Chapter 2
Atoms, Molecules and Ions
CHAPTER 2 (P.49-68)
• Atomic number , mass number and isotopes.
• The periodic table .
• Molecules and ions .
• Chemical formulas .
• Naming compounds
Atomic Structure
Elements: are composed of extremely small particles called atoms.
ضِرْلأَا يفِ لاَوَ تِاوَامَ سَّلا يفِ #ةٍ رْذَ &لُاقَثْمِ &هُنْعَ &بُ &زُعْيَ لاَ{
:أبس( } #نٍيب:مِ #بُاتَكِ يفِ لاَإِ &رُبكِأَ لاَوَ كَلذَ نٍمِ &رُغَصْأَ لاَوَ
3 .)
Atom: is the basic unit of an element that can enter into chemical combination
Atom consists of:
Electron (e) (-ve charge) Proton (p) (+ve charge) Neutron (n) (neutral)
Subatomic Particles
mass p = mass n = 1840 x mass e
-2.2
2.3 Atomic number , mass number
and isotopes.
Atomic number (Z) = number of protons in nucleus.
A
X
Z
1
H
1 126
C
8336Kr
Mass Number
Atomic Number Element Symbol
2.3
In the neutral atom: the No. of protons is equal the No. of electrons .
So the atomic number also= No. of electrons .
Mass number (A) = number of protons + number of neutrons = atomic number (Z) + number of neutron
No. of neutron= mass No. (A)- atomic No. (Z)
4
He
2
Examples :
elements
Atomic Number (Z) 11 11 8 6 80
Mass Number (A) 20 22 17 14 200
No. of electrons (e) 11 11 8 6 80
No. of protons (p) 11 11 8 6 80
No. of neutrons (n) 9 11 9 8 120
Give the number of protons, neutrons, and electrons in each of the following species:
Example 2.1
20Na
11 22Na
11 17O
8 14C
6 200Hg
80
Define the element 6329X?
The element with atomic number 29 is cupper (Cu) and its mass number is 63
6 protons, 8 =(14 - 6) neutrons, 6 electrons
Do You Understand Isotopes?
How many protons, neutrons, and electrons are in 146C ?
How many protons, neutrons, and electrons are in 116C ? 6 protons, 5 =(11 - 6) neutrons, 6 electrons
Isotopes are atoms of the same element (X) with different numbers of neutrons in their nuclei
1
H
1 21
H (D)
31H (T)
235
U
92 23892
U
12
C
6 136
C
146C
examples :
Isotopes of an atom have essentially the same chemical behavior .
1 P 1 P 1 P 0 n 1 n 2n
Isotopes of Hydrogen
12
C
6 136
C
146C
Isotopes of an atom have essentially the same chemical behavior .
235
U
92 23892
U
uranium-235 uranium-238
Practice Exercise:
How many protons, neutrons, and electrons are in the following isotopes
Practice Exercise:
How many protons, neutrons, and electrons are in the following isotope of copper: 63Cu?
How can I get the atomic number: look at the periodic table
→ then find the number of p, n & e.
63
Cu
29
P=29 n=34
e=29
Allotrope is one of tow or more distinct forms of an element as O2 , O3 .
Allotropes
O-O (O2) and O3
Allotropes are different structural forms of the same element and can exhibit quite different physical properties and chemical behaviors.
Allotropes
Graphite Diamond
the carbon atoms are bonded together in sheets of a
hexagonal lattice arrangement.
the carbon atoms are bonded together in a tetrahedral lattice arrangement.
allotropes of an element differ on the structure of the same atoms, (i.e. how the atoms are arranged).
isotopes of the element differ on the number of
neutrons of the atoms (i.e. the composition of subatomic particles in an atom).
The Difference between Allotropes and Isotopes
2.4 The periodic table
Period
Group
Alkali Metal Noble Gases
Halogen
Alkaline Earth Metal
2.4
Periodic Table
The periodic Table: is a chart in which elements having similar chemical and physical properties are grouped
together.
The elements in the modern periodic table are arranged by
atomic number
Metal
Metalloid Nonmetal
.
.
.
