INDONESIAN JOURNAL OF CHEMISTRY Vol,11,No.3,November2011
EdltorlnChle'
Prot, Dr, Hamo Owl Pranowo, M.SI Email: hamodp@ugm.ac.id or
Department of Chemistry,ｕｮｩｶ･ｲｳｾ｡ｳ Gadjah Mada
Sekip Utara, Yogyakarta Indonesia 55261,TeVFax(0062·274r545188,
ｗ･｢ｳｾ･ : http://www.ljc.chemlstry.ullm.lc.ld
Email :IJcullm@yahoo,com
ｾｴｯ､｢ｲｄｬｬｭｈｯＧｾｉＬｦＩｬｏｬｦｻ･ｰｉＲｏＧｉｏ ｄｯｲＢ［ｾｊｵｬｹＲＰＱＰ
hamopranowo@yahoo,com
Vice Editor In Chll' ｐｲｯｦＬｄｲＮｍｵ､｡ｳｩｲＬｍＬｅｮｾ Drs.lqmaITahir.M.Si
Email: mudasir@ugm.ac.id
Email:iqmal@ugm.acJd
EdllorlalBoard
Prof. Dr. KarnaWijaya.M.Enll, (PilysicallMafarlaIChemisfry)
Prof. Dr. JuminarOrganicChemislry)
Prof. Dr. Nuryono, MS(IncrrJanic Chemisfry)
Dr. Ria Amlunanto, M.Si.reomputetlonaVPhysical Chamistry)
Dr.TriJokoRaharjo,M.SI·rBiochemislrylBioenalysis) Dr. Nurul HidayatAprilita(AflIliytic8VEnvironmentaIChamistry)
Advisory Editorial Board Dr. Brian Williams (Adelaida University Australia)
Prof.Dr.DI.He.Ｖ･ｭ､ｍｒｯ､｡Ｈｕｮｩｶ･ｬｳｾｹｯｬ
Innsbruck,Austrial
Dr.DirllBWl(Utre<;htUniverslty,Netheriands) Prof. Dr. M.Gross(LooIsPasteurUniversity,france)
Prof.Dr.HardjonoSastrohamidjojo(Universltas
GadjahMada,lndonesfa)
Prof.Dr.David. St.C, Black (Univars1ty of New South
Wales,Australia)
Prof.Dr.ｍ｡ｸｌｵＨｕｮｩｶ･ｲｳｾｹｯｬｑｵ･･ｮｳｴ｡ｮ､Ｌａｵｳｬｲ｡ｬｬ｡Ｉ
Prof. Dr. Bochori(Bandung Instiluta of Technology, Indonesia)
Prof.ｄｲＮａｴｬ､ｵｉｒ｡Ｇｵｦｐ｡ｴｨｯｮｾＨｈ｡ＤＸｮｵ､ｩｮ University,
Indonesia)
Prof.Dr.NaokiYoshioka(KeioUniverslty,Japan)
Assoc.Prof. Dr. Wan Ahmad Kamil Mahmood Ｈｕｮｩｶ･ｲｳｾｹｓ｡ｩｮｳ Mataysia)
Administrator Or. Akhmad Syoufian WarakustartiLlstyartwangl,A,Md DjokoPrlhandono
Prof.Dr.Muhammad Idil'ls Saleh (UniversitySalns
Malaysia)
DI.HeryHaenJdin(Perlamlna,lndonesia)
Proi.Dr.liplzulFalah(UnlvflrsitasGadjahMada,
Indonesia)
Prof. Sri Juari Santosa, M.Eng, Ph.D. (Universitas GadjahMada,lr>donesia)
Prof.Or.EndanIlTnWahyuni,MS(UnlversllasGadjah Mada,lndonesia)
Prof.Dr,Bambang Rusdiarso, DEA (Universitas Gadjah
Mada, Indonesia)
Prof.Or.WegaTnsuneryantl,M.S.,Ph.O.Eng Ｈｕｮｩｶ･ｲｳｾ｡ｳｇ｡､ｊ｡ｨｍ｡､｡Ｌｬｮ､ｯｮ･ｳｬ｡Ｉ
Prof.Dr.Sabinn MatsjehＨｕｮｩｶ･ｲｳｾ｡ｳ Gadjah
Mada,lndonesia)
Dr. Winarto Haryadi, M,S;.Ｈｕｮｩｶ･ｲｳｾ｡ｳ Gadjah Mada,
Indonesia)
RobbyNoorCahyono,S.Si.,M.5c EmieKumiawati,SH
Alms and Scope
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｣ＺＺＺ･ｾ］ＧｾｴｾｾｾｊｾﾷＺＺｲ
ｾｾｉｾｲ
ＨｾｾｲｴｾｾｉｾｾｾｾｾＧ
ｾｾｦｊｾｾｾｯ｡ｊＧＺｾｾｾ
ｾｾＱ･［ｾＬ
ＧｓＢｾｾ
I'rlDONESlAN JOURHAL OF CHEMISTRY ｙｯｬＮＱＱＬｎｯＮＳＬｾＲＰＱＱ
CONTENTS
ｓｾ o.rMItlw.ａ ｾ for NowI ｯｬｯｮｬ｣Ｚ･ＭＮｾＮ SynttMsla, Charac:tlriullon -..d AntImicrobial E....lu8tlon ofSome 2-(.- t.titl/tlldAnlU.-.yndon-3·-yl)_"3,4-th. .INlIlO ＨＢｳＮ｢Ｉｬｮ｣ｬｯｬｋ｢ｹｬｩ･ｭｩｬｮｬｐ｟ＮｓＯｬｩｓｨｊｰ｡ｬｓｩｮｧｨＮ｡ｮ､ｎｬ､ｨｬｾ
ｾｮ Eh<;t low.m
no..
Qu.lllyofCureumln lmprim.d Polymer by Em!ShlqiuAzlzl.MolId NoorAhmlll.A.K.M.S/'IlIllqull... OIhyarArbaln.andlqmlllT.hIrno..
