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Chapter 2

Atoms, Molecules and Ions

(2)

CHAPTER 2 (P.49-68)

• Atomic number , mass number and isotopes.

• The periodic table .

• Molecules and ions .

• Chemical formulas .

• Naming compounds

(3)
(4)

Atomic Structure

Elements: are composed of extremely small particles called atoms.

ضِرْلأَا يفِ لاَوَ تِاوَامَ سَّلا يفِ #ةٍ رْذَ &لُاقَثْمِ &هُنْعَ &بُ &زُعْيَ لاَ{

:أبس( } #نٍيب:مِ #بُاتَكِ يفِ لاَإِ &رُبكِأَ لاَوَ كَلذَ نٍمِ &رُغَصْأَ لاَوَ

3 .)

Atom: is the basic unit of an element that can enter into chemical combination

(5)

Atom consists of:

Electron (e) (-ve charge) Proton (p) (+ve charge) Neutron (n) (neutral)

Subatomic Particles

(6)

mass p = mass n = 1840 x mass e

-

2.2

(7)

2.3 Atomic number , mass number

and isotopes.

(8)

Atomic number (Z) = number of protons in nucleus.

A

X

Z

1

H

1 126

C

8336

Kr

Mass Number

Atomic Number Element Symbol

2.3

In the neutral atom: the No. of protons is equal the No. of electrons .

So the atomic number also= No. of electrons .

Mass number (A) = number of protons + number of neutrons = atomic number (Z) + number of neutron

No. of neutron= mass No. (A)- atomic No. (Z)

4

He

2

Examples :

(9)

elements

Atomic Number (Z) 11 11 8 6 80

Mass Number (A) 20 22 17 14 200

No. of electrons (e) 11 11 8 6 80

No. of protons (p) 11 11 8 6 80

No. of neutrons (n) 9 11 9 8 120

Give the number of protons, neutrons, and electrons in each of the following species:

Example 2.1

20Na

11 22Na

11 17O

8 14C

6 200Hg

80

Define the element 6329X?

The element with atomic number 29 is cupper (Cu) and its mass number is 63

(10)

6 protons, 8 =(14 - 6) neutrons, 6 electrons

Do You Understand Isotopes?

How many protons, neutrons, and electrons are in 146C ?

How many protons, neutrons, and electrons are in 116C ? 6 protons, 5 =(11 - 6) neutrons, 6 electrons

(11)

Isotopes are atoms of the same element (X) with different numbers of neutrons in their nuclei

1

H

1 21

H (D)

31

H (T)

235

U

92 23892

U

12

C

6 136

C

146

C

examples :

Isotopes of an atom have essentially the same chemical behavior .

1 P 1 P 1 P 0 n 1 n 2n

Isotopes of Hydrogen

(12)

12

C

6 136

C

146

C

Isotopes of an atom have essentially the same chemical behavior .

(13)

235

U

92 23892

U

uranium-235 uranium-238

(14)

Practice Exercise:

How many protons, neutrons, and electrons are in the following isotopes

(15)

Practice Exercise:

How many protons, neutrons, and electrons are in the following isotope of copper: 63Cu?

How can I get the atomic number: look at the periodic table

→ then find the number of p, n & e.

63

Cu

29

P=29 n=34

e=29

(16)

Allotrope is one of tow or more distinct forms of an element as O2 , O3 .

Allotropes

O-O (O2) and O3

Allotropes are different structural forms of the same element and can exhibit quite different physical properties and chemical behaviors.

(17)

Allotropes

Graphite Diamond

the carbon atoms are bonded together in sheets of a

hexagonal lattice arrangement.

the carbon atoms are bonded together in a tetrahedral lattice arrangement.

(18)

allotropes of an element differ on the structure of the same atoms, (i.e. how the atoms are arranged).

isotopes of the element differ on the number of

neutrons of the atoms (i.e. the composition of subatomic particles in an atom).

The Difference between Allotropes and Isotopes

(19)

2.4 The periodic table

(20)

Period

Group

Alkali Metal Noble Gases

Halogen

Alkaline Earth Metal

2.4

Periodic Table

(21)

The periodic Table: is a chart in which elements having similar chemical and physical properties are grouped

together.

The elements in the modern periodic table are arranged by

atomic number

(22)

Metal

Metalloid Nonmetal

.

