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4 1_{L abTeknolog iProduk,}2_{LabTeknikReaks iKimia ,}3_{LabOrganik ,}4_Mahasiswa u a i R s a ti s r e v i n U a i m i K k i n k e T n a s u r u J 3 9 2 8 2 u r a b n a k e P , m a n a P a y d i w a n i B s u p m a K * 1 _{HP081365699792 ,e-mali :a_farjli@ymai.lcom} a r t s b A c t The synthesi so fzeoltie4A frompalm lfyashha sbeendone .The synthesi swa s y b t u o d e ir r a c mixing o fsodium siilcate and sodium aluminate soluiton sfo r3 0 7 t a t e z il a t s y r c s a w n o it u l o s e h t n e h t ,s r u o h o_Cand80o_{Cf o r8hour sandf ollowed} 0 2 1 t a g n i y r d y b o_{Cfo r3hours .The produc twa scharacteirzedby usinginfrared} x d n a y rt e m o t o h p o rt c e p s -ray dfiractomerty .Some physica lparamete r o fthe e t a n i m u l a m u i d o s d n a e t a c il i s m u i d o s f o t n u o m a n o it a ir a v e h t e r a e s o h t , n o it c a e r n o it a m r o f l e g e r u t a r e p m e t t n e r e f fi d o w t d n a , ) 0 2 / 0 8 ; 0 4 / 0 6 ; 0 5 / 0 5 ; 0 6 / 0 4 ; 0 8 / 0 2 ( e h t t a h t w o h s s tl u s e r e h T . t e i d u t s n e e b o s l a e v a h zeoltie4Acanbeobtainedi nt he t a s i s y l a t s y r c e r u t a r e p m e t d n a e t a n i m u l a m u i d o s o t e t a c il i s m u i d o s f o 0 4 / 0 6 o it a r 0 8 o_{C .} : s d r o w y e K Infrared spectrophotometry , Palm lfy ash , Synthesis , X-ray Z , y r t e m o t c a r fi d eoltie4A

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a s a w a K Zeoil tadalahkirsta laluminasiilkadengansusunan a k il i s l a r d e h a rt e t i r a d k u t n e b r e t , i s n e m i d a g it a k g n a r e k 4 O i S ( -4 _{)dan alumina (AlO4}-5 _{)yang teirka tmelalu iatom} a g g n o r k u t n e b m e m k u t n u , n e g i s k o -rongga dan saluran 2 9 9 1 , n a d m a H [ r u t a r e t g n a y n il a t s ir k a rt n i l u k e l o m i s n e m i d m a l a d Murn idanHelmawait ,2006] .Zeoil tmemiilk isfiat , l u k e l o m g n ir a y n e p i tr e p e s , a w e m it s i t a g n a s g n a y t a fi s , n a a k u m r e p f it k e l e s , s a n a p p a d a h r e t li b a t s , n o it a k r a k u n e p n a d i s a k if i d o m i d h a d u m nl -ai lain ,sehingga zeoil tbanyak s e s o r p i a g a b r e b k u t n U . s e s o r p i rt s u d n i m a l a d n a k a n u g i d h i b e l s it e t n i s t il o e z , n e b r o s d a n a d , n o it a k r a k u n e p , k it il a t a k i n i l a H . m a l a t il o e z g n i d n a b i d n a k a n u g i d k a y n a b g n a y n a i n r u m e k i a y n u p m e m s it e t n i s t il o e z n a k a n e r a k i d itngg isehingga lebihstabli ,lebihaktfi ,dan lebih selekit f a j a g n e s s it e t n i s t il o e Z . m a l a t il o e z n a g n e d n a k g n i d n a b i d s e s o r p n a g n e d s u s u h k n a u lr e p e k k u t n u a i s u n a m h e l o t a u b i d . a y n n a u lr e p e k n a g n e d i a u s e s a i m i k y s it e t n i s t il o e z u t a s h a l a s n a k a p u r e m A 4 t il o e Z ang t a g n a s a y n n a a n u g g n e P . s a h k g n a y r