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LAMPIRAN
Lampiran 1 Difraktogran XRD Material Mesopori Silika F (0,9 : 1) General information
Analysis date 2018/07/04 11:11:12 Sample name Silika asam Oleat
5
Measurement date 2018/07/04 10:53:05 File name 683XRD18.ras Operator administrator
Comment
Measurement profile
Peak list
Meas. data:683XRD18/Data 1 BG data:683XRD18/Data 1 Calc. data:683XRD18/Data 1
2-theta (deg)
Intensity (cps)
20 40 60 80
0 1000 2000 3000 4000
Lampiran 2. Analisa BET Material Mesopori Silika A (0,2 : 1) Press
(Po) P0 P/Po Volume @ STP
cc cc/gr
38.68 762.11 0.050754 0.6251 9.16568915 57.2 762.11 0.075055 0.6792 9.958944282 76.53 762.11 0.100419 0.7251 10.63196481 95.92 762.11 0.125861 0.7639 11.20087977 114.88 762.11 0.150739 0.8007 11.74046921 134.01 762.11 0.175841 0.8334 12.21994135 153.18 762.11 0.200995 0.8671 12.71407625 172.36 762.11 0.226162 0.8968 13.14956012 191.72 762.11 0.251565 0.9271 13.59384164 210.06 762.11 0.27563 0.9592 14.06451613 230.39 762.11 0.302305 0.9908 14.52785924 265.82 762.11 0.348795 1.0501 15.3973607 303.75 762.11 0.398565 1.1131 16.32111437 342.12 762.11 0.448912 1.1768 17.25513196 379.57 762.11 0.498051 1.2567 18.42668622 417.74 762.11 0.548136 1.3347 19.57038123 455.31 762.11 0.597433 1.4305 20.97507331 500.85 762.11 0.657189 1.5617 22.89882698 538.1 762.11 0.706066 1.7015 24.94868035 575.38 762.11 0.754983 1.8818 27.59237537 611.2 762.11 0.801984 2.141 31.39296188 653.9 762.11 0.858013 2.7707 40.62609971 691.35 762.11 0.907153 3.7482 54.95894428 724.75 762.11 0.950978 5.6201 82.40615836 746.5 762.11 0.979517 7.3751 108.1392962 758.31 762.11 0.995014 8.4384 123.7302053 724.57 762.11 0.950742 7.6676 112.4281525 684.18 762.11 0.897744 5.7042 83.63929619 643.19 762.11 0.84396 3.8155 55.9457478 603.22 762.11 0.791513 2.7395 40.1686217 565.26 762.11 0.741704 2.2558 33.07624633 523.56 762.11 0.686987 1.9512 28.60997067 495.84 762.11 0.650615 1.8051 26.46774194 446.02 762.11 0.585244 1.6071 23.56451613 415.52 762.11 0.545223 1.5071 22.09824047 380.93 762.11 0.499836 1.4129 20.7170088 329.62 762.11 0.43251 1.2107 17.75219941 299.43 762.11 0.392896 1.1532 16.90909091 264.03 762.11 0.346446 1.0903 15.98680352 226.4 762.11 0.29707 1.0239 15.01319648
188.53 762.11 0.247379 0.959 14.06158358 150.35 762.11 0.197281 0.8936 13.1026393 112.64 762.11 0.1478 0.8205 12.03079179 74.9 762.11 0.09828 0.7354 10.7829912
Hasil Perhitungan Distribusi Ukuran Pori Sampel A Mengunakan Metode Barret-Joyner-Halenda (BJH)
Radius Pore Volume
dV(r) dS(r) dV(logr) dS(logr)
Angstrong cc cc/gr
