Risalah Data Keselamatan Safety data sheet

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Safety data sheet

Mukasurat (Page): 1/21 BASF Risalah Data Keselamatan (BASF Safety data sheet)

Tarikh / Disemak (Date / Revised): 22.10.2019 Versi (Version): 5.1 Produk (Product): HEXAMOLL® DINCH

(30679820/SDS_GEN_MY/MS) Tarikh cetakan (Date of print) 14.06.2022

1. Pengenalan bahan kimia dan pembekal

HEXAMOLL® DINCH

Nama bahan kimia:

Nombor CAS: 166412-78-8 Kegunaan: pelembut

Syarikat:

BASF (Malaysia) Sdn Bhd

Lot 19.02 Level 19, 1 Powerhouse No 1 Persiaran Bandar Utama 47800 Petaling Jaya

Selangor D.E, MALAYSIA

Nombor Telefon: +60 3 7612 1888 Nombor Telefax: +60 3 7612 1777 Maklumat kecemasan:

Nombor Kecemasan Kebangsaan +603 7612 1999

Nombor Kecemasan Antarabangsa:

Nombor Telefon: +49 180 2273-112

2. Pengenalan Bahaya

Pengelasan bahan dan campuran:

Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini.

Unsur label dan pernyataan berjaga-jaga:

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Produk tidak memerlukan label amaran bahaya menurut kriteria GHS . Bahaya lain yang tidak menyebabkan pengelasan:

Jika berkenaan, maklumat yang diberikan dalam bahagian ini tentang bahaya lain tidak

menyebabkan pengelasan tetapi mungkin menyumbang kepada bahaya bahan atau campuran secara keseluruhan.

Lihat seksyen 12 - Keputusan PBT dan Penilaian vPvB

3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia

Keadaan kimia

1,2-Cyclohexanedicarboxylic acid, diisononyl ester (Kandungan (berat/berat): >= 99.5 %) Nombor CAS: 166412-78-8

4. Langkah-Langkah Pertolongan Cemas

Nasihat am:

Tanggalkan pakaian yang tercemar.

Jika tersedut:

Jika kesukaran berlaku selepas tersedut wap/aerosol, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan.

Apabila terkena kulit:

Basuh bersih-bersih dengan sabun dan air.

Apabila terkena mata:

Basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air sambil membuka mata.

Apabila tertelan:

Segera basuh mulut dan kemudian minum 200-300 ml air.

Nota kepada doktor:

Gejala: Simptom dan/atau kesan tidak diketahui setakat ini Nota kepada doktor:

Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui.

5. Langkah-Langkah Pemadaman Kebakaran

Bahan pemadam yang sesuai:

karbon dioksida, serbuk kering, semburan air, busa Bahaya tertentu:

Produk mudah terbakar. Sejukkan bekas yang berbahaya dengan semburan air.

Peralatan perlindungan khusus:

Gunakan alat pernafasan serba lengkap.

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Maklumat lanjut:

Lupuskan sisa kebakaran dan air pemadam api yang tercemar menurut peraturan rasmi. Kumpul air pemadam api yang tercemar secara berasingan, jangan biarkan ia mengalir ke dalam sistem pembetung atau efluen.

6. Langkah-Langkah Pelepasan Tidak Sengaja

Langkah pencegahan diri:

Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik.

Langkah berjaga-jaga untuk alam sekitar:

Pelepasan ke alam sekitar mestilah dielakkan.

Kaedah pembersihan atau penyerapan:

Kutip dengan bahap penyerap yang sesuai. Lupuskan bahan yang diserap mengikut peraturan.

7. Pengendalian dan Penyimpanan;

Pengendalian

Pastikan pengalihudaraan menyeluruh di kawasan simpanan dan di tempat kerja.

Penyimpanan

Maklumat lanjut tentang keadaan penyimpanan: Bekas hendaklah disimpan tertutup rapat di tempat yang kering.

8. Kawalan pendedahan dan perlindungan diri

Komponen dengan parameter kawalan tempat kerja

Tiada had pendedahan pekerjaan yang diketahui.