• Positive ions are called:
a. positrons.
b. anions.
c. cations.
d. nucleons.
• The elements located in group 7A of the periodic table are called:
a. alkali metals.
b. noble gases.
c. chalcogens.
d. halogens.
What are the ions present in the compound (NH4)2SO4 ?
NH3, H2, and SO2
N3–, H+, S2–, O2–
NH42+ and SO4–
NH4+ and SO42– (3 IONS)
(NH4+)2 and SO42–
1- Selenium (34Se) element is:
(a) a nonmetal
(b) found in group 6A (c) both a and b
2- Gallium (Ga) element is found in the periodic table in
(a) period 3, group 1B (b) period 3A, group 4 (c) period 4, group 1A (d) period 4, group 3A
3- Which of the following sets of
elements is expected to have similar chemical properties?
a) Sulfur and phosphorous b) Sulfur and oxygen
c) Sulfur and argon
4- Which of these elements is most likely to be a good conductor of
electricity?
Which of the following is metal?
A. N
B. S
C. He
D. Fe
Chemistry In Action
Natural abundance of elements in Earth’s crust
Natural abundance of elements in human body
2.4
2.5 MOLECULES AND IONS.
H2 H2O NH3 CH4
The monatomic gases are the single atoms of noble gases; He, Ne, Ar, Kr, Xe, Rn.
A molecule is an aggregate of two or more atoms in a definite arrangement held together by chemical forces.
Diatomic molecule: contains only two atoms
H2, N2, O2, Br2, HCl, CO, NO, KCl
Polyatomic molecule:
contains more than two atoms
O3, H2O, NH3, CH4 ,NaOH
Molecule
Cation
an ion with a +ve charge (lose electron/s)
Na+, K+, Mg2+
Al3+, N3-
Anion
an ion with a -ve charge ( Gain electron/s)
Ion
Monoatomic cation Polyatomic cation Monoatomic anion Cl-, Br-,S2-
Polyatomic anion OH-, PO43-
NH4+
Ion
is an atom, or group of atoms, that has a net positive or negative charge.• Which of the following is an example of
polyatomic cation?
• A) Mg+2
• B) NH4+1
• C)O-2
• D) SO4-2
• Which of the following is an example of monatomic anion?
• A) Mg+2
• B) NH4+1
• C)O-2
• D) SO4-2
11Na electronsprotons 1111 +11Na electronsprotons 1110
17Cl electronsprotons 1717 -17Cl electronsprotons 1718
Cation
anion
11Na electronsprotons 1111 +11Na electronsprotons 1110
17Cl electronsprotons 1717 -17Cl electronsprotons 1718
Cation
anion
13 protons, 10 (13 – 3) electrons
34 protons, 36 (34 + 2) electrons
Do You Understand Ions?
How many protons and electrons are in ?1327Al 3+
How many protons and electrons are in ?7834Se2-
3 27
13 Al
2 78
34
Se
2.5
Different Ions of Some Elements
Metals tend to form cations
Nonmetals tend to form anions
Nonmetals are on the right side of the periodic table (with the exception of H) (blue).
Metalloids border the stair-step line (with the exception of Al, Po, and At).
Metals are on the left side of the chart (green color)
31P
15 3- 11B
5 196Au
79 222Rn 86
26 54-26=28
26-2=24 2+
0 0
18- 3=15
86
2.6 CHEMICAL FORMULAS.
2.6
ةغَيصلا ةيئيَزُجلا
ةغَيصلا ةيئانْبلا
جذَومَن ةٍرُكلا اصعْلاوَ
جذَومَن ءلمِ
غارُفلا
A molecular formula shows the exact number of atoms of each element in the smallest unit of a substance
An empirical formula shows the simplest whole-number ratio of the atoms in a substance
H2O H2O
molecular empirical
C6H12O6 CH2O
O3 O
N2H4 NH2
ةيلوَلأَا ةغَيصلا ئزُجلل ةٍرْوصْ طسَّبأَ
دوجوَ بسَّن يطعْت ئزُجلل ةنوكمَلا تِارْذلا نٍمِ سيلوَ ةبسَّن رُغَصْأب
يطعْت نأَ يرْوَرُضلا تِارْذلل حيحصلا ددعْلا
ةيئيَزُجلا ةغَيصلا
حيحصلا ددعْلا ىلعَ يوتَحت لخديَ رُصنْعَ لكِ تِارْذَ نٍمِ
هدحوَ رُغَصْأَ بيكِرُت يفِ
)ئزُجلا( ةٍدامَلا يفِ
ةيئيَزُجلا ةغَيصلا نٍمِ
ةغَيصلا داجيَإِ عيطتَسَّن رُيغ سكعْلاوَ ةيلوَلأَا
حيحصْ
• The Empirical Formula may the same or different from the Molecular Formula
• How can we get the Empirical Formula?