17.0104 7.89E-04 4.12E-04 4.85E-01 1.61E-02 1.90E+01 19.0508 2.32E-03 7.06E-04 7.41E-01 3.09E-02 3.25E+01 21.4453 3.50E-03 4.51E-04 4.21E-01 2.22E-02 2.07E+01 24.3238 5.31E-03 5.76E-04 4.73E-01 3.22E-02 2.65E+01 28.3321 7.75E-03 5.00E-04 3.53E-01 3.25E-02 2.30E+01 33.4405 1.07E-02 5.49E-04 3.29E-01 4.22E-02 2.52E+01 39.763 1.47E-02 5.52E-04 2.77E-01 5.04E-02 2.53E+01 48.5205 2.12E-02 6.32E-04 2.60E-01 7.03E-02 2.90E+01 63.8661 3.87E-02 8.57E-04 2.68E-01 1.25E-01 3.91E+01 92.7887 6.58E-02 7.26E-04 1.56E-01 1.53E-01 3.30E+01 158.5703 1.16E-01 5.30E-04 6.69E-02 1.88E-01 2.37E+01 342.4974 1.59E-01 1.60E-04 9.32E-03 1.19E-01 6.94E+00 1205.7581 1.84E-01 1.71E-05 2.84E-04 4.11E-02 6.81E-01
0
Lampiran 3. Analisa BET Material Mesopori Silika B (0,3 : 1)
Hasil Perhitungan Distribusi Ukuran Pori Sampel B Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V dD dV dV/dD D (nm)
15.8631 2.6247E-02 2.7376 6.682E-02 2.441E-02 1.58631 18.6007 9.3070E-02 2.8277 2.115E-02 7.480E-03 1.86007 21.4284 1.1422E-01 2.2946 2.223E-02 9.688E-03 2.14284 23.723 1.3645E-01 4.5191 4.213E-02 9.323E-03 2.3723 28.2421 1.7858E-01 4.9172 1.487E-02 3.024E-03 2.82421 33.1593 1.9345E-01 4.1166 1.771E-02 4.302E-03 3.31593 37.2759 2.1116E-01 5.3931 1.655E-02 3.069E-03 3.72759 42.669 2.2771E-01 8.2981 2.151E-02 2.592E-03 4.2669 50.9671 2.4922E-01 13.21 1.975E-02 1.495E-03 5.09671 64.1771 2.6897E-01 24.8736 2.295E-02 9.227E-04 6.41771 89.0507 2.9192E-01 68.7911 7.694E-02 1.118E-03 8.90507 157.8418 3.6886E-01 778.9749 4.513E-02 5.794E-05 15.78418 936.8167 4.1399E-01 876.0214 0.000E+00 0.000E+00 93.68167 1812.838 4.1399E-01 -1812.84 -4.140E-01 2.284E-04 181.2838
Lampiran 4. Analisa BET Material Mesopori Silika C (0,5 : 1)
Hasil Perhitungan Distribusi Ukuran Pori Sampel C Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V dD dV dV/dD D (nm)
15.7605 1.3737E-02 1.7739 4.8414E-02 2.729E-02 1.57605 17.5344 6.2151E-02 2.7848 3.1781E-02 1.141E-02 1.75344 20.3192 9.3932E-02 3.2292 2.5548E-02 7.912E-03 2.03192 23.5484 1.1948E-01 4.048 2.7960E-02 6.907E-03 2.35484 27.5964 1.4744E-01 5.9029 2.8110E-02 4.762E-03 2.75964 33.4993 1.7555E-01 5.5715 1.1450E-02 2.055E-03 3.34993 39.0708 1.8700E-01 4.8699 1.2250E-02 2.515E-03 3.90708 43.9407 1.9925E-01 8.1856 1.7100E-02 2.089E-03 4.39407 52.1263 2.1635E-01 13.5984 1.6050E-02 1.180E-03 5.21263 65.7247 2.3240E-01 24.0823 1.6010E-02 6.648E-04 6.57247 89.807 2.4841E-01 70.6305 1.7340E-02 2.455E-04 8.9807 160.4375 2.6575E-01 1975.4861 2.8320E-02 1.434E-05 16.04375 2135.9236 2.9407E-01 -2135.924 -2.9407E-01 1.377E-04 213.5924
Lampiran 5. Analisa BET Material Mesopori Silika D (0,6 : 1)
P P0 P/P0 cc/g Volume (cc) gram
42.3897 760 0.055775921 45.63963 3.21303 0.0704 77.7562 760 0.102310789 57.53168 4.05023 0.0704 114.17 760 0.150223684 68.5767 4.8278 0.0704 152.854 760 0.201123684 78.69844 5.54037 0.0704 190.958 760 0.251260526 88.83651 6.25409 0.0704 245.687 760 0.323272368 101.6543 7.15646 0.0704 298.052 760 0.392173684 112.8467 7.94441 0.0704 329.691 760 0.433803947 120.1132 8.45597 0.0704 367.638 760 0.483734211 128.2514 9.0289 0.0704 412.058 760 0.542181579 138.3038 9.73659 0.0704 449.918 760 0.591997368 