Abstract
X- Ray Crystallography Reports Relevant to Chapter 5
Figure A13.1.1. X-Ray Crystal Structure of Thioimidate 440. ... 713 Figure A13.2.1. X-Ray Crystal Structure of Amidine (R)-450•HBr. ... 724
APPENDIX 14
Spectra Relevant to Chapter 6
Figure A14.1. 1H NMR (500 MHz, CDCl3) of compound 568. ... 862 Figure A14.2. Infrared spectrum (thin film/NaCl) of compound 568. ... 863 Figure A14.3. 13C NMR (126 MHz, CDCl3) of compound 568. ... 863
Figure A14.4. 1H NMR (500 MHz, CDCl3) of compound 570. ... 864 Figure A14.5. Infrared spectrum (thin film/NaCl) of compound 570. ... 865 Figure A14.6. 13C NMR (126 MHz, CDCl3) of compound 570. ... 865 Figure A14.7. 1H NMR (500 MHz, CDCl3) of compound 572. ... 866 Figure A14.8. Infrared spectrum (thin film/NaCl) of compound 572. ... 867 Figure A14.9. 13C NMR (126 MHz, CDCl3) of compound 572. ... 867 Figure A14.10. 1H NMR (500 MHz, CDCl3) of compound 574. ... 868 Figure A14.11. Infrared spectrum (thin film/NaCl) of compound 574. ... 869 Figure A14.12. 13C NMR (126 MHz, CDCl3) of compound 574. ... 869 Figure A14.13. 1H NMR (500 MHz, CDCl3) of compound 581. ... 870 Figure A14.14. Infrared spectrum (thin film/NaCl) of compound 581. ... 871 Figure A14.15. 13C NMR (126 MHz, CDCl3) of compound 581. ... 871 Figure A14.16. 1H NMR (500 MHz, CDCl3) of compound 582. ... 872 Figure A14.17. Infrared spectrum (thin film/NaCl) of compound 582. ... 873 Figure A14.18. 13C NMR (126 MHz, CDCl3) of compound 582. ... 873 Figure A14.19. Infrared spectrum (thin film/NaCl) of compound 537. ... 874 Figure A14.20. 1H NMR (500 MHz, CDCl3) of compound 540. ... 875 Figure A14.21. Infrared spectrum (thin film/NaCl) of compound 540. ... 876 Figure A14.22. 13C NMR (126 MHz, CDCl3) of compound 540. ... 876 Figure A14.23. Infrared spectrum (thin film/NaCl) of compound 549. ... 877 Figure A14.24. 1H NMR (500 MHz, CDCl3) of compound 499. ... 878 Figure A14.25. Infrared spectrum (thin film/NaCl) of compound 499. ... 879 Figure A14.26. 13C NMR (126 MHz, CDCl3) of compound 499. ... 879 Figure A14.27. 1H NMR (500 MHz, CDCl3) of compound 503. ... 880 Figure A14.28. Infrared spectrum (thin film/NaCl) of compound 503. ... 881 Figure A14.29. 13C NMR (126 MHz, CDCl3) of compound 503. ... 881 Figure A14.30. 1H NMR (500 MHz, CDCl3) of compound 504. ... 882 Figure A14.31. Infrared spectrum (thin film/NaCl) of compound 504. ... 883 Figure A14.32. 13C NMR (126 MHz, CDCl3) of compound 504. ... 883 Figure A14.33. 1H NMR (500 MHz, CDCl3) of compound 505. ... 884 Figure A14.34. Infrared spectrum (thin film/NaCl) of compound 505. ... 885 Figure A14.35. 13C NMR (126 MHz, CDCl3) of compound 505. ... 885 Figure A14.36. 1H NMR (500 MHz, CDCl3) of compound 506. ... 886 Figure A14.37. Infrared spectrum (thin film/NaCl) of compound 506. ... 887 Figure A14.38. 13C NMR (126 MHz, CDCl3) of compound 506. ... 887