• Answer: Divide all the numbers by the largest Common devisor.
• e.g. The empirical formula of H2O is H2O
• e.g. the empirical formula of C6H12O6 is CH2O (divide the numbers 6, 12 and 6 by the largest common devisor 6)
It must be noted that :
• Write the Empirical formulas for the following molecules
Acetylene C2H2 divided by 2 CH
Glucose C6H12O6 divided by 6 CH2O
Nitrous oxide N2O , the Empirical formulas is same as molecular formula N2O
Caffeine C8H10N4O2 divided by 2 C4H5N2O
EXAMPLE 2.3
Examples
• Which of the following is empirical formula
A. O3 >>>>>> O B. H2SO4 C. S8 >>>>>>> S
D. C6H12O6 >>>> CH2O
نكميلا يتلا ةغيصلا بولطملا اهطيسبت اهطيسبت نكميلا ةيناثلا ةباجلاا ةحيحصلا ةباجلاا يه
• Which of the following is molecular formula
A. CO2 B. H2SO4 C. S8
D. CH4O
نكمي يتلا ةغيصلا بولطملا اهطيسبت يتلا هديحولا يه ةثلاثلا ةباجلاا ةباجلاا يه اهطيسبت نكمي ةحيحصلا
O H
H H
H
C C
Cl Cl
Cl
H
CH4O
CH3OH
CHCl3
or
Molecular formula
of Methanol Molecular formula
of Chloroform Write the Molecular formula of Methanol and Chloroform, using the structural formulas below:
Write the empirical formulas for the following molecules if possible:
Compounds Name Molecular Formula Empirical Formula
acetylene C2H2 CH
glucose C6H12O6 CH2O
nitrous oxide N2O N2O
caffeine C8H10N4O2 C4H5N2O
Ionic compounds
• consist of a combination of cations and an anions
• the sum of the charges on the cation(s) and anion(s) in each formula unit must equal zero
Formula of Ionic Compounds
• Write the formula of magnesium nitride?
• Write the formula of a)chromium sulfate , b)titanium oxide?
