Saran - KESIMPULAN DAN SARAN - KADAR TEKTOKUINON PADA EKSTRAK KAYU DAN KULIT JATI (Tectona gran

BAB V KESIMPULAN DAN SARAN

5.2 Saran

Penelitian lanjutan tentang pemanfaatan ekstrak kayu Jati untuk berbagai penggunaan misalnya sebagai pengawet alami, insektisida, aditif, dan lainnya, diperlukan untuk mendorong peningkatan diversifikasi produk dan efisiensi pemanfaatan limbah sumberdaya alam biomassa hasil hutan.

DAFTAR PUSTAKA

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[Skripsi]. Bogor: Fakultas Kehutanan, Institut Pertanian Bogor.

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Fakultas Kehutanan, Institut Pertanian Bogor.

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LAMPIRAN

24 Lampiran 1 Komponen Kimia dalam Ekstrak Kayu dan Kulit Jati (Tectona grandis L.f)

Asal Bagian

Pohon Pelarut Jenis Kuinon Konsentrasi

Relatif (%) Jawa Barat Kayu Etanol/Toluen (1:1) phenol, 4-methoxy- (Hydroquinone monomethyl ether) 1,74

1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 0,79

1,4-naphthalenedione (naphthoquinone) 0,16

9,10-Anthracenedione (9,10-anthraquinone) 0,58

1,4-naphthalenedione, 2,3-dimethyl- (2,3-dimethylnaphthoquinone) 1,96 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 24,67 9,10-anthracenedione, 2-(1,1-dimethylethyl)- (2-tert-butylanthraquinone) 0,25

9,10-anthracenedione, 1,4-diamino- 1,03

chrysophanol (1,8-dihydroxy-3-methylanthraquinone) 0,64

jumlah kuinon 31,82

Jawa Barat Kayu Etanol/Toluen (1:2) 2,6-naphthoquinone, 1,5-diamino- 0,17

9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 7,47 chrysophanol (1,8-dihydroxy-3-methylanthraquinone) 0,80

jumlah kuinon 8,44

Jawa Barat Kayu Etanol/Toluen (2:1) 1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 0,55

9,10-Anthracenedione (9,10-anthraquinone) 0,50

9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 11,88 9,10-anthracenedione, 2-(1,1-dimethylethyl)- (2-tert-butylanthraquinone) 0,12

9,10-anthracenedione, 1,4-diamino- 0,34

jumlah kuinon 13,39

Jawa Timur Kayu Etanol/Toluen (1:1) phenol, 4-methoxy- (Hydroquinone monomethyl ether) 0,94

1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 0,73

1,4-naphthalenedione (naphthoquinone) 0,53

1,4-naphthalenedione, 2-methyl (2-methylnaphthoquinone) 0,48

9,10-Anthracenedione (9,10-anthraquinone) 2,10

Lapachol 0,50

9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 23,85 9,10-anthracenedione, 2-(1,1-dimethylethyl)- (2-tert-butylanthraquinone) 0,96 9,10-anthracenedione, 1-ethyl- (1-ethyl anthraquinone) 0,33

1-methoxyanthraquinone 0,25

1,4-naphthalenedione,2-hydroxy-3-methyl- (phthiocol) 0,28

1,4-naphthalenedione, 2-hydroxy- (lawsone) 0,20

jumlah kuinon 31,15

Jawa Timur Kayu Etanol/Toluen (1:2) phenol, 4-methoxy- (Hydroquinone monomethyl ether) 0,92 1,4-naphthalenedione, 2-methyl (2-methylnaphthoquinone) 1,18 1,4-naphthalenedione,2-hydroxy-3-methyl- (phthiocol) 0,32

9,10-Anthracenedione (9,10-anthraquinone) 1,25

Lapachol 0,26

9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 21,81

jumlah kuinon 25,74

Jawa Timur Kayu Etanol/Toluen (2:1) 1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 1,28 1,4-naphthalenedione, 2-methyl (2-methylnaphthoquinone) 2,10 1,4-naphthalenedione,2-hydroxy-3-methyl- (phthiocol) 0,57