Peralatan perlindungan peribadi Perlindungan pernafasan:

Perlindungan pernafasan tidak diperlukan.

Perlindungan tangan:

Sarung tangan pelindung kalis kimia (EN 374) getah nitril (NBR) - 0.4 mm ketebalan salutan

Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai.

Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374):

Nota tambahan : Spesifikasi adalah berdasarkan ujian –ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan

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yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian.

Perlindungan mata:

Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan:

Perlindungan badan mestilah dipilih berdasarkan tahap aktiviti dan pendedahan.

Langkah kebersihan dan keselamatan am:

Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik.

9. Sifat Fizikal dan Kimia

Bentuk: cecair

Warna: Tidak berwarna

Bau: hampir tiada bau

Ambang bau: tidak ditentukan nilai pH:

Tidak boleh digunakan, keterlarutan yang sangat rendah

takat tuang: -54 °C (DIN ISO 3016)

Suhu didih: dianggarkan 394 °C (1,013 hPa)

Tidak boleh disuling tanpa

penguraian pada tekanan normal.

(Arahan 92/69/EEC, A.2)

Takat kilat: 224 °C

Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku.

(Arahan 92/69/EEC, A.9, cawan tertutup)

Tahap penyejatan:

Nilai boleh dianggarkan berdasarkan Pemalar Hukum Henry atau tekanan wap.

Kemudahbakaran (pepejal/gas): tidak mudah terbakar (diterbitkan daripada takat kilat)

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Had letupan bawah:

(dianggarkan 170 °C, dianggarkan 1013 hPa)

Takat bawah letupan

bahan/campuran telah ditentukan.

Takat letupan ini menerangkan suhu bagi cecair mudah terbakar apabila kepekatan wap tepu bercampur dengan udara bersamaan dengan had bawah letupan.

(, udara)

Had letupan atas:

Akibat tindakan penguraian terma (lihat Penguraian terma), had letupan atas tidak dapat ditentukan menurut standard DIN EN 1839.

Untuk cecair tiada kaitan untuk pengelasan dan pelabelan.

Suhu pencucuhan: 330 °C (Arahan 92/69/EEC, A.15)

Penguraian terma: Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku.

pencucuhan sendiri: Suhu: 20 °C Tidak swacucuh.

Jenis ujian: Swanyalaan spontan pada suhu bilik.

Bahaya letupan: Berdasarkan struktur kimia tiada petunjuk ciri-ciri mudah meletup.

Sifat yang menggalakkan kebakaran: Berdasarkan sifat strukturnya produk ini tidak dikelasifikasikan sebagai pengoksida.

Tekanan Wap: < 0.000001 hPa (20 °C)

(Arahan 92/69/EEC, A.4)

Kepekatan: 0.944 - 0.954 g/cm3 (20 °C)

(DIN 51757) Ketumpatan wap relatif (udara):

tidak ditentukan Keterlarutan dalam air:

< 0.02 mg/l (25 °C)

Keterlarutan (kualitatif) pelarut: pelarut organik terlarut

Pekali petakan n-oktanol/air (log Pow): 10 (25 °C)

(Arahan 92/69/EEC, A.4) Penjerapan/air-tanah: log KOC: 6.59

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Tegangan permukaan: 70.6 mN/m

(20 °C; 90 % SATURATION)

(Arahan 92/69/EEC, A.5, Kaedah Gelang Berharmoni OECD)

Kelikatan, dinamik: 44 - 60 mPa.s (20 °C)

Nilai telah ditentukan melalui pengiraan daripada kelikatan kinematik

Jisim molar: 424.66 g/mol

10. Kestabilan dan Kereaktifan

Keadaan yang perlu dielakkan:

Tiada langkah waspada khas selain menyimpan bahan kimia dengan kemas

Penguraian terma: Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku.

Bahan yang perlu dielakkan:

agen pengoksida yang kuat Kakisan kepada

logam:

Tiada kesan mengakis pada logam

Tindak balas berbahaya:

Bertindak balas dengan agen pengoksida yang kuat.

Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

Bahan penguraian berbahaya:

Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

11. Maklumat Toksikologi Ketoksikan akut

Penilaian ketoksikan akut:

Tidak toksik selepas sekali ditelan. Tidak toksik selepas sekali terkena kulit Data eksperimen/dikira:

LD50 tikus (melalui mulut): > 5,000 mg/kg (Garispanduan OECD 423) LD50 tikus (dermal): > 2,000 mg/kg (Garispanduan OECD 402)

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Kerengsaan

Penilaian kesan merengsa:

Boleh menyebabkan sedikit kerengsaan pada kulit. Tidak merengsakan mata.

Data eksperimen/dikira:

Kakisan/Kerengsaan kulit arnab: merengsa sedikit (Garispanduan OECD 404)

Kerosakkan/kerengsaan mata yang serius arnab: tidak merengsa (Garispanduan OECD 405)

Pemekaan pernafasan/kulit

Penilaian pemekaan:

Kesan pemekaan kulit tidak diperhatikan dalam kajian haiwan.

Data eksperimen/dikira:

Ujian pemaksimum tikus kasturi marmut: Tidak memeka (Garispanduan OECD 406)

Kemutagenan sel germa

Penilaian kemutagenan:

Tiada kesan mutagen didapati dalam pelbagai ujian dengan bakteria, Bahan tidak mutagen dalam kajian dengan mamalia.

Kekarsinogenan

Penilaian kekarsinogenan:

Dalam kajian jangka panjang ke atas haiwan, apabila bahan, pada kepekatan yang tinggi, diberi makan kepada haiwan tersebut, tiada kesan karsinogen diperhatikan.

Ketoksikan pembiakan

Penilaian ketoksikan pembiakan:

Keputusan kajian haiwan tidak menunjukkan kesan gangguan kesuburan.

Ketoksikan perkembangan

Penilaian keteratogenan:

Tiada petunjuk kesan ketoksikan/teratogen diperhatikan dalam kajian haiwan.

Ketoksikan khusus organ sasaran (sekali pendedahan):

Penilaian sekali STOT:

Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan.

Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang)

Penilaian ketoksikan dos berulang:

Kesan kepada ginjal tikus jantan dikesan selepas pendedahan berulang. Kesan tersebut adalah khusus kepada tikus jantan dan diketahui tidak berkaitan dengan manusia.

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Bahaya penyedutan

Tidak boleh digunakan

12. Maklumat Ekologi Keekotoksikan

Ketoksikan kepada ikan:

LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, statik) Diuji pada keterlarutan melebihi maksimum. Perincian kesan toksik berkaitan dengan kepekatan nominal.

Invertebrat air:

EC50 (48 h) > 100 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 1, statik)

Perincian kesan toksik berkaitan dengan kepekatan nominal. Keterlarutan produk adalah rendah dalam medium ujian. Eluat telah diuji.

Tumbuhan akuatik:

EC50 (72 h) > 100 mg/l (kadar pertumbuhan), Scenedesmus subspicatus (Garispanduan OECD 201, statik)

Perincian kesan toksik berkaitan dengan kepekatan nominal. Keterlarutan produk adalah rendah dalam medium ujian. Eluat telah diuji.

Mikroorganisma/Kesan ke atas enap cemar diaktifkan:

EC20 (180 min) > 1,000 mg/l, Enap cemar diaktifkan, domestik, aerobik (DIN EN ISO 8192-OECD 209-88/302/EEC,P. C, akuatik)

Ketoksikan kronik kepada ikan:

Tiada data diperoleh.

Ketoksikan kronik kepada invertebrata akuatik:

Tiada kesan kepekatan yang diperhatikan (21 hari), >= 0.021 mg/l, Daphnia magna (Garispanduan OECD 211, semistatik)

Keterlarutan produk adalah rendah dalam medium ujian. Larutan akueus disediakan dengan pelarut telah diuji. Ujian kepekatan had sahaja (ujian HAD).