u t k u rt s i a y n u p m e m r a k u n e p n a d n a p a r e y n e p , n a g n ir a y n e p s e s o r p m a l a d s a u l n a d a k il i s n a r u p m a c i r a d s i s e t n i s i d t a p a d A 4 t il o e Z . n o i . u t n e tr e t i s a r e p o i s i d n o k n a d i s i s o p m o k n a g n e d a n i m u l a m u ir t a n a p u r e b t a p a d a k il i s r e b m u S siilkat ,siilka thidrat , , s s a l g r e t a w siilkasol ,siilkagel ,clay ,siilkat erpresiptias i n a d calcined isilca .Sedangkan sumbe ralumina berupa t a n i m u l a m u ir t a n , aluminium sufla t dan aluminium u l u h a d r e t i ti l e n e p a p a r e b e B . ] 6 0 0 2 , li a m s I [ a d i s k o r d i h l e m h a l e t akukan sintesi szeoil t4A dengan menggunakan i a g a b e s s a t a i d t u b e s r e t n a h a b i r a d n i a l e s u k a b n a h a b . a k il i s r e b m u s i r a d a s i s t a d a p h a b m il u t a s h a l a s n a k a p u r e m t i w a s u b A 0 0 7 u h u s n a g n e d r e li o b m a l a d i d g n a k g n a c n a r a k a b m e p o C-0 0 8 o_{C ,dapa tberupa bottom ash dan lfy ash .Abu sawi t} i l a k l a n o i g n u d n a g n e m a g u j n a d a k il i s k a y n a b g n u d n a g n e m . m u ir t a n n a d m u il a k i tr e p e s Fly ash merupakan abu . r e li o b i d n a r a k a b m e p s e s o r p i r a d l i s a h n a g n ir g n a y g n a b r e t a y n m u m u a d a P lfy ash dtiangkap dengan menggunakan . e n o l c y c Ukuran lfy ash yang dihaslikan yatiu 100–200 h s e m .Fly ash banyak mengandung unsu rsiilka yang k u t n e b r e b amorphou syangl ebihr eaktfi( mudahbereaks)i , a tr e s r a s e b g n a y s e s o r p i g r e n e n a k h u t u b m e m k a d it n a d n a i n r u m e k i k il i m e m speciifcsurfacearea(SSA )yang s e s i g g n it ua idenganspesiifkas iyangdiinginkan[Sapurta , 6 0 0 2 dalam Febiranto , 2010] . Suilstyanto (2010 ) a w h a b , n a k r o p a l e m lfy ash sawi tmempunya ikandungan l a s a t i w a s g n a k g n a c n a d t u b a s u b A . t a r e b % 7 , 6 8 a k il i s t u r u tr e b a k il i s r a d a k r e b u a i R i s n i v o r P -turu t61,3dan76,2% . ) 7 0 0 2 , k k d a n ir h a Z ( t a r e b k u t n e b m a l a d t i w a s i rt s u d n i t a d a p h a b m i L lfy ash d i s a u l a y n t a k g n i n e m n a g n e d g n ir i e s t a k g n i n e m u a i R i s n i p o r p

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8 9 i rt s u d n i n a g n a b m e k r e P . ti w a s i rt s u d n i n a d n a n u b e k r e p h a b m il s a ti t n a u k n a t a k g n i n e p a d a p k a p m a d r e b n a k a t i w a s g n a y akan dibuang ke ilngkungan . Untuk seitap n a k a ) S B T ( r a g e s h a u b n a d n a t m a j/ n o t 0 3 n a h a l o g n e p g n ir e s g n a y g n a k g n a c % 9 2 , 6 n a d t u b a s % 4 1 , 3 1 n a k li s a h i d r a k a b n a h a b i a g a b e s n a k a n u g i d bolier .Dar itota lbera t i d r a k a b i d g n a y t i w a s g n a k g n a c n a d t u b a s bolier ,dapa t , V N P T P [ n a r a k a b m e p i r a d a s i s u b a t a r e b % 5 1 h e l o r