CHAPTER 5: CONCLUSION AND RECOMENDATION
5.1 Conclusion
31
32
Results on the effect of temperature against time showed in figure 4.6 shows that the higher the reaction temperature, the greater the concentration of end product yields.
The more heat is applied during reaction of step 2, the more frequents the molecules collided and resulting more the successful collision reaction. The activation energy, Ea calculated is 12,642.46 J mol-1k-1 when using the alternative version of Arrhenius equation. Furthermore, the value of rate constant increases with time shown in table 4.6. This shows that the sulfonation reaction also temperature dependent.
From all the result, the author believed the research objectives are achieved when the sulfonation reaction of non-ionic surfactants can produce high yield sulfonated product which is 65.91% using 1:1.2 mole of non-ionic surfactants to sodium bisulfite at present of catalyst and reacted at the boiling point temperature which is 82.5oC.
5.2 Recommendation
From this research, the author recommends several future works as follows:
1. The compatibility of reactants mole ratio is different which each other as the higher the number of carbons used as surfactants source the more compact and the geometry of the molecules structures hindered double bonds which make it harder for a successful reaction to happen. Thus the reactants mole ratio should be study in order to produce high yield of sulfonated product when using different type of ionic surfactants.
2. The effect of the amount and type of catalyst should be studied in order to minimize the amount usage of expensive catalyst for bigger production of sulfonated anionic surfactants product.
3. The effect of pressure toward reaction should be studied as it can improve the yield of sulfonated product.
4. The effect of pH value during the reactions should be investigated as it can affect the yield of sulfonated anionic surfactants.
33
REFERENCES
[1] Berger. P.D, and Berger C.H (2012). “2-Alkyl Alkoxylated Alcohol Sulfonate”. US Patent No. 2012/0004431 A1. Washington, DC: U.S.
[2] Farouq Ali, S.M, Thomas, S., “Principle of EOR” in A realistic Look at Enhanced Oil Recovery. 1st. ed., 1994, pp. 222-223.
[3] Sheng. J.J.. “Sulfactants flooding” in Modern Chemical Enhanced Oil Recovery, Elsevier., 2011, pp. 239-240.
[4] Products for Enhanced Oil Recovery (2011). Hunstman Technical Bulletin Online. Available: http://www.hunstman.com/technicalbulletin
[5] Rusell D and Maddox. J.J, (1978). “Surfactants oil recovery process usable in high temperature, high salinity formations”, US Patent No. 4,077,471 A.
Washington, DC: U.S.
[6] Donaldson, E.C , Chillingarian, G.V and Yen, T.F. (1985). Introduction of oil recovery in Enhance Oil Recovery, 1st. ed. 1985, pp. 12.
[7] Foster N.C (1997). “Sulfonation and Sulfation Processes”: CHEMITON. 2-7 [8] Zelenev, A.S. , Shchukin E.D., Pertsov A.V. and Amelina E.A (2001).
“Colloid and Surface Chemistry”. Two phase titration. 148-150.
[9] O‟Lenick, J.A. (2005). Capped Nonionic Surfactants in US Patent No.
6,878,682 B1. South Pittsburg. TN: U.S
[10] Berger. P.D, and Berger C.H (2000). Anionic surfactants based on alkene sulfonic acid in US Patent No. 6,043,391. Washington, DC: U.S.
34
[11] Hirasaki G.J , Miller C.A and Pope G.A . Result of phase behaviour experiment”in Surfactant based enhanced oil recovery and foam mobility control. 2005, pp. 1-27.
[12] Cullum D.C. Two phase titration of ionic surfactants with surfactants of opposite charge in Introduction to Surfactant Analysis, 1994, Pp. 59-60.
[13] Ellis R.J. et al. (1974). Bisulfite Reaction Olefins in US Patent No. 3,943,174.
Washington, DC: U.S.
[14] Norton C.J and Ned F.S. (1969). Preparation of Sulfonates by the Reaction of Olefins and Bisulfite in US Patent No. 3,479,397.Marathod Company. Ohio, U.S
[15] J.A.T Ortega. “Sulfonation / Sulfation Processing Technology for Anionic Surfactant Manufacture”. Universidad de la Salle,Columbia, 2011. Available:
http://www.intechopen.com
35
APPENDIX
1.
Experiment Setup.
Three necked round bottom flask is heated, Nitrogen gas is allow to purge out the formation of water.
2. Two phase separation using centrifuge
Top layer: Non-ionic Surfactants (Liquid)
Bottom layer: Potassium Chloride (Solids)
36
3. FTIR result based on Step 1 reaction
Step 1 reaction:
3.
4.
5.
