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Composition of solids obtained via HTC at 90% water loading

Dalam dokumen 1.2 Objective and Scope of the Study (Halaman 86-142)

This is most likely an outlier due to the high inhomogeniety of MSOW; this particular sample likely to contained very small amount of ash.

From Figure 4.1(a), as well as Table 4.6, it can be observed that the highest amount of solid yield was found for experiment 12A (275C, 20 mins, and 90% water); the literature reported solid yield percentage is 72% [151], which is less than the solid yield found for experiment 12A. This is due to the high ash content in the MSOW of DNCC; the amount of ash in the biocoal in literature is reported to be between 22.8 - 46.0 % [91, 100]. In contrast, the ash content of the biocoal produced in this study ranged from 60.7 - 75.5%, with an outlier at 31.6%. This could be due to presence of high amounts of construction sand in the MSOW of Bangladesh.

However, the dry ash-free carbon content of 65.2% for experiment 12A (275C, 20 mins, and 90% water) matched the biocoal mass percentage (derived from biomass) of around

63% [151]. Heilmannet al. reported that the carbon content of biocoal derived via HTC of algae (Dunaliella salina) was 66.3 % [152].

At higher temperatures, solid yield decreases because hydrothermal liquefaction and hy- drothermal gasification takes place [90, 92, 102, 152]. At longer residence times, the biocoal yield is also reported to decrease [153]. These are consistent with the findings of this study. The reported biocoal or hydrochar is said to have a calorific value (HHV) between 15-20 MJ/kg [89, 91, 92]. The calculated calorific value (HHV) for the biocoal produced in this study ranged from 9.56 - 14.92 MJ/kg.

Table 4.7, shows that experiment 12A (275C, 20 mins, and 90% water) had the highest carbon content. Figure 4.2(a) shows that experiment 12A has a HHV higher (11.5 MJ/kg) than the parent MSOW sample (10.90 MJ/kg). These observations are consistent with literature. Yoshikawa and Bergeet al. reported that the HHV and carbon content of the biocoal should be higher than the parent MSOW fraction [91, 100].

90% water loading, maximum (83 %) of the energy was retained in biocoal with respect to the parent MSOW sample.

(a) (b)

(c)

75.7 82.7

44.3 0

20 40 60 80 100

240 275 300

Energy Retenon / %

Temperature/ °C

20 minutes

79.7

57.1 52.5

0 20 40 60 80 100

240 275 300

Energy Retenon / %

Temperature/ °C

30 minutes

70.2

55.3

76.9

0 20 40 60 80 100

240 275 300

Energy Retenon / %

Temperature/ °C

40 minutes

FIGURE4.6: Energy retention by biocoals obtained at various conditions with 90% water loading

Figure 4.7 shows the SEM images of the dried parent MSOW sample with a number of hydrothermally treated dried samples including MSOW and wood. Compared to the struc- ture of biocoal obtained from HTC of wood (Figure 4.7d), the biocoal obtained from HTC of MSOW (Figure 4.7b and 4.7c) had retained an amorphous structure inherited from its parent MSOW sample (Figure 4.7a). Wood surface showed some pores opening up on the surface after hydrothermal carbonization while biocoal (obtained from HTC of MSOW) had a surface covered with fragmented particles. Fragmentation occurred randomly for a number of particles while some particles managed to retain their shapes. This means fragments from some of particles was covering the surface of the solid block shaped par- ticles. It was observed for all the hydrothermally carbonized MSOW samples irrespective of the reaction conditions. Such structure is typically observed for biocoal produced from high ash containing biomass feedstocks, such as, algae [154]. It could be also noted that MSW generated in Singapore had a similar structure after hydrothermal carbonization as reported by Parshettiet al.[155]. This structural property is also very important for post- utilization of biocoal from MSOW. The combustion/gasification of biocoal is expected to be dominated by surface reaction due to the lack of pores [156].

FIGURE4.7: SEM images of the parent and hydrothermally carbonized sam- ples (dried)

Conclusions and Recommendations

5.1 Conclusion

MSW sampling at DNCC landfill site yielded a composition of waste comprising of mostly organic waste (more than 74%); providing the possibility to harness energy from waste. The remaining fractions of MSW are cotton, plastic, paper, wood, leather, rubber, and other inorganics. The moisture content of the MSOW (organic waste) was determined to be 70.2%. The sampling was conducted during dry season; the moisture content might vary during monsoon season.

The presence of significant amount of ash in the MSOW of Bangladesh lowers the calorific value of the biocoal produced. The biocoal obtained from DNCC MSOW had signifi- cantly high amount of ash as compared to other literature reports.

The analyses of experimental results revealed that at higher temperatures and longer reac- tion time, the solid yield decreases. A general trend in decreasing HHV with increasing re- action temperature is also observed. Based on the factorial design of HTC experiments on MSOW, the optimum condition was determined. The optimum condition for hydrother- mal carbonization of DNCC MSOW was found to be at at 275C, with a reaction time of 20 minutes, and at a water loading of 90% by mass. The HHV of the biocoal produced

75

at these conditions was slightly higher, had the highest solid yield, and had the highest carbon content. Moreover, the biocoal produced at the optimum condition retained about 83% of the energy content of parent MSOW.

No pore formation was observed for the biocoal from SEM analyses. Therefore, the surface reaction might be the dominating mechanism during its possible post-utilization (i.e. combustion or gasification).

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Dalam dokumen 1.2 Objective and Scope of the Study (Halaman 86-142)