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(1)

Glass Ukur dan Spatula Mortar

Molding Neraca

Oven Magnetizer

(2)

Gaussmeter Vial Ballmill

Hidraulic press Thermolyne Furnace High Temperature

Jangka Sorong

(3)

Hematit Barium Karbonat

Mangan Oksida Polimer Celuna WE - 518

Aquades Resin

(4)

LAMPIRAN 2

MAGNET – PHYSICS Dr. STEINGROEVER GmbH

PERMAGRAPH

(HASIL PENGUJIAN PERMAGRAF MAGNET

BaFe

12-x

Mn

x

O

19

)

(5)

(6)

(7)

LAMPIRAN 3

HASIL PENGUJIAN SEM/EDAXMAGNET

BaFe

12-x

Mn

x

O

19

(8)

(9)

(10)

LAMPIRAN 4

HASIL PENGUJIAN XRD MAGNET

BaFe

12-x

Mn

x

O

19

(11)

(12)

(13)

(14)

< Group: 0444 Data: X-0,1 > < Group: 0444 Data: X-0,1 >< Group: 0444 Data: X-0,1 > < Group: 0444 Data: X-0,1 >

500 1000 1500 2000

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

Profile

Smoothing Profile

B.G. Subtract Profile

Ka1 Profile

Peak

I (CPS)

Theta-2Theta (deg)

I (CPS)

(15)

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

(CPS)

(deg)

20 40 60 80 100

0

20

40

60

80

100

10 20 30 40 50 60 70 80

(%)

(deg)

20 40 60 80 100

0 20 40 60 80 100

10 20 30 40 50 60 70 80

BaFe12O19(27-1029)

Fe2O3(33-0664)

(%)

(deg) ********** SEARCH / MATCH RESULT **********

Group Name : 0444

Data Name : X-0,1

File Name : X-0,1.PKR

Sample Name : X-0,1

Comment :

Date & Time : 05-14-13 13:26:29

(16)

********** SEARCH / MATCH RESULT **********

Group Name : 0444

Data Name : X-0,1

Sample Name : X-0,1

Comment :

No. Card Chemical Formula S L d I R

Chemical Name (Mineral Name) Dx WT% S.G.

1 27-1029 BaFe12O19 0.911 0.556(20/36) 0.890 0.806 0.399

Barium Iron Oxide 5.29 P63/mmc

2 33-0664 Fe2O3 0.243 0.300( 6/45) 0.648 0.359 0.070

Iron Oxide ( Hematite, syn ) 5.27 R-3c

(17)

Group Name : 0444

Data Name : X-0,1

Sample Name : X-0,1

Comment :

