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PROOF Correction on Atom Indonesia Name of All Authors : Article Title : Study of Cellulose-N,N'-Methylenebisacrylamide- Acrylic Acid as Pb

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PROOF Correction on Atom Indonesia Name of All Authors :

Article Title :

Study of Cellulose-N,N'-Methylenebisacrylamide- Acrylic Acid as Pb

2+

ion Adsorbent E-mail :

Line

Number Original Text Correction Note / Change

4

STUDY OF CELLULOSE- N,N'-METHYLENE BISACRYLAMIDE - ACRYLIC ACID AS Pb

2+

ADSORBENT

STUDY OF CELLULOSE- N,N'- METHYLENE BISACRYLAMIDE -

ACRYLIC ACID AS Pb

2+

ION ADSORBENT

Added : ION

14

Cellulose can be used as a metal ion adsorbent. However, it is specific to certain metal ions and has some drawbacks. To increase the capture of certain metal ions, cellulose needs to be modified. Cellulose modification was carried out using N, N'- methylenebisacrylamide (MBA) as crosslinking agent and acrylic acid (AA) as grafting agent. Gamma rays from Cobalt-60 was used as the initiator by simultaneous irradiation method. The aim of this study is to improve and observe the capture ability of cellulose as Pb2+ metal ion adsorbent. The characterization was performed by FTIR, DSC, SEM, and EDX. The thermal analysis and ion exchange capacity measurement showed that the resulting copolymer has a better thermal stability and ion exchange ability than pure cellulose.

The applications of the copolymer on Pb2+ ion adsorption indicated that the maximum adsorption is 99.8 % of 3 ppm Pb2+ ion sorbent at pH ≈ 7. SEM analysis showed that the copolymer is porous and a functional substance structure while pure cellulose appears fibrous. EDX Analysis showed Pb2+

metal ion adsorption by cellulose- MBA-AA.

Cellulose can be used as a metal ion adsorbent.

However, it is specific to certain metal ions and has some drawbacks. To increase the capture of certain metal ions, cellulose needs to be modified. Cellulose modification was carried out using N, N'- methylenebisacrylamide (MBA) as crosslinking agent and acrylic acid (AA) as grafting agent. Gamma rays from Cobalt-60 was used as the initiator by simultaneous irradiation method. The aim of this study is to improve and observe the capture ability of cellulose as Pb2+

metal ion adsorbent. The characterization was performed by FTIR, DSC, SEM, and EDX. The thermal analysis and ion exchange capacity measurement showed that the resulting copolymer has a better thermal stability and ion exchange ability than pure cellulose. The applications of the copolymer on Pb2+ ion adsorption indicated that the maximum adsorption is 99.8 % of 3 ppm Pb2+ ion sorbent at pH ≈ 7. SEM analysis showed that the copolymer is porous while pure cellulose appears fibrous. EDX Analysis showed Pb2+

metal ion adsorption by cellulose-MBA-AA.

Removed :

and a functional substance structure

133 adsorption of Pb

2+

. adsorption of Pb

2+

ion. Added :

ion 422 The differences of functional

g r oups contain in the polymer can be seen in Table 1.

The differences of functional g r oups contain ed in the polymer can be seen in Table 1.

Added : ed

724

Fig. 11. Spectrum of cellulose-MBA-AA in adsorbing Pb2+.

Fig. 11. Spectrum of cellulose-MBA-AA in

adsorbing

Pb

2+

ion. Added :

ion

(2)

735 The grafting degree attained was 353 %.

The copolymerization degree attained was 353 %.

removed : grafting;

Added :

copolymerization

Please return to Atom Indonesia Editorial Office via e-mail: [email protected] This original sheet should be returned to:

PPIKSN-BATAN, Secretariat of Atom Indonesia, Gedung 71, Lantai 1, Kawasan Puspiptek Serpong, Tangerang, Indonesia 15310

Author Signature(s) December 15

th

2018

Meri Suhartini

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