Faculty of Science - Faisaliha Branch
(King Abdul-Aziz University) DEPARTMENT Chemistry
General Chemistry CHME 202
1436 H First semester ـ
By
Prof Dr. Sana Arab
Physical Chemistry
Prof Dr. Sana Arab
Office location: - Building 05, Third floor 309-2 A
Office hours: Sn. ,Tu. (12.00 -1.30 )
Contact number(s):0505600455
[email protected] mail address:
- E
Website: [email protected]
ررمٌّا فٍِ
فيرعتلا ةدالما ةذاتسأب
(
تيملعلا ثاجردلا
)
أ . د . برع رهاط ءانس
شىيرىٌاىثٌا
ءايّيو /
ًٌولأا فرشٌا حثذرِ عِ زارِّ ريذمرت ءايسيف
(
1397/1398 ـه
)
صصخذ َىٍتد زارِّ ريذمرت َاع ءايّيو َىٍتد
( 1398/1399 ـه
)
ريرطجاٌّا
زارِّ ريذمرت حيورح حيئايسيف ءايّيو (
1403 ـه
)
ٖارىروذٌا حيترهو حيئايسيف ءايّيو
( 1407 ـه
)
ٖارىرود حٌاضر يوأ } (
يٍّع ) جذجت خإثٌا خايٍو يف
{
نراشِ رارضأ
حيترهو حيئايسيف ءايّيو –
ْداعِ ًوآذ (
1417 ـه
)
رارضأ
حيترهو حيئايسيف ءايّيو –
ْداعِ ًوآذ (
1429 ـه
)
حٍيو و ايٍعٌا خاضارذٌٍ
حٍحرِ و شىيرىٌاىثٌا
( 9
َاىعأ .)
ُطل حطيئر ءايّيىٌا
(
ٓيِاع .)
حيتررٌا حيٍو جذيّع -
حيٍّعٌا َاطللأا –
جذجت (
4/4 / 1422 ـه
- 16 / 4 / 1429 ـه
)
خايٍىٌا ضعت صٌاجِ يف ىضع .
كيمحرٌا ْاجٌو خاثٌاطٌا قوذٕص ْاجٌ يف جىضع
اهلغش تم يتلا تيرادلإا بصانلما
خايٍىٌا حٍىيه جداعاو جهإٌّا ريىطرٌ ْاجٌ يف جىضع .
رىشٌا و قىفرٌا خاداهش ِٓ ذيذعٌا ًٍع يىصحٌا ُذ ذلو
.
ةلحرم يف سيردتلا يف ةكراشملا ايلعلا تاساردلاو سويرولاكبلا
.
لئاسر ىلع فارشلإا ريتسجام
و هاروتكد
نم معد ىلع لوصحلا مولعلل زيزعلا دبع كلملا ةنيدم
ايجولونكتلاو عبسل
يملعلا رشنلا ةزئاج ىلع لوصحلا مت امك لئاسر ثحبل
ريتسجام ةلاسر نم لتسم
(
درفِ فارشا اهِٕ صّخ )
و
ٓيرٌاضرٌ
(
نررشِ فارشا
.)
ًٍع يىصحٌٍ حِذمِ زاحتأ ُيىحذ نراشِ رارضأ حجرد
.
خارّذؤٌّا و خاروذٌا ِٓ ذيذعٌا يف حوراشٌّا .
طاشٌٕا ّٓض حيٍىٌا يف خاوذٌٕا و خارضاحٌّا ِٓ دذع ءامٌإ يف حوراشٌّا حيٍّعٌا خايمرٌٍّاو يفامثٌا ُضىٌّا يف .
يثحبلاو يملعلا طاشنلا
دذع رشٔ
( ) 43 و اثحت (
) 1 رشٌٍٕ يىثمِ
( ) 2 رشٌٍٕ داذعلاا دحذ .
ةيمهعنا تلاجمنا يف رشنهن ةمدقم ثاحبأ ميكحت .
حٌاضر جرشع يذحإ حشلإِ
ريرطجاِ
ًئاضر دض و
ٖارىــرود خاــيــٍو يف
دىعض هٌٍّا حعِاج يف و خاــٕثٌا .
ًٍع يىصحٌٍ حِذمِ زاحتأ ُيىحذ
حيٕمرٌاو َىٍعٌٍ سيسعٌا ذثع هٌٍّا حٕيذِ ِٓ ُعد
Publish Year Publish Place
Literature and research
NO.
1991
International Jour.Chem . Structural Effects and Mechanism of the inhibition of Acid
Corrosion of Steel by some Nitriles.
1
1991
Proc Pakistan AcadSci Comments on Gill’s Approach to the Evaluation of Ionic Radii in
Non- Aqueous Solvents.
