Appendix 5 – Spectra Relevant to Chapter 4 713
Appendix 5
Spectra Relevant to Chapter 4:
Mechanistic Investigations of Ni-Catalyzed Asymmetric
Reductive Cross-Couplings with Alkenyl Bromide Electrophiles
Appendix 5 – Spectra Relevant to Chapter 4 714
0 .0 0 .5 1 .0 1 .5 2 .0 2 .5 3 .0 3 .5 4 .0 4 .5 5 .0 5 .5 6 .0 6 .5 7 .0 7 .5 8 .0 8 .5 9 .0 9 .5 1 0 .0 1 0 .5 f1 ( p p m )
A ( m ) 7 .4 8 B (m ) 7 .3 7 C ( d ) 4 .3 3 D ( m ) 1 .6 0 E (d d d d ) 0 .8 5
F (m ) 0 .7 1 G ( m ) 0 .6 2
1.00 1.021.0 2
1.0 2
1.0 0
1.0 0
3.0 9
1.9 7
ParameterValue TitleJLH-4-265-crude OriginVarian Solventcdcl3 Temperature25.0 Pulse Sequences2pul Number of Scans8 Receiver Gain0 Relaxation Delay1.0000 Pulse Width5.1000 Acquisition Time2.4999 Acquisition Date2016-05-15T17:02:06 Spectrometer Frequency300.09 Spectral Width4796.2 Lowest Frequency-596.9 Nucleus1H Acquired Size11990 Spectral Size65536
19 8
Cl
Appendix 5 – Spectra Relevant to Chapter 4 715
0 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 1 0 0 1 1 0 1 2 0 1 3 0 1 4 0 1 5 0 1 6 0 1 7 0 1 8 0 1 9 0 2 0 0 2 1 0 f1 ( p p m )
6.46.6
20 .0
69 .1
12 7.2
12 8.3
12 8.6
14 1.7
ParameterValue TitleJLH-4-265-crude OriginVarian Solventcdcl3 Temperature25.0 Pulse Sequences2pul Number of Scans256 Receiver Gain30 Relaxation Delay1.0000 Pulse Width7.9500 Acquisition Time0.8684 Acquisition Date2016-05-15T17:02:50 Spectrometer Frequency75.47 Spectral Width18867.9 Lowest Frequency-1126.8 Nucleus13C Acquired Size16384 Spectral Size32768
19 8
Cl