Mg 3N2
3 × +2 = +6 2 × -3 = -6
Mg 2+ N3-
Cr 2(SO4)3
2 × +3 = +6 3 × -2 = -6
Cr 3+ SO42-
Ti 2O 4
2 × +4 = +8 4 × -2 = -8
Ti 4+ O2-
1. An anion is defined as
A. a charged atom or group of atoms with a net negative charge.
B. a stable atom.
C. a group of stable atoms.
D. an atom or group of atoms with a net positive charge.
2. Atoms of the same element with different mass numbers are called
A. ions.
B. neutrons.
C. allotropes.
D. chemical families.
E. isotopes.
3. How many neutrons are there in an atom of lead 82Pb whose mass number is 208?
A. 82
B. 126
C. 208
D. 290
E. none of them
4. An atom of the isotope sulfur-31 consists of how many protons, neutrons, and electrons?
(p = proton, n = neutron, e = electron) A. 15 p, 16 n, 15 e
B. 16 p, 15 n, 16 e C. 16 p, 31 n, 16 e D. 32 p, 31 n, 32 e E. 16 p, 16 n, 15 e
5. A magnesium ion, Mg2+, has
A. 12 protons and 13 electrons.
B. 24 protons and 26 electrons.
C. 12 protons and 10 electrons.
D. 24 protons and 22 electrons.
E. 12 protons and 14 electrons.
6. A sulfide ion, S2- , has:
A. 16 protons and 16 electrons B. 32 protons and 16 electrons C. 16 protons and 14 electrons D. 16 protons and 18 electrons E. 32 protons and 18 electrons
2.7 NAMING COMPOUNDS.
Page 64
) +)
1 2+))
Naming Ionic compounds
Metals
Positive ion Cation
Non metals Negative ion Anion
( 1A , 2A ,3A & transition metals)
Fixed charge metals
Variable charge metals Cations have
same name as the metal element
Ag+ silver ion ,Zn2+ zinc ion , Al3+ Aluminum ion , Li+ lithium ion , Ca2+ calcium ion
If the metal can form more than 1 cation, the charge is indicated by a Roman numeral in parenthesis after the metal name.
Fe2+ iron(II) ,Au+ gold(I), Cu+ copper(I) , Fe3+ iron(III) Au3+ gold(III) Cu2+ copper (II) Hg2 +2mercury(I) Hg2+ mercury (II)
monoatomic anions
Polyatomic anions
Dr. LAILA AL-HARBI
(STOCK SYSTEM)
Naming Ionic compounds
• 2. Variable charge metals:
• If the metal has more than one oxidation state, the charge is indicated by a Roman numeral in parenthesis after the metal name.
• Most of the transition metals are variable charge metals.
• E.g. Common metals which exist in more than one positive state:
• Fe2+ iron(II) ,Au+ gold(I), Cu+ copper(I) , Fe3+ iron(III) Au3+ gold(III) Cu2+ copper (II) Hg2 +2mercury(I) Hg2+ mercury (II)
• 3. Polyatomic cations: consist of nonmetals:
H3O+ hydronium ion NH4+ ammonium
Dr. LAILA AL-HARBI
Dr. LAILA AL-HARBI
Variable charge metals
Metal (cation)
Divalent elements Monovalent
elements
Lithium (Li+) Sodium (Na+) Potassium (K+) Robidium (Rb+) Silver (Ag+)
Magnisium (Mg2+) Calcium (Ca2+) Strontium (Sr2+) Barium (Ba2+) Lead (Pb2+) Zinc (Zn2+)
trivalent elements
Aluminium (Al3+) Galium (Ga3+)
Transition metals
(Fe2+) iron(II) (Fe3+) iron(III)
(Cr3+) chromium (III) (Cu2+) cupper (II) (Cu+) cupper (I)
(Mn2+) manganese(II) (Mn3+) manganese(III) (Mn4+) manganese(IV) (Mn7+) manganese(VII) (Sn2+) stannous or tin(II) (Hg22+) mercury(I)
(Hg2+) mercury(II)
Common name of metal cation:
NH4+ ammonium
• Some Cations of variable charge have name for each oxidation state
• Example
Fe2+ iron(II) ferrous , Fe3+ iron(III) ferric Cu+ copper(I) cuprous , Cu2+ Copper (II) cupric Hg2 +2mercury(I) mercurous
Hg2+ mercury (II) mercuric
Mercury (Hg) is the only metal has this formula when it form cation with only one positive charge :
Hg22+ NOT Hg+
The cation of two positive charges has the formula Hg2+
NOTE
Dr.
LAIL A AL- HAR
BI
nonmetal (anion)
Hydrogen hydride (H-) Oxygen oxide (O2-) Nitrogen nitride (N 3-)
Metals form only type of cation
Metals form more than one type of cation (Transition Metals)
1. Group 1A )alkaline Metals(: +1
2. Group 2A )alkaline Earth Metals(: +2 3. Group 3A: +3
4. Group 5A: -3 )= 5-8(
5. Group 6A: -2 )= 6-8(
6. Group 7A )halogens(: -1 )= 7-8(
Nonmetals
• 1. monoatomic anions: change ending to -ide
• E.g. Oxygen→Oxide Sulfur → Sulfide
Hydrogen →Hydride chlorine → Chloride Florine → Floride Bromine → Bromide
• Polyatomic anions: most end in -ate or -ite; usually contain O (oxy)
• Know polyatomic anions on handout.