e p i d e k g n a u b i d a y n a s a i b i n i n a r a k a b m e p a s i s u b A . ] 1 1 0 2 n a l a j n u b m i n e m k u t n u n a k a n u g i d , n a g n a u b m e p t a p m e t a e r a a d a p n u b m it h a n a t i a g a b e s n a d k a s u r g n a y n a n u b e k r e p . k ir b a p r a ti k e s i d n a k u k a l e m , ) 6 9 9 1 ( r a b k A sintesi szeoil t4A dengan u b a n a k a n u g g n e m layang batubarasebaga isumbe rsiilka m u m it p o i s a r e p o i s i d n o k n a k t a p a d n e m n a d waktu n a s a n a m e p r u t a r e p m e t , m a j 0 1 n a k u d a g n e p ge l100°Cdan u t k a w pemanasange lselama8j am .Murn idanHelmawat i f n a m e m h a l e t ,) 6 0 0 2 ( aatkanabusabuts awi tberupabottom . A 4 t il o e z s i s e t n i s n e m k u t n u a k il i s r e b m u s i a g a b e s h s a n a k i s a ir a v m e m n a g n e d volumer eaktan ,waktupengadukan n a s a n a m e p u t k a w n a d gel .Kondis iterbaik untuksintesi s n a g n i d n a b r e p n a k t a p a d i d t i w a s t u b a s u b a i r a d A 4 t il o e z e m u l o v reaktan natirum siilka t dan natirum alumina t n a s a n a m e p u t k a w n a d m a j 3 n a k u d a g n e p u t k a w , 0 4 / 0 6 ge l . m a j 8 n a k a n u g g n e m i n i n a it il e n e p a d a P lfyashsawi tsebaga i n a a n u g g n e P . A 4 t il o e z s i s e t n i s a d a p a k il i s r e b m u s lfyash n a a i d e s r e t e k a d a p n a g n a b m it r e p n a k r a s a d r e b n a k u k a li d i n i i d a m a t u r e t , h e l o r e p i d k u t n u n a h a b n a h a d u m e k n a d n a g n u d n a k n a a d e b r e p a n e r a k a g u j n a D . u a i R i s n i p o r P n a it il e n e p i r a d n a k a n u g i d g n a y u k a b n a h a b a d a p a k il i s k u k a li d s i s e t n i s s e s o r p a d a p a k a m , a y n m u l e b e s an vairas i m u ir t a n n a d t a k il i s m u ir t a n ( n a t k a e r e m u l o v n a g n i d n a b r e p k u t n u k i a b r e t i s i s o p m o k i u h a t e g n e m k u t n u ) t a n i m u l a n a a d e b r e p n a ij a k a u d a tr e S . A 4 t il o e z a y n k u t n e b r e t n a s a n a m e p r u t a r e p m e t ge l 70 , 80o_{C yang sanga t} a t s ir k n a k u t n e b m e p u j a l a d a p h u r a g n e p r e b lzeoil t4A .Pada h u r a g n e p k i a b r e t i s i d n o k n a k t a p a d a d i d i n i n a it il e n e p n a s a n a m e p r u t a r e p m e t n a d n a t k a e r e m u l o v n a g n i d n a b r e p l e g padas intesi szeoil t4Adar ibahandasa rlfyashsawi.t . 1 . 1 Sintesi sZeoil t4A h a b m il n a h a b n a k a n u g g n e m n a g n e d t il o e z s i s e t n i S dar i i t u p il e m a y n a s a i b , r a s a d n a h a b i a g a b e s s e s o r p u t a u s n a u k a lr e p n a ir e b m e p u a t a i s a r a p e r p u ti a y a jr e k n a p a h a t n a k u k a li d u lr e p l a w a n a u k a lr e P . r a s a d n a h a b p a d a h r e t l a w a n e n o p m o k n a k fi t k a g n e m k u t n u d u s k a m n a g n e d -komponen l o e z s i s e t n i s m a l a d n a k u lr e p i d g n a y ti ,selain