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Ensemble of independent adhesive elements

d

Figure 5.8: An ensemble of springs against a rough rigid surface. The response of each element is as in the previous section and there is no interaction between the elements.

Consider an ensemble of springs hanging from a flat rigid surface and sitting above a rough rigid surface. The rough surface has a probability distribution of heights P(¯h).

The distance between the flat surface and the mean height of the rough surface is ¯d.

For each spring, if the height of the rough surface against it is ¯h, the energy is given by:

E¯ = 1

2( ¯d−¯h−δ)¯2−γe¯ δ¯, (5.9) where ¯δ is still the separation between the spring and the surface. From the energy, it follows that all of the analysis of the previous section carries through if ¯d of the previous section is replaced by ¯d−¯h. The force in the spring is now given by:

F¯(¯h) = ¯d−h¯−δ.¯

We restrict our attention to the case ¯γ >1. Thus, if the height of the rigid surface is ¯h, the snap-in and snap-off dilatation are given by:

snap-in = 1 + ¯h+ log(¯γ), d¯snap-off = ¯h+ ¯γ.

5.3.1 Loading

During loading, if the dilatation is ¯d, all springs with ¯δ≤1 + log(¯γ) snap into contact.

Defining

snap-in = ¯d−(1 + log(¯γ)),

all springs where ¯h ≥ ¯hsnap-in are in contact at dilatation ¯d. The total force of the ensemble, ¯FN, is given by:

N( ¯d) = Z

−∞

F¯(¯h)P(¯h)d¯h

= Z

−∞

( ¯d−¯h−δ)P¯ (¯h)d¯h

= ¯d−<h >¯ − Z

−∞

δP¯ (¯h)d¯h.

(5.10)

Without loss of generality < ¯h > can be set to zero, since this is the same as using the level of mean heights as the reference level. If ¯h≥h¯snap-in, the springs snap into contact and ¯δ = 0. Otherwise, ¯δ is given by the solution to:

d¯−¯h−¯δ= ¯γe¯δ.

Thus,

N( ¯d) = ¯d−

Z ¯hsnap-in

−∞

¯δ(¯h)P(¯h)d¯h.

5.3.2 Unloading

Suppose we load up to a minimimum dilatation ¯dmin and then start increasing the dilatation. All springs where the height of the rigid surface is greater than or equal to ¯hmin = ¯dmin − (1 + log(¯γ)) have snapped into contact. On unloading, some of these snap out of contact. So, for given ¯d during unloading, we define ¯hsnap-off as the height of the rough surface above which the springs are in contact and below which the springs have either snapped out of contact or never came into contact. It can be

seen that:

¯hsnap-off = max(¯hmin,d¯−γ).¯ So, during unloading, the force is given by,

N( ¯d) = Z

−∞

F¯(¯h)P(¯h)d¯h

= Z

−∞

( ¯d−¯h−δ)P¯ (¯h)d¯h

= ¯d−

Z max(¯hmin,d−¯¯ γ)

−∞

δP¯ (¯h)d¯h.

(5.11)

5.3.3 Energy dissipation

In one loading-unloading cycle, if the minimum dilatation is ¯dmin, all the springs where

¯h≥¯hmin snap into and out of contact. Thus, the total energy dissipated in one cycle is given by:

∆ ¯E( ¯dmin) = (∆ ¯Esnap-in+ ∆ ¯Esnap-off) Z

¯hmin

P(¯h)d¯h, (5.12) where ∆ ¯Esnap-in and ∆ ¯Esnap-off are given by equation 5.7.

5.3.4 Force evolution

From here, the heights of the rigid surface has are assumed to have a Gaussian probability distribution with an rms roughness σ. Thus,

P(¯h) = 1

√2πσe¯h2/2σ2.

Consider a loading-unloading cycle of an ensemble of springs. The hysteresis in the individual springs manifests as a hysteresis is the global response (Figure5.9). At a large dilatation, the force is initially tensile and on further loading, the springs snap into contact and are subsequently compressed. The total force reaches a tensile peak and then becomes compressive. After reaching a minimum dilatation, the system is unloaded and the springs remain in contact until their snap-off point is reached and thus, during unloading, the force is greater (more positive) than during loading. With

further increase in dilatation, the force reaches a peak tensile value and then decays to zero. The tensile peak during unloading is greater than the peak achieved during loading. We define the peak tensile force during unloading as the adhesive strength ( ¯Fmax) of the surface. We now study the dependence of the adhesive strength on d¯min,γ,¯ and σ.

0 1 2 3 4

−0.6

−0.4

−0.2 0 0.2 0.4 0.6 0.8

Dilatation (d¯) Force(¯FN)

¯ γ= 2

σ= 1 LoadingUnloading

Figure 5.9: A typical loading-unloading process for the ensemble. The hysteresis of each element leads to the hysteresis in the ensemble response.