Penilaian ketoksikan daratan:

Organisma hidupan tanah:

LC50 (14 hari) > 1,000 mg/kg, Eisenia foetida (Garispanduan OECD 207, Tanah tiruan)

Tiada kesan kepekatan yang diperhatikan (56 hari) > 1,000 mg/kg, Eisenia foetida (, Tanah tiruan) EC10 (28 hari) > 1,000 mg/kg, (, tanah semula jadi)

EC10 (28 hari) 447 mg/kg, (, tanah semula jadi) Tumbuhan darat:

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Tiada kesan kepekatan yang diperhatikan (20 hari) > 1.000 mg/kg, Avena sativa (Garispanduan OECD 208)

Tiada kesan kepekatan yang diperhatikan (21 hari) > 1.000 mg/kg, Brassica napus (Garispanduan OECD 208)

Tiada kesan kepekatan yang diperhatikan (21 hari) > 1.000 mg/kg, Vicia sativa (Garispanduan OECD 208)

Bukan-mamalia darat lain:

Mobiliti

Penilaian pengangkutan di antara bahagian di persekitaran:

Diikuti dengan pendedahan kepada tanah, penjerapan ke atas zarah tanah

Keterusan dan boleh keterdegradasikan

Maklumat penyingkiran:

90 - 100 % Pembentukan CO2 relatif kepada nilai teori (60 hari) (OECD 301B; ISO 9439;

92/69/EEC, C.4-C) (aerobik, enap cemar diaktifkan, domestik, tidak disesuaikan)

70 - 80 % Pembentukan CO2 relatif kepada nilai teori (28 hari) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobik, enap cemar diaktifkan, domestik, disesuaikan)

Penilaian kestabilan dalam air:

Maklumat tentang Kestabilan dalam Air (Hidrolisis):

Potensi Biotumpukan

Penilaian potensi bioakumilasi:

Tidak dijangka terakumulasi dalam organisma.

Potensi Biotumpukan:

Faktor Kebiopekatan: 189 (30 hari), Brachydanio rerio (Garispanduan OECD 305 E)

Maklumat tambahan

Nasihat ekotoksikologi lain:

Jangan lepaskan sisa yang tidak dirawat ke dalam air semula jadi.

13. Maklumat Pelupusan

Mestilah dibuang atau dibakar mengikut peraturan tempatan.

Kod sisa menurut katalog sisa Eropah atau EWC (European waste catalog) tidak boleh ditentukan kerana ia bergantung pada penggunaannya.

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Pembungkusan tercemar:

Bungkusan yang tercemar hendaklah dikosongkan sejauh yang boleh; kemudian ia boleh dihantar untuk dikitar semula setelah dibasuh bersih-bersih.

14. Maklumat Pengangkutan

Pengangkutan domestik:

Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan

Pengangkutan laut IMDG

Pengangkutan udara IATA/ICAO

Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC

Peraturan: Tidak dinilai

Penghantaran yang diluluskan:

Tidak dinilai Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai

15. Maklumat Pengawalseliaan

Peraturan lain

Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini.

16. Maklumat lain

Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya.

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Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

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1. Identification of the chemical and of the supplier

HEXAMOLL® DINCH

Chemical name: 1,2-Cyclohexanedicarboxylic acid, diisononyl ester CAS Number: 166412-78-8

Use: plasticizers

Company:

BASF (Malaysia) Sdn Bhd

Lot 19.02 Level 19, 1 Powerhouse No 1 Persiaran Bandar Utama 47800 Petaling Jaya

Selangor D.E, MALAYSIA Telephone: +60 3 7612 1888 Telefax number: +60 3 7612 1777 Emergency information:

National emergency number:

+603 7612 1999

International emergency number:

Telephone: +49 180 2273-112

2. Hazard identification

Classification of the substance and mixture:

No need for classification according to GHS criteria for this product.

Label elements and precautionary statement:

The product does not require a hazard warning label in accordance with GHS criteria.

Other hazards which do not result in classification:

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

See section 12 - Results of PBT and vPvB assessment.

3. Composition/information on ingredients

Chemical nature

1,2-Cyclohexanedicarboxylic acid, diisononyl ester (Content (W/W): >= 99.5 %) CAS Number: 166412-78-8

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4. First-Aid Measures

General advice:

Remove contaminated clothing.