2
1992
Internationl Jour.Chem . Effect of some S- Alkylisothiouronium lodides on the Corrosion of
Steel in 1.0 M Hydrochloric Acid.
3
1993
CorrosionInhibition of Acid Corrosion of Steel by Some S- Alkylisothiouronium lodide.
4
1994
TheElectrochemical Socity of India Effect of Water –Organic Solvent Mixtures on Pitting Corrosion of
Mild Steel.
5
1995
PortuglineElectrochmica Acta.
Intermolecular Interaction and the Conductance of some tetra Alkyl Ammonium Salts in Ethylene Glycol-Ethanol Mixture at 30
C.
6
2001
Bull of ElectroChemistry Electrochemical Behaviour of Al–Si Alloys in Acid and Alkaline
Media.
7
2001
Journal of AppliedElectro –chemistry The role of chloride ions and pH in the corrosion and pitting of Al
-Si alloys.
8
2002
CorrosionInfluence of N-heterocyclic compounds on the corrosion of Al-Si alloy in hydrochloric acid-effect of pH and temperature
9
Publish Year Publish Place
Literature and research
NO.
2002 International
Journal of Chemistry The effect of temperature on the inhibition of the acid corrosion
of mild steel by some sulfonium bromide derivatives . 10
2004 Al-AZhar Bull Sci
Inhibition effect of phenacyl dimethyl sulfonium bromide and some of It's ρ -substituted derivatives on corrosion of mild steel in acid solutions.
11
2004 Al-AZhar Bull Sci
Inhibition of steel corrosion in acid solution by five member's ring of sulfonium bromides.
12
2005 Bull. Electro.Chem.
Effect of temperature on corrosion inhibition of iron base metallic glass alloy in nutral solutions.
13
2005 Metrial. Sci. Res.
Utilization of Ammi majus L.Fruits Extracts as Inhibitors for Mild Steel Corrosion in Acid Media.
14
2006 Commun.Fac.Sci.
Synergistic action of some thiosemiarbazone derivatives with chloride ion on the corrosion inhibition of iron base metallic glass.
15
2006 Chem. Sau.J
Synergism and antagonism in iron base metallic glass corrosion inhibition by thiosemiarbazone compounds and bromide ions.
16
2006 Portugaliae
Electrochimica Acta Corrosion inhibition of steel in phosphric acid by phenacyl
dimethyl sulfonium bromide and some of it's ρ -substituted derivatives.
17
2007 Inter.Jou.App.Che.
Thermodynamic Study on Corrosion Inhibition of Fe78 B13 Si 9 Metallic Glass in Na2 SO4 Solution at Different Temperatures.
18
Publish Year Publish Place
Literature and research
NO.
2007
Oriental Juornal. of electro chem.
Electrochemical Study of Amorphous Ni89P11 Alloy in HCl Solutions.
19
2008
Materials Letters Structure effect of some thiosemicarbazone derivatives on the
corrosion inhibition of Fe78 B13 Si9 glassy alloy in Na2 SO4 solutions.
20
2008
Materials Research Bulletin Inhibition action of thiosemicarbazone and some of its p-
substituted compounds on the corrosion of iron-base glass alloy in 0.5M H2 SO4 at 30o
21
2008
Inter.Jou App.Che Effect of strong acids on the electrochemical behavior Ni89P11
glassy alloy.
22
2008
Chem. Sau.J Use of some drugs for steel corrosion inhibition in sulfuric acids
solutions in presence of some halides.
23
2008
Egyptian Chem. Soc.
Chemical Composition of Ammi majus its Inhibion Activity Against Corrosion .
24
2008
J. of Korean chemical society Synergistic Effect of Azadirachta Indica Extract and Iodide Ions on
the Corrosion Inhibition of Aluminium in Acid Media.
25
2008
Inter-national Journal of electro-
chemical science
Effect of Temperature on the Corrosion Inhibition on Mild Steel in 2.0M H2SO4 by Some Organic Compounds Containing S and N Atoms in Absence and Presence of Halides .
26
Publish Year Publish Place
Literature and research
NO.
