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IOP Conference Series: Materials Science and Engineering • Open Access • Volume , Issue • October • Article number • rd International Conference on Advanced Material for Better Future , ICAMBF • Surakarta, Central Java • October through October • Code
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Utilization of Yogyakarta natural zeolites to reduce NH and NO levels in shrimp pond water and its kinetic rate study 4 2
Anggoro D.D. ; Buchori L.; Sumantri I.; Ivan; Sejati D.A.B.; Oktavianty H.
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Department of Chemical Engineering, Diponegoro University, Semarang, 50275, Indonesia a
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Natural zeolite is an unique crystal that has a very small and uniform pore size when compared to other adsorbents, such as activated carbon and silica gel. This study aims to determine the potential of natural zeolite as an adsorbent, to absorb toxic gases in pond water, especially shrimp ponds and to study its kinetics rate of NH and NO adsorption. This study consisted of two stages: activated zeolite using NaOH, and tested the absorption power of NH and NO gases. Zeolite was activated using NaOH where 25 grams of zeolite were mixed with 0.5N NaOH and heated for 2 hours at 70°C, then stirred and dried in an oven at 110°C for 4 hours. Then zeolite was cooled in a desiccator. The results of NH and NO gas adsorption showed that natural zeolites can reduce NH and NO gas levels in shrimp pond water. The rate constant of pseudo-second-order, and the initial adsorption rate at any given time t, can be predicted from the equation which is full zeolite obtained the best perform of NH and NO adsorption. © Published under licence by IOP Publishing Ltd.
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Indonesia’s Natural Zeolite as an Adsorbent for Toxic Gases in Shrimp Ponds Anggoro, D.D. Sumantri, I. Buchori, L.
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Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
Published under licence by IOP Publishing Ltd
International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 011001
IOP Publishing doi:10.1088/1757-899X/578/1/011001
1
International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 011001
IOP Publishing doi:10.1088/1757-899X/578/1/011001
2
PREFACE
3
rdInternational Conference on Advanced Material for Better Future 2018 (ICAMBF 2018)
The 3
rdInternational Conference on Advanced Material for Better Future 2018 (ICAMBF 2018) was held on October 15-16, 2018 in Surakarta, Central Java, Indonesia. ICAMBF 2018 is an international scientific forum that was initiated to overcome material problems as well as factors affecting them that have emerged as the main issue and challenge attracting more attention from various scientists, government, and regulatory bodies worldwide. The ICAMBF 2018 was attended by leading scientists from countries near and abroad who work in the field of material.
This event based on theme Smart Materials for A Smart World that aims to provide a forum for scientists, researchers, and engineers within the nation and from around the world to present, discuss, share, and exchange their knowledge, experiences, and research finding on all aspects of material. Thus, this conference can give an excellent overview in all scope of fields including Functional Material, Material Chemistry and Physics, Advanced Nanomaterials, Polymer and Composites, Drug and Biomaterials Energy, Electrical, Optical and Magnetic Materials, Advanced Materials for Energy, Green Energy Materials, Batteries and Energy Storage Materials, Graphene and 2D Energy Materials, Separation Materials, Construction Materials, Metallurgy and Alloy Materials.
We are pleased to our outstanding invited speakers Prof. Ru-Jen Lin, Prof. Dr. Santiago Gómez-Ruiz, Prof. Dato’ Dr. Burhanuddin Yeop Majlis, Prof. Santiago Gomez, Prof. Ari Handono Ramelan, Assoc. Prof. Dr. Alfi Khatib and other participated speakers for sharing the best knowledge in Advanced Material.
We also thanks to all researchers and student who participate in conference by submitting their papers to convey the current science discussed at ICAMBF 2018, all of the organizing committee wish you get awesome conference experience, and reviewers for their valuable revision of these papers.
Prof. Ir. Ari Handono Ramelan, M.Sc (Hons), Ph.D
Chairman of ICAMBF 2018
Dean of Faculty Mathematics & Natural Sciences
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Published under licence by IOP Publishing Ltd
International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 011002
IOP Publishing doi:10.1088/1757-899X/578/1/011002
1
Chairman
Prof. Ir. Ari Handono Ramelan, M.Sc., (Hons), Ph.D.