Figure A14.39. 1H NMR (500 MHz, CDCl3) of compound 507. ... 888 Figure A14.40. Infrared spectrum (thin film/NaCl) of compound 507. ... 889 Figure A14.41. 13C NMR (126 MHz, CDCl3) of compound 507. ... 889 Figure A14.42. 1H NMR (500 MHz, CDCl3) of compound 508. ... 890 Figure A14.43. Infrared spectrum (thin film/NaCl) of compound 508. ... 891 Figure A14.44. 13C NMR (126 MHz, CDCl3) of compound 508. ... 891 Figure A14.45. 1H NMR (500 MHz, CDCl3) of compound 509. ... 892 Figure A14.46. Infrared spectrum (thin film/NaCl) of compound 509. ... 893 Figure A14.47. 13C NMR (126 MHz, CDCl3) of compound 509. ... 893 Figure A14.48. 1H NMR (500 MHz, CDCl3) of compound 510. ... 894 Figure A14.49. Infrared spectrum (thin film/NaCl) of compound 510. ... 895 Figure A14.50. 13C NMR (126 MHz, CDCl3) of compound 510. ... 895 Figure A14.51. 1H NMR (500 MHz, CDCl3) of compound 511. ... 896 Figure A14.52. Infrared spectrum (thin film/NaCl) of compound 511. ... 897 Figure A14.53. 13C NMR (126 MHz, CDCl3) of compound 511. ... 897 Figure A14.54. 1H NMR (500 MHz, CDCl3) of compound 512. ... 898 Figure A14.55. Infrared spectrum (thin film/NaCl) of compound 512. ... 899 Figure A14.56. 13C NMR (126 MHz, CDCl3) of compound 512. ... 899 Figure A14.57. 1H NMR (500 MHz, CDCl3) of compound 513. ... 900 Figure A14.58. Infrared spectrum (thin film/NaCl) of compound 513. ... 901 Figure A14.59. 13C NMR (126 MHz, CDCl3) of compound 513. ... 901 Figure A14.60. 1H NMR (500 MHz, CDCl3) of compound 514. ... 902 Figure A14.61. Infrared spectrum (thin film/NaCl) of compound 514. ... 903 Figure A14.62. 13C NMR (126 MHz, CDCl3) of compound 514. ... 903 Figure A14.63. 1H NMR (500 MHz, CDCl3) of compound 515. ... 904 Figure A14.64. Infrared spectrum (thin film/NaCl) of compound 515. ... 905 Figure A14.65. 13C NMR (126 MHz, CDCl3) of compound 515. ... 905 Figure A14.66. 1H NMR (500 MHz, CDCl3) of compound 516. ... 906 Figure A14.67. Infrared spectrum (thin film/NaCl) of compound 516. ... 907 Figure A14.68. 13C NMR (126 MHz, CDCl3) of compound 516. ... 907 Figure A14.69. 1H NMR (500 MHz, CDCl3) of compound (S)-546. ... 908 Figure A14.70. Infrared spectrum (thin film/NaCl) of compound (S)-546. ... 909 Figure A14.71. 13C NMR (126 MHz, CDCl3) of compound (S)-546. ... 909 Figure A14.72. 1H NMR (500 MHz, CDCl3) of compound 518. ... 910 Figure A14.73. Infrared spectrum (thin film/NaCl) of compound 518. ... 911
Figure A14.74. 13C NMR (126 MHz, CDCl3) of compound 518. ... 911 Figure A14.75. 1H NMR (500 MHz, CDCl3) of compound 519. ... 912 Figure A14.76. Infrared spectrum (thin film/NaCl) of compound 519. ... 913 Figure A14.77. 13C NMR (126 MHz, CDCl3) of compound 519. ... 913 Figure A14.78. 1H NMR (500 MHz, CDCl3) of compound 522. ... 914 Figure A14.79. Infrared spectrum (thin film/NaCl) of compound 522. ... 915 Figure A14.80. 13C NMR (126 MHz, CDCl3) of compound 522. ... 915 Figure A14.81. 1H NMR (500 MHz, CDCl3) of compound 523. ... 916 Figure A14.82. Infrared spectrum (thin film/NaCl) of compound 523. ... 917 Figure A14.83. 13C NMR (126 MHz, CDCl3) of compound 523. ... 917 Figure A14.84. 1H NMR (500 MHz, CDCl3) of compound 524. ... 918 Figure A14.85. Infrared spectrum (thin film/NaCl) of compound 524. ... 919 Figure A14.86. 13C NMR (126 MHz, CDCl3) of compound 524. ... 919 Figure A14.87. 1H NMR (500 MHz, CDCl3) of compound 525. ... 920 Figure A14.88. Infrared spectrum (thin film/NaCl) of compound 525. ... 