AddllionEfflCl ofSulph.nlll<: Ac:ld to tIMSynthKl. 013,.-.thyl.n.dloxyblnulclehyd. byFetlF.UmahandSanuslGugu!e
Th.ActinFr.<;tion fromNlrJfI//'IItlv••nd Its Actlv1ty '1l.ln.tU7DC.ll U ... by Heny EkowaU, 217-222
EQPra$llstl,andUndrilUl.lutl
TIM OptlmlutlonofEnzymltl<: Synthesl.forlIuroyl-H_lthyl Glu<:amlcle Surf.e1.nll by
ZUMn.MuyilhtJh, seri 8lmlISemblr1ng,ZUI Allian. and T}8hJono Herawan
Synthell.of5,7-dlhydroxy-3·...'-dlmethoxylsof\lvofromEugenolbyAndiHalrltAli'nuckln. ｓｉ｢ｨｉｾＬ ChairtAttww. andMUIlofi
Synthwl. ofT«plneolfrom ..ｾｮ･ｍ CI!I1yudbyｔｃｎＧＨｾｉｴｏｬｉｴＮ by NanikWijIY"d.H.mOwl
F'rInowo,.,unm,andTrtyono
HydrotysIsofe.t>ohydratHInCIIUYIIPulp.ndTsplo<:aFlourundlr"Ic:rowIYllrrIdlltlonby23&-2045
Ｆ｡ｈ･ｲｭｬｬｴｬＮｊｯＮＮｮＮＮｩ､ｉｩａｮｭｬＮｾｾＮ TItIC..so.n.ti.OnoSupamo.Ind8ln'lbfong
-
ChlrKtIlriutlonof 0.58 kb DNA StIlblnl SynthlH encodingGInIｆｾｮＱ from M11lnjoPIInt 2<16-252(Gnefumgnemon)byTriJokoRatllr1o,RosyidaAzllRizkl,SII"Nom'IIIEthicII.ElyRulIlnll.IndL
HertlntoNugroho
TIOJ8e1dtfor PtIotOCllt.lytlc DllIr.dlItion of Humic Ac:ld In PulWltir byWlnauti And.yenl.nd
A'lu.UnNMSagyo
Pr.llmlnary Study of the Utlliutlonoflhe Fly Ash from Co.l.fl..cl PowerPr.ntfor
ImmoblllZltlon of Radlo.e1I.,. W••t.by Harry Poemomo
Effie!01CrOl.linklng 10 IhI M.c.h.nl<:al Property of ApIIIII G.I.tin HybridforBon.
Sub.lltutlonPurpo.KbySuoarao.Sulamo.KanjT$UIU.lklDe¥04Ana,andKunlol.hIkIwa
Mlorptlonof ca(ll), Pb(ll).nd Ag(l)on Sulfonlto-$lll<:aｈｾ p. . ...-Ifrom RIce Hull Ash by
ｓｩｉｬｓｵｩｬｬｉｴｲｬＮｎｵｲｹｯｮｯＬｉｾｾｲｴｉｮｉＮＢＢＧｅｫｯｓｲｬｋｵｮｬｬＱｬ
UtIllutlon of RIceHulk • RIwMIterlIl In SyntMsls of "1IOpOO"0UI Slllc:lWlMe....,by219-2&1
Su)lnllII'ldAgulKl.nalkl
PNpIrItIon.ndChlIrectIrtutlon Ion SlIectIYI EII<:trodeCd(I)8IHd on Chlt_1nf"YC
MlmbrwwbyA.SefIo5IPlngglbun
NOn,
A N_Phenolic:Compound from Acetone Extnct 01U<:hIn(lInN/lvUON T.yI. byIrIdD,J.Chwn.,2011,ff(J),rTJ.l1'
ADSORPTION OF Ca(lI), Pb(ll) AND Ag(I) ON SULFONATO-SILICA HYBRID PREPARED FROM RICE HULL ASH
Sltl Sulastrl'.1, NuryonoJ.·, Indrianll Klrtlnl', and Eko Sri Kunarti' Ｇｓｴｾｗｮｬｯｬｄｯ｣ｴｯｴｬｬ･ Pro:lgram,o.{Wlmerlt01ChemIslIy,ｆｋｴｊｬｦｹ｣ｦｬＮｬＯｴｬｨｴｬｭ｡ｾＮｲｯ ｾｲｬＬｬｦｦｬＯ
so.lI(>f'.
ｕｮｎｬｉｲｳｊｴＮＧｾｍ｡､ •.YogyWll., IIldon/lsi.
'DllplrlmllllolChlmi&lIY, FlCUlfyofMathlmalicsIIldNItutaIｾｳＮ Sla'-Ulllvef3ltyofYogya1<llrll.
ｾｴＮｮｧＬｙｯｧｹ｡Ｑ＼ｬｬｲｬｬＮｬｬｬ､ｯｮ＼ｊｓｪ｡
ﾷｾｯｉｃｍｭｩｳＱＱｹＮｆｍＺｬｉｉｲｹｯｬｍｉｴｨｉｭｉｬｬｩ｣ｳ･ｮ､ｎｍｵｲ｡ｩｓ｡ｩｉｯｮ｣･ｳＬｾＧｾｍ｡､ｉＮ
ｂｉＮＲｴＮｳＮＯｬﾥｉｕｴｉｴＧ｡ＬｙｾＵＵＲｂＱＬｾ
ｒｷＺ｡ｩｶ･､ｾＲｉＵＮＲＰｦｦ［ａ｣ｴ［Ｚ･ｦｉｴ･､ｾｦｾＲＰＱＱ
ABSTRACT
273
ｉｮｉｨｩｳＱＸｳ･｡ｲ､ＱＬＮ｣｢ｯｲｰｉｩｯｲｉｯｉｃ･ＨｉｦＩＬｐ｢ＨｬｦＩ｡ｮ､ａｧＨＢｉｮｾｾｯｮｉｏＺｾｴｯＭＮＮｳｩｩ｣｡ｨｹｴｯｲｬ､ＨｓｓｈＩ
ｾｦｲｯｭｲｩ｣･ｬｬｵｬｵｨＨｒｈａＩｨｵ｢ｎｮ｡ｴｶ､ｩｦｋｉＮ ｔｉｬｉｰｴＧｉｉﾻｦＧｬｊｴｩｯｮｯｴｓｓｈｾｗＸＤ｣ＺＸｉｲｩ･､ｯ｣Ｎｴ｢ｹｯｬ､､ｬｬｴｩｯｮ
01metUPlrNIics /lytJrid(uSH)wiftlhydrogenpetlJ16de{HzOJJ«JIutionｾＮ MSHWl!Sprwpared, .,..