Sebelas Maret University, Indonesia Co-Chairman Dr. Sayekti Wahyuningsih, MSi Sebelas Maret University, Indonesia Secretary Ahmad Marzuki, SSi, PhD Sebelas Maret University, Indonesia
Prof. Ir. Ari Handono Ramelan, M.Sc., (Hons), Ph.D.
Sebelas Maret University, Indonesia Ahmad Marzuki, SSi, PhD Sebelas Maret University, Indonesia Venty Suryanti. M.Phil. PhD Sebelas Maret University, Indonesia Dr. Sayekti Wahyuningsih, MSi Sebelas Maret University, Indonesia Dr.Desi Suci Handayani, M.Si. Sebelas Maret University, Indonesia Prof. Dr. Santiago Gómez-Ruiz
Rey Juan Carlos University, Móstoles (Madrid), Spain
Prof. Ko Tzu Hsiang Lung Hwa University, Taiwan Prof. Dato Dr. Burhanuddin Yeop
Majlis
Universiti Kebangsaan Malaysia (UKM), Malaysia
Prof Roger Narayan Joint Department of Biomedical Engineering, University of North
Carolina/North Carolina State University, USA
Dr. Agus Supriyanto, S.Si. M.Si Sebelas Maret University, Indonesia Dr. Eng. Risa Suryana, S.Si. M.Si. Sebelas Maret University, Indonesia Dr.rer.nat Witri Wahyu Lestari, M.Sc.
Sebelas Maret University, Indonesia Teguh Endah Saraswati, M.Sc, Ph.D Sebelas Maret University, Indonesia Dr. Tetri Widiyani, M.Si. Sebelas Maret University, Indonesia Dr. Artini Pangastuti, M.Si. Sebelas Maret University, Indonesia
CONFERENCE COMMITTEE/ORGANIZER
Scientific
Committee
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Materials Chemistry and Physics (MCP)
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International Conference on Advanced Materials for Better Future 2018 15–16 October 2018, Solo Paragon Hotel, Indonesia
011001 OPEN ACCESS
PREFACE
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011002 OPEN ACCESS
Conference Committee/Organizer View article PDF Open abstract
011003 OPEN ACCESS
Peer review statement
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012001 OPEN ACCESS
Color Stability of Anthocyanins Copigmentation from Red Rice (Oryza sativa L.) Bran by Spectrophotometry UV-Vis E V Maylinda, A Rinadi, E A Putri, G Fadillah and S Wayuningsih
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012002 OPEN ACCESS
Synthesis and Characterization of Some Bromochalcones Derivatives V H E Susanti and W A E Setyowati
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012003 OPEN ACCESS
Facile Synthesis of Carboxylated Activated Carbon Using Green Approach for Water Treatment L Mahardiani, S Saputro, F Baskoro, N M Zinki and M Taufiq
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012004 OPEN ACCESS
Synthesis and characterization of hematite (α-Fe O ) from lathe waste using co-precipitation -calcination method L M Khoiroh, M N Al-Chabib and A Prasetyo
2 3
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012005 OPEN ACCESS
Synthesis and characterization of chitosan-pectin as adsorbent of dyes B Hastuti, S Hadi, S N Afifah and B Mulyani
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Synthesis of Sodalite from Indonesian Kaolin with Conventional and Alkali Fusion Method S N Khalifah, M Cahyawati, D K D Cahyani, A Arifah and A Prasetyo
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Synthesis and characterization complex Cobalt(II) with sulfadiazine M K Widowati, S B Rahardjo, S Hastuti and B F Ariyani
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Synthesis and Characterization Complex Nickel(II) with Diphenylamine Y A Rasyda, S B Rahardjo and F Nurdiyah
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Functional Materials (FM)
012009 OPEN ACCESS
Structure and Morphology of The (Ni, Co) Mo/Indonesian Natural Zeolite G M H A Ichsan, K D Nugrahaningtyas, D M Widjonarko and F Rahmawati
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012010 OPEN ACCESS
Surface modification of activated carbon using an atmospheric pressure dielectric barrier discharge (DBD) plasma jet R W Lubis, T E Saraswati, U H Setiawan and K Kusumandari
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012011 OPEN ACCESS
Synthesis of nanosize manganese oxides from its ore using solvothermal method
F D Y P Abi, R Kusumaningrum, W B Widayatno, A S Wismogroho, A Noviyanto, N T Rochman and M I Amal View article PDF
Open abstract
012012 OPEN ACCESS
Local Wood's Bio-Oil Upgrading Using Non-sulfided (Co, Mo)/USY Catalyst K D Nugrahaningtyas and E Prasetyorini
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012013 OPEN ACCESS
Identification of chemical structure of anthocyanin and other active substances of red color melinjo peels by FTIR and LC-MC analysis E Tarmizi, A Z E Putri, M A Nusandari, Y A Husnil, R Saragih and L H Lalasari
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012014 OPEN ACCESS
The influence of scale-up treatment from red color melinjo peels mass on the produced anthocyanin characteristics E Tarmizi, A Z E Putri, M A Nusandari, Y A Husnil, R Saragih and L H Lalasari
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012015 OPEN ACCESS
Influence of Cd, Mn, and Co addition on the structural and optical properties of TiO crystal S Wahyuningsih, C Purnawan and D N Aisyah