FTIR result for experiment step 1reaction is summarized base on Appendix 5 Functional Group Molecular Motion Wane Numbers, cm-1
Alkanes =CH Stretch 3077.27
Alkanes C=C Stretch 1637.80
Alcohols O-H Stretch 3467.38
TDA-6 Ethoxylate R-O-(CH2CH2O)x-OH
Methalyl Chloride CH2=C (CH3) CH2-Cl +
N2
H2O
Surfactants Salts
R-O-(CH2CH2O)x-OK + Potassium
Hydroxide KOH Surfactants Salts
R-O-(CH2CH2O)x-OK + N2
Non-ionic Surfactants R-O-(CH2CH2O)x-O CH2C(CH3)=CH2
+ KCl
37
Ethers C-O-C Stretch (diaryl) 1112.01
4. FTIR result based on Step 2 reaction
FTIR result for experiment step 2reaction is summarized base on Appendix 5 Functional Group Molecular Motion Wane Numbers, cm-1
Sulfonates S=O Stretch 1352.07
Sulfonates S-O Stretch 950.96
38
5. IR Absorptions for Representatives Functional Groups
Functional Group Molecular Motion Wavenumber (cm-1)
alkanes
C-H stretch 2950-2800
CH2 bend ~1465
CH3 bend ~1375
CH2 bend (4 or more) ~720
alkenes
=CH stretch 3100-3010
C=C stretch (isolated) 1690-1630 C=C stretch (conjugated) 1640-1610
C-H in-plane bend 1430-1290
C-H bend (monosubstituted) ~990 & ~910 C-H bend (disubstituted - E) ~970 C-H bend (disubstituted - 1,1) ~890 C-H bend (disubstituted - Z) ~700
C-H bend (trisubstituted) ~815
alkynes
acetylenic C-H stretch ~3300
C,C triple bond stretch ~2150
acetylenic C-H bend 650-600
aromatics
C-H stretch 3020-3000
C=C stretch ~1600 & ~1475
C-H bend (mono) 770-730 & 715-685
C-H bend (ortho) 770-735
C-H bend (meta) ~880 & ~780 & ~690
C-H bend (para) 850-800
alcohols O-H stretch ~3650 or 3400-3300
39
C-O stretch 1260-1000
ethers
C-O-C stretch (dialkyl) 1300-1000 C-O-C stretch (diaryl) ~1250 & ~1120 aldehydes
C-H aldehyde stretch ~2850 & ~2750
C=O stretch ~1725
ketones
C=O stretch ~1715
C-C stretch 1300-1100
carboxylic acids
O-H stretch 3400-2400
C=O stretch 1730-1700
C-O stretch 1320-1210
O-H bend 1440-1400
esters
C=O stretch 1750-1735
C-C(O)-C stretch (acetates) 1260-1230 C-C(O)-C stretch (all others) 1210-1160 acid chlorides
C=O stretch 1810-1775
C-Cl stretch 730-550
anhydrides
C=O stretch 1830-1800&1775-1740
C-O stretch 1300-900
amines
N-H stretch (1 per N-H bond) 3500-3300
N-H bend 1640-1500
C-N Stretch (alkyl) 1200-1025
C-N Stretch (aryl) 1360-1250
N-H bend (oop) ~800
amides
N-H stretch 3500-3180
C=O stretch 1680-1630
N-H bend 1640-1550
N-H bend (1o) 1570-1515
alkyl halides
C-F stretch 1400-1000
C-Cl stretch 785-540
40
C-Br stretch 650-510
C-I stretch 600-485
nitriles C,N triple bond stretch ~2250
isocyanates -N=C=O stretch ~2270
isothiocyanates -N=C=S stretch ~2125
imines R2C=N-R stretch 1690-1640
nitro groups
-NO2 (aliphatic) 1600-1530&1390-1300 -NO2 (aromatic) 1550-1490&1355-1315
mercaptans S-H stretch ~2550
sulfoxides S=O stretch ~1050
sulfones S=O stretch ~1300 & ~1150
sulfonates
S=O stretch ~1350 & ~11750
S-O stretch 1000-750
phosphines
P-H stretch 2320-2270
PH bend 1090-810
phosphine oxides P=O 1210-1140
41 6. Chemicals MSDS
(Blank page on purpose)
p. 1
0
2
0
He a lt h Fire
Re a c t iv it y P e rs o n a l P ro t e c t io n
2 0 0 E
Material Safety Data Sheet
Aluminum nitrate nonahydrate MSDS
Section 1: Chemical Product and Company Identification
Product Name: Aluminum nitrate nonahydrate Catalog Codes: SLA1981
CAS#: 7784-27-2 RTECS: BD1050000
TSCA: TSCA 8(b) inventory: Aluminum nitrate nonahydrate CI#: Not available.