so4JeI
process,byIdding3U hydrochJorieIddsohAionto
mmunr
01sodiIJmｾｴ･ (NatSiQ3l lOMion .ndＳＨｬｲｩｭ･ｬｨｯｸｹｳｩｊｹＯＩＭＱｾｮｬｨＯｯｩ (UPTS)to181Ch pH of 1.0.SoIlJIionof Nll:SiOs wasglrllraledfromdeslructKx1 of
RHAwilhlSOdium hydroxideS4)/uIkInfollowedwithhfHllingal 500 "Cfor30mitt.TIleSSHＨｘｏ､ｾ was
characllrlz(J(JwithFcwrilrIfllnsfonnInfra/'ld (FTlR) spfIdfOSlXlpy, X-ray diffraclion (XRD)Ｎｮ｡ｬｹｾＮＢ Irllfl1Y
､ｾ X-ray (EDX)ｾｬｬｏｓｲｯｰｹ and determination or/on-Ixchangeｾｰ･｣ｊｴｹ for $Odiumion(N.'). Thl
ｴｴ､ｳｯｲｰｴｩｯｮｯｦａＧｩｊＨｉＩＮｮ､ｃＮＨｉＯＩ｟ｬＸｲＺｯｮ､ｵ｣ｴＹ､ｬｮＮ｢｡ｬ｣ｨＧｙＳｴＱｭｩＱｶ｡ｲｩｯｵＧｾｬｴ｡ｬｩｯｮｳｲｲｸｏｏｬｬｬｯｯｲＮｔｨ･
Idtott1enlion
wa.
cak;uI.l&dba(#/(lfl､ｾｯｦｾｴｉｯｍ bef0!8sndafleradlOipOOnproceudeterminedｾｬｴｏｭｩ｣｡｢ｳ｣＼｢｡ｮ｣ｬｾＨａａｓＩｭ｡ｴｨｯ､Ｎ Theadsorptionr::llaraclM'we.t1V3lUaltlduUlgfl'lO(/6/oi
iMJthafmLMlgmuirandF!8UndIidrttdsorptionloClllaJlBteｬｉｬｬｬｾＮ c::MsUntsand-vtol/tdsorptirxl.RId
oIdlanK:terizatiotllYyEDX andFTIRｉｨ｡ｷ･､ｱｵ｡ｬｩｲｂｾＯｊｬｉｉ SSHMi｢･･ｲＡＮｳｵ｣｣･ｵａＮｴｉｹｾｴｬｩｺ･､ｬｬｬｬｦｬｩ｣ｨ __
bc1ieel&dbyappeanncaｯｉｾｾｯｉｾｐＧｄｉＮｰｮ｡ｭ｡ｬｹ､｡ｮｯｬＨｓｩＭｏｈＩＬｉｩｉ｡ｵｍＨｓｩＭｏＭｓｉｊＬ
maIJIyIMa(-CHr)｡ｮ､ｾｯｉｾｐＧｄｉＮｰ (SH). TheXRDdoIlalhawedamrxphoul.strllCtUo'eoiSSH,
. , . , to sifcagal(SG)and USH.Thestudyoledlorptjonｾ IhowedItlfIIoIdd8fiQr7ofU$HIntoSSH ｾｲｨ･ｾ｣｡ｰ｡｣ｩｴｹｦｯｲｎ｡ﾷｦｲｯｭｏＮＱＲＳｴｯｏＮＵＱＧｴｮｭｃｬｬｦｧＮｔｨ･｣ｨｦｊｮｲｩ｡ＢＧｦｉｭ｣ｴｩｯｮｉｊｉｧｲｯｯｰｦｲｯｭ
denoIlorrren:ap/IJandfrommeree,ototo.wIbrNtoｾ /heedIorptjoncapacity01Ca(JI}.Howe...,/he ｾｯｲｲｩ･ｲｯｴｾＮｦｯｲ｢ｯｬｨｩｯｮｬｯｬｐｬ＾Ｈｉｑ｡ｮ､ａｧＨｬＩｩｯｉ｡ｱｵ･ｯｗｬｴｬｏｨｊｴｩｯｮｩｬｕｓｈＢｓｇ＾ｓｓｈＮ
Ktywont.:ttdsrxpliOfl,silica,rica,hybrid.•ulforNJto
Rioetwsk.!hepredominanlbyproduclInthe milling
proceuddomestic IIIlriculture,isusualyeitherburned
ｏｬ､ｩｦ･｡ｴ､･､Ｎｲ･ｳｵｬｬｲｬｧｮｯｴｯ､ｲｩｮｾ｟ｬｩｮｧＬ｢ｵｴ
8110 inenvironmental poIulion. Aseoonsequanc:e,
espadaIyin!hefleldofmaterilllsc:ienal.il.lTIlIkessense ｬｏｾｲｩ･･ｨｕｳｫｮｨＨｒｈａＮＩＮＮＮｴｉｩ｣ＺｴｬＮｏｃｬｴｲ｜ｐＰＵＸ､ｯｦ
extfemeIypu-earnorpholAsilieaextrae:ledfromrice huskbyeseriesofproceuinc:U:lirlgKidIeadling. ｰｹｲｯｉｹｳｩｳＬ｡ｮ､ｾ｡ｮ､ｭ･ｹ｢･ｵｳ･､｡ｳ
.-e.toI.WCI!Itorsileltbasedrnaleriall. ｉｮａｬｃＸｮｴｬｩｭ･ｳＬＸｏｉＭｧ･ｉｭ･ｬｨｯ､ｳ｛ＱＭＲＩｾ｢･･ｮ
consideredpromiUlglorpreparingllllrarw.., highpurity,
.lngleand mlllli<:omponent oxidaglalll8s and ceramic ｣ｯｭｰｯｳｾＮｳ with the advantages of highpurity,lower
,Intlring temperalllre, a high degreeofhomogeneity,
ＧｾＭＮ｡ｲＮｔ｟ＢＺＧＦＲＮＮｶＴＵＴＤＧｎ
EmoI_:nuljO'aO_mlpaGugm.ac.id
high yield, smallproeestJngtime,costsffectlveness
and envltonment frienctly(3-4J.Mo$l 01!hi soI-ge!