9,10-Anthracenedione (9,10-anthraquinone) 0,88

9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 20,9

9,10-anthracenedione, 1,4-diamino- 0,25

jumlah kuinon 25,98

Jawa Barat Kulit Etanol/Toluen (1:1) phenol, 4-methoxy- (Hydroquinone monomethyl ether) 0,43 2 5-cyclohexadiene-1 4-dione, compd. with 1,4-benzenediol (quinhydrone) 0,41 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 0,53

jumlah kuinon 1,37

Jawa Barat Kulit Etanol/Toluen (1:2) 1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 0,31 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 1,50

9,10-anthracenedione, 1,4-diamino- 0,16

jumlah kuinon 1,97

Jawa Barat Kulit Etanol/Toluen (2:1) 2 5-cyclohexadiene-1 4-dione, compd. with 1,4-benzenediol (quinhydrone) 1,82 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 0,75

jumlah kuinon 2,57

Jawa Timur Kulit Etanol/Toluen (1:1) phenol, 4-methoxy- (Hydroquinone monomethyl ether) 1,00 2 5-cyclohexadiene-1 4-dione, compd. with 1,4-benzenediol (quinhydrone) 1,29 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 4,33

jumlah kuinon 6,62

Jawa Timur Kulit Etanol/Toluen (1:2) 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 6,38

jumlah kuinon 6,38

Jawa Timur Kulit Etanol/Toluen (2:1) 1,4-naphthalenediol (.alpha.-naphthoquinhydrone) 0,20 9,10-anthracenedione, 2-methyl- (2-methyl anthraquinone) 0,24

jumlah kuinon 0,44

30.540 40.838

14.508 17.919 26.86926.97027.13027.19927.38827.53927.60627.71027.82628.003

19.384 19.99320.24220.54720.64120.77120.838 21.44721.60921.74921.79721.94522.03222.34822.66322.76923.023 23.17823.24523.33923.46323.58823.795 28.97229.205 29.63229.77630.088 30.28830.32730.99231.11331.31831.20631.39631.60531.78731.68631.85432.08032.22432.56932.68032.77032.94733.10433.313 33.89134.24134.37234.539 35.05635.43735.57635.97036.22236.542 37.277 37.942

15.944 29.498 30.001

24.517 24.91225.090 25.73025.944 39.509 42.207

15.867

14.422 17.656 18.37218.602

2.384 45.561

Lampiran 2 Kromatogram analisis GCMS ekstrak kayu Jati Jawa Barat dengan pelarut etanol/toluena 1:1

PUSLITBANG HASIL HUTAN REPORT

Tuning File : C:\GCMSsolution\System\Tune1\Tuning PT. Holcim\03052012.qgt

Chromatogram Ekstrak no.1 C:\GCMSsolution\Data\Project1\Ekstrak no.1.qgd

1 2.384 5885031 0.30 Carbon dioxide (CAS) Dry ice

2 14.422 2867554 0.15 Benzene, methyl(1-methylethyl)- (CAS) Cymol 3 14.508 39906408 2.05 l-Limonene

4 15.867 3930979 0.20 Benzene, 1-methyl-4-(1-methylethenyl)- (CAS) 1-Methyl-4-isopropenylbenzene 5 15.944 33948436 1.74 Phenol, 4-methoxy- (CAS) Hqmme

6 17.656 3854096 0.20 Benzoic acid, 2-methyl-, methyl ester (CAS) Methyl o-toluate 7 17.919 35727362 1.83 2-Methoxy-4-methylphenol

8 18.372 9027967 0.46 1,2-Benzenediol (CAS) Pyrocatechol 9 18.602 3739923 0.19 2,3-Dimethoxytoluene

10 19.384 16570462 0.85 Phenol, 4-ethyl-2-methoxy- (CAS) p-Ethylguaiacol 11 19.993 11105895 0.57 Phenol,

4-ethenyl-2-methoxy-12 20.242 6123340 0.31 1,2-Benzenedicarboxylic acid, monomethyl ester (CAS) Methyl hydrogen phthalate 13 20.547 3583718 0.18 Phenol, 2,6-dimethoxy- (CAS) 2,6-Dimethoxyphenol

