pyrolysis by 33% wt. Addition of zeolite catalyst in pyrolysis proved to be able to increase the content of phenol and decrease the content of acetic acid in bio-oil by 6% . Meanwhile, yield of CO2 increases by 20% in the use of catalysts due to the release of oxygen in the oxygenate compounds. The results of this study showed that the resulting bio-oil still does not meet the specifications of liquid fuels but can be utilized as a renewable chemical feedstock.

Keywords: pyrolysis; biomass; natural zeolite; modified

How to Cite This Article: Suhendi, E., Wibowo, A., Lestari, T., and Kurniawan, T (2020), Effect of Acid Concentration on the Activation of Bayah Natural Zeolite for Palm Kernel Shell Pyrolysis Application, Reaktor, 20(3), 109-116, https://doi.org/10.14710/reaktor.20.3.109-116

INTRODUCTION

Primary energy consumption in Indonesia reached 998.06 BOE (Barrel Oil Equivalent) in 2016 and increased by 5.9% in 2017 (Ika, 2017; MEMR, 2017). The use of fossil energy has many negative impacts, one of them is carbon emissions which can cause global warming and climate change issue.

Renewable energy is a solution to meet future national energy needs. Recently, the use of renewable energy in Indonesia is still low, which the energy mix in the renewable energy sector is only 7.7% in 2017 (Wijiatmoko, 2017).

Biomass such as palm kernel shell can be used as a new renewable energy source because it has great potential in Indonesia. According to data from the Association of Indonesian Palm Oil Entrepreneurs (GAPKI), the potential for biomass production from the Indonesian palm oil industry in 2018 will reach around 9.46 million tons (GAPKI, 2018).

Pyrolysis is a technology that can be utilized to convert biomass into liquid (bio-oil), solid (char), and gas products. Pyrolysis is a process of thermal decomposition of biomass at temperatures of 350 to 650 oC without the presence of air or oxygen (Basu,

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117

p-ISSN 0852 – 0798 e-ISSN 2407 – 5973

Acredited: SK No.: 60/E/KPT/2016

Website: http://ejournal.undip.ac.id/index.php/reaktor/

Reaktor, Vol. 20 No. 3, September Year 2020, pp. 117-121

Mathematical Modeling for Determination of Correlation Between Current Density and Dissolved Oxygen in Yeast Microbial Fuel

Cell-Based Biosensor

Marcelinus Christwardana*

)

and Linda Aliffia Yoshi

Department of Chemical Engineering, Institut Teknologi Indonesia, Jl. Raya Puspitek Serpong, South Tangerang, Indonesia 15320

*)Corresponding author: [email protected]; [email protected] (Received : March 28, 2020; Accepted: June 26, 2020)

Abstract

Experiments were conducted to study the correlation between current density and dissolved oxygen (DO) and to develop a model for estimating the value of current density in yeast MFC based DO biosensors. A curve between current density and DO was made, and data analysis was performed using free-online data fitting, namely zunzun.com.

One linear regression and nine different exponential models were used as an approach to determine the correlation between current density and DO. Current density increased rapidly as DO concentrations increased, where high DO concentration accelerated the Oxygen Reduction Reaction (ORR) in the cathode part. The exponential model shows a better fit compared to the linear line model, with R2, SSQABS, and RMSE values were 0.9975, 0.4745, and 0.3444, respectively. The exponential equation found in the correlation was y = 1.532e0.320x. The results showed that exponential was the best model to describe the relationship between DO concentration and current density that occurred in the MFC-based DO biosensor yeast.

Keywords: exponential equation, mathematical modeling, biosensor, yeast, dissolved oxygen

How to Cite This Article: Christwardana, M., and Yoshi, L.A (2020), Mathematical Modeling for Determination of Correlation Between Current Density and Dissolved Oxygen in Yeast Microbial Fuel Cell-Based Biosensor, Reaktor, 20(3), 117-121, https://doi.org/10.14710/reaktor.20.3.117-121

INTRODUCTION

Microbial Fuel Cell (MFC) is an electrochemical device that can convert chemical energy into electrical energy. Microorganisms are used as biocatalysts by consuming substrates to carry out metabolism, and then produce protons and electrons (Christwardana et al., 2017). Protons from the anode side move to the cathode side through the membrane separator, while electrons go away to the cathode side through an external circuit.

MFC can be widely used for various sectors, such as electricity generation, biohydrogen production, battery, wastewater treatment, or biosensors (Debabov, 2008; Yang et al., 2015; Zhao et al., 2017). In each use, microorganisms are located on the side of the anode along with the substrate. Each microorganism only consumes a specific substrate.

Consumption of substrate by microorganisms will activate redox reactions, especially NAD/NADH and FAD/FADH2 in the metabolism process as evidence of

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Superabsorbent Polymer in Drug Delivery System

by Aji Prasetyaningrum

Submission date: 22-Dec-2020 02:59PM (UTC+0700) Submission ID: 1480451494

File name: C_09_2020_REAKTOR_ACRYLAMIDE.pdf (815.53K) Word count: 5090

Character count: 27832

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8 < 1 %

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AGRIVITA Journal of Agricultural Science is a peer-reviewed, scientific journal published by Faculty of Agriculture Universitas Brawijaya Indonesia in collaboration with

Article 49 Paragraph (2) letter e of the Government Regulation of the Republic of Indonesia Number 18 of 2021 can be given to foreigners within a certain period. Ownership of houses