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Internal pressure of liquids from the ca

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Fig. 2. Measured and calculated isochoric heat capacities of argon as a function of densityin the supercritical region
Fig. 6. Second temperature derivative of external pressure (orof the internal pressure, ( first temperature derivative∂Pint/∂T)V) as a function of density along the near- andsupercritical isotherms of pure water calculated from crossover equation of state [41].Symbols are derived from direct isochoric heat capacity measurements [65,66,72].
Fig. 9. Isothermal( CVmaximum and minimum loci (or isochoric temperature maximum and minimum of the internal pressure) of water and carbon dioxide calculated from crossoverequation of state [41,62].Dashed lines are isothermal maximum (CA) and minimum (AB) of CVand isochoric maximum and minimum of the internal pressure, where (∂Pint/∂T)V=∂CV/∂V)T=0.
Fig. 11. Internal pressure of carbon dioxide and light water as a function of temperature along the various liquid and vapor isochores near the phase transition curve calculated from thecrossover equation of state [41,62]
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Internal pressure of liquids from the ca

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