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012016 OPEN ACCESS
Textile Wastewater Treatment by Using Plasma Corona Discharge in a Continuous Flow System M Amrial, K Kusumandari, T E Saraswati and Y H Suselo
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012017 OPEN ACCESS
Synthesis and characterization of vanadium doped Bi Ti O as photocatalyst material R Handayani, W N Safitri, N Aini, A Hardian and A Prasetyo
4 3 12
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012018 OPEN ACCESS
Synthesis Of Imprinted Ionic Material (SiO2(BGS/RHA)-TMPDT-Im-Au) For Adsorption Of Ion Au(III) S Hastuti, S Wahyuningsih, T Martini and I N Hayati
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012019 OPEN ACCESS
Patterned Porous Silicon Prepared by Reactive Ion Etching Technique R Suryana, N D Pratiwi, M Handayani, M Santika and O Nakatsuka
View article PDF Open abstract
012020 OPEN ACCESS
The effectiveness of the activated carbon from coconut shell and corn cob to adsorb Pb(II) ion and it's analysis using solid-phase spectrophotometry S Saputro, L Mahardiani, M Masykuri and A Z Jazuli
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012021 OPEN ACCESS
Properties of biosurfactant produced by Pseudomonas putida grown in Crude Palm Oil (CPO) V Suryanti, D S Handayani, A Masykur and Lindasari
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012022 OPEN ACCESS
Optimization of the use of fly ash and natural zeolite activated as composite for an adsorbent of lead heavy metal (Pb) Pranoto, T Martini, B M W Sunardi and E P Anandita
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Advanced Nanomaterials (ANM)
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012023 OPEN ACCESS
I-V characteristics on G4 DNA molecule: Electric field and current dependent hopping amplitude model E N Sinurat and E Yudiarsah
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012024 OPEN ACCESS
Influence of magnetic and electric field on I-V characteristic of the G4 DNA molecule L Apriyanti and E Yudiarsah
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012025 OPEN ACCESS
Modelling electric field influence on density of states (dos) and localization length of poly(da)-poly(dt) dna F Rahmani and E Yudiarsah
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012026 OPEN ACCESS
Utilization of Yogyakarta natural zeolites to reduce NH and NO levels in shrimp pond water and its kinetic rate study D D Anggoro, L Buchori, I Sumantri, Ivan, D A B Sejati and H Oktavianty
4 2
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012027 OPEN ACCESS
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012028 OPEN ACCESS
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Improving method of TiO -Fe O composite materials for self-cleaning glass preparation J P Ramadhani, S Wahyuningsih and A H Ramelan
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012030 OPEN ACCESS
Improving preparation method of TiO -NiO composite materials for self-cleaning glass I Farichah, S Wahyuningsih and A H Ramelan
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A control of TiO nanostructures by hydrothermal condition and their application: a short review R Hidayat, G Fadillah and S Wahyuningsih
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One Pot and Sonically Assisted Synthesis of Fe O and SiO @Fe O OA Saputra, WW Lestari and FR Wibowo
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Comparative Study of three non-destructive techniques for metal loss inspection in pipe walls J L Quiroga, J E Quiroga and P P Diaz
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International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 012026
IOP Publishing doi:10.1088/1757-899X/578/1/012026
1
Utilization of Yogyakarta natural zeolites to reduce NH 4 and NO 2 levels in shrimp pond water and its kinetic rate study
D D Anggoro 1 , L Buchori 1 , I Sumantri 1 , Ivan 1 , D A B Sejati 1 , H Oktavianty 1
1
Department of Chemical Engineering, Diponegoro University, Semarang, 50275, Indonesia
E-mail: [email protected]
Abstract. Natural zeolite is an unique crystal that has a very small and uniform pore size when compared to other adsorbents, such as activated carbon and silica gel. This study aims to determine the potential of natural zeolite as an adsorbent, to absorb toxic gases in pond water, especially shrimp ponds and to study its kinetics rate of NH
4and NO
2adsorption. This study consisted of two stages: activated zeolite using NaOH, and tested the absorption power of NH
4and NO
2gases. Zeolite was activated using NaOH where 25 grams of zeolite were mixed with 0.5N NaOH and heated for 2 hours at 70
oC, then stirred and dried in an oven at 110
oC for 4 hours. Then zeolite was cooled in a desiccator. The results of NH
4and NO
2gas adsorption showed that natural zeolites can reduce NH
4and NO
2gas levels in shrimp pond water. The rate constant of pseudo-second-order, and the initial adsorption rate at any given time t, can be predicted from the equation which is full zeolite obtained the best perform of NH
4and NO
2adsorption.