mllhodl [5) ofprepar1rGlAS GlasaC'*WI1Ie1 are
alkOllidebased,andlhel8fore,controlofhydrolysill'lnd
condensationruaion ofdifferent melllalkoxideis
ｴｬｴ＼ＺｯｮＧＪｉｧ､ｾｾｲ､Ｓｬｨ･ｴｯｴｭ･ｬｩｯｮｯｦ･｣ｯｮｶｮｯｮ ｮ｡ｴｷｯｲｫｩｮｷｨｩ､ｬｬｨｬｬｙｬｲｩｯｵｬｭ･ｴ｡ｬｩｯｮｬ｟ｾＮ
Se-.l8ll8mptshlYebeencarriedOUlinc:llldirlg lTIlIIchingofhydrolysistaleBbychemicllmodifielllionl lIIitIlehelalirlgigands.'}'I"lVlesiBoflTllAlicomponen
8Ikoxidn01partial prehydrotysisofa!<exIdI$(6) •
Meehanicaly stabIa metrices, such . .dMmicalIy
mocfllltdliieaO&!surfaces,hall'llawakened growing
InllrtS1becalJSelhekncwltdgtlOOQllirtdwithlhen1
permits !he transf., 01 somepropertle,found in
homogeneouschemistry totheImmobilizedstalS.
274 1ndo..J.ChM!..1D1f,ff/3J,Z1,.rn
｟ｬｴｷｳｩｬ｣｡Ｍ｡ｬｬｬ､ｬ･､｣ｷｶｾｬｉｉｴｬｬ｣ｴｬ｟ｷｩ､･ｉｹ
UMdflvariousted'noIogies[7-6).
n-
maBials _bIespeciationdr.eeelemenbandareusefulin toMng many ptOblems In nudear te<:hnl:*lgy, eIIclroI'Mcs,metaIIurtlY.rnnng,medicine.19ricu1llQ,flIItlerielIlIIId enYironmenlalltudlM. A/Ihougtlelarge
body of dataha,
*"
reported aboolanchorlild ailicas.new applications .... continuously demending further Inlolmatfon.
SilicagelIs-.n Inorganic supponwidelyｾｳ･､ in menychemicalproeesees.lmingsevlralK:lentiflcand
tec::hnlcalapplicationt(10-11).ThissupJlOl'thasbeen
In<n:Jslrqy
lISfIdbeeeuseitasurfaceon..
many ｾ､ｵｬｬｦｏｬｾＮｬｯｬｬｳｴｨ･ｲｭｬｬ｡ｮ､｣ｨ･ｲｮｩ･｡ｬIlIlbiiuliondtRlg the 1lI81;tionproceu｛Ｑｾ IIhas •
Illgh-'- . . .ＨｾｭＲＱｧＩＬｬｔｉｩ｣ＺＺｲｯｰｯｲｕｬｩｭｩｮｬｨ･
I'1ItIQ85-alO'AandltcantJ.used.1rellIm.ty1ow
eottll31·SianalOf'Ol4ISOl'IslIicagel8U1_beI'I8",,1Q • \veakIICidＨｰｋｂＮｧＮｾＩ［ It!uslheycanintefadwilhpolar c:ompoo.nd$lhroughbolhltronghydrogenbondsand d!;)oI..-dipoleIntW8Ctlons_lt>eweUkJlQ'Ml8renlted acid[14-151.Dueto theprueneeofthese groupsof
adds, silicagel is .bl.to,daofb the mollvaried of
chemk;:al species such IScyclicamlnes [16].Ilmlde.
[1T].proteins[18). bIoIogfcallyactivephoephates [19] •
• ndliso lorsorpllonIntheS8pll11ltion prooessofthe
p1alln...nmetal120],w11hout pre...o::.osmodlftcation with ＮｮｾＮｔｨ･ｬｬｬｏｬｩｴｩｯ｡ｴｩｯｮｯｬｬｨ･ｳｬｬｩ｣｡ｧ･ｩ
lJUrr-isusuallydonebyuU1gMapproprialemolea.lle ｾｾｱ･ｧ･ｮｴＮｩｉｉｉｬｬＸＤＧｾＮ
stablelXMlklntbond ••ｦｯｲｭ･､｛ＱＰＩＮｾＮＱｯ
IncruNthecharlcanbtl0'I'III'lXlIMbyIu1Iwｾ
ｩｮＮａｉ｢ｉ･ｱｵ･ｮｴｾｳｴＸｰＮｷｉｬｨＮｶＮｷＮｴｹｯｴ
orglWcfln:tions.fOIlhemanydesiredputpOHS.T'IlU$,
modified ••ICIIiswidely uMdi'l｣ｴｷｭＮｾｹ (10].lI$
aupportlcrlTlll18rialsv«thc:alalyricpropel1la(111.3S
QqI.le$Irlltionagenl01me18ls (211. forIorH:Jlchange
[22),abo forconlamWlants I'lIITlOYaI fromwaste.muent
slreem.(23],andlormanyotherpurpoHt. InprevlousrePQrt.wade.cribedthainve.tigation. ofＮｾｴｨ･ｴｩ｣ schemea aiminllatthepreparation of ｯｲｬｬ｡ｮｬｯＭｬｮｯｲｧ｡ｾｰｯｉｾｲｨｹ｢ｲｩ､ｬ｢ｹｵ｡ｩｮｬｬｬｲＸ､ｩｴｩｯｮｬｬｬ
heteroganeou!lrout" [241: and for lha.Mlyof
lJdsofptioneqlJilibriumprooanesdtladivalanlc:ations ｣ｯ｢ｬｬｉｴＬｮｩ｣Ｚｫ｡ｬＬ｡ｮ､ｯｯｰｰ｡ｲｦｲｯｲｮｾｬｏｫｊｴｩｯｮＮ
HomoganotarotDIIIIlngRHA8$thealbIOU'OIlfor ｰｲ･ｰ｡ｲ｡Ａｩｯｮｯｬ｡ＧｊｬｩｮｯＮ｡ｮ､ｾｬｉＩｴｬｲｩ､ｳ［｡ｮ､
IheQorptIonn.Jdyd _ _metallonl alto hadbeen
ｲ･ｰｯｬＧｉ･､｛ＲＵＭＲＶｊＮｔｨ･ＮＭｵｊ｢ＺｯｉｴｨｬＱｾ｣Ｚ｡ｰ｡､ｴｹ
oItn.harddvalantdMtlystlOW8dhltamirloltlOltfiad
.-e.