146.2756 10.2978 0.0704 473.813 760 0.623438158 156.5256 11.0194 0.0704 511.425 760 0.672927632 163.6776 11.5229 0.0704 554.624 760 0.729768421 172.2102 12.1236 0.0704 591.58 760 0.778394737 179.3722 12.6278 0.0704 619.716 760 0.815415789 187.3878 13.1921 0.0704 651.424 760 0.857136842 191.821 13.5042 0.0704 689.852 760 0.9077 199.804 14.0662 0.0704 721.678 760 0.949576316 206.875 14.564 0.0704 757.176 760 0.996284211 214.6193 15.1092 0.0704 756.737 760 0.995706579 213.8835 15.0574 0.0704 715.255 760 0.941125 204.348 14.3861 0.0704 682.44 760 0.897947368 195.9702 13.7963 0.0704 637.488 760 0.8388 187.1946 13.1785 0.0704 608.615 760 0.800809211 181.0866 12.7485 0.0704 569.223 760 0.748977632 172.9119 12.173 0.0704 532.108 760 0.700142105 167.0341 11.7592 0.0704 494.42 760 0.650552632 160.669 11.3111 0.0704 435.009 760 0.572380263 149.456 10.5217 0.0704 415.719 760 0.546998684 146.321 10.301 0.0704 372.675 760 0.490361842 137.3886 9.67216 0.0704 308.018 760 0.405286842 125.0634 8.80446 0.0704 300.134 760 0.394913158 123.7706 8.71345 0.0704 258.497 760 0.340127632 114.0915 8.03204 0.0704 227.889 760 0.299853947 107.5661 7.57265 0.0704 190.377 760 0.250496053 97.76577 6.88271 0.0704 150.055 760 0.197440789 87.3598 6.15013 0.0704 112.957 760 0.148627632 76.89531 5.41343 0.0704 76.4887 760 0.100643026 65.12259 4.58463 0.0704 37.3793 760 0.049183289 50.34219 3.54409 0.0704
Hasil Perhitungan Distribusi Ukuran Pori Sampel D Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V (cc/g) dD dV dV/dD D (nm)
16.5963 1.8869E-02 1.8189 2.040E-02 1.121E-02 1.65963 18.4152 3.9266E-02 2.5271 2.525E-02 9.993E-03 1.84152 20.9423 6.4519E-02 3.0228 1.922E-02 6.357E-03 2.09423 23.9651 8.3734E-02 2.7119 2.777E-02 1.024E-02 2.39651 26.677 1.1150E-01 3.408 1.695E-02 4.974E-03 2.6677 30.085 1.2845E-01 5.7486 1.969E-02 3.425E-03 3.0085 35.8336 1.4814E-01 7.8285 1.591E-02 2.032E-03 3.58336 43.6621 1.6405E-01 9.0516 1.795E-02 1.983E-03 4.36621 52.7137 1.8200E-01 12.8415 9.050E-03 7.047E-04 5.27137 65.5552 1.9105E-01 27.3253 1.580E-02 5.782E-04 6.55552 92.8805 2.0685E-01 63.2447 1.307E-02 2.067E-04 9.28805 156.1252 2.1992E-01 1235.2056 1.225E-02 9.917E-06 15.61252 1391.3308 2.3217E-01 -1391.3308 -2.322E-01 1.669E-04 139.1331
Lampiran 6. Analisa BET Material Mesopori Silika E (0,7 : 1)
Hasil Perhitungan Distribusi Ukuran Pori Sampel E Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V(cc/g) dD dV dV/dD D(nm)
15.6172 2.0892E-02 2.1449 3.6006E-02 1.679E-02 1.56172 17.7621 5.6898E-02 2.0596 1.2826E-02 6.227E-03 1.77621 19.8217 6.9724E-02 1.8906 2.3333E-02 1.234E-02 1.98217 21.7123 9.3057E-02 4.3829 5.6863E-02 1.297E-02 2.17123 26.0952 1.4992E-01 5.3184 2.1340E-02 4.012E-03 2.60952 31.4136 1.7126E-01 3.909 1.2750E-02 3.262E-03 3.14136 35.3226 1.8401E-01 5.1011 2.2740E-02 4.458E-03 3.53226 40.4237 2.0675E-01 8.9304 2.2600E-02 2.531E-03 4.04237 49.3541 2.2935E-01 14.1521 3.7320E-02 2.637E-03 4.93541 63.5062 2.6667E-01 25.6379 2.1600E-02 8.425E-04 6.35062 89.1441 2.8827E-01 67.0716 2.0440E-02 3.047E-04 8.91441 156.2157 3.0871E-01 2525.7212 1.7780E-02 7.040E-06 15.62157 2681.9369 3.2649E-01 -2681.9369 -3.2649E-01 1.217E-04 268.1937