.

.

(23)

• Positive ions are called:

a. positrons.

b. anions.

c. cations.

d. nucleons.

The elements located in group 7A of the periodic table are called:

a. alkali metals.

b. noble gases.

c. chalcogens.

d. halogens.

What are the ions present in the compound (NH4)2SO4 ?

NH3, H2, and SO2

N3–, H+, S2–, O2–

NH42+ and SO4

NH4+ and SO42– (3 IONS)

(NH4+)2 and SO42–

(24)

1- Selenium (34Se) element is:

(a) a nonmetal

(b) found in group 6A (c) both a and b

2- Gallium (Ga) element is found in the periodic table in

(a) period 3, group 1B (b) period 3A, group 4 (c) period 4, group 1A (d) period 4, group 3A

3- Which of the following sets of

elements is expected to have similar chemical properties?

a) Sulfur and phosphorous b) Sulfur and oxygen

c) Sulfur and argon

4- Which of these elements is most likely to be a good conductor of

electricity? 

Which of the following is metal?

A. N

B. S

C. He

D. Fe

(25)

Chemistry In Action

Natural abundance of elements in Earth’s crust

Natural abundance of elements in human body

2.4

(26)

2.5 MOLECULES AND IONS.

(27)

H2 H2O NH3 CH4

The monatomic gases are the single atoms of noble gases; He, Ne, Ar, Kr, Xe, Rn.

A molecule is an aggregate of two or more atoms in a definite arrangement held together by chemical forces.

Diatomic molecule: contains only two atoms

H2, N2, O2, Br2, HCl, CO, NO, KCl

Polyatomic molecule:

contains more than two atoms

O3, H2O, NH3, CH4 ,NaOH

Molecule

(28)

Cation

an ion with a +ve charge (lose electron/s)

Na+, K+, Mg2+

Al3+, N3-

Anion

an ion with a -ve charge ( Gain electron/s)

Ion

Monoatomic cation Polyatomic cation Monoatomic anion Cl-, Br-,S2-

Polyatomic anion OH-, PO43-

NH4+

Ion

is an atom, or group of atoms, that has a net positive or negative charge.
(29)

• Which of the following is an example of

polyatomic cation?

• A) Mg+2

B) NH4+1

• C)O-2

• D) SO4-2

• Which of the following is an example of monatomic anion?

• A) Mg+2

• B) NH4+1

C)O-2

• D) SO4-2

(30)

11Na electronsprotons 1111 +11Na electronsprotons 1110

17Cl electronsprotons 1717 -17Cl electronsprotons 1718

Cation

anion

(31)

11Na electronsprotons 1111 +11Na electronsprotons 1110

17Cl electronsprotons 1717 -17Cl electronsprotons 1718

Cation

anion

(32)
(33)

13 protons, 10 (13 – 3) electrons

34 protons, 36 (34 + 2) electrons

Do You Understand Ions?

How many protons and electrons are in ?1327Al 3+

How many protons and electrons are in ?7834Se2-

 3 27

13 Al

 2 78

34

Se

(34)

2.5

Different Ions of Some Elements

Metals tend to form cations

Nonmetals tend to form anions

(35)

Nonmetals are on the right side of the periodic table (with the exception of H) (blue).

Metalloids border the stair-step line (with the exception of Al, Po, and At).

Metals are on the left side of the chart (green color)

(36)

31P

15 3- 11B

5 196Au

79 222Rn 86

26 54-26=28

26-2=24 2+

0 0

18- 3=15

86

(37)

2.6 CHEMICAL FORMULAS.

(38)

2.6

ةغَيصلا ةيئيَزُجلا

ةغَيصلا ةيئانْبلا

جذَومَن ةٍرُكلا اصعْلاوَ

جذَومَن ءلمِ

غارُفلا

(39)

A molecular formula shows the exact number of atoms of each element in the smallest unit of a substance

An empirical formula shows the simplest whole-number ratio of the atoms in a substance