bends toIIdtorbhardbasee:atIonIinhigher Imountthatlll18l'Cll$llOmodlI'iadsiicll.Intheｾ worII .... n-tigated theadlQrPliOn P!OC8Mn01 ca(lI).
"«!)
IndPb(1I) in aqUllOU. lIOflltionon.ulfonatomoditied.Hiclpreparad fromricehull a.sh
SiIi$ululriet81
... IiicaMlUrClI.ThepresentRI.Idy
ems
loＸＧｴｉｫｊ｡ｴ･Ｑｴｬ｡ｾ､ｬｬｩｩ｣｡ｭｯｯＺｬｩｦｩ｣Ｚｬｴｩｯｯｍｨ
m8l'CllploandS\Monalo llrouPS onlha adIorption
ｾｵｳｩｮｧｬｗｏｬｉｯｉｨ･ｲｭｭｯ､･ｬｳＨｆｾ｡ｮ､
...,.,,"'"
EXPERlMENTALSECTION
Precl.notoflOdiumdicata(Na,5lO,)toMionfor IOl-geIpnx:essWMprapatedfromricehulla.sh(RHA)
ｾ Ipn:ICIIdurereportedbytb)ulo(13].Sampled
RtiA_mixlldv.tllNIOHlIOIuIion2Mlndthe ｲｩｴｫｮ｟ｾｬｴｩｭｬ､ｩｮｬｨｯｬｰｬ｡ｴ｡ｬｩｬ｣ｗｹ
atIClltlan_haatadlt500"Cfol"JOrni'lIn.fl.maca.. Therem..wasoi:uolvedinwaterloobtilinaoklliond ｎｾｔｨ｡ｬｬｬｬｬｧＸｲｬｬｧｬＪｬ｡､ｾＩﾭ
propena-l-1hiof{J.4PTS)frorn Aldridl.calioM01 Ca(ll)•
ｾＨｉＩＮ｡ｮ､ｐ｢ＨｬｉＩｬｮ｣ｨｬｯｲｬ､｡｡ｮ､ｴｗｴｲ｡ｬ｡ＢＨｧｲ･｡ｴ｡ｲ
1han98"'pl6ityfrornMartk),andhydroganparOllide ＺｭｲＮＨｍ･ｮ［ｬ｣Ｉｾｵｳ･､Ｎｬｕｐｐｬｩ｡､Ｎ
Proeaduno
Sol-plpI'OC8$'forfN8PIrItJon oral/Ironlto.111c1 h,M"
ｐｲ･｣ＺｵｲＤｑｲｯｬｾｬｉｏｦｬｬｴｩｯｮＲｓｭｌ｟ｭｏＺ･､ ｾＢｭｬｍｐｔｓ｡ｮ､ｬｨ｡ｮｬｨ｡ｭｩｸｬｵｲ･｟ｬ､､｡､ｷｩｬｨ
hydrochloridaldd3Mdropbydropand_11irTad
MJMy iii hipH017.0.The galformed _ kept
OYWnight..-dtlen_Wllhadwilhwa.klordarto ｢｡ｦｲ･｡､ｬ､､｢ｹｾｷｩｬｨｬｵｮｬｙ｡ｲｬ｡ｬｰｈ
ndlcatorpapar.Thaget_drilIdat70"ClWIdwas groundadinto200n....nInper1idaslu.Thaproducl obtainadwasdiclmodilllldwltllTl8'l:lp!OpfOpylgroup
(lTl8'I:IptolIiIicaｨｾＬ MSH).ThesimilarwOOlwas
rapaatadwitlloullllOci1lonofMPTSloobtlinsiliclgel
(SG)asthecontrolpmduct.Thesilicamodified wilh
mercaplopropyillroupeWallOJddozadwtth H.o. to
prodllCesulfonicacid moieties on the,1I1ca llUrface.
ｔｾｬｉｹＮｬＮＰＱＱＰｦｍｓｈｗｬｉｬｬｬｬｕｓｰ･ｮ､･､ｉｮＱＶｭｬｯｦ
aqueous33%(wi)H.o,...mto continuout.tifring at
roomtemparauafor 1 h [30].The producedmaterial
wasfi/larad, waahadMYeralti'neswithwaler..-d
elhanoland thendriedat 100 "C Q'oII8m/ght. The
ttMonlclddlJOUl)lllltll(tledlolhaporlWlb-. ｏｏｬＧｗＸｬＧｴ･､ｩＧ､ｯｬｏ､ｬｬｍｔｬ､｜ＺＺｬｯ｡ｴ｡ｾＧｉｬｲｯｵｧｨ
i:lraItion'rihNaOH IIOk.«ion (tl.lｬＮｬｾ The sold
productwufilered0«. wahadwillidalorUad..ner.