1. Introduction
Development of cultivation systems from traditional to intensive with the majority shrimp ponds have potential towards increasing environmental pollution. Less optimal utilization of excessive feed will cause accumulation of organic matter. Decomposition of organic matter requires oxygen in the process, so that the availability of oxygen for the biota in it is reduced. If this happens continuously it will cause death for shrimp and other biota. Pollution materials that are difficult to decompose by microorganisms also cause hoarding and result in damage to the environment which will directly disrupt organisms that live in these environments. Organic pollution materials that function as fertilizers are actually detrimental due to algae blooms and aquatic plantscausing oxygen competition in the waters. The above factors are the cause of the decline in the body's resistance to the attack of the disease because of the poor quality of the environment, if this is left continuously then mass death will occur so that the population will decline [1].
Traditional methods for nitrogen removal from wastewater are denitrification, nitrification, chemical coagulation, adsorption, selective ion exchange, ammonia stripping, electrodialysis, filtration, reverse osmosis [2, 3, 4, 5]. Removal processes of dissolved nitrogen compounds, can vary.
For intensive RAS (Return Activated Sludge), the most common practice involves utilizing nitrifying
bacteria to convert ammonia-nitrogen to nitrate-nitrogen [6]. The rate limiting step of this process is
the oxidation of ammonia [7]. Incomplete nitrification occurs when a lack of NOB (Nitrite Oxidizing
Bacteria) productivity is present, leading to increased concentrations of nitrite. The adsorption process
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Published under licence by IOP Publishing Ltd
International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 012003
IOP Publishing doi:10.1088/1757-899X/578/1/012003
1
Facile Synthesis of Carboxylated Activated Carbon Using Green Approach for Water Treatment
L Mahardiani 1* , S Saputro 1 , F Baskoro 2,3 , N M Zinki 1 , and M Taufiq 1
1
Department of Chemistry Education, Faculty of Teacher Training and Education, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan, Surakarta, Indonesia
2
Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30010, Taiwan (ROC)
3
Institute of Chemistry, Academia Sinica, Taipei 11529, Taiwan (ROC)
E-mail: [email protected]
Abstract. A chemical treatment by using oxidizing agents is the most common methodology to modify or create functional groups on activated carbon. The modified activated carbon obtained from chemical oxidation needs further treatment and produced waste, therefore a new approach is needed. A facile green approach is reported. In this approach the activated carbon was oxidized using air without additional chemical treatment to increase the content of acidic surface functional groups, especially carboxyl groups. The formation of carboxyl groups was confirmed by Temperature Programmed Decomposition, Boehm titration, and Infra-red spectroscopy results. The Boehm titration result showed higher contents of carboxyl groups by three-fold. The carboxylated activated carbon synthesized by green approach showed excellent performance for water treatment.
1. Introduction
Activated carbon (AC) is a common term used to describe carbon-based materials produced from various carbonaceous rich materials, such as wood, coal, lignite and coconut shell [1]. Activated Carbon is inexpensive and have been applied for many purposes, and as an adsorbent is one of it. It has been proven that AC is an excellent adsorbent for organic and inorganic pollutant removal for both in aqueous or gaseous environment [2,3]. However, it is believed that it is important to enhance the effectiveness of AC as adsorbent for specific usage. Therefore, the modification of surface of AC is necessary to develop affinity for certain contaminant [4]. One of the methods to modify is by chemical activation since it able to create acidic functional groups onto the surface of activated carbon [5, 6].