tiupelrakuan u a t a n a k fi t k a e d n e m k u t n u a n u g r e b a g u j i n i l a w a g n a y n a k u lr e p i d k a d it g n a y n e n o p m o k n a k g n a li h g n e m t il o e z i r o t o g n e m u a t a t il o e z s i s e t n i s u g g n a g g n e m t a p a d .s i s e t n i s li s a h i r a d , l a m r e h t o r d i h i s i d n o k h a w a b i d t a u b i d t il o e Z s k a e r n a r u p m a c iyangt erdri idar ipereaksi-pereaks isiilkat , m e t s i s i m a l a k u d o r P . n o it a k s i n e j a p a r e b e b n a d t a n i m u l a a N 2 – OSi 2 – lA2O3 –H2Obergantungpadakomposis ig ,el k u t n u n a k a n u g i d g n a y n a t k a e r i r a d a k i s if n a d a i m i k t a fi s a i m i k i s i s o p m o k h u r u l e s , n a r u p m a c t a u b m e m dan jeni s 2 9 9 1 , n a d m a H [ l a t s ir k i s i d n o k a tr e s a d a g n a y n o it a k dalam . ] 6 0 0 2 , it a w a m l e H n a d i n r u M . 2 . 1 Faktor-Fakto ryang Mempengaruh iSintesi sZeoil t A 4 a r a c n a g n e d n a k m u m it p o i d t a p a d t il o e z n a li b a t s e K a e r i s i d n o k n a d , r u t a r e p m e t , n a t k a e r i s i s o p m o k h il i m e m ks i g n a y m u m u a r a c e S . ] 7 9 9 1 , n i a t s u M [ i a u s e s g n a y s i s e t n i s , l A /i S h a b s i n n i a l a r a t n a i s a s il a t s ir k k u d o r p i h u r a g n e p m e m n a k u d a g n e p , i s k a e r u t k a w , n a m a s a e k t a j a r e d , r u t a r e p m e t 7 8 9 1 , n e tr a M n a d s b o c a J [ a k il i s r e b m u s t a fi s n a d dalam l a H . ] 9 9 9 1 , n i m r a p m i S -ha l tersebu t dapa t diuraikan A 4 t il o e Z . ti l o e z i r a d l A /i S h a b s i N : t u k ir e b i a g a b e s t a k ir e t n o k il i s m o t a p a it e s n a d 1 = l A /i S o i s a r i k il i m e m n a d , n e g i s k o m o t a i u l a l e m m u i n i m u l a m o t a t a p m e n a g n e d a r a c n a g n e d t a p a d i d a s i b i n i o i s a R . a y n k il a b e s a r u p m a c n a k i s a ir a v m e m n natirum siilka t dan natirum u j a l t a p e c r e p m e m n a k a r u t a r e p m e t n a t a k g n i n e P . t a n i m u l a , A 4 t il o e z s i s e t n i s m a l a D . l a t s ir k n a k u t n e b m e p n a k u t n e b m e p t a p e c r e p m e m n a k a r u t a r e p m e t n a t a k g n i n e p 2 9 9 1 , n a d m a H ( t a p a d i d g n a y l a t s ir k n a r u k u n a d l a t s ir K m a l a d Akba rdkk ,2006) . . 3 . 1 Karakteirsas iZeolti a k i s if r e t e m a r a p n a u t n e n e p n a k a p u r e m t il o e z i s a s ir e t k a r a K t a fi s i u h a t e g n e m k u t n u t il o e z i r a d a i m i k n a d -sfia tzeoil t t il o e z n a g n e d u t a s t il o e z a r a t n a n a k a d e b i d t a p a d a g g n i h e s i s a s ir e t k a r a k , i n i n a it il e n e p a d a P . a y n n i a l zeoil tdliakukan k u t n u h a r e m a r f n i i rt e m o t o f o rt k e p s n a k a n u g g n e m i n i i j u h a l e t e S . ti l o e z a y n k u t n e b r e t i u h a t e g n e m i r a d i s a r b i v n a p a r e s a p u r e b i s a s ir e t k a r a k n a k ir e b m e m u lr e p t u b e s r e t n a r a n e b e k n a k it k u b m e m k u t n u a k a m , ti l o e z n e m n a g n e d i s a s ir e t k a r a k n a k t u j n a li d ggunakan . X r a n i s r e t e m o t k a r fi d . 