.-.ddMd at roomtempera...0YlImight.Thesample
｟｣ｮ｡ｲＮ｣ｴ･ｲｩｺ｡､ｵｳｩｮｧｘｒｄＮｆｔＭｬｒｾ｡ｮ､
..
ｉｦｉ､ｯＮｊＮｃｨｍｴｾＲＰＱＱＬ 11(3),213-218 275
F1g2.lnfra*'lP'dJlIdproducts;siialgel(A), men:apkl8lbH)tIrld(B)II'lClsuronamsiIic8h)Uld(e) IaotMnrnolMlMNptlotl
The""ll;hlldsolplionmethod_usedlol' ｾｉｨ･ｾｯｦ｡､ｳｯｦｰｬｩｯｮｾｬｩｮｧｯｦ
100mgdadlotberJlsuspendedin50.0mLd."
lIqUMlUSmetallonlllvariousirlillillconcentrations.TIIey
W$'8mee/'lanlee.ltystlrredfor1hBlaroomtempetlllture
(298 K).TheISOkJtionawerecentrifugedandthe
supemeUlnt Wilt determined by atomic: abaorptlon
OCM, H---"I;Ja<o
",.cO--J,...M••
ﾷＭｈＮ｣ｏＭＭｊｉｾ
...
Jc"o
Jc","
｟ＮｉＭｏＢｾｾ
...ｾＢＬ｣ＺｏｊＧｾＮｈ
JeM'
Jcllo
L
ｴＺＷｾﾷｊｈａＭＭ
f-
ｾＺＷｾＧＩｈＬｯ
,
,
Fig 1. RMetiofl oftullOlla!o-sHIca hybridformation ••p'.(e) fom1alion ofsiloxane borldlng; (blmlXliflcatlonofaHica
withmlreaplo group, lind(clOltidationofmllrcapm group wi1h hydrogen peroxide
spectr'o$COpy.The amount of metalIonsItClsotbed
ＨｾＩｗＸｓ｣｡ｬｬ［ＺＺｬＬｬｬ｡ｉ｡､ｦｲｯｭｬｨ･ｾｳ｡ｬｯｮＺ m.1Cｾｃｊｖ
'Mlefe
Co
andC .... thelnitiIl IiIw:lequilibrium｣Ｚｯｮｯｉｴｉｴｲ｡ｴｩｯｮｯｦｭｦｬｬ｡ｬｬｯｮＮｩｮｭｭｯｬｬｴＮＮＮｾｉｹＮｖ
IBthe¥Dlumeolthe&QUeClU'solution(LIandMisthe
Ｏｬ｜｡ｍｯｦ｡､ｳｯｲ｢･ｭＨｉｬＩﾷｔｨ･ｾｾｷ｡ｳ
c.m.doutwi1h III lIIOsort:Mlnb (SO, MSH, 8Ild SSH).
Thesborptioncapacity{blwaseaIcUa:edfrom '
---
RESULT AND DISCUSSIONThe Ivaelionlorthekml-'lonofIItAfonal:o I1'IOCifIedsiicaltvoughancJllflllUlfonatjonrouteis ｾｩｮｆｬｧＬＧｯｯｮｳｩｳｴｩｮｧｯｦｬｨａｍｯｾｔｨｯｯ･
ｮ･ｫｬ､･ｬｯｲｭｵ｜ｩｯＺｯＧｬ､ＤｬｉｯｄｾＮｬｲ｡ｭ･ｙｬｬＺｗＱｬ｡ｬ｡ｩｬｩ｣｡｢ｹ
eddingacidinsoluIion01 sibleenloro (Fig. 1(8»'
Immobiizallon ofmlltalptogroups thesi5ea <luring
formation01
0eI
(Fig. 1(b)), lIIld •CUlidnon01thernmobilizedsulfhydrytgrouPtlOlheeorre&J)Ollding
sU:!orIicacid moietieswithHA,(FIg.1(e». Experiment
wllt1volunMltl'lcmetl\od ahowsthatintheinvestigated
276
..
eatll) Indo,J.CII_.. 201',11(3),27J-118 ｾ"
...
4.2014 122.0 PtJ{l1} ｾ""
ＱＷＮｾ"."
"-"
m. 91.81m.
1.692 ｯＮｾ 2.20 1.10 O.lIM
2.101 G.ne 2.50 2.16 0.9Il6 2.S1' G.lIM 1.67 1.82 0.ll92
'-E""
-c'
t:
-. .-
::
,-
-
.
--- !:
--
--.
_ _
.._
0 " , " , ,c._
_:t}'
1-
_.
,-ｾ-.
----
.-FI1l3.Correlalioneu...ｯｉｴｨ･｡ｭｯｵｲｲｴｯｦｾＱＱｯｮｳadsorbed....rsus concen..-atiOf'l01 metal1Ofl8II
equilibrium
\hecation eJlchangecapacilyfor
N.·
from0.123to0.575mm$g.
ｐｴｬｰＢＭＧｬｾｯｦｰ＼Ｇｏ､ｬｯ｣Ｚｴｳ
InfIowedlf*holl!Hlproduc:tslllvanou.tttga;
oIit1modilie:etionby ...SlAfonatillnrudiotl ...
pefbmt<ltomonitDrctlangesonilssuf. .(Fig.2). Siicllgeiltidentifledlllffilhlprua"lC8ofsp«:ifte spedI1IoIstrell:tlirllYibr.rliooIrom--OHlromeilanol group(3425c:m·').8endingvitntionotr.atgroup
ｾＢＢＱＱＶＳＶ･ｮＢＧＮｓｰ･｣ｴｮｬＸＱＱＰＸＰＮｮ､ＷＹＵｯＺｭﾷＧ
OOIMS from strekftng and bending YibnlliON, respeetiveIy,oISl-OlromsioXane($i-O-Si).Tl'le
preseneeof IhemereaptopropytWOUP' InIhe
Mu:tiOl'lloll:ed material Wilsevidenced by thepresenc:e ofstrongC-l-lllJelehlngWlnilionsoflhepropyldl.IM,t 29OOcm·'127}.nd._kYibratioo<XlfT'8spondlngtoltll -5Hgroop.12580em",Nlndicated InFill. 2.fOfIhe
sulton.lionreaction.thlItllolgroups In the MSH Wilr8
oxidized by HIOlto sulfonic acid unl1$.How1!v.r,
SiliSulastrlelal.