5.3.5 Depth-dependence of adhesive strength

−10 0 1 2

0.5 1 1.5 2 2.5

d¯m in Adhesionstrength(¯Fmax)

¯

γ= 2,σ= 1

¯

γ= 2,σ= 2

¯

γ= 4,σ= 1

Figure 5.10: Dependence of the adhesion strength on (a) ¯dmin, the minimum dilatation achieved during the loading phase. For ¯dmin/σ < 1, the adhesive strength remains nearly constant.

The adhesive strength depends on ¯dmin, the minimum dilatation achieved during the loading phase. With decreasing ¯dmin, a larger fraction of the elements snap-into contact and contribute to adhesion, and thus the adhesive strength increases (Figure 5.10). For ¯dmin/σ < 1, the adhesive strength remains nearly constant since the new springs that snap into contact when compressed beyond ¯dmin/σ = 1 snap out of contact before the force peaks and thus do not contribute to the adhesive strength.

5.3.6 Dependence of adhesive strength on roughness

Experiments show that over a large range of roughness, the adhesion strength de- creases with increasing surface roughness, but for a relatively short range it increases with increasing roughness [104, 82, 105, 106, 107]. In our model, ¯Fmax decreases monotonically with increasing σ (Figure 5.11) which agrees with variation seen in experiments for a large range of roughness.

Our model does not include two potentially important factors, the spatial structure of roughness and elastic interactions between contacts. Our conjecture is that one or both of these is necessary for the non-monotonicity of adhesion strength.

0 1 2 3 4 5 0

0.5 1 1.5 2 2.5 3 3.5 4

Roughness (σ)

Adhesionstrength(¯Fmax) ¯γ= 2

¯ γ= 3

¯ γ= 4

Figure 5.11: Dependence of ¯Fmax on σ. The adhesion strength decreases monotoni- cally with increasing roughness.

5.3.7 Depth-dependent energy dissipation

−20 −1 0 1 2 3

0.2 0.4 0.6 0.8 1 1.2 1.4

d¯min

Energydissipated(¯E/¯γ) σ = 1 ¯γ= 2

¯ γ= 2.5

¯ γ= 3

¯ γ= 3.5

¯ γ= 4

(a)

(pJ)

100 200 300 400 500 600

1.6

1.5

1.4

1.3

(b)

Figure 5.12: Depth dependence of hysteresis during a loading-unloading cycle: (a) In our simulations, hysteresis increases with decreasing indentation depth and saturates to a constant value at about ¯dmin/σ = 0. (b) In experiments of Kesari et al., hysteresis increases with the indentation depth (reproduced with permission from [107]). Note:

Decreasing ¯dmin in (a) corresponds to increasing|hmin| in (b).

Kesari et al. [107] studied how the energy dissipated in a loading-unloading cycle depends on the minimum dilatation achieved during loading (Figure 5.12b). Figure 5.12a shows the energy dissipated during a loading-unloading cycle as a function of

min in our model. When ¯dmin/σis betwen 0 and 3, the energy dissipated variation is similar to what is observed in the experiments (Note: In Figure 5.12, decreasing ¯dmin in (a) corresponds to increasing |hmin| in (b)). For ¯dmin/σ <0, the energy dissipated is nearly constant since the probability density of heights is small in this region (note that when ¯dmin = 0, all springs where ¯h ≥ −(1 + log(¯γ)) have already snapped into contact).

5.3.8 Dependence of energy dissipation on surface roughness and surface energy

For a single element, the energy dissipated can be significant compared to the re- versible surface energy (Section 5.2.2). The presence of roughness can reduce the dissipation considerably. Surprisingly, even for a rough surface, if ¯γ 1, the dissi- pation can be a considerable fraction of, and even larger than, the reversible work of adhesion ¯γ (Figure 5.13). For a given ¯dmin/σ, the energy dissipated decreases with increasing roughness, and this decrease is stronger for larger ¯dmin/σ.

0 1 2 3 4 5

0 0.2 0.4 0.6 0.8 1 1.2 1.4

σ Energydissipated(¯E/¯γ)

d¯m in= 0 γ¯= 2

¯ γ= 2.5

¯ γ= 3

¯ γ= 3.5

¯ γ= 4

(a)

0 1 2 3 4 5

0 0.2 0.4 0.6 0.8 1 1.2 1.4

σ

Energydissipated(¯E/¯γ) ¯dm in= 1 ¯γ= 2

¯ γ= 2.5

¯ γ= 3

¯ γ= 3.5

¯ γ= 4

(b)

Figure 5.13: Energy dissipated during a loading-unloading cycle as a function of σ for different ¯γ: (a) ¯dmin = 0 and (b) ¯dmin/σ= 1.

In this section, the linear elastic spring were non-interacting. In the next section, we extend the formulation to the contact of three dimensional rough surfaces, and incorporate long-range elastic interactions and inelastic (viscoelastic and viscoplastic)

effects.

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