921 Figure A14.89. 13C NMR (126 MHz, CDCl3) of compound 525. ... 921 Figure A14.90. 1H NMR (500 MHz, CDCl3) of compound 530•HCl. ... 922 Figure A14.91. Infrared spectrum (thin film/NaCl) of compound 530•HCl. ... 923 Figure A14.92. 13C NMR (126 MHz, CDCl3) of compound 530•HCl. ... 923 Figure A14.93. 1H NMR (500 MHz, CDCl3) of compound 531. ... 924 Figure A14.94. Infrared spectrum (thin film/NaCl) of compound 531. ... 925 Figure A14.95. 13C NMR (126 MHz, CDCl3) of compound 531. ... 925 Figure A14.96. 1H NMR (500 MHz, CDCl3) of compound 532. ... 926 Figure A14.97. Infrared spectrum (thin film/NaCl) of compound 532. ... 927 Figure A14.98. 13C NMR (126 MHz, CDCl3) of compound 532. ... 927 Figure A14.99. 1H NMR (500 MHz, CDCl3) of compound 533. ... 928 Figure A14.100. Infrared spectrum (thin film/NaCl) of compound 533. ... 929 Figure A14.101. 13C NMR (126 MHz, CDCl3) of compound 533. ... 929 Figure A14.102. 1H NMR (500 MHz, CDCl3) of compound 534. ... 930 Figure A14.103. Infrared spectrum (thin film/NaCl) of compound 534. ... 931 Figure A14.104. 13C NMR (126 MHz, CDCl3) of compound 534. ... 931 Figure A14.105. 1H NMR (500 MHz, CDCl3) of compound 536. ... 932 Figure A14.106. Infrared spectrum (thin film/NaCl) of compound 536. ... 933 Figure A14.107. 13C NMR (126 MHz, CDCl3) of compound 536. ... 933 Figure A14.108. 1H NMR (500 MHz, CDCl3) of compound 538. ... 934
Figure A14.109. Infrared spectrum (thin film/NaCl) of compound 538. ... 935 Figure A14.110. 13C NMR (126 MHz, CDCl3) of compound 538. ... 935 Figure A14.111. 1H NMR (500 MHz, CDCl3) of compound 541. ... 936 Figure A14.112. Infrared spectrum (thin film/NaCl) of compound 541. ... 937 Figure A14.113. 13C NMR (126 MHz, CDCl3) of compound 541. ... 937 Figure A14.114. 1H NMR (500 MHz, CDCl3) of compound 542. ... 938 Figure A14.115. Infrared spectrum (thin film/NaCl) of compound 542. ... 939 Figure A14.116. 13C NMR (126 MHz, CDCl3) of compound 542. ... 939 Figure A14.117. 1H NMR (500 MHz, CDCl3) of compound 544. ... 940 Figure A14.118. Infrared spectrum (thin film/NaCl) of compound 544. ... 941 Figure A14.119. 13C NMR (126 MHz, CDCl3) of compound 544. ... 941 Figure A14.120. 1H NMR (500 MHz, CDCl3) of compound 590•HCl. ... 942 Figure A14.121. Infrared spectrum (thin film/NaCl) of compound 590•HCl. ... 943 Figure A14.122. 13C NMR (126 MHz, CDCl3) of compound 590•HCl. ... 943 Figure A14.123. 1H NMR (300 MHz, CDCl3) of compound 550. ... 944 Figure A14.124. Infrared spectrum (thin film/NaCl) of compound 550. ... 945 Figure A14.125. 13C NMR (126 MHz, CDCl3) of compound 550. ... 945 Figure A14.126. Infrared spectrum (thin film/NaCl) of compound 592. ... 946 Figure A14.127. 1H NMR (500 MHz, CDCl3) of compound 593. ... 947 Figure A14.128. Infrared spectrum (thin film/NaCl) of compound 593. ... 948 Figure A14.129. 13C NMR (126 MHz, CDCl3) of compound 593. ... 948 Figure A14.130. 1H NMR (500 MHz, CDCl3) of compound (S)-552. ... 949 Figure A14.131. Infrared spectrum (thin film/NaCl) of compound (S)-552. ... 950 Figure A14.132. 13C NMR (126 MHz, CDCl3) of compound (S)-552. ... 950