If inhaled:

If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:

Rinse mouth and then drink 200-300 ml of water.

Note to physician:

Symptoms: (Further) symptoms and / or effects are not known so far Note to physician:

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire-Fighting Measures

Suitable extinguishing media:

carbon dioxide, dry powder, water spray, foam Specific hazards:

The product is combustible. Cool endangered containers with water-spray.

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

6. Accidental Release Measures

Personal precautions:

Handle in accordance with good industrial hygiene and safety practice.

Environmental precautions:

Discharge into the environment must be avoided.

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Methods for cleaning up or taking up:

Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

7. Handling and Storage

Handling

Ensure thorough ventilation of stores and work areas.

Storage

Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

8. Exposure controls and personal protection

Components with occupational exposure limits

No occupational exposure limits known.

Personal protective equipment Respiratory protection:

Respiratory protection not required.

Hand protection:

Chemical resistant protective gloves (EN 374) nitrile rubber (NBR) - 0.4 mm coating thickness

Manufacturer's directions for use should be observed because of great diversity of types.

Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.

temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection:

Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice.

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9. Physical and Chemical Properties

Form: liquid

Colour: colourless

Odour: almost odourless

Odour threshold: not determined pH value:

not applicable, of very low solubility

pour point: -54 °C (DIN ISO 3016)

boiling temperature: approx. 394 °C (1,013 hPa)

Cannot be distilled without

decomposition at normal pressure.

(Directive 92/69/EEC, A.2)

Flash point: 224 °C

When exposed to high temperatures over a long period of time, formation of outgassing flammable

decomposition products may occur.

(Directive 92/69/EEC, A.9, closed cup)

Evaporation rate:

Value can be approximated from Henry's Law Constant or vapor pressure.

Flammability (solid/gas): hardly combustible (derived from flash point) Lower explosion limit:

(approx. 170 °C, approx. 1013 hPa) The lower explosion point of the substance/mixture has been determined. The explosion point describes the temperature of a flammable liquid at which the

concentration of the saturated vapour mixed with air equals the lower explosion limit.

(DIN EN 15794, air)

Upper explosion limit:

As a consequence of the thermal decomposition behavior (see Thermal decomposition) it is not possible to determine the upper explosion limit according to standard DIN EN 1839.

For liquids not relevant for classification and labelling.

Ignition temperature: 330 °C (Directive 92/69/EEC, A.15) Thermal decomposition: When exposed to high temperatures

over a long period of time, formation of outgassing flammable

decomposition products may occur.

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Self ignition: Temperature: 20 °C not self-igniting

Test type: Spontaneous self- ignition at room-temperature.

Explosion hazard: Based on the chemical structure there is no indicating of explosive properties.

Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.

Vapour pressure: < 0.000001 hPa (20 °C)

(Directive 92/69/EEC, A.4)

Density: 0.944 - 0.954 g/cm3 (20 °C)

(DIN 51757) Relative vapour density (air):

not determined Solubility in water:

< 0.02 mg/l (25 °C)

Solubility (qualitative) solvent(s): organic solvents soluble

Partitioning coefficient n-octanol/water (log Pow): 10 (25 °C)

(Directive 92/69/EEC, A.8) Adsorption/water - soil: log KOC: 6.59 (OECD Guideline 121) Surface tension: 70.6 mN/m

(20 °C; 90 % SATURATION)

(Directive 92/69/EEC, A.5, OECD harmonized ring method)

Viscosity, dynamic: 44 - 60 mPa.s (20 °C)

The value was determined by calculation from the detected kinematic viscosity.

(calculated (from kinematic viscosity))

Molar mass: 424.66 g/mol

10. Stability and Reactivity

Conditions to avoid:

No special precautions other than good housekeeping of chemicals.

Thermal decomposition: When exposed to high temperatures over a long period of time, formation of outgassing flammable decomposition products may occur.

Substances to avoid:

strong oxidizing agents

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Corrosion to metals: No corrosive effect on metal.