2009
Phys. Chem. NewsINFLUENCE OF Cr ADDITION ON THE ELECTROCHEMICAL BEHAVIOR OF Ni –BASE METALLIC GLASSES IN HCl
27
2009
Modern AppliedScience Aloe Plant Extract as Environmentally Friendly Inhibitor on the
Corrosion of Aluminum in Hydrochloric Acid in Absence and Presence of Iodide Ions
28
2010
Oriental Journal ofChemistry The use of Ruta chalepensi as corrosion inhibitor for steel
corrosion in 2M sulphuric acid solution 29
2010
InternationalJournal of Chemistry Corrosion and Corrosion Inhibition of Mild Steel in H2SO4
Solutions by Zizyphus Spina-Christi as Green Inhibitor 30
2010
Journal of AmericanScience Voltammetry Determination Of Some Trace Elements In Tap
Water Samples Of Jeddah Area In The Kingdom Of Saudi Arabia 31
2010
Life Science JournalEstimating Of Some Trace Elements In Mineral Water In The Kingdom Of Saudi Arabia
32
2010
Nature and ScienceElectrochemical techniques for measuring some trace heavy metals in Taps Water of Riyadh in Saudi Arabia .
33
2010
Journal of SaudiChemical Society Medicago Sative plant as safe inhibitor on the corrosion of steel
in 2.0M H2SO4 solution 34
Publish Year Publish Place
Literature and research
NO.
2011
CORROSIONSynergistic Effect of Zizyphus Spina-Christi and Chloride Ions on the Corrosion Inhibition of Mild Steel in Sulfuric Acid Solution.
35
2012
Nature and ScienceThe Role Of Natural Mineral Dead Sea Waters Therapy In Various Rheumatic Diseases
36
2012
Science JournalThe use of Clay Minerals of the Dead Sea as Drugs 37
2012
J. of Koreanchemical society The electrochemical behavior of Ni –base metallic glasses
containing Cr in H2SO4 solutions 38
2013
Life Science JournalDetermination of Some Trace Elements in Blood of Rheumatoid Arthritis Patients in Some Areas of Saudi Arabia Kingdom.
39
2013
Journal of AmericanScience Determination Of Copper Trace Element In Rheumatoid Arthritis
Patients In Some Areas Of Saudi Arabia Kingdom 40
2013
The Arabian Journalfor Science and Engineering Susceptibility of 254 SMO Alloys to Crevice Corrosion in NaCl
Solution 41
2014
Open Journal ofPhysical Chemistry.
The Crevice Corrosion of 316L SS Alloy in NaCl Solution at Different Applied Potentials
42
2014
Journal of SaudiChemical Society Passivity characteristics on Ni(Cr)(Fe)SiB glassy alloys in
phosphate solution 43
Course requirement Theoretical units
Course No.
Course name
General Chemistry - 110 4
Chem. 202 General Chemistry 2
Course Information
Description of the course:
This course include the following chapters:
1. The kinetic molecular theory of liquids and solids ( Chap. 11) 2. Physical Properties of Solutions (Chap. 12)
3. Thermochemistry (Chap. 6)
4. Entropy, Free Energy, and Equilibrium (Chap. 18) 5. Reactions in Aqueous Solution (Chap.4)
6. Electrochemistry (Chap. 19)
7. Chemical Kinetics (Chap. 13)
8. Nuclear Chemistry (Chap. 23)
Teaching methodology:
The fundamental method of transmitting material to the students is by
1. Traditional lectures.
2. Power point presentations, white board.
3. Active learning via group discussions, & solving problems.
4. Web resources will be used where appropriate
Policies and Procedures:
1. All cell phones must be turned off during lecture.
2. Students are expected to arrive for class on-time so as not to disrupt a lecture in progress.
3. All homework assignments will have a due date on them: Typically a student will have two weeks in which to complete an assignment.
Late homework assignments will not be accepted.
Homework as a bonus must be produced at the end of
the last lecture in semester.
( ررقمنا نع تامىهعم )
This course is designed to learn basic concepts of
basic knowledge of chemistry especially physical
chemistry, including thermochemistry, spontaneity of
reaction, thermodynamics, physical properties of
solution, kinetics, and nuclear reactions,
electrochemistry.
Expectations and Outcomes
This course is designed to learn basic concepts of physical chemistry.
a)
Selected topics in thermochemistry; includes exothermic &
endothermic reactions, bond energy, Enthalpy, Hess law, Calorimetry.
b)
Selected topics in thermodynamics; includes first law, second law& Third law of thermodynamics, Entropy, Free Energy.
c)
Selected topics in Physical properties of solutions; includes concentration units, solute, solvent, Henry’s & Raolt’s laws, colligative properties.
d)
Introductory Chemical Kinetics will be investigated. To learn
basic aspects of both experimental and theoretical chemical
kinetics and how this information is applied to problems of
chemical interest.
e) Introductory Nuclear Chemistry. Radioactivity, radioactive decay, binding energy half life time, fission & fusion nuclear
reaction.
f) Basics in Electrochemistry. Learn basic aspects of both experimental and theoretical electrochemistry, and how this
information is applied to problems of chemical interest. Students will have reviewed and deepened there understanding of galvanic and electrolytic cells.