Lampiran 7. Analisa BET Material Mesopori Silika F (0,9 : 1)
Hasil Perhitungan Distribusi Ukuran Pori Sampel F Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V(cc/g) dD dV dV/dD D(nm)
15.4555 2.3209E-02 2.0466 0.029601 1.446E-02 1.54555 17.5021 5.2810E-02 3.0861 0.017356 5.624E-03 1.75021 20.5882 7.0166E-02 1.0954 0.052954 4.834E-02 2.05882 21.6836 1.2312E-01 4.0772 0.05467 1.341E-02 2.16836 25.7608 1.7779E-01 4.1543 0.02198 5.291E-03 2.57608 29.9151 1.9977E-01 3.5968 0.03252 9.041E-03 2.99151 33.5119 2.3229E-01 6.1494 0.04165 6.773E-03 3.35119 39.6613 2.7394E-01 9.4459 0.04388 4.645E-03 3.96613 49.1072 3.1782E-01 13.8202 0.10582 7.657E-03 4.91072 62.9274 4.2364E-01 24.9256 0.06402 2.568E-03 6.29274 87.853 4.8766E-01 67.6563 0.05249 7.758E-04 8.7853 155.5093 5.4015E-01 964.2886 0.03559 3.691E-05 15.55093 1119.7979 5.7574E-01 -1119.7979 -0.57574 5.141E-04 111.97979
Lampiran 8. Analisa BET Material Mesopori Silika G (1 : 1)
Hasil Perhitungan Distribusi Ukuran Pori Sampel G Mengunakan Metode Barret-Joyner-Halenda (BJH)
D (Å) V(cc/g) dD dV dV/dD D(nm)
16.5019 0.0000E+00 1.7672 2.7573E-03 1.560E-03 1.65019 18.2691 2.7573E-03 1.1836 5.5997E-03 4.731E-03 1.82691 19.4527 8.3570E-03 2.3564 9.6273E-02 4.086E-02 1.94527 21.8091 1.0463E-01 3.9915 2.5120E-02 6.293E-03 2.18091 25.8006 1.2975E-01 5.278 1.4960E-02 2.834E-03 2.58006 31.0786 1.4471E-01 7.528 0.0000E+00 0.000E+00 3.10786 38.6066 1.4471E-01 7.2742 0.0000E+00 0.000E+00 3.86066 45.8808 1.4471E-01 7.2183 1.0858E-01 1.504E-02 4.58808 53.0991 2.5329E-01 11.3768 9.9600E-03 8.755E-04 5.30991 64.4759 2.6325E-01 26.1468 1.1490E-02 4.394E-04 6.44759 90.6227 2.7474E-01 2686.7727 0.0000E+00 0.000E+00 9.06227 2777.3954 2.7474E-01 -2777.3954 -2.7474E-01 9.892E-05 277.7395
Lampiran 9. Daftar gambar-gambar penelitian
1. Campuran asam oleat (1,49 gram), air demineralisasi dan HCl 0,1 N (A)
2. Campuran TEOS dan APMS (B)
3. Campuran A + B distirrer selama 2 jam pada suhu kamar
4. Dimatangkan dalam oven pada suhu 80oC
5. Proses pencucian dengan air demineralisasi
6. Proses pengeringan pada suhu 50oC kemudian padatan dikalsinasi pada suhu
13. Dimatangkan dalam oven pada suhu 80oC
14. Proses penyaringan dan pencucian dengan air demineralisasi
15. Silika yang diperoleh setelah proses penyaringan dan dikeringkan pada suhu 50oC
16. Padatan silika setelah dikalsinasi pada suhu 550oC selama 6 jam
23. Dimatangkan dalam oven pada suhu 80oC
24. Silika yang diperoleh setelah proses penyaringan dan dikeringkan pada suhu 50oC
25. Padatan silika setelah dikalsinasi pada suhu 550oC selama 6 jam