Hazardous reactions:

Reacts with strong oxidizing agents.

No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

Experimental/calculated data:

LD50 rat (oral): > 5,000 mg/kg (OECD Guideline 423) LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:

May cause slight irritation to the skin. Not irritating to the eyes.

Skin corrosion/irritation rabbit: Slightly irritating. (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:

Skin sensitizing effects were not observed in animal studies.

Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)

Germ cell mutagenicity

Assessment of mutagenicity:

No mutagenic effect was found in various tests with bacteria, microorganims and mammalian cell culture. The substance was not mutagenic in studies with mammals.

Carcinogenicity

Assessment of carcinogenicity:

In long-term animal studies in which the substance was given in high concentrations by feed, a carcinogenic effect was not observed.

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Reproductive toxicity

Assessment of reproduction toxicity:

The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:

No indications of a developmental toxic / teratogenic effect were seen in animal studies.

Specific target organ toxicity (single exposure):

Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

Effects on the kidney of male rats were detected after repeated exposure. These effects are specific for the male rat and are known to be of no relevance to humans.

Aspiration hazard

not applicable

12. Ecological Information Ecotoxicity

Toxicity to fish:

LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, static)

Tested above maximum solubility. The details of the toxic effect relate to the nominal concentration.

Aquatic invertebrates:

EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An eluate has been tested.

Aquatic plants:

EC50 (72 h) > 100 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An eluate has been tested.

Microorganisms/Effect on activated sludge:

EC20 (180 min) > 1,000 mg/l, activated sludge, domestic, aerobic (DIN EN ISO 8192-OECD 209- 88/302/EEC,P. C, aquatic)

Chronic toxicity to fish:

No data available.

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Chronic toxicity to aquatic invertebrates:

No observed effect concentration (21 d), >= 0.021 mg/l, Daphnia magna (OECD Guideline 211, semistatic)

The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Limit concentration test only (LIMIT test).

Assessment of terrestrial toxicity:

Soil living organisms:

LC50 (14 d) > 1,000 mg/kg, Eisenia foetida (OECD Guideline 207, artificial soil)

No observed effect concentration (56 d) > 1,000 mg/kg, Eisenia foetida (OECD Guideline 222, artificial soil)

EC10 (28 d) > 1,000 mg/kg, soil dwelling microorganisms (OECD 217, natural soil) EC10 (28 d) 447 mg/kg, soil dwelling microorganisms (OECD 216, natural soil) Terrestrial plants:

No observed effect concentration (20 d) > 1.000 mg/kg, Avena sativa (OECD Guideline 208) No observed effect concentration (21 d) > 1.000 mg/kg, Brassica napus (OECD Guideline 208) No observed effect concentration (21 d) > 1.000 mg/kg, Vicia sativa (OECD Guideline 208) Other terrestrial non-mammals:

No data available.

Mobility

Assessment transport between environmental compartments:

Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

Persistence and degradability

Elimination information:

90 - 100 % CO2 formation relative to the theoretical value (60 d) (OECD 301B; ISO 9439;

92/69/EEC, C.4-C) (aerobic, activated sludge, domestic, non-adapted)

70 - 80 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge, domestic, adapted)

Assessment of stability in water:

No data available.

Information on Stability in Water (Hydrolysis):

No data available.

Bioaccumulation potential

Assessment bioaccumulation potential:

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Accumulation in organisms is not to be expected.

Bioaccumulation potential:

Bioconcentration factor: 189 (30 d), Brachydanio rerio (OECD Guideline 305 E)

Additional information

Other ecotoxicological advice:

Do not release untreated into natural waters.

13. Disposal Considerations

Must be disposed of or incinerated in accordance with local regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.

14. Transport Information

Domestic transport:

Not classified as a dangerous good under transport regulations

Sea transport IMDG

Air transport IATA/ICAO

Transport in bulk according to Annex II of MARPOL and the IBC Code

Regulation: Not evaluated

Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated

Ship Type: Not evaluated

15. Regulatory Information

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Other regulations

If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection.

16. Other Information

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the

corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.