Synonym:
Chemical Name: aluminum nitrate nonahydrate Chemical Formula: Al(NO3)3.9H2O
Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400 Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Aluminum nitrate nonahydrate 7784-27-2 100
Toxicological Data on Ingredients: Aluminum nitrate nonahydrate: ORAL (LD50): Acute: 3632 mg/kg [Rat]. 3980 mg/kg [Mouse]. 4280 mg/kg [Rat].
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator). Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
p. 2 Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
p. 3 Precautions:
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits:
TWA: 2 Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid.
Odor: Not available.
Taste: Not available.
Molecular Weight: 375.13 g/mole Color: Not available.
pH (1% soln/water): Not available.
Boiling Point: Decomposition temperature: 135°C (275°F) Melting Point: 73°C (163.4°F)
Critical Temperature: Not available.
Specific Gravity: 1.058 (Water = 1) Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
p. 4 Easily soluble in cold water. Soluble in hot water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 3632 mg/kg [Rat].
Chronic Effects on Humans: Causes damage to the following organs: lungs, mucous membranes.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
DOT Classification: CLASS 5.1: Oxidizing material.
Identification: : Aluminum Nitrate UNNA: UN1438 PG: III
p. 5 Special Provisions for Transport: Marine Pollutant
Section 15: Other Regulatory Information
Federal and State Regulations: TSCA 8(b) inventory: Aluminum nitrate nonahydrate
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS C: Oxidizing material. CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R8- Contact with combustible material may cause fire. R36/38- Irritating to eyes and skin.
HMIS (U.S.A.):
Health Hazard: 2 Fire Hazard: 0 Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2 Flammability: 0 Reactivity: 0 Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/11/2005 11:15 AM Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages.
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Material Safety Data Sheet
Ethanol, Absolute
ACC# 89308
Section 1 - Chemical Product and Company Identification
MSDS Name: Ethanol, Absolute Catalog Numbers: NC9602322
Synonyms: Ethyl Alcohol; Ethyl Alcohol Anhydrous; Ethyl Hydrate; Ethyl Hydroxide; Fermentation Alcohol; Grain Alcohol; Methylcarbinol; Molasses Alcohol; Spirits of Wine.
Company Identification:
Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410
For information, call: 201-796-7100 Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
64-17-5 Ethanol ca.100 200-578-6
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: colorless clear liquid. Flash Point: 16.6 deg C.
Warning! Causes severe eye irritation. Flammable liquid and vapor. Causes respiratory tract irritation. This substance has caused adverse reproductive and fetal effects in humans. May cause central nervous system depression. May cause liver, kidney and heart damage. Causes moderate skin irritation.
Target Organs: Kidneys, heart, central nervous system, liver.
Potential Health Effects
Eye: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivitis and corneal damage.
Skin: Causes moderate skin irritation. May cause cyanosis of the extremities.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation.
Chronic: May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage.
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Section 4 - First Aid Measures
Eyes: Get medical aid. Gently lift eyelids and flush continuously with wate r.
Skin: Get medical aid. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to- mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively. Persons with skin or eye disorders or liver, kidney, chronic respiratory diseases, or central and peripheral nervous sytem diseases may be at increased risk from exposure to this substance.
Antidote: None reported.
Section 5 - Fire Fighting Measures
General Information: Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol- resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Flash Point: 16.6 deg C ( 61.88 deg F)
Autoignition Temperature: 363 deg C ( 685.40 deg F) Explosion Limits, Lower:3.3 vol %
Upper: 19.0 vol %
NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well- ventilated area away from incompatible substances. Flammables-area. Do not store near perchlorates, peroxides, chromic acid or nitric acid.
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Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Ethanol 1000 ppm TWA 1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm
IDLH
1000 ppm TWA; 1900 mg/m3 TWA
OSHA Vacated PELs: Ethanol: 1000 ppm TWA; 1900 mg/m3 TWA Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Section 9 - Physical and Chemical Properties
Physical State: Clear liquid Appearance: colorless
Odor: Mild, rather pleasant, like wine or whis pH: Not available.
Vapor Pressure: 59.3 mm Hg @ 20 deg C Vapor Density: 1.59
Evaporation Rate:Not available.
Viscosity: 1.200 cP @ 20 deg C Boiling Point: 78 deg C
Freezing/Melting Point:-114.1 deg C
Decomposition Temperature:Not available.
Solubility: Miscible.
Specific Gravity/Density:0.790 @ 20°C Molecular Formula:C2H5OH
Molecular Weight:46.0414
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, oxidizers.
Incompatibilities with Other Materials: Strong oxidizing agents, acids, alkali metals, ammonia, hydrazine, peroxides, sodium, acid anhydrides, calcium hypochlorite, chromyl chloride, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, mercuric nitrate, potassium-tert- butoxide, magnesium perchlorate, acid chlorides, platinum, uranium hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, permanganic acid, ruthenium (VIII) oxide, uranyl perchlorate, potassium dioxide.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.