14 20.641 3017232 0.15 Phenol, 2-methoxy-5-(1-propenyl)-, (E)- (CAS) Phenol, 2-methoxy-5-propenyl 15 20.771 4152084 0.21 Phenol, 2-methoxy-4-propyl- (CAS) 5-PROPYL-GUAIACOL

16 20.838 2744185 0.14 1H-Indene-1,3(2H)-dione (CAS) 1,3-Indandione 17 21.447 5772718 0.30 (-)-Epicamphor

18 21.609 2170879 0.11 1,5,9-UNDECATRIENE, 2,6,10-TRIMETHYL-, (Z)-19 21.749 3025611 0.16 1,4-Naphthalenedione (CAS) NAPHTHOQUINONE

20 21.797 2621092 0.13

21 21.945 3605519 0.18 Geranic acid

22 22.032 7453726 0.38 Phenol, 2-methoxy-4-(1-propenyl)-, (E)- (CAS) (E)-Isoeugenol 23 22.348 1917085 0.10 Pentadecane (CAS) n-Pentadecane

24 22.663 4629720 0.24 Ethanone, 1-(4-hydroxy-3-methoxyphenyl)- (CAS) Acetovanillone 25 22.769 15369838 0.79 1,4-Naphthalenediol (CAS) .alpha.-Naphthoquinhydrone

26 23.023 2368517 0.12

27 23.178 7682374 0.39 2,2-DIMETHYL-INDAN-1,3-DIONE 28 23.245 10319504 0.53 GERMACRANE-A

29 23.339 2217653 0.11 Naphthalene, 1,6,7-trimethyl- (CAS) 2,3,5-Trimethylnaphthalene 30 23.463 3772287 0.19 3,3-DIMETHOXY-6,6-DIMETHYL-CYCLOHEXA-1,4-DIENE

31 23.588 2716576 0.14

32 23.795 5826292 0.30 Naphthalene, 1,4,6-trimethyl- (CAS) 1,4,6-Trimethylnaphthalene

2-metil antrakuinon

Area Conc% Name Peak# R.Time

33 24.517 4187239 0.21 1-Naphthalenol, 2-methyl- (CAS) 2-Methyl-1-naphthol 34 24.912 2004518 0.10 Octadecane (CAS) n-Octadecane

35 25.090 2336745 0.12 Phenol, 4-ethyl-2-methoxy- (CAS) p-Ethylguaiacol

36 25.730 4714217 0.24

37 25.944 16216314 0.83 3-(p-hydroxy-m-methoxyphenyl)-2-propenal 38 26.869 4683096 0.24 6,10-DODECADIEN-3-OL,

3,7,11-TRIMETHYL-39 26.970 3351507 0.17

40 27.130 3059385 0.16

41 27.199 14476675 0.74 4-ethyl-4'-cyano-1,1'-biphenyl

42 27.388 4203950 0.22

43 27.539 12866222 0.66 2,6,10,14,18,22-Tetracosahexaene, 2,6,10,15,19,23-hexamethyl- (CAS) Squalene

44 27.606 2768696 0.14

45 27.710 13695512 0.70 Dibenzo[b,e][1,4]dioxin (CAS) Dibenzo-p-dioxin

46 27.826 9392220 0.48 Carbazic acid, 3-(1-butylpentylidene)-, ethyl ester (CAS) DI-N-BUTYL KETONE N 47 28.003 37355559 1.92 Hexadecanoic acid (CAS) Palmitic acid

48 28.972 11310996 0.58 9,10-Anthracenedione (CAS) 9,10-Anthraquinone 49 29.205 2149778 0.11 OXACYCLOTETRADECA-4,11-DIYNE

50 29.498 80286073 4.12 [1,1'-Biphenyl]-2-ol, 5-(1,1-dimethylethyl)- (CAS) 4-tert-Butyl-2-phenylphenol 51 29.632 7236479 0.37 Octadecanoic acid, methyl ester (CAS) Methyl stearate

52 29.776 29660893 1.52 1,4-Naphthalenedione, 2,3-dimethyl- (CAS) 2,3-Dimethylnaphthoquinone