H2O H2O

molecular empirical

C6H12O6 CH2O

O3 O

N2H4 NH2

ةيلوَلأَا ةغَيصلا ئزُجلل ةٍرْوصْ طسَّبأَ

دوجوَ بسَّن يطعْت ئزُجلل ةنوكمَلا تِارْذلا نٍمِ سيلوَ ةبسَّن رُغَصْأب

يطعْت نأَ يرْوَرُضلا تِارْذلل حيحصلا ددعْلا

ةيئيَزُجلا ةغَيصلا

حيحصلا ددعْلا ىلعَ يوتَحت لخديَ رُصنْعَ لكِ تِارْذَ نٍمِ

هدحوَ رُغَصْأَ بيكِرُت يفِ

)ئزُجلا( ةٍدامَلا يفِ

ةيئيَزُجلا ةغَيصلا نٍمِ

ةغَيصلا داجيَإِ عيطتَسَّن رُيغ سكعْلاوَ ةيلوَلأَا

حيحصْ

(40)

• The Empirical Formula may the same or different from the Molecular Formula

• How can we get the Empirical Formula?

Answer: Divide all the numbers by the largest Common devisor.

• e.g. The empirical formula of H2O is H2O

• e.g. the empirical formula of C6H12O6 is CH2O (divide the numbers 6, 12 and 6 by the largest common devisor 6)

It must be noted that :

(41)

• Write the Empirical formulas for the following molecules

 Acetylene C2H2 divided by 2 CH

 Glucose C6H12O6 divided by 6 CH2O

Nitrous oxide N2O , the Empirical formulas is same as molecular formula N2O

Caffeine C8H10N4O2 divided by 2 C4H5N2O

EXAMPLE 2.3

(42)

Examples

Which of the following is empirical formula

A. O3 >>>>>> O B. H2SO4 C. S8 >>>>>>> S

D. C6H12O6 >>>> CH2O

نكميلا يتلا ةغيصلا بولطملا اهطيسبت اهطيسبت نكميلا ةيناثلا ةباجلاا ةحيحصلا ةباجلاا يه

Which of the following is molecular formula

A. CO2 B. H2SO4 C. S8

D. CH4O

نكمي يتلا ةغيصلا بولطملا اهطيسبت يتلا هديحولا يه ةثلاثلا ةباجلاا ةباجلاا يه اهطيسبت نكمي ةحيحصلا

(43)

O H

H H

H

C C

Cl Cl

Cl

H

CH4O

CH3OH

CHCl3

or

Molecular formula

of Methanol Molecular formula

of Chloroform Write the Molecular formula of Methanol and Chloroform, using the structural formulas below:

(44)

Write the empirical formulas for the following molecules if possible:

Compounds Name Molecular Formula Empirical Formula

acetylene C2H2 CH

glucose C6H12O6 CH2O

nitrous oxide N2O N2O

caffeine C8H10N4O2 C4H5N2O

(45)

Ionic compounds

• consist of a combination of cations and an anions

(46)

• the sum of the charges on the cation(s) and anion(s) in each formula unit must equal zero

(47)
(48)

Formula of Ionic Compounds

(49)

Write the formula of magnesium nitride?

Write the formula of a)chromium sulfate , b)titanium oxide?

Mg 3N2

3 × +2 = +6 2 × -3 = -6

Mg 2+ N3-

Cr 2(SO4)3

2 × +3 = +6 3 × -2 = -6

Cr 3+ SO42-

Ti 2O 4

2 × +4 = +8 4 × -2 = -8

Ti 4+ O2-

(50)

1. An anion is defined as 

A. a charged atom or group of atoms with a net negative charge.

B. a stable atom.

C. a group of stable atoms.

D. an atom or group of atoms with a net positive charge.

 

2. Atoms of the same element with different mass numbers are called 

A. ions.

B. neutrons.

C. allotropes.

D. chemical families.

E. isotopes.

 

3. How many neutrons are there in an atom of lead 82Pb whose mass number is 208? 

A. 82

B. 126

C. 208

D. 290

E. none of them

(51)

4. An atom of the isotope sulfur-31 consists of how many protons, neutrons, and electrons?

(p = proton, n = neutron, e = electron)  A. 15 p, 16 n, 15 e

B. 16 p, 15 n, 16 e C. 16 p, 31 n, 16 e D. 32 p, 31 n, 32 e E. 16 p, 16 n, 15 e  

5. A magnesium ion, Mg2+, has 

A. 12 protons and 13 electrons.

B. 24 protons and 26 electrons.

C. 12 protons and 10 electrons.

D. 24 protons and 22 electrons.

E. 12 protons and 14 electrons.

 