• Carbonate CO3-2 , Nitrate NO3- , Sulfate SO4-2 ,
• Phosphate PO4-3
Cyanide CN- , Hydroxide OH- ,Oxide O2-2
See table 2.3
B. Naming Anions
Nonmetal polyatomic anions
(SO42-) sulfate , (SO32-) sulfite
(NO3-) nitrate (NO2-) nitrite
(PO43-) phosphate (PO33- ) phosphite
(ClO4– ) perchlorate (ClO3- ) chlorate
(HSO4-) hydrogen sulfate or bisulfate
(HPO42-) hydrogen phosphate or biphosphate
(CO32–) carbonate
(HCO3– ) hydrogen carbonate or bicarbonate (H2PO4-) dihydrogen phosphate
تا تاتيربك تي تيتيربك
• Ionic compounds names start with the positive ion (metal) (include Roman numeral in parenthesis ONLY IF metal has variable charge) followed by the negative ion (nonmetal).
• NaCl Sodium Chloride
• BaCl2 Barium Chloride
• K2O Potassium oxide
• KNO3 Potassium Nitrate
• Na2CO3 Sodium Carbonate
• FeCl2 Iron(II) Chloride → ferrous Chloride
• FeCl3 Iron(III) Chloride → ferric Chloride
• Cr2S3 Chromium(III) Sulfide
• (NH4)3PO4 Ammonium Phosphate
• Cu(NO3)2 Cupper(II)nitrate
• PbO Lead(II) oxide
Example 2.5 p61:
Name the following compounds:
(a) Cu(NO3)2
1. Cation: Copper cation (can form two types of cation →Stock system) →
Copper (II)
2. Anion: NO3- anion has a common name Nitrate
Thus: the name of the compound is:
Copper (II) nitrate
لُدابت ةٍدعَاق تِاؤفِاكتَلا
Dr. LAILA AL-HARBI
(b) KH
2PO
41. Cation: K form only one type of cation
→ Potassium Note: not potassium (I) 2. Anion: H2PO4-has a common name dihydrogen phosphate
Thus: the name of the compound is:
Potasium dihydroen phosphate
Dr. LAILA AL-HARBI
• Write the chemical formula for the following
compounds
• Mercury(I)nitrite Hg2 (NO2)2
• Cesium sulfide Ce2S
Calcium phosphate
Ca3 (PO4)2
• Write the chemical formula for the following
compounds
• Rubidium sulfate
• Rb 2 SO4
• Barium hydride
• BaH 2
Name the following ionic compounds:
Cu(NO3)2 KH2PO4 NH4SCN
H2O2 Li2SO3 Ca3(PO3)2 KMnO4
Cupper(II) nitrate
Potassium dihydrogen phosphate Ammonium thiocyanate
Hydrogen peroxide Lithium sulfite Calcium phosphite
Potassium permenganate Hg2Cl2 Mercury(I) chloride
K2CrO4 Potassium chromate Br2O7 Dibromine heptoxide
Write formulas for the following ionic compounds:
MnO K2HPO4 NH4ClO2
Pb(OH)2 NaHCO3 Ba(CN)2 RbHSO4 HgBr2 Manganese(II) oxide
Potassium hydrogen phosphate Ammonium chlorite
Lead hydroxide Sodium bicarbonate Barium cyanide
Rubidium hydrogensulfate Mercury(II) bromide
SrH2 Strontium hydride
• Ionic Compounds
• often a metal (cation) + nonmetal (anion)