53 30.001 91016200 4.67 2-NAPHTHALENECARBOXYLIC ACID, 1,4-DIHYDROXY-3-(3-METHYL-2-BUTENYL 54 30.088 14097433 0.72 Nonadecanoic acid (CAS) n-Nonadecanoic acid

55 30.288 2592267 0.13 o-Menthone

56 30.327 2918547 0.15 Octadecane (CAS) n-Octadecane

57 30.540 480848596 24.67 9,10-Anthracenedione, 2-methyl- (CAS) 2-METHYL ANTHRAQUINONE 58 30.992 25555811 1.31 9,12-Octadecadienoic acid (Z,Z)- (CAS) Linoleic acid

59 31.113 8657168 0.44 1,4-Naphthalenedione, 2,3-dimethyl- (CAS) 2,3-Dimethylnaphthoquinone

60 31.206 9619671 0.49

61 31.318 4805256 0.25 9,10-Anthracenedione, 2-(1,1-dimethylethyl)- (CAS) 2-tert-Butylanthraquinone 62 31.396 7532267 0.39 Tricosane (CAS) n-Tricosane

63 31.605 3136054 0.16 2,5-DIMETHYL-3-PHENYL-FURAN

64 31.686 2352017 0.12

65 31.787 20030569 1.03 9,10-Anthracenedione,

1,4-diamino-66 31.854 5560655 0.29

67 32.080 3874396 0.20 HEXADECA-2,6,10,14-TETRAEN-1-OL, 3,7,11,16-TETRAMETHYL-, (E,E,E)-68 32.224 7135320 0.37 1,3-Dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one

69 32.569 12604182 0.65 Tetracosane (CAS) n-Tetracosane

70 32.680 2726066 0.14 8,11-Octadecadiynoic acid, methyl ester (CAS) METHYL-8,11-OCTADECADIYNOATE 71 32.770 3882574 0.20 (-)-Nortrachelogenin

72 32.947 3359478 0.17

73 33.104 3008576 0.15 Tetradecanal (CAS) Myristaldehyde 74 33.313 12466332 0.64 Chrysophanol

75 33.891 16671813 0.86 Tetracosane (CAS) n-Tetracosane

76 34.241 1988769 0.10 Oxaziridine, 3-(4-nitrophenyl)-2-propyl- (CAS) C-P-NITROPHENYL-N-N-PROPYL 77 34.372 3171979 0.16 Eicosane (CAS) n-Eicosane

78 34.539 4047553 0.21 Tetradecanal (CAS) Myristaldehyde

79 35.056 2013948 0.10 1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester (CAS) Bis(2-ethylhexyl) 80 35.437 22317487 1.14 Octacosane (CAS) n-Octacosane

81 35.576 2599536 0.13 Ethanone, 1-(4-hydroxy-3-methoxyphenyl)- (CAS) Acetovanillone 82 35.970 5541277 0.28 Eicosane (CAS) n-Eicosane

83 36.222 7057833 0.36 Tridecanal (CAS) Tridecanaldehyde 84 36.542 5508743 0.28 TETRACOSANE,

1-BROMO-85 37.277 22958217 1.18 Tetratetracontane (CAS) n-Tetratetracontane

86 37.942 13130831 0.67 3,7-Dihydroxy-9-methoxy-1-methyl-6H-dibenzo[B,D]pyran-6-one 87 39.509 20016514 1.03 Tetratetracontane (CAS) n-Tetratetracontane

88 40.838 534227833 27.41 1,6,10,14,18,22-TETRACOSAHEXAEN-3-OL, 2,6,10,15,19,23-HEXAMETHYL 89 42.207 16828941 0.86 Tetratetracontane (CAS) n-Tetratetracontane

90 45.561 9766200 0.50 Nonacosane (CAS) n-Nonacosane 1949237046 100.00

Dalam dokumen KADAR TEKTOKUINON PADA EKSTRAK KAYU DAN KULIT JATI (Tectona grandis L.f) JAWA BARAT DAN JAWA TIMUR ADE YUNIA PURNAMA PUTERI (Halaman 31-39)