6. A sulfide ion, S2- , has: 

A. 16 protons and 16 electrons B. 32 protons and 16 electrons C. 16 protons and 14 electrons D. 16 protons and 18 electrons E. 32 protons and 18 electrons  

(52)

2.7 NAMING COMPOUNDS.

(53)

Page 64

) +)

1 2+))

(54)

Naming Ionic compounds

Metals

Positive ion Cation

Non metals Negative ion Anion

( 1A , 2A ,3A & transition metals)

Fixed charge metals

Variable charge metals Cations have

same name as the metal element

Ag+ silver ion ,Zn2+ zinc ion , Al3+ Aluminum ion , Li+ lithium ion , Ca2+ calcium ion

If the metal can form more than 1 cation, the charge is indicated by a Roman numeral in parenthesis after the metal name.

Fe2+ iron(II) ,Au+ gold(I), Cu+ copper(I) , Fe3+ iron(III) Au3+ gold(III) Cu2+ copper (II) Hg2 +2mercury(I) Hg2+ mercury (II)

monoatomic anions

Polyatomic anions

Dr. LAILA AL-HARBI

(STOCK SYSTEM)

(55)

Naming Ionic compounds

(56)

• 2. Variable charge metals:

• If the metal has more than one oxidation state, the charge is indicated by a Roman numeral in parenthesis after the metal name.

• Most of the transition metals are variable charge metals.

• E.g. Common metals which exist in more than one positive state:

• Fe2+ iron(II) ,Au+ gold(I), Cu+ copper(I) , Fe3+ iron(III) Au3+ gold(III) Cu2+ copper (II) Hg2 +2mercury(I) Hg2+ mercury (II)

• 3. Polyatomic cations: consist of nonmetals:

H3O+ hydronium ion NH4+ ammonium

Dr. LAILA AL-HARBI

(57)

Dr. LAILA AL-HARBI

Variable charge metals

(58)

Metal (cation)

Divalent elements Monovalent

elements

Lithium (Li+) Sodium (Na+) Potassium (K+) Robidium (Rb+) Silver (Ag+)

Magnisium (Mg2+) Calcium (Ca2+) Strontium (Sr2+) Barium (Ba2+) Lead (Pb2+) Zinc (Zn2+)

trivalent elements

Aluminium (Al3+) Galium (Ga3+)

Transition metals

(Fe2+) iron(II) (Fe3+) iron(III)

(Cr3+) chromium (III) (Cu2+) cupper (II) (Cu+) cupper (I)

(Mn2+) manganese(II) (Mn3+) manganese(III) (Mn4+) manganese(IV) (Mn7+) manganese(VII) (Sn2+) stannous or tin(II) (Hg22+) mercury(I)

(Hg2+) mercury(II)

Common name of metal cation:

NH4+ ammonium

(59)

Some Cations of variable charge have name for each oxidation state

Example

Fe2+ iron(II) ferrous , Fe3+ iron(III) ferric Cu+ copper(I) cuprous , Cu2+ Copper (II) cupric Hg2 +2mercury(I) mercurous

Hg2+ mercury (II) mercuric

Mercury (Hg) is the only metal has this formula when it form cation with only one positive charge :

Hg22+ NOT Hg+

The cation of two positive charges has the formula Hg2+

NOTE

Dr.

LAIL A AL- HAR

BI

(60)
(61)
(62)

nonmetal (anion)

Hydrogen hydride (H-) Oxygen oxide (O2-) Nitrogen nitride (N 3-)

(63)

Metals form only type of cation

Metals form more than one type of cation (Transition Metals)

1. Group 1A )alkaline Metals(: +1

2. Group 2A )alkaline Earth Metals(: +2 3. Group 3A: +3

4. Group 5A: -3 )= 5-8(

5. Group 6A: -2 )= 6-8(

6. Group 7A )halogens(: -1 )= 7-8(

Nonmetals

(64)

1. monoatomic anions: change ending to -ide

E.g. Oxygen→Oxide Sulfur → Sulfide

Hydrogen →Hydride chlorine → Chloride Florine → Floride Bromine → Bromide

Polyatomic anions: most end in -ate or -ite; usually contain O (oxy)

Know polyatomic anions on handout.

