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CH-01

December - Examination 2018 B.Sc. Pt. I Examination

Inorganic Chemistry Paper - CH-01

Time : 3 Hours ] [ Max. Marks :- 50

Note: The question paper is divided into three sections A, B and C. Write answers as per the given instructions.

{ZX}e : àíZ nÌ VrZ IÊS>m| "A', "~' Am¡a "g' ‘| {d^m{OV h¡& à˶oH$ IÊS>

Ho$ {ZX}emZwgma àíZm| Ho$ CÎma Xr{OE&

Section - A 10

×

1 = 10 (Very Short Answer Type Questions)

Note: Answer all Questions. As per the nature of the question delimit your answer in one word, one sentence or maximum up to 30 words. Each question carries 1 mark.

IÊS> - "A' (A{V bKw CÎmar¶ àíZ)

{ZX}e : g^r àíZm| Ho$ CÎma Xr{OE& Amn AnZo CÎma H$mo àíZmZwgma EH$ eãX,

467

(2)

CH-01 / 900 / 5 (2) (Contd.)

(ii) Define solvation energy.

{dbm¶H$Z D$Om© H$mo n[a^m{fV H$s{OE&

(iii) Which bond is formed by collateral-overlapping of p-p orbitals?

p-p

H$jH$m| Ho$ g‘nmpíd©H$ A{Vì¶mnZ go H$m¡Zgm ~§Y ~ZVm h¡?

(iv) Why the surface of freshly cut metal is shiny?

YmVwAm| H$s VmOm H$Q>r gVh, M‘H$Xma ³¶m| hmoVr h¡?

(v) Give formula for calculation of % ionic character?

%

Am¶{ZH$ JwU H$s JUZm H$m gyÌ Xr{OE&

(vi) What is the energy gap between 1S and 2P band called?

1S

d

2P

~¡ÊS> Ho$ ‘ܶ D$Om© A§Vamb H$mo ³¶m H$hVo h¢?

(vii) What are Crown Ethers? Give one example.

H«$mCZ B©Wa ³¶m h¢? EH$ CXmhaU Xr{OE&

(viii) Why the alkali metals are strong reducing agents?

jma YmVwE± à~b AnMm¶H$ ³¶m| hmoVr h¢?

(ix) Give full name and structure of EDTA.

EDTA

H$m gånyU© Zm‘ d g§aMZm Xr{OE&

(x) How will you obtain B2H6 from BF3.

Amn

BF3

go

B2H6

H¡$go àmßV H$amoJo?

(3)

Section - B 4

×

5 = 20 (Short Answer Type Questions)

Note: Answer any four question. Each answer should not exceed 200 words. Each question carries 5 marks.

(IÊS> - ~) (bKw CÎmar¶ àíZ)

{ZX}e : {H$Ýhr§ Mma àíZm| Ho$ CÎma Xr{OE& Amn AnZo CÎma H$mo A{YH$V‘

200 eãXm| ‘| n[agr{‘V H$s{OE& à˶oH$ àíZ 5 A§H$mo§ H$m h¡&

2) What is lattice energy? Discuss the factors affecting lattice energy.

OmbH$ D$Om© ³¶m h¡? Bgo à^m{dV H$aZo dmbo H$maH$m| H$s {ddoMZm H$s{OE&

3) What are semiconductors? Discuss its types with suitable examples.

AÕ©MmbH$ ³¶m h¢? BgHo$ àH$ma CXmhaU g{hV g‘PmBE&

4) BaSO4 is insoluble in water while MgSO4 is soluble, Why?

BaSO4

Ob ‘| A{dbo¶ h¡ O~{H$

MgSO4

{dbo¶, ³¶m|?

5) Explain type of hybridisation, no of unpaired electrons and geometry of NH3 molucule?

NH3

AUw ‘| g§H$aU H$m àH$ma, EH$mH$s Bb¡³Q´>mZ H$s g§»¶m d Á¶m{‘{V g‘PmB¶o&

6) How does the Molecular orbital theory is better than valence bond

(4)

CH-01 / 900 / 5 (4) (Contd.)

8) What do you mean by Na/K pump? Explain its function.

Amn

Na/K

nån go ³¶m g‘PVo h¢? BgH$m H$m¶© g‘PmBE&

9) What are borohydrides? Explain with examples.

~moamoS>mBS´>mBS> ³¶m h¢? CXmhaU g{hV g‘PmB¶o&

Section - C 2

×

10 = 20 (Long Answer Type Questions)

Note: Answer any two questions. You have to delimit your each answer maximum upto 500 words. Each question carries 10 marks.

(IÊS> - g) (XrK© CÎmar¶ àíZ)

{ZX}e : {H$Ýhr§ Xmo àíZm| Ho$ CÎma Xr{OE& AnZo CÎma A{YH$V‘ 500 eãXm| ‘|

n[agr{‘V H$s{OE& à˶oH$ àíZ 10 A§H$mo§ H$m h¡&

10) Discuss valence bond theory taking example of hydrogen molecule.

Also explain its limitation.

hmBS´>moOZ AUw H$m CXmhaU boVo hþE g§¶moOH$Vm ~§Y {gÕm§V g‘PmBE&

BgH$s gr‘mE± ^r g‘PmBE&

11) What are electron deficient compounds? Explain the formation of three centered - 2 electron bond in diborane. Draw suitable diagram.

Bb¡³Q´>mZ ݶyZ ¶m¡{JH$ {H$go H$hVo h¢? S>mB~moaoZ ‘| 3 Ho$ÝÐ-2 Bb¡³Q´>m°Z

~§Y H$m {Z‘m©U {H$g àH$ma hmoVm h¢? C{MV {MÌ ~ZmBE&

(5)

12) What are inter-halogen compounds? Give one method of preparation example and geometry each of AB3 and AB6 type compounds. Also discuss the structure of IF5 and IF7.

AÝVa hobmoOZ ¶m¡{JH$ ³¶m h¢?

AB3

d

AB6

àH$ma Ho$ ¶m¡{JH$m| H$s EH$

- EH$ {daMZ {d{Y, CXmhaU d g§aMZm Xr{OE& {ZåZ H$s g§aMZm ^r g‘PmB¶o -

IF5

d

IF7.

13) Discuss the elements of S-block on following basis:

S-

ãbmH$ Ho$ VËdm| H$s {ZåZ AmYma na ì¶m»¶m H$s{OE&

(i) Ionisation Potential /

Am¶ZZ {d^d

(ii) Electronic Configuration /

Bb¡³Q´>m{ZH$ {dݶmg

(iii) Oxidation state /

Am³grH$aU AdñWm

(iv) Atomic radii /

na‘mÊdr¶ {ÌÁ¶m

Referensi

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