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EXPERIMENTAL STUDIES OF PHYSICAL PROPERTIES OF FERROELECTRIC LIQUID CRYSTALS

A thesis submitted to the Bangalore University

for the Degree of

portor uf #ll$loeoplg

in the Faculty of

Science

BY

SHARANABASAVA M. EHENED

Liquid Crystal Laboratory RAMAN RESEARCH INSTITUTE

Bangalore - 560

080,

India

NOVEMBER 1992

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Dedicated To

My Mother

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DECLARATION

I hereby declare that the entire work embodied in this thesis is t h e result of the

investigations carried out by me independently in the Liquid Crystal Laboratory, Raman

Research Institute, Bangalore, and that no part of it has been submitted for the award

of any Degree, Diploma, Associateship, Fellowship or any other similar title.

A

.. --_1)

SHARANABASAVA M. KHENED

"CERTIFIED"

Professor N.V.MADHUSUDANA Head

Liquid Crystal Laboratory Raman Research Institute

BANGALORE 560080

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CERTIFICATE

I certify that this thesis has been composed by Mr. Sharanabasava M. Khened based

on the investigations carried out by him at the Liquid Crystal Laboratory, Raman Re-

search Institute, Bangalore, under my supervision. The subject matter of this thesis has

not previously formed the basis of the award of any Degree, Diploma, Associateship,

Fellowship or other similar title.

Professor S. CHANDRASEKHAR Liquid Crystal Laboratory Raman Research Institute BANGALORE 560080

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ACKNOWLEDGEMENTS

T h e work presented in this thesis has been carried out under t h e supervision of Professor S.Chandrasekhar F.R.S. Working under hinl ha.s been a rich and rewarding experience and

I

consider myself fortunate to have had this unique opportunity. I a m deeply indebted to him for his unfailing inspiration, guidance a n d help through t h e years.

I a m very grateful to Prof. N.V.Madhusudana for evincing interest i11 the progress of m y work and for providing the necessary facilities t o me.

I wol~ld like t o express my sincere t,l~anks to Dr.S.I<rishna Prasad for his invalu- able help, friendly advice and inspiring discussions. This work could not have gone so well without his help. I owe him a lot.

My special thanks are due to Prof. R. Shashidhar with whom I was associated a t t h e beginning and to Dr. V. N. Raja. for his help with t h e Xray experiments. It is a pleasure to thank my co-workers Ms. Geetha G. Nair and Mr.

D.

S Shankar Rao who were.always ready with a helping hand for any of my needs. Their cooperation and friendliness has made my stay in t h e Lab more enjoyable and fruitful.

My thanks are due to Dr.B.I<.Sadashiva and Mr.B.Shivkumar for kindly provid- ing m e the samples; to Mr.I<.Subramanya and Mr.H.Subramonyam for their help in preparing t h e sample cells; to Mr. P.N.Ramachandra and Mr.M.R.Suhrahmanyam for their support in various ways; t o Mr.V.Nagaraj for his help in t h e design a n d fabrication of the sample oven; to Messrs. Mani, Majeed, Ishaq and Dhason for technical assistance; to Dr. A. Ratnakar and the staff of the RRI Library for their courteous help in getting hold of the literature and for t h e excellent xeroxing of t h e text and drawings of this thesis; to Mr.C.R.Ra~llaclla~ldra Rao a n d Mr.Itaju for their assistance in preparing the figures.

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My teacher colleagues Mr.P.R.Mahes11wara Murthy and Ms.

H.

P. Padmini, and also Ms. I<.Usha, who along with all the other friends, made t h e days I have spent in Lab the most memorable. My gratitude to all of them.

My profound thanks to Mr.S.Raghavachar for his kind help in t h e official matters.

Its my duty to thank the Management of the Taranatha Shikshana Samsthe Raichur and the Principal and the members of the Governing Body of L.V.D.College Raichur, for sponsoring my name for the Teacher Fellowship and for providing me an opportunity to work for my Ph.D. I am thankful to the University Grants Com- mission, New Dellli, for awarding the fellowship. 1 owe a lot to Mr.D.R.Baluragi and my other colleagues at L.V.D.College for their help in a number of ways, I thank them all.

I a m most grateful to my father, to whom this thesis is a dream come true, who has always been a source of inspiration to me. I take this opportunity to thank my brother Shiva.prasad who forced me to take up this venture and helped me in bringing it to a successful completion. I also thank my father-in-law Sri D.Virupaksha Gouda for encouragi~lg me to do research.

Finally I would like to thank my wife Pallavi who is mainly responsible for my undertaking this task. She along with my son Chaithanya always kept me in good spirits throughout these four years. It was entirely because of their many sacrifices that I was able to concentrate on the research work. The main credit of this thesis should go to tlicrri; without Pallavi, I am sure, I woultl not 11avc cotnl,lct,cd t,liis task.

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CONTENTS

Chapter I

Chapter I1 Measurement of spontaneous polarisa- tion

Chapter I11 Dielectric studies in the vicinity of the A-C* transition

Chapter IV Determination of rotational viscosity in the smectic C* and smectic A phases

Chapter V Experi~nental studies in the vicinity of the C*

-

I* transition

Chapter VI High pressure studies on ferroelectric

liquid crystals

Referensi

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