Sl.I!llncacidpeak$8l 1028
an'"
PNkS 1l1095-1065em" Cl)I'I'espondingtos)'lTll'l'lellie C-SslretdWlg
ｖＱｾｉｩｯｮｳＮｰ･｡ｫ｡｡ｴＹＶＰＭＹＵＰ｡ｮﾷＧｦｯｦＸｓＩｉｍＧｬｉｬｬｊｩｲＺ･Ｍｳ ｳｴｲ･ｬｃＺｨｩｮｧＮｾｰ･｡ｫＤ｡ｴＱＰＲＸＬＬＲｓＨＮＸｮ､ＱＰＸＴ｡ｮＭＧｦｯｲ
S:Oslrelching cametbe dislingu\$hedIrom !he broad
and strong siIoxane absofption lINk becauseofthe ｯｶ･ｲｉ｡ｰｰｩｮｧｯｦ｢ｩｬｮ､ｳｦＲＸｊＮｾＬｬｨ･ｲ･ｉＸｾｙＹ
InaeaseoIlheintensityoflheｨｾＩＨＩＧｴ n.nd freQuency
belwllen3200and3400cn,.'lrtdltledis.appearanceof
l!leweak-$HpeakII2580a11"indlclllolthaithe
IWlfonation reaCliOn had indeedoccurr&d,withthe
eubsequentoxJdalionof_SHgrOUPllo_SO.Hgroups
Fromthe x_ray diffraction pattem(datais not
dIOwn), three produeu (SG, MSH.ndSSH).thaiare
almllarto!hose reported eyei')Where. show abroad
peakwithmaximumintenlity.round 29 • 21-23'.
AcoordingtoKalaphatyetal. 129],slllcawilhthewide
band andthemaximum peak al 29 • 20-22"is
characteristicofsilica for..-norpl'loul structure.
Thereby.resunddIarltctariudonwithXRD males lhatmodiricationdlilicawithbolhmarcaptoand suffonalogroupsdonotcaull8lhedlangeollhesiiea ＢＢＢＧＢｾＮ AdsorptionI$ott-m Toi'lYestigateltleadaorplioncapac:ity,Yarious ｯｯｲＧｩｃＪＢｬｬｬＧＳｴｩｴｮｳ､｣Ｎ･ＺｉｉＩＬｐ｢ＨＮＩ｡ｮ､ａｑＨｉＩｾｷ･ｲ･ llimodfot1hwithadsorbenl8lrooml8r'np8t'8t1n.The uparimantdata is axprllll8dinfig. 3asｃｕｾ ｾｬｨ･｡ｭｯｯＮＮｮｴｯｦｭ･ｦ｡ｬｯｮｳ｡｣Ａｬｯｬ｢･､ｙ･ｬＧｓｬＮｬｬ
eoncentrr.ion of metalIons818Ql.illbrUn.For
inIerpretationollheadMlfPlionuperirnentaldala,1WO
iIotMrm{langmuirandFreundlicto) rnoc:IaIa_eUS«!
｛Ｓｏ｝Ｎｔｨ･ｾｬｬｓｉｩｯｮｯｦｉｨ･ｕｯｮｧｲｮｵＢｭｯ､･ｬｬｳＺ
ｭﾷＱ｢Ｎｾ
wheremisthelI!Tlounlofmelalionladaortlec! (mmolfg)llIequilibltum:Cialtleconoanlrlltionofmetal Ionlelequilibrium:l(represenl$theLang.muireon
(Ummol) thairetatea to theaffinity of twldlrIQlites.,;:
277
m_K,C" ｾｋｦｬ･ｬｴｬＮｆＢＧｬｭ､ｬｩ｣ｨｯｯｮｳｬ｡ｮｴｲ･ｬｯｴ･､ｴｯＮ､ｬｏｦｰｬｩｯｮ
eepeeityofltdlOl1>tnllW'dnletlMoF...ｯｯＨｈｪ｣ｨｾ ｎｬｬｉｬＸ､ｴｯｾｩｮｬ･ｮｕｹＮｋＮ｡ｮ､ｮ･･ｮｍ
eab.Ul8dfn:m\he . . andrurceptolh ...ｾ
aflDllm ... 1Dll
c.