1 41-0846 Ba3Fe32O51 0.829 0.600(18/30) 0.884 0.811 0.430

Barium Iron Oxide 7.18 --- P63/mmc

2 27-1029 BaFe12O19 0.911 0.556(20/36) 0.890 0.806 0.399

3 43-0002 BaFe12O19 0.947 0.382(21/59) 0.911 0.849 0.295

4 39-1433 BaFe12O19 0.826 0.440(22/52) 0.828 0.795 0.290

5 76-0123 FeOOH 0.345 0.455( 5/13) 0.801 0.683 0.249

4.32 --- P-3m1

6 13-0087 Fe+3O(OH) 0.255 0.714( 5/10) 0.393 0.647 0.182

Iron Oxide Hydroxide ( Feroxyhite, syn ) 4.39 --- P312

7 74-1121 BaFe12O19 0.958 0.232(22/124) 0.888 0.834 0.171

5.29 --- P63/mmc

8 89-6176 Ba0.98Fe11.93O18.84 0.970 0.227(22/125) 0.888 0.848 0.171

5.25 --- P63/mmc

9 79-1742 BaFe11.9O19 0.963 0.229(22/122) 0.882 0.842 0.170

5.26 --- P63/mmc

10 89-6175 Ba0.97Fe11.90O18.74 0.970 0.227(22/126) 0.887 0.842 0.169

5.23 --- P63/mmc

11 84-0757 BaFe12O19 0.951 0.227(22/126) 0.903 0.822 0.168

5.30 --- P63/mmc

12 89-6172 Ba0.87Fe11.08O17.15 0.943 0.227(22/125) 0.885 0.836 0.168

4.82 --- P63/mmc

13 89-6173 Ba0.91Fe11.68O18.02 0.962 0.224(22/127) 0.884 0.843 0.167

5.07 --- P63/mmc

14 89-6174 Ba0.94Fe11.90O18.07 0.968 0.224(22/126) 0.886 0.835 0.166

5.16 --- P63/mmc

15 30-0143 BaO 0.652 0.444( 4/10) 0.606 0.557 0.150

Barium Oxide 7.22 --- P63/mmc

16 85-0827 D2 0.481 0.538( 7/15) 0.553 0.489 0.146

0.10 --- Pa-3

17 36-0765 H2O 0.538 0.267( 4/18) 0.884 0.607 0.143

Ice --- ---

18 85-1252 H2 0.288 0.500( 6/13) 0.616 0.407 0.125

0.07 --- P63/mmc

19 13-0089 Fe(OH)2 0.281 0.556( 5/16) 0.454 0.490 0.123

Iron Hydroxide 3.53 --- P-3m1

20 78-0133 BaFe12O19 0.962 0.237(22/119) 0.718 0.725 0.123

(18)

Group Name : 0444

Data Name : X-0,1

Sample Name : X-0,1

Comment :

21 29-0712 Fe5O7(OH).4H2O 0.285 0.667( 4/ 6) 0.307 0.599 0.123

Iron Oxide Hydroxide Hydrate ( Ferrihydrit 3.80 --- P

22 75-1550 FeO 0.254 1.000( 5/ 5) 0.183 0.602 0.110

( Wuestite, syn ) 5.99 --- Fm-3m

23 85-1254 H2 0.673 0.545( 6/12) 0.716 0.273 0.106

0.07 --- P63/mmc

24 52-0513 Fe 0.230 1.000( 3/ 8) 0.173 0.579 0.100

Iron 7.57 --- Fm-3m

25 33-0664 Fe2O3 0.243 0.300( 6/45) 0.648 0.359 0.070

Iron Oxide ( Hematite, syn ) 5.27 --- R-3c

(19)

(20)

(21)

(22)

500 1000 1500 2000

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

Profile

Smoothing Profile

Ka1 Profile

Peak

I (CPS)

Theta-2Theta (deg)

I (CPS)

(23)

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

(CPS)

(deg)

20 40 60 80 100

0

20

40

60

80

100

10 20 30 40 50 60 70 80

(%)

(deg)

20 40 60 80 100

0 20 40 60 80 100

10 20 30 40 50 60 70 80

BaFe12O19(27-1029)

Fe2O3(33-0664)

(%)

Group Name : 0444

Data Name : X-0,7

Sample Name : X-0,7

Comment :

Date & Time : 05-14-13 15:01:45

(24)

Group Name : 0444

Data Name : X-0,7

Sample Name : X-0,7

Comment :

1 27-1029 BaFe12O19 0.928 0.556(20/36) 0.824 0.842 0.386

2 33-0664 Fe2O3 0.280 0.300( 6/45) 0.629 0.336 0.063

Iron Oxide ( Hematite, syn ) 5.27 R-3c

(25)

Group Name : 0444

Data Name : X-0,7

Sample Name : X-0,7

Comment :

