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Nitric oxide reactivity of Copper(II), Managanese(II) and Iron(III) complexes with N-donor and O-donor Iigands

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Figure 2 X-band EPR spectra of complexes 2.1 (a) and 2.2 (b) at 77 K in acetonitrile.
Figure 7 ORTEP diagram of complex 4.1 (50% thermal ellipsoid plot; H-atoms are removed for clarity).
Figure 12 UV-visible spectra of complexes 5.1 (a) and 5.2 (b) before (black trace) and after addition of NO in methanol.
Figure 2.2 ORTEP diagram of complexes (a) 2.1 and (b) 2.2 (50% thermal ellipsoid plot, hydrogen atoms are omitted for clarity).
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Conclusion 54 Experimental section 59 Experimental section 81 Results and discussion 88

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electronic structures of group 9 metallocorroles with axial

Introduction Understanding the factors that determine the stability and reactivity of metal complexes in high oxidation states could greatly facilitate the design of catalysts for