Tllble2ci1playtlhecoef!ldwlttolＺＧＺＮＮ］Ｍｾｾ
fl'lOd«5IIlongWIllMUMfromT.ble1.1he R'VlIIUlllI forboll'lthe ｾ｡ｮ､ｆｴ･ｷｬ､ｬｩ｣ｨｩｳｯｴｴｷｭｭｯ､･ｬｳ _ _ moetly .!loYeO.90,wggMtingflBlbothmodelsc::loMlyfilthe l»lperlmental ｾＮｔｨ･ｬｴ､ｳｯｲｰｴｩｯｮ｣｡ｰ｡｣ｩｴｹｯｦｴｾ
monolllyer(b) luesｦｯｲｾＨｬｬＩ on .dsorbents wasIn
order.sa> SSH > MSH.Till.factcanbeex,pl.llned
1,l.1rlg haI'd acid PfOPllItYoIClI(II)'nd .i19actlv8.01the Ｘｃ｢ｯｦ｢･ｮｴｳＮａ､､ｬ｢｡ｦｭ･ｮＺ［｡ｰｴｯｧｲｯｵｰｳｫＩｴｉｍｯｾｩｃｬｉ
ｾ theｾ of theQorbent.Htlnce.the ｾ｡ｦｃＸＨｬｉＩｬｬｬｮｴ･ｲｬｬ･ｬ｜Ｏｬｬｩｬｴｬｭ･ｮＺ｡ｰｬｏｧｲｯｵｰｳ
ｾ .. -ak.ｾＬ by0lCIdri0nproceuｬ･ｬｴ､Ｂｾ III bmIIb01U'onaIo(-5O)H)thetwd_af
ｾＮｗｮｾ .00 . .eepdyill ncruMd,M
... DilhnntphenomenaOClCUlonsoftmetalloNaf ａｱＨＱＩｾｐ｢ＨｬｉＩＮ｜ｏＧｬｬｨｴｨ･｡ｩｭｩＢｲ･･ｰ･･ｩｴｹｖＸｬｵ･ｯｲ､･ｲｦ｡Ｂ
twotlrJIｾｳｯｲ｢･ｮｴｳ (80 "MSH).However, the Increase
ofeepecity forAg(I)Ietllgtler th,nPb(1i}and thisｲ｡ｬＬｬｾ is Ilmllarto thllprevlo\lson8repol'\8d[26j.Ttlachangaof IKeactivesfrornmen:apIDtolWlfonalobyoldd.lion
1Nd•.todBdll'l8the IIdsorptioneIf4)8CiliIIs.lt isdearlhat
oxId8tionQ!lUMIlmproYtllTlelllafl'lydroptUcpropertyof Ｘ､･ｯｲｴｉ･ｮｴＧｬｬｑ｣ｨＮｩｲｉｬＱｩｮＱＱｷｩｴｬＢｾＱｬｬＸ､･ｯｬ｢
IlardmetalloN.lfthe8d5orplloneapaQtyYN.IMoi tlnemetallcqonSSH . .ｾ . . . onieroi Ag(l)-Pb(II) >C8(1l) ilotlIaIn«l• • •prob8bIydlJeto ｉｨ･｢ｯｮ､ｩｮｧｴｷ･ｯｬｃ｡ＨｬｬＩｲｯｯｮｩ｣Ｉ･ｮ､ｬｮ｣ｯｭｾｯｦ
OICIdBIion..lonicbondmByMrHC!ytobebrol<endownin
lIqIJeOIJS(po!ar)lOkIIionvi'soIvetionand\he1,ll"\o
oxidized mereaptOgroupsntaract'ft1lh Ag(I)andPb(II)
bBtterlhan'NithC.(Ii).
CONCLUSION
Ch8mleII ...modiIcrioroisusedwldfllylo
otQintheo.lnld propertiM andperfoImanoe01 tl'llWiU.ln"pr'III8JIIIs:tu:ty,thecNmical(llIJonato)
ｾｾＭ］ｾｾｾ］
dMrtyirllil:n . .suc:cesstul . . . . .rnodifIcItionaf
､｣｡ｰ｡ｲｴｩ｣ｬｍＮｔｨ･ｲｮｇｬｦｴｬＶ､ｾ｢ｵｭｧ｜ｨ･ ｉｬＬｬｲｯｮ｡ｬＸ､ｭｯｬ･ｴｹＮｮ､ｴｾｰｲ｡ｉ･ｏ＼ＺＸｯｦｴｨ･ＱＧｬｬｮ｣ｴｬｯｮ･Ｑ ｧｲｯｵｰｳｴｬ｡､ｮｯＮｴｦ･｣ｴｯｮｴｾＮｴｲｵ･ｴｊｲｬｬｯｴｳｊｬｩ｣｡Ｎｈ･ｮ＼Ｚ･Ｌ
.... COI'IC:Uiondrewnfromtheprlllft..lIJdYls1tllll:1NI: slMonItionroutllcanMIIIJ"iZedfa"lheg_rationot ｾｩ｣Ｚｲｯｯｮｩ｣Ｉｐｦｏｐｬｬｉｴｙｯｴ｡､ｳｯｲ｢･ｮｴｓｬｊｾＮ
lmpr'oYementoftllelonlcpropertyleelsoexpecledto M .bl.toincrll8H euloes.sIndesorblng metalionI adsorbed, 8S weH '1, IIntlanQ!lttlereversibilityof
adsorbent
ACKNOWLEDGEM!HT
Wethar*-hlGmerlIlor.c:torafHghet ｅ､ｵｃｩｬ｢Ｌｒ･ｰｵ｢ｬ｣ｯｬｾｨｏｉｉｧｨｮｬｓ･｡ｮＺＺｮ
grwltIHilahKampe**Z011fa"flnenciafllJpporI, . . , LV.Simmll)llngend E.Y.W. Hebibl fa" ...
_ _nee Incollectingupermentdalll.
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3.Nqg-.M.K,ｾＬ M.,andDey. A, Ind.
PatlllllepplicalionNo. 127M)EUl)1, 2001.
4. NuQ-,ILK,end CMtterjIIII. IL, 2004, J.EiJr.
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ｾｙＮＬｾＧＹＹＰｾＧＧ［ＧＧＺＱｾｾｾＮ･ｮ､
6.
ｾｾＺＧｾＮｾＮｾｩＮＬｒＬＧＹＹＰＬｊＮ
7. Eeql,lena,J., and Solans, C.. 2001,CoNoid8 Surl" A,180,65-92
8.
［ＺｾｒｆＺｦＺｾＧｾｾＧｒＮｾｾｾ･ｮｾｾＬｊＧＶＺＺ
ｾｬＬｊＮ CoIoi::fhll'fft-Sd,241, 1.45-51.
i.
ｾｾ｡Ｚｾ［Ｕｾ｜ｴｾｾＺ
ＱＰＮａｲｉ｢ｬ､ＬｌｎＮｈＮＬＸｮ､ａｩｲｯｬ､ｩＬｃＮＬＲＰＰＰＬｾＬ19,4,367-373.
11.:=: MM,..
ｓ］ＺＺｮａＮＬｙＮｾｾｾＺＬ
ｾＧｾ
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