1 41-0846 Ba3Fe32O51 0.864 0.567(17/30) 0.875 0.832 0.412

2 27-1029 BaFe12O19 0.928 0.556(20/36) 0.824 0.842 0.386

3 52-0513 Fe 0.255 1.000( 3/ 8) 0.393 0.767 0.301

Iron 7.57 --- Fm-3m

4 43-0002 BaFe12O19 0.976 0.364(20/59) 0.859 0.861 0.269

5 39-1433 BaFe12O19 0.836 0.400(20/52) 0.798 0.803 0.256

6 85-0825 D2 0.513 0.667( 4/ 8) 0.638 0.602 0.256

0.10 --- Fm-3m

7 13-0087 Fe+3O(OH) 0.260 0.714( 5/10) 0.442 0.678 0.214

8 76-0123 FeOOH 0.322 0.364( 4/13) 0.785 0.700 0.200

4.32 --- P-3m1

9 85-0827 D2 0.513 0.417( 5/15) 0.714 0.551 0.164

0.10 --- Pa-3

10 74-1121 BaFe12O19 0.973 0.221(21/124) 0.851 0.814 0.153

5.29 --- P63/mmc

11 84-0757 BaFe12O19 0.970 0.216(21/126) 0.873 0.809 0.153

5.30 --- P63/mmc

12 89-6175 Ba0.97Fe11.90O18.74 0.987 0.216(21/126) 0.848 0.830 0.152

5.23 --- P63/mmc

13 89-6176 Ba0.98Fe11.93O18.84 0.983 0.216(21/125) 0.849 0.827 0.152

5.25 --- P63/mmc

14 79-1742 BaFe11.9O19 0.979 0.219(21/122) 0.844 0.822 0.152

5.26 --- P63/mmc

15 89-6172 Ba0.87Fe11.08O17.15 0.965 0.216(21/125) 0.844 0.826 0.151

4.82 --- P63/mmc

16 89-6173 Ba0.91Fe11.68O18.02 0.975 0.214(21/127) 0.844 0.823 0.149

5.07 --- P63/mmc

17 89-6174 Ba0.94Fe11.90O18.07 0.983 0.214(21/126) 0.846 0.819 0.148

5.16 --- P63/mmc

18 78-0133 BaFe12O19 0.981 0.226(21/119) 0.793 0.738 0.132

5.36 --- P63/mmc

19 30-0143 BaO 0.742 0.333( 3/10) 0.577 0.678 0.130

20 85-1251 H2 1.000 0.417( 5/15) 0.523 0.568 0.124

(26)

Group Name : 0444

Data Name : X-0,7

Sample Name : X-0,7

Comment :

21 29-0712 Fe5O7(OH).4H2O 0.288 0.667( 4/ 6) 0.269 0.621 0.111

Iron Oxide Hydroxide Hydrate ( Ferrihydrit 3.80 --- P

22 40-1047 Ba2Fe14O22 0.536 0.364(16/44) 0.556 0.508 0.103

Barium Iron Oxide 1.81 --- R

23 85-1254 H2 0.685 0.545( 6/12) 0.656 0.282 0.101

0.07 --- P63/mmc

24 33-0664 Fe2O3 0.280 0.300( 6/45) 0.629 0.336 0.063

Iron Oxide ( Hematite, syn ) 5.27 --- R-3c

(27)

(28)

(29)

(30)

500 1000 1500 2000

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

Profile

Smoothing Profile

Ka1 Profile

Peak

I (CPS)

Theta-2Theta (deg)

I (CPS)

(31)

0 500 1000 1500 2000

10 20 30 40 50 60 70 80

(CPS)

(deg)

20 40 60 80 100

0

20

40

60

80

100

10 20 30 40 50 60 70 80

(%)

(deg)

0 20 40 60 80 100

10 20 30 40 50 60 70 80

BaFe12O19(27-1029)

(%)

Group Name : 0444

Data Name : X-1,5

Sample Name : X-1,5

Comment :

Date & Time : 05-14-13 13:54:20

(32)

Group Name : 0444

Data Name : X-1,5

Sample Name : X-1,5

Comment :

1 27-1029 BaFe12O19 0.915 0.583(21/36) 0.859 0.835 0.418

(33)

Group Name : 0444

Data Name : X-1,5

Sample Name : X-1,5

Comment :

