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LEMBAR

HASIL PENILAIAN SEJAWAT SEBIDANG ATAU PEER REVIEW KARYA ILMIAH : JURNAL ILMIAH

Judul Jurnal Ilmiah (Artikel) : Permeability improvement of polyethersulfone-polietylene glycol (PEG-PES) flat sheet type membranes by tripoly-phosphate-crosslinked chitosan (TPP-CS) coating.

Nama/ Jumlah Penulis : Gunawan/11 Status Pengusul : penulis ke-4

Identitas Jurnal Ilmiah : a. Nama Jurnal : International Journal of Biological Macromolecules b. Nomor ISSN : 0141-8130 atau 1879-0003

c. Vol, No., Bln Thn : Volume 152, 1 June 2020

d. Penerbit : Elsevier

e. DOI artikel (jika ada) :

f. Alamat web jurnal : https://www.sciencedirect.com/journal/international- journal-of-biological-macromolecules/vol/152/suppl/C Alamat Artikel : https://doi.org/10.1016/j.ijbiomac.2020.02.290

g. Terindex : Scopus

Kategori Publikasi Jurnal Ilmiah : Jurnal Ilmiah Internasional

(beri pada kategori yang tepat) Jurnal Ilmiah Nasional Terakreditasi Jurnal Ilmiah Nasional Tidak Terakreditasi

Hasil Penilaian Peer Review :

Komponen Yang Dinilai

Nilai Maksimal Jurnal Ilmiah

Nilai Akhir Yang Diperoleh Internasional

Nasional Terakreditasi

Nasional Tidak Terakreditasi

a. Kelengkapan unsur isi jurnal (10%) 4 4

b. Ruang lingkup dan kedalaman pembahasan (30%)

12 10

c. Kecukupan dan kemutahiran

data/informasi dan metodologi (30%)

12 11

d. Kelengkapan unsur dan kualitas terbitan/jurnal (30%)

12 12

Total = (100%) 40 37

Nilai Pengusul = 0,4/10 x 37 = 1,48 Catatan Penilaian artikel oleh Reviewer:

1. Kesesuaian dan kelengkapan unsur isi jurnal:

Artikel ini sesuai dengan kepakaran penulis dan penulisannya sesuai dengan syarat penulisan di jurnal tersebut (International Journal of Biological Macromolecules) dengan similarity sangat baik (19%).

2. Ruang lingkup dan kedalaman pembahasan:

Ruang lingkup tulisan ini tentang perkembangan permeabilitas membrane tipe lembaran datar dari plisulson- polietilen glikol (PEG-CS) dengan pelapisan tripolifosfat tertaut silang dengan kitosan (TPP-CS). ada Langkah dimetodologi namun tidak ada dibahas dalam pembahsana . penjelasan gambar yang kurang jelas.

3. Kecukupan dan kemutakhiran data/informasi dan metodologi:

Data/Informasi yang disajikan cukup baik dan disertai literatur 25%byang tahun terbit kurang dari lima tahun dari artikel ini terbit. Metodologi disajikan dengan detil sehingga mudah untuk dikerjakan ulang oleh peneliti lain.

4. Kelengkapan unsur dan kualitas terbitan:

Unsur terbitan lengkap, dan kualitas terbitan baik merupakan jurnal internasional bereputasi Q1.

Semarang, 10 Juli 2021 Reviewer I

Prof. Dr. Dra. Meiny Suzery, M.S.

NIP.196005101989032001

Unit Kerja :FSM Universitas Diponegoro Bidang Ilmu: Kimia Organik

40

(2)

LEMBAR

HASIL PENILAIAN SEJAWAT SEBIDANG ATAU PEER REVIEW KARYA ILMIAH : JURNAL ILMIAH

Judul Jurnal Ilmiah (Artikel) : Permeability improvement of polyethersulfone-polietylene glycol (PEG-PES) flat sheet type membranes by tripoly-phosphate-crosslinked chitosan (TPP-CS) coating.

Nama/ Jumlah Penulis : Gunawan/11 Status Pengusul : penulis ke-4

Identitas Jurnal Ilmiah : a. Nama Jurnal : International Journal of Biological Macromolecules b. Nomor ISSN Cetak

Nomor ISSN Online : :

0141-8130 1879-0003

c. Vol, No., Bln Thn : Volume 152, 1 June 2020

d. Penerbit : Elsevier

e. DOI artikel (jika ada) :

f. Alamat web jurnal : https://www.sciencedirect.com/journal/international- journal-of-biological-macromolecules/vol/152/suppl/C Alamat Artikel : https://doi.org/10.1016/j.ijbiomac.2020.02.290

g. Terindex : Scopus

Kategori Publikasi Jurnal Ilmiah : Jurnal Ilmiah Internasional

(beri pada kategori yang tepat) Jurnal Ilmiah Nasional Terakreditasi Jurnal Ilmiah Nasional Tidak Terakreditasi

Hasil Penilaian Peer Review :

Komponen Yang Dinilai

Nilai Maksimal Jurnal Ilmiah

Nilai Akhir Yang Diperoleh Internasional

Nasional Terakreditasi

Nasional Tidak Terakreditasi

a. Kelengkapan unsur isi jurnal (10%) 4 4

b. Ruang lingkup dan kedalaman pembahasan (30%)