1 . 3 . 1 SpekrtoskopiI nframerah a d o t e m u t a s h a l a s n a k a p u r e m h a r e m a r f n i i p o k s o rt k e p S . ti l o e z r a s a d a k g n a r e k r u t k u rt s i s a s ir e t k a r a k g n e m k u t n u 0 0 3 1 ( g n a d e s h a r e m a r f n i h a r e a d a d a p m u rt k e p S -200cm- )1 i s a s ir e t k a r a k k u t n u n a k a n u g i d srtuktu rkerangka zeolti , l a t n e m a d n u f i s a r b i v t a u m e m i n i h a r e a d a d a p a n e r a k O )l A ,i S ( l a r d e h a rt e t a k g n a r e k 4 yang merupakan satuan . ti l o e z a k g n a r e k n u g n a b m e p n a u t a s a g g n i h e s , k if i s e p s g n a y a rt k e p s i a y n u p m e m t il o e Z n e d i g n e m k u t n u n a k a n u g i d t a p a d -itifkas idanmembedakan t il o e z m u m u a r a c e S . a y n k o p m o l e k m a l a d t il o e z a p a r e b e b k u t n u k i a b k if i s e p s g n a y R I a rt k e p s l e d o m i a y n u p m e m A 4 t il o e z i s a s ir e t k a r a k ,l a n r e t s k e n u p u a m l a n r e t n i i s a r b i v t a h il i d t a p a d padaTabe l1. ( t r e b m I t u r u n e M 1994) ,bahwarasioptiaserapan650 -0 0 5 / 0 0 5 -420 cm-1 _{dapa tmenentukan terbentuknya kirsta l} 0 5 6 h a r e a d a d a p n a p a r e s a ti P . A 4 t il o e z i r a d -500 cm-1 ,t il o e z a k g n a r e k i r a d a d n a g n i c n i c i s a r b i v n a k a p u r e m A 4 t il o e Z g n a b m o l e G n a g n a li B n a d i s a s ir e t k a r a K . 1 l e b a T

9 9 . 1 l e b a T Karakteirsas iZeoil t4A . o N Karakterisitk BlianganGelombang( cm-1 ₎ .1 . 2 . 3 . 4 O )l A ,i S ( n a t a k i s ir t e m i s a g n a t n e R 4tertahedral ti l o e z a k g n a r e k l a r d e h il o p a d n a g n i c n i c i s a r b i V O )l A ,i S ( n a t a k i k u k e t i s a r b i V 4 a y n a d A p -oirpoirt erbukadar izeolti 0 5 2 1 - 09 5 0 5 6 - 05 0 0 0 5 - 04 2 0 2 4 - 03 0 ) 6 9 9 1 ( r a b k A : r e b m u S 0 0 5 h a r e a d a d a p n a k g n a d e s -420 cm-1 _{merupakan vibras i} O T n a t a k i k u k e t 4 .Deraja tterbentuknya zeoil t4A dapa t r e b n a k u t n e ti d -dasarkan besarnya rasioptia serapanpada 0 5 6 g n a b m o l e g n a g n a li b h a r e a d -500/500-420cm-1_. n a g n e d g n u ti h i d t a p a d h a r e m a r f n i n a p a r e s a y n r a s e B 4 9 9 1 , tr e b m I [ s u m u r n a k a n u g g n e m dalam Murn i dan :] 6 0 0 2 , it a w a m l e H n a k a n u g g n e m n a g n e d g n u ti h i d t a p a d R I n a p a r e s a y n r a s e B : s u m u r 0 0 1 ) ( ) ( % x I k u s a m s a ti s n e t n I I s a ti s n e t n I T o ) 7 9 9 1 , n e d n e s e F n a d n e d n e s s e F (