Expectations and Outcomes
Students who successfully complete this course should have a
good background for pursuing other courses in chemistry
and other sciences that require knowledge of the material
addressed in Physical Chemistry II. One of the keys to
success in a Physical Chemistry Course is to do lots of
problems. In additional to Physical Chemistry textbooks, a
problem solving books exist.
Outcome a : They will learn the basic concepts associated with thermochemistry.
Outcome a.1: Students will review and understand exothermic and endothermic reactions.
Outcome a.2: Students will learn the concept of internal energy and enthalpy.
Outcome b: Student should learn key concepts associated with introductory Thermodynamics
Outcome b.1: Students will understand the first law of
thermodynamics, Entropy and second law of hermodynamics.
Outcome b.2: Students will learn the Gibbs free energy and how to correlate the different thermodynamic functions in a law.
Outcome b.3: Students will learn the spontaneity of the reaction
and how do a chemist exploring a chemical process.
Outcome c They will learn the basic concepts associated with ideal and real solutions.
Outcome c.1: Students will learn the phase rule and study colligative properties.
Outcome c.2: Students will review and understand Raoult’s and Henry’s Law.
Outcome d Students should learn basic aspects of
both experimental and theoretical chemical kinetics
and how this information is applied to problems of
chemical interest.
Outcome d.1: Students will have reviewed and
deepened there understanding of differential rate laws, integrated rate laws, temperature dependence of reaction rates, and reaction mechanisms.
Outcome d.2: Students should understand the basic
concepts of catalysis.
Outcome e They will learn the fundamentals of
radioactivity as an introduction to nuclear chemistry.
Outcome e.1: Students will have reviewed and deepened there understanding of radioactivity and binding energy, half life time.
Outcome e.2: They will have reviewed and deepened there understanding nuclear reactions, fission and fusion reactions.
Outcome f To learn basic aspects of both experimental and theoretical electrochemistry, and how this information is applied to problems of chemical interest.
Outcome f.1: Students will have reviewed and deepened
there understanding of galvanic and electrolytic cells.
Course Objectives
This course is designed to learn basic concepts of kinetics chemistry.
1. Introduction of Chemical Kinetics, basic aspects of both experimental and theoretical chemical kinetics and how this information is applied to problems of chemical interest.
2. Basic Concepts of Reaction Kinetics. Reaction Rate and
Stoichiometry. Order and Molecularity. Derivation of the Rate Equation.
3. Units for the rate constant. Rate Law & Reaction Orders and Half-life.
4. Determining Reaction Order. Differential and Integrated methods
Chemistry, by Chang 9 th ed . , 2007, McGraw-Hill.
Useful books:
1. Chemistry , by Mortimer , 6 th . ed . , Wadsworth Inc.
2. Chemistry , by Steven S . Zumdahl , 6 th . ed . ,
Houghton Mifflin College Div. College publishing.
لودج أ.
د . برع رهاط ءانس
ىعجرملا مقرلا ةبعشلل
ررقملا ةبعشلا ةداملا مسا تبسلا دحلاا نينثلاا ءاثلاثلاءاعبرلااسيمخلاةعمجلا ةيادب تقولا
تقو ءاهتنلاا
ىنبملا ةفرغلا
10765 CHEM-344 CC1 ةيكرحلا ءايميكلا Y Y Y 09:0009:50 05A 311A
10669 CHEM-202 CE1 )2( ةماع ءايميك Y Y Y 10:00 10:50 05A 304A
10696 CHEM-202 CF3 )2( ةماع ءايميك Y Y Y 11:00 11:50 05A 304A
ممشيو ةيهكنا تاجردنا عيزىتو تابناطنا ميىقت بيناسأ :
اهذاِلاعو اهدذعو اهرغيصو اهتىٍضأو خاراثرخلاا .
اهذاِلاعو حفرعٌّا رداصِو اهرغيصو اهتىٍضأو عيراشٌّا .
ًصفٌا يف حوراشٌّا –
جريصل خاراثرخا –
خاثجاىٌا –
حيٍّع خلاامِ
.
اهت َاسرٌلاا ةجاىٌا خاضايطٌا
( بايغٌاو رىضحٌا ,
راثرخلاا ٓع فٍخرٌا ,
ًّرىِ ريغٌا خاراثرخا ,
جرضاحٌّا ٓع رخؤرٌا ,
خاثجاىٌا ,
شغٌا ,
ياىجٌا ,
فرصرٌا
يعِاجٌا َرحٌات كئلاٌا صثٌٍاو
).
مصفنا للاخ اهنم عقىتمناو اهتينوؤسمو تابناطنا ءادأ مييقت :
باعيرضلاا ًٍع حيٌاع جرذلو جسيّرِ حيٍمع