12 11

c. Kecukupan dan kemutahiran

data/informasi dan metodologi (30%)

12 11

d. Kelengkapan unsur dan kualitas terbitan/jurnal (30%)

12 12

Total = (100%) 40 38

Nilai Pengusul = 0,4/5 x 38 =

3,04

Catatan Penilaian artikel oleh Reviewer :

1. Kesesuaian dan kelengkapan unsur isi jurnal:

Artikel sesuai dengan kepakaran penulis, lengkap unsur dalam isi jurnal (4) yaitu judul, abstrak (berisi latar belakang, metode dan hasil),Grafik dan tabel disitasi dan dibahas, penulisan sesuai dengan panduan penulisan jurnal International Journal of Biological Macromolecules. Tata penulisan terjadi dengan baik. (4)

2. Ruang lingkup dan kedalaman pembahasan:

Cukup mendalam dalam membahas sintesis membran dan karakterisasinya , namun ada beberap typo dan ada step dalam metodologi yang tidak ada pembahsanannya serta gambar yang tidak jelas penomorannya. (11)

3. Kecukupan dan kemutakhiran data/informasi dan metodologi:Referensi yang digunakan menunjang pembahasan dan metodologi yang digunakan uptodate (25 % referensi dengan tahun terbit sebelum 5 tahun artikel ini terbit. (11) 4. Kelengkapan unsur dan kualitas terbitan:

Secara umum kelengkapan unsur artikel lengkap. Kualitas International Journal of Biological Macromolecules cukup bagus dan konsisten terindex di sopus peringkat Q1 (Bidang energy) SJR 0,97 (2019). (12)

Catatan: Turnitin: 19%

Semarang, 2 Februari 2021 Reviewer 1I

Prof. Dr. M. Cholid Djunaidi, S.Si, M.Si NIP.197007021996031004

Unit Kerja :FSM Universitas Diponegoro Bidang Ilmu: Kimia Analitik

40

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International Journal of Biological MacromoleculesVolume , Pages - June

Permeability improvement of polyethersulfone- polietylene glycol (PEG-PES) flat sheet type

membranes by tripolyphosphate-crosslinked chitosan (TPP-CS) coating

Lusiana R.A. , Sangkota V.D.A., Sasongko N.A., Gunawan G., Wijaya A.R., Santosa S.J., Siswanta D., Mudasir M. , Abidin M.N.Z. , Mansur S., Othman M.H.D.

Save all to author list

a a a a b c

c c d d d

Department of Chemistry, Faculty Science and Mathematics, Universitas Diponegoro, Jl. Prof. H. Soedarto, S.H., Tembalang, Semarang, Jawa Tengah, Indonesia

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang (UM), Malang, Jawa Timur, Indonesia

Department of Chemistry, Faculty Science and Mathematics, Universitas Gadjah Mada, Jl. Sekip Utara, Sleman, Yogyakarta, Indonesia

Advanced Membranes Technology Research Centre (AMTEC), University Technology Malaysia, UTM, Skudai, 81310, Johor, Malaysia

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Chitosan-tripoly phosphate (CS- TPP) synthesis through cross- linking process: The effect of concentration towards membrane mechanical characteristic and urea permeation

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Abstract

In this study, improvement of urea and creatinine permeability of polyethersulfone (PES) membrane by coating with synthesized tripolyphosphate-crosslinked chitosan (TPP-CS) has been conducted. Original and modified membranes, e.g. pristine PES, polyethersulfone-polyethylene glycol (PES-PEG) and PES- PEG/TPP-CS membranes were characterized using FTIR, DTG, SEM, AFM, water uptake, contact angles, porosity measurement, tensile strength test and permeation tests against urea and creatinine. The results show that the PES modification by TPP-CS coating has been successfully carried out. The water uptake ability, hydrophilicity and porosity of the modified membranes increase significantly to a greater degree. All modified membranes have good thermal stability and tensile strength and their permeation ability towards urea and creatinine increase with the increasing concentration of TPP-CS.

PES membrane has urea clearance ability of 7.36 mg/dL and creatinine of 0.014 mg/dL; membrane PES- PEG shows urea clearance of 11.87 mg/dL and creatinine of 0.32 mg/dL; while PES-PEG/TPP-CS membrane gives urea clearance of 20.87–36.40 mg/dL and creatinine in the range of 0.52–0.78 mg/dL.

These results suggest that the PES-PEG membrane coated with TPP-CS is superior and can be used as potential material for hemodialysis membrane. © 2020 Elsevier B.V.

Author keywords

Clearance capability; Hemodyalisis; Membranes; Modification

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P Na O O

O O P

P O

O O O O

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P O

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OH

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Xue, J., Zhao, W., Nie, S., Sun, S., Zhao, C.

(2013) Carbohydrate Polymers, 95 (1), pp. 64-71.  . doi: 10.1016/j.carbpol.2013.02.033

Lusiana, R.A.; Department of Chemistry, Faculty Science and Mathematics,

Universitas Diponegoro, Jl. Prof. H. Soedarto, S.H., Tembalang, Semarang, Jawa Tengah,

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Russian Academy of Sciences, Moskva, Russian Federation

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Sant Longowal Institute of Engineering and Technology, Longowal, India

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