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Synthetic and mechanistic studies into the kinetic resolution of alpha-olefins using C1- and C2- symmetric zirconocene polymerization catalysts

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Figure 1.2  DSC thermographs for poly(3,4-dimethyl-1-pentene-co-ethylene) with (red,  solid) and without (blue, dashed) sequential nucleation and annealing
Figure 1.3  Methylene sequence length distribution from SNA analysis of poly(3,4- poly(3,4-dimethyl-1-pentene-co-ethylene)
Figure 1.6   13 C{ 1 H} NMR spectrum of poly(4-co-ethylene); eg = end group.
Figure 1.8  Diagram of sequential nucleation and annealing (SNA) temperature program.
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