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Ch. 9. Atomic Structure

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Ch. 9. Atomic Structure Ch. 9. Atomic Structure

이 병 호

서울대 전기공학부

[email protected]

(2)

Fig. 9-1, p.296

Orbital Magnetism

Orbital Magnetism

(3)

Torque Torque

d dt

d dt

= ×

=

= × = L r p F p

τ r F L

(4)

U

= ×

= − ⋅ τ μ B

μ B

(5)

2 q

= m

μ L

(6)

Fig. 9-2, p.298

2

2

Bohr magneton 2

z z

e

l B l

e

B

e

e L m

e m m

m e

m μ

μ μ

= −

= − = −

=

=

=

(7)

Fig. 9-3, p.298

Larmor Precession Larmor Precession

L

sin

sin sin

2 Larmor frequency

1

sin 2

2 2

e

z L l

e e

d L d

d dt B dt q LB dt

m

d d e

dt L dt m B

e eB

U L m

m m

θ φ

μ θ θ

ω φ

θ

ω

=

= = =

= = =

= − ⋅ = ⋅ = =

L L τ

L

μ B L B =

(8)

Fig. 9-4, p.300

Normal Zeeman Effect Normal Zeeman Effect

0 L l

E = E + = ω m

(9)

Fig. 9-5, p.301

Normal Zeeman Effect

Normal Zeeman Effect

(10)

Normal and Anomalous Zeeman Effect

Normal and Anomalous Zeeman Effect

(11)

Fig. 9-6, p.302

Spin – Classical Analogy Spin – Classical Analogy

2 2

2 2

s i

e e

s

e

q q

m m

e g m g

= =

= −

=

μ L S

μ S

(12)

Fig. 9-7c, p.305

Stern-Gerlach Experiment

Stern-Gerlach Experiment

(13)

Fig. 9-8, p.306

1 2

1 1 2 , 2

( 1) 3

2 2 , 2

s

z s

s m

S s s S m

=

= −

= + =

= = −

= =

= = =

Spin Spin

(14)
(15)

Fig. 9-9, p.308

( )

o s 2

e

e g U

m

= + = − + = − ⋅

μ μ μ L S μ B

(16)

Fig. 9-10, p.310

Spin-Orbit Interaction

Spin-Orbit Interaction

(17)

Fig. 9-11, p.310

(18)

Fig. 9-12, p.310

( 1)

with , 1, ,

, 1, ,

z j j

J j j

J m m j j j

j l s l s l s

= +

= +

= = − ⋅⋅⋅ −

= + + − ⋅⋅⋅ − J L S

=

=

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