• The cation is always named first and the anion second
• anion (nonmetal), add “ide” to element name
ةينويَلأَا تِابكِرُمَلا نم مسلإا نوكتي •
زلفلالا هيلي زلفلا فاضي • ide
زلفلالل
Mg(OH)2 magnesium hydroxide
KCN potassium cyanide
2.7
BaCl2 barium chloride K2O potassium oxide
1. Binary compounds are compounds formed from just two elements
2. Ternary compounds are compounds formed from three elements.
Ionic compounds
Molecular Compounds
Diborane B2H6
Methane CH4
Silane SiH4
Ammonia NH3
Phosphine PH3
Water H2O
Hydrogen sulfide H2S
2- common names of some molecular compounds
ةيئيَزُجلا تِابكِرُمَلا
لا + تازلف هابشأ نم نوكتت •
تازلف تازلف لا + تازلف لا •
ةيئيزجلا تابكرملا مظعم •
نوكتت) رصنعلا ةيئانث نوكت (طقف نيرصنع نم لثم هعئاش ءامسأ هل اهضعب •
H2O, NH3, CH4
هتياهنل فاضي ريخلأا رصنعلا •
ide
1- Consists of (metalloid + nonmetal)
or (nonmetal + nonmetal)
Many molecular compounds are binary compounds
PCl3
SiC
3- last element ends in -ide
4- element further left in periodic table is 1st (less electronegative)
(HCl) H(1A) and Cl(7A), so hydrogen is 1st, the name is
hydrogen chloride
5- element closest to bottom of group is 1st (less electronegative)
(SiC) Si(4A) and C also belongs to
(4A) ,but (Si) is closest to bottom of the group, so silicon is 1st ,
the name is silicon carbide
رصانعلا بتكت •
لودجلا راسي هدوجوملا برقلأا وأ يرودلا .لاوأ راسيلل ةيوتحملا تابكرملا •
نم ةرذ نم رثكأ ىلع نع ربعي رصنعلا سفن رصنعلل تارذلا ددع تائدابلا مادختساب اهل ةينانويلا
6- if more than one compound can be formed from the same elements, use prefixes to indicate number of each kind of atom.
Examples
Note
• Note that mono- is never used for the first element
• For oxides, the ending “a” in the prefix is omitted.
• N2O4 dinitrogen tetroxide not (dinitrogen tetraoxide)
• For oxides, the ending “o” in the prefix is omitted.
• N2O dinitrogen monoxide not (dinitrogen monooxide )
Dr. LAILA AL-HARBI
HI hydrogen iodide
PF3 phosphorus trifluoride H2O2 Hydrogen peroxide
N2O4 dinitrogen tetraoxide
NO2 nitrogen dioxide
N2O dinitrogen monooxide
Examples of Molecular Compounds
2.7 TOXIC!
Laughing Gas
ICl3 Iodine trichloride
Name the following molecular compounds:
SO2 SiCl4 BrF7 P4O10 Cl2O7 CH4 CS2
Sulpher dioxide
Silicon tetrachloride Bromine heptaflouride
Tetraphosphorus decoxide Dichlorine heptoxide
Methane
Carbon disulphide Br2O7 Dibromine heptoxide
Write formulas for the following molecular compounds:
SF4 N2O5 SO3 Si2Br6 PCl5 P4S10 N2O2 Sulphur tetraflouride
Dinitrogen pentoxide Sulfur trioxide
Disilicon hexabromide
Phosphorus pentachloride
Tetraphosphorus decasulphide Nitrogen peroxide
CO Carbon monoxide
IF7 Iodine heptaflouride
Fill the blanks in the following table
name formula anion cation
Barium bicarbonate Ba(HCO3)2 -HCO3 +Ba2 Iron(III)nitrite Fe(NO2)3 -NO2 +Fe3
Hyrdogen flouride HF -F +H
Manganise(IV)oxide MnO2 -O2 +Mn4
Sodium peroxide Na2O2 -O22 +Na
Cesium chlorate CsClO3 -ClO3 +Cs
Lithium nitride Li3N -N3 +Li
• Which of these pairs of elements would be most likely to form an ionic compound?
(a) P and Br (b) Cu and K (c) C and O (d) O and Zn (e) Al and Rb
• Which of these pairs of elements would be most likely to form a molecular compound?
(a) Na and Br (b) C and O (c) Ca and O (d) Zn and O (e) Mg and Cl
8. Which of the following compounds is named lithium carbonate?
A) Na2CO3 B) LiHCO3
C) LiCO
D) Li2CO3
9. What is the name of KClO?
A) potassium chlorite B) potassium chloride C) potassium hypochlorite D) potassium oxide
10. What is the formula for ammonium sulfate?
A) NH4SO4 B) NH4(SO4)2 C) (NH4)2SO4 D) NH4S