Carbonate CO3-2 , Nitrate NO3- , Sulfate SO4-2 ,

Phosphate PO4-3

Cyanide CN- , Hydroxide OH- ,Oxide O2-2

See table 2.3

B. Naming Anions

(65)

Nonmetal polyatomic anions

(SO42-) sulfate , (SO32-) sulfite

(NO3-) nitrate (NO2-) nitrite

(PO43-) phosphate (PO33- ) phosphite

(ClO4 ) perchlorate (ClO3- ) chlorate

(HSO4-) hydrogen sulfate or bisulfate

(HPO42-) hydrogen phosphate or biphosphate

(CO32–) carbonate

(HCO3) hydrogen carbonate or bicarbonate (H2PO4-) dihydrogen phosphate

تا تاتيربك تي تيتيربك

(66)

Ionic compounds names start with the positive ion (metal) (include Roman numeral in parenthesis ONLY IF metal has variable charge) followed by the negative ion (nonmetal).

NaCl Sodium Chloride

BaCl2 Barium Chloride

K2O Potassium oxide

KNO3 Potassium Nitrate

Na2CO3 Sodium Carbonate

FeCl2 Iron(II) Chloride → ferrous Chloride

FeCl3 Iron(III) Chloride → ferric Chloride

Cr2S3 Chromium(III) Sulfide

(NH4)3PO4 Ammonium Phosphate

Cu(NO3)2 Cupper(II)nitrate

PbO Lead(II) oxide

(67)
(68)
(69)

Example 2.5 p61:

Name the following compounds:

(a) Cu(NO3)2

1. Cation: Copper cation (can form two types of cation →Stock system) →

Copper (II)

2. Anion: NO3- anion has a common name Nitrate

Thus: the name of the compound is:

Copper (II) nitrate

لُدابت ةٍدعَاق تِاؤفِاكتَلا

Dr. LAILA AL-HARBI

(70)

(b) KH

2

PO

4

1. Cation: K form only one type of cation

→ Potassium Note: not potassium (I) 2. Anion: H2PO4-has a common name dihydrogen phosphate

Thus: the name of the compound is:

Potasium dihydroen phosphate

(71)

Dr. LAILA AL-HARBI

Write the chemical formula for the following

compounds

Mercury(I)nitrite Hg2 (NO2)2

Cesium sulfide Ce2S

Calcium phosphate

Ca3 (PO4)2

• Write the chemical formula for the following

compounds

• Rubidium sulfate

Rb 2 SO4

• Barium hydride

BaH 2

(72)

Name the following ionic compounds:

Cu(NO3)2 KH2PO4 NH4SCN

H2O2 Li2SO3 Ca3(PO3)2 KMnO4

Cupper(II) nitrate

Potassium dihydrogen phosphate Ammonium thiocyanate

Hydrogen peroxide Lithium sulfite Calcium phosphite

Potassium permenganate Hg2Cl2 Mercury(I) chloride

K2CrO4 Potassium chromate Br2O7 Dibromine heptoxide

(73)

Write formulas for the following ionic compounds:

MnO K2HPO4 NH4ClO2

Pb(OH)2 NaHCO3 Ba(CN)2 RbHSO4 HgBr2 Manganese(II) oxide

Potassium hydrogen phosphate Ammonium chlorite

Lead hydroxide Sodium bicarbonate Barium cyanide

Rubidium hydrogensulfate Mercury(II) bromide

SrH2 Strontium hydride

(74)

Ionic Compounds

• often a metal (cation) + nonmetal (anion)

The cation is always named first and the anion second

• anion (nonmetal), add “ide” to element name

ةينويَلأَا تِابكِرُمَلا نم مسلإا نوكتي

زلفلالا هيلي زلفلا فاضي ide

زلفلالل

(75)

Mg(OH)2 magnesium hydroxide

KCN potassium cyanide

2.7

BaCl2 barium chloride K2O potassium oxide

1. Binary compounds are compounds formed from just two elements

2. Ternary compounds are compounds formed from three elements.

Ionic compounds

(76)