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) 7 9 9 1 , n e d n e s e F n a d n e d n e s s e F ( = A : a n a m i D Absorban s (Serapan) T=Transmtian . 2 . 3 . 1 Dfiraks iSina rX k u t n u g n it n e p a d o t e m n a k a p u r e m X r a n i s i s k a r fi D k u t n u n a k a n u g i d a s a i b i n i k i n k e T . ti l o e z i s a s ir e t k a r a k g n e m l i s a h a n e r a k , fi t a ti l a u k a r a c e s t il o e z i s a k if it n e d i g n e m h a d u s g n a y r a d n a t s n a g n e d n a k k o c o c i d t a p a d m a r g o t k a r fi d . a d a Jeni sKirsta ldiketahu idengancara membandingkan k a c n u p -puncak dfiraktogram dengan data dfiraktogram t u d u s h a r e a d a d a p r u k u i d A 4 t il o e z i s a s ir e t k a r a K .r a d n a t s 4 i r a d ) θ 2 ( i s k a r fi d o _{hingga 40}o _{.Menuru tMura t(1992) ,} a d a p n a k t a p a d i d A 4 t il o e z i s k a r fi d a l o p daerahsudu t2θ= n a d 2 , 0 3 ; 2 , 7 2 ; 6 2 ; 2 , 4 2 ; 8 , 1 2 ; 5 , 6 1 ; 5 , 2 1 ; 4 , 0 1 ; 4 , 7 A 4 t il o e z s a ti n il a t s ir k n a k u t n e n e m g n a y i s k a r fi d n a D . 4 , 4 3 7 0 1 , 4 ; 1 5 , 5 ; 1 1 , 7 ; 1 7 , 8 ; 9 2 , 2 1 = ) Å ( d a g r a h a d a p h a l a d a 4 9 9 1 , tr e b m I [ 6 2 6 , 2 n a d 7 8 9 , 2 ; 8 7 2 , 3 ; 7 0 4 , 3 ; 4 1 7 , 3 ; m a l a d Murn idanHelmawait ,2006.]

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n a h a B -bahanyangdigunakanpadapeneilitani n iadalah lfy h s a sawti ,NaOH ,A(lOH)3 dan aquades .Alat-ala tyang h a l a d a i n i n a it il e n e p a d a p n a k a n u g i d furnace , oven , , k i n a k e m k u d a g n e p itmer ,ketra sindikato rpH universal , s a tr e k , s a l e g t a l a h a l m u j e s , ri a s a g n a n e p , r e t e m o m r e t , g n ir a s tachometer , corong buchner , spekrtofotomete r . k it il a n a n a g n a b m it n a d X r a n i s r e t e m o t k a r fi d , h a r e m a r f n i i ri d r e t i n i n a it il e n e p m a l a d n a k a n u g i d g n a y l e b a ir a V a d p a t e t l e b a ir a v i r a d n vairabe lberubah .Vairabe ltetap n a s a n a m e p u t k a w , ) m a j 3 ( n a k u d a g n e p u t k a w h a l a d a ge l(8 ,) m a j (Murn idan Helmawait ,2006) .Vairabe lberubah e m u l o v n a g n i d n a b r e p u ti a y n a u a j n it a u d n a g n e d n a k u k a li d , 0 8 / 0 2 ( t a n i m u l a m u ir t a n n a g n e d t a k il i s m u ir t a n n a t k a e r 40/60 ,50/50 ,60/40 ,80/20 )dan dua vairas itemperatu r s a n a m e p b ange l(70o _,80o_{C .)} n a it il e n e P r u d e s o r P . 1 Preparas iFlyAsh h s a y l F sawi tyangdigunakan pada peneilitan in iberasa l m u l e b e S . u a i R , n a w a l a l e P , a rt u P t a k ir e S . T P i r a d , n a k a n u g i d lfy ash sawi ttelrebih dahulu diayak untuk ( a y n n a r u k u n a k m a g a r e y n e m ≤200mesh.) . 2 PersiapanReaktan m a r g 5 2 n a k r u b e l e m n a g n e d t a u b i d t a k il i s m u ir t a N lfyash : 1 ( H O a N m a r g 5 , 2 6 n a d 2,5) , sedangkan natirum , H O a N m a r g 0 5 , 0 3 n a k r u p m a c n e m n a g n e d t a u b i d t a n i m u l a A m a r g 5 6 , 1 2 (lOH)3danaquades. . 