1 41-0846 Ba3Fe32O51 0.835 0.633(19/30) 0.878 0.812 0.451

2 27-1029 BaFe12O19 0.915 0.583(21/36) 0.859 0.835 0.418

3 13-0087 Fe+3O(OH) 0.267 1.000( 7/10) 0.543 0.646 0.351

4 43-0002 BaFe12O19 0.953 0.491(27/59) 0.816 0.812 0.325

5 39-1433 BaFe12O19 0.818 0.500(25/52) 0.773 0.768 0.297

6 85-0825 D2 0.506 1.000( 6/ 8) 0.567 0.501 0.284

0.10 --- Fm-3m

7 30-0143 BaO 0.700 0.556( 5/10) 0.619 0.660 0.227

8 13-0089 Fe(OH)2 0.305 0.667( 6/16) 0.554 0.576 0.212

Iron Hydroxide 3.53 --- P-3m1

9 85-0827 D2 0.506 0.667( 8/15) 0.676 0.441 0.199

0.10 --- Pa-3

10 76-0123 FeOOH 0.345 0.727( 8/13) 0.583 0.466 0.197

4.32 --- P-3m1

11 74-1121 BaFe12O19 0.971 0.326(31/124) 0.758 0.756 0.187

5.29 --- P63/mmc

12 84-0757 BaFe12O19 0.958 0.320(31/126) 0.785 0.733 0.184

5.30 --- P63/mmc

13 89-6176 Ba0.98Fe11.93O18.84 0.976 0.320(31/125) 0.764 0.750 0.183

5.25 --- P63/mmc

14 79-1742 BaFe11.9O19 0.972 0.323(31/122) 0.751 0.749 0.182

5.26 --- P63/mmc

15 89-6175 Ba0.97Fe11.90O18.74 0.978 0.320(31/126) 0.754 0.752 0.181

5.23 --- P63/mmc

16 89-6172 Ba0.87Fe11.08O17.15 0.954 0.320(31/125) 0.751 0.751 0.180

4.82 --- P63/mmc

17 89-6173 Ba0.91Fe11.68O18.02 0.973 0.316(31/127) 0.751 0.750 0.178

5.07 --- P63/mmc

18 89-6174 Ba0.94Fe11.90O18.07 0.976 0.316(31/126) 0.753 0.740 0.176

5.16 --- P63/mmc

19 22-0346 Fe(OH)3 0.346 0.500( 4/ 8) 0.527 0.654 0.173

Iron Hydroxide --- ---

20 78-0133 BaFe12O19 0.970 0.323(30/119) 0.757 0.696 0.170

(34)

Group Name : 0444

Data Name : X-1,5

Sample Name : X-1,5

Comment :

21 77-0247 FeOOH 0.383 0.750( 9/14) 0.525 0.349 0.137

4.29 --- P-3m1

22 36-0766 H2O 0.723 0.550(11/20) 0.550 0.450 0.136

Ice --- ---

23 36-0765 H2O 0.545 0.400( 6/18) 0.614 0.540 0.133

Ice --- ---

24 85-1260 H2 0.494 0.778( 7/11) 0.443 0.353 0.122

0.09 --- P63/mmc

25 85-1251 H2 0.958 0.417( 5/15) 0.524 0.547 0.119

0.06 --- P63/mmc

26 75-0449 Fe3O4 0.559 0.571( 8/16) 0.658 0.305 0.115

( Magnetite ) 5.34 --- Fd-3m

(35)

LAMPIRAN 5

HASIL PENGUJIAN VECTOR NETWORK

ANALYZER (VNA) BaFe12-xMnxO19

(36)

(37)

LAMPIRAN 6

PERHITUNGAN STOKIOMETRI

(38)

massa serbuk yang diinginkan

MnO (x)

Ferit (12

-X) %mol MnO

%mol Ferit

massa MnO

massa Ferit

massa BaCO3

massa

total MnO Ferit BaCO3

0.1 11.9 0.83333333 99.166667 3.547 950.215 197.33 1151.092 0.369771 99.05881 20.57142

0.3 11.7 2.5 97.5 10.641 934.245 197.33 1142.216 1.117932 98.15079 20.73128

0.5 11.5 4.16666667 95.833333 17.735 918.275 197.33 1133.34 1.877812 97.22855 20.89364 0.7 11.3 5.83333333 94.166667 24.829 902.305 197.33 1124.464 2.649689 96.29174 21.05857 1 11 8.33333333 91.666667 35.47 878.35 197.33 1111.15 3.830626 94.85848 21.31089 1.3 10.7 10.8333333 89.166667 46.111 854.395 197.33 1097.836 5.040206 93.39045 21.56934

1.5 10.5 12.5 87.5 53.205 838.425 197.33 1088.96 5.863025 92.39182 21.74515