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BAB V
KESIMPULAN DAN SARAN
5.1 Kesimpulan
1. Reaksi α-pinene membutuhkan energi yang cukup besar sehingga diperlukannya katalis asam. Energi yang cukup besar ini dibutuhkan untuk membentuk karbokation dimana karbokation memiliki peran penting dalam reaksi α-pinene.
2. Reaksi hidrasi α-pinene bersaing dengan reaksi isomerisasi α-pinene karena kedua reaksi memiliki tahapan mekanisme reaksi yang sama yaitu karbokation dimana karbokation yang berperan penting adalah pinanyl carbocation. Pinanyl carbocation merupakan karbokation kunci dimana penyusunan ulang dari karbokation yang akan mengarahkan ke arah mana reaksi terjadi.
3. berdasarkan hasil pemodelan molekular pada penelitian ini , karbokation yang lebih mudah stabil adalah isobornyl dan fenchyl sehingga kedua karbokation ini lebih mudah terbentuk dimana produk akhir mengarah pada borneol dan fenchol.
5.2 Saran
1. Kajian lebih lanjut mengenai peta mekanisme khususnya pada pemodelan transition state dapat dilakukan pada studi selanjutnya.
2. Eksperimen reaksi α-pinene dapat dilakukan kembali dengan menggunakan beberapa katalis asam lain untuk mendukung hasil kajian teoritis pada studi selanjutnya.
3. Metode solvent lain seperti IEFPCM-DMSO atau gas-phase dapat dilakukan untuk memperjelas kecenderungan data dan menyempurnakan penelitian ini.
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