3 Prose sSintesi sZeoil t4A n a k r u p m a c n e m n a g n e d n a k u k a li d A 4 t il o e z s i s e t n i s s e s o r P n a g n e d t a k il i s m u ir t a n n a t u r a l n a d t a n i m u l a m u ir t a n n a t u r a l t a n i m u l a m u ir t a n n a d t a k il i s m u ir t a n e m u l o v n a g n i d n a b r e p 0 2 / 0 8 n a d 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 sambi ldiadukselama k u t n e b r e t n a k a n a d n e g o m o h n a r u p m a c a g g n i h m a j 3 ge l n a i d u m e K . h it u p a n r a w r e b g n a y ge ltersebu tdimasukkan r u t a r e p m e t i s a ir a v n a g n e d n a k s a n a p i d n a d n e v o m a l a d e k n a s a n a m e p ge l70 ,80°C selama 8 jam .Hasi lsintesi s c i d u d i s e r , g n ir a s i d uc idenganaquade ssampa ipH nertal , 0 2 1 u h u s a d a p n e v o m a l a d n a k g n ir e k i d n a i d u m e k ° C n a g n e d i s a s ir e t k a r a k i d s i s e t n i s l i s a H . m a j 3 a m a l e s l a n a k a n u g g n e m a t spekrtofotomete r inframerah. Untuk i r a d i s a s ir e t k a r a k l i s a h n a r a n e b e k t a u k r e p m e m r e m a r f n i i p o k s o rt k e p s ah ,maka dlianjutkan karakteirsas i . X r a n i s r e t e m o t k a r fi d n a k a n u g g n e m n a g n e d

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. 1 . 3 Pengaruh Vairas iPerbandingan Volume Reaktan n a s a n a m e P r u t a r e p m e T n a d Ge lpadaSintesi sZeoil t 4 i s a ir a v h u r a g n e p i r a j a l e p i d , i n i n a it il e n e p a d a P n a d t a k il i s m u ir t a n u ti a y n a t k a e r e m u l o v n a g n i d n a b r e p ) 0 2 / 0 8 n a d 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 ( t a n i m u l a m u ir t a n n a s a n a m e p r u t a r e p m e t n a d ge l( °70 Cdan 08 ° )C . . 2 . 3 Pengaruh Vairas iPerbandingan Volume Reaktan k u t n u Sintesi s Zeoil t 4A pada Temperatu r n a s a n a m e P Ge l700_C a d a p s i s e t n i s k u d o r p h a r e m a r f n i i p o k s o rt k e p s a s il a n a l i s a H n a s a n a m e p e r u t a r e p m e t ge l 70oC dengan vairas i 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 n a t k a e r e m u l o v n a g n i d n a b r e p . 1 r a b m a G a d a p n a k t a h il r e p i d 0 2 / 0 8 n a d . 1 r a b m a G Spekrtogram inframerah hasi lsintesi spada p r u t a r e p m e t emanasan g le 70o_{C dengan} r e m u l o v n a g n i d n a b r e p i s a ir a v eaktan20/80 , 0 2 / 0 8 n a d 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 . n a g n i d n a b r e p i s a ir a v k u t n u h a r e m a r f n i m u rt k e p s i r a D 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 n a t k a e r e m u l o v /40dan80/20dapa t n a g n a li b a d a p o i s a r u ti a y a y n n a p a r e s o i s a r g n u ti h i d 0 5 6 g n a b m o l e g -500/500-420 untuk menentukan itngka t . A 4 t il o e z l a t s ir k n a k u t n e b m e p . 3 . 3 Pengaruh Vairas iPerbandingan Volume Reaktan r u t a r e p m e T a d a p A 4 t il o e Z s i s e t n i S k u t n u n a s a n a m e P Ge l80oC h a r e m a r f n i i p o k s o rt k e p s a s il a n a l i s a H produksintesi spada r u t a r e p m e t pemanasan ge l 80o_{C dengan vairas i} 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 n a t k a e r e m u l o v n a g n i d n a b r e p . 