Molecular Compounds

Diborane B2H6

Methane CH4

Silane SiH4

Ammonia NH3

Phosphine PH3

Water H2O

Hydrogen sulfide H2S

2- common names of some molecular compounds

ةيئيَزُجلا تِابكِرُمَلا

لا + تازلف هابشأ نم نوكتت

تازلف تازلف لا + تازلف لا

ةيئيزجلا تابكرملا مظعم

نوكتت) رصنعلا ةيئانث نوكت (طقف نيرصنع نم لثم هعئاش ءامسأ هل اهضعب

H2O, NH3, CH4

هتياهنل فاضي ريخلأا رصنعلا

ide

1- Consists of (metalloid + nonmetal)

or (nonmetal + nonmetal)

Many molecular compounds are binary compounds

PCl3

SiC

3- last element ends in -ide

(77)

4- element further left in periodic table is 1st (less electronegative)

(HCl) H(1A) and Cl(7A), so hydrogen is 1st, the name is

hydrogen chloride

5- element closest to bottom of group is 1st (less electronegative)

(SiC) Si(4A) and C also belongs to

(4A) ,but (Si) is closest to bottom of the group, so silicon is 1st ,

the name is silicon carbide

رصانعلا بتكت

لودجلا راسي هدوجوملا برقلأا وأ يرودلا .لاوأ راسيلل ةيوتحملا تابكرملا

نم ةرذ نم رثكأ ىلع نع ربعي رصنعلا سفن رصنعلل تارذلا ددع تائدابلا مادختساب اهل ةينانويلا

(78)

6- if more than one compound can be formed from the same elements, use prefixes to indicate number of each kind of atom.

Examples

(79)

Note

Note that mono- is never used for the first element

For oxides, the ending “a” in the prefix is omitted.

N2O4 dinitrogen tetroxide not (dinitrogen tetraoxide)

For oxides, the ending “o” in the prefix is omitted.

N2O dinitrogen monoxide not (dinitrogen monooxide )

Dr. LAILA AL-HARBI

(80)

HI hydrogen iodide

PF3 phosphorus trifluoride H2O2 Hydrogen peroxide

N2O4 dinitrogen tetraoxide

NO2 nitrogen dioxide

N2O dinitrogen monooxide

Examples of Molecular Compounds

2.7 TOXIC!

Laughing Gas

ICl3 Iodine trichloride

(81)

Name the following molecular compounds:

SO2 SiCl4 BrF7 P4O10 Cl2O7 CH4 CS2

Sulpher dioxide

Silicon tetrachloride Bromine heptaflouride

Tetraphosphorus decoxide Dichlorine heptoxide

Methane

Carbon disulphide Br2O7 Dibromine heptoxide

(82)

Write formulas for the following molecular compounds:

SF4 N2O5 SO3 Si2Br6 PCl5 P4S10 N2O2 Sulphur tetraflouride

Dinitrogen pentoxide Sulfur trioxide

Disilicon hexabromide

Phosphorus pentachloride

Tetraphosphorus decasulphide Nitrogen peroxide

CO Carbon monoxide

IF7 Iodine heptaflouride

(83)

Fill the blanks in the following table

name formula anion cation

Barium bicarbonate Ba(HCO3)2 -HCO3 +Ba2 Iron(III)nitrite Fe(NO2)3 -NO2 +Fe3

Hyrdogen flouride HF -F +H

Manganise(IV)oxide MnO2 -O2 +Mn4

Sodium peroxide Na2O2 -O22 +Na

Cesium chlorate CsClO3 -ClO3 +Cs

Lithium nitride Li3N -N3 +Li

(84)

Which of these pairs of elements would be most likely to form an ionic compound? 

(a) P and Br (b) Cu and K (c) C and O (d) O and Zn (e) Al and Rb

Which of these pairs of elements would be most likely to form a molecular compound?

(a) Na and Br (b) C and O (c) Ca and O (d) Zn and O (e) Mg and Cl

(85)

8. Which of the following compounds is named lithium carbonate?

  A) Na2CO3   B) LiHCO3

  C) LiCO

  D) Li2CO3

9. What is the name of KClO?

  A) potassium chlorite   B) potassium chloride   C) potassium hypochlorite   D) potassium oxide

10. What is the formula for ammonium sulfate?

  A) NH4SO4   B) NH4(SO4)2   C) (NH4)2SO4   D) NH4S

Referensi

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