Regardless of the advantage of chemical activation, the waste that produced after its activation can not be avoided. Recently the synthesize and modification of materials is based on the green chemistry principles. Green chemistry offers an alternative to the traditional environment protection agenda, such as preventing waste production and minimizing the use of reagents and solvents [7].
Air oxidation is one alternative to alter the surface [6,8]. This method is facile since AC was
oxidized only by using the air to create the acidic functional groups such as carboxylic, phenolic, and
lactone [9]. In addition, there was no waste produced and use no reagents or solvents during the
oxidizing process. There are some experimental techniques that able to identify the formation of
functional groups crafted onto the surface of AC. Infra-red spectroscopic methods also applicable to
distinguished different functional groups based on the bands observed at different wavenumbers.
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Published under licence by IOP Publishing Ltd
International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 012019
IOP Publishing doi:10.1088/1757-899X/578/1/012019
1
Patterned Porous Silicon Prepared by Reactive Ion Etching Technique
R Suryana
1, N D Pratiwi
1, M Handayani
1, M Santika
1and O Nakatsuka
21
Department of Physics, Faculty of Mathematics and Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A Kentingan Surakarta 57126, INDONESIA
2
Department of Materials Physics, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, JAPAN
E-mail: [email protected]
Abstract. A previous study, porous silicon (PSi) have been fabricated by electrochemical anodization method. The PSi surfaces have an inhomogeneous pores size in the range of 95–
1450 nm. In this study, we have prepared patterned PSi using RIE technique in CF
4gas which is activated by RF plasma. Before the RIE process, the surfaces Si was patterned using the photolithography method. Then, the Si surfaces were etched in various etching time to form patterned PSi. The patterned PSi samples were characterized by SEM, Dektak profilometer, and four-point probe equipment. We found the pore sizes and the pore depths for each the etching time were about 5.30 m and 12.6 nm; 5.19 m and 19.6 nm; 4.30 m and 23.8 nm;
3.40 m and 28.0 nm for 10 min, 20 min, 30 min, and 40 min, respectively. The pores depths increased with increasing the etching time. Meanwhile, the resistivity of patterned PSi increased with increasing the etching time i.e., 1.14×10
-4.cm, 1.79×10
-4.cm, 2.36×10
-4.cm, and 2.60×10
-4.cm for 10 min, 20 min, 30 min, and 40 min, respectively. This indicated that the pore could be considered as defects or dislocation inside material which resist electrons diffuse toward the electrode.
1. Introduction
Due to porous silicon (PSi) has good physical, chemical, and optical properties that can be applied in
electronic and optic devices, research on PSi from year to year is increasing [1-7]. The previous study,
we have fabricated PSi using the electrochemical anodization method on Si(100) surfaces [8]. The
pores have an inhomogeneous pores size in the range of 95 nm–1450 nm. In addition, there were two
groups of pores, i.e., the spherically shaped pores and the irregular shaped pores. The inhomogeneous
pores size and the irregular shaped pores can be difficult in the device applications because the PSi
fabrication is unreproducible. Therefore, in this research, the regular PSi fabrication has been
conducted by a combination of photolithography and reactive ion etching (RIE) techniques. These
techniques have good control of homogenous size and shape, porosity and depth pore of the Si
surfaces [9]. The patterned PSi samples were characterized by the scanning electron microscopy
(SEM) to observe the pore shapes and sizes, the Dektak profilometer to measure the diameter and the
depth of pores, and the four-point probe (4PP) equipment to calculate the resistivity of pores.
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International Conference on Advanced Materials for Better Future 2018 IOP Conf. Series: Materials Science and Engineering 578 (2019) 012097
IOP Publishing doi:10.1088/1757-899X/578/1/012097
1
Comparative Study of three non-destructive techniques for metal loss inspection in pipe walls
J L Quiroga
1, J E Quiroga
2and P P Diaz
11
Facultad de Ingeniería Mecatrónica, Universidad Santo Tomás, Cra 27 Calle 9, Bucaramanga, Colombia
2