2 r a b m a G a d a p n a k t a h il r e p i d 0 2 / 0 8 n a d n a g n i d n a b r e p i s a ir a v k u t n u h a r e m a r f n i m u rt k e p s i r a D t a p a d 0 2 / 0 8 n a d 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 n a t k a e r e m u l o v n a g n a li b a d a p o i s a r u ti a y a y n n a p a r e s o i s a r g n u ti h i d 0 5 6 g n a b m o l e g -500/500-420 untuk menentukan itngka t . A 4 t il o e z l a t s ir k n a k u t n e b m e p r a b m a G 2 . Spekrtogram inframerah hasi lsintesi spada p r u t a r e p m e t emanasan g le 80o_{C dengan} r e m u l o v n a g n i d n a b r e p i s a ir a v eaktan 20/80 , . 0 2 / 0 8 n a d 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 0 5 6 n a p a r e s a ti p o i s a r a w h a b , ) 4 9 9 1 ( t r e b m I t u r u n e M -m c 0 0 5 -1_dan500-420cm-1_{dapa tmenentukankirstailntia s} g n a y n a p a r e s o i s a r i a li n r a s e b n i k a m e S . A 4 t il o e z i r a d i d a jr e t g n a y n a p a r e s a l u p r a s e b n i k a m e s i tr a r e b , t a p a d i d 0 5 6 g n a b m o l e g n a g n a li b h a r e a d a d a p -500 cm-1 _{.Ha lin i} i r a d k u t n e b r e t g n a y a d n a g n i c n i c a y n k a y n a b n a k a t a y n e m i k a m e s n a d t il o e z a k g n a r e k nbesa rpula kirstailntia szeoil t i s a ir a v k u t n u n a p a r e s o i s a r n a g n u ti h r e p l i s a h i r a D . A 4 0 4 / 0 6 , 0 5 / 0 5 , 0 6 / 0 4 , 0 8 / 0 2 ( n a t k a e r e m u l o v n a g n i d n a b r e p n a a s a n a m e p r u t a r e p m e t n a d ) 0 2 / 0 8 n a d g 0el (7 o _,80o_{C) ,} a d a p u ti a y r a s e b r e t g n a y n a p a r e s o i s a r i a li n h e l o r e p i d e p rbandingan volume reaktan 50/50 dan 60/40 pada n a s a n a m e p r u t a r e p m e t g 0el 8 o_{C sebesa r 1,7061 dan} t a p a d a g u j n a p a r e s o i s a r n a g n u ti h r e p l i s a h i r a D . 2 9 9 6 , 1 n a s a n a m e p e r u t a r e p m e t h u r a g n e p t a h il i d ge lterhadapl aju ti l o e z l a t s ir k n a k u t n e b m e p .Untuk temperatur ep manasan l e g 70o_{C dapa tdiilha tbahwa pembentukan kirsta lzeoil t} n a k u t n e b m e p n a g n e d n a k g n i d n a b i d a n r u p m e s m u l e b 0 8 r u t a r e p m e t a d a p l a t s ir k oC .Hali n imungkindikarenakan n a s a n a m e p r u t a r e p m e t ge l telralu rendah untuk a d a p n a k u k a li d n a s a n a m e p a k i J .t il o e z l a t s ir k n a k u t n e b m e p l a t s ir k n a k u t n e b m e p u j a l a k a m i g g n it g n a y r u t a r e p m e t a k ij n u m a N . t a p e c n a g n e d g n u s g n a lr e b n a k a t il o e z i g g n it u l a lr e t r u t a r e p m e t a d a p n a k g n u s g n a li d n a s a n a m e p r u t a r e p m e t i t a w e l e m ( pembentukan kirstalnya ) maka n a k a k u d o r p u a t a n i a l k u d o r p i d a j n e m h a b u r e b a s i b k u d o r p 0 9 9 1 , a r g o D [ i s a d a r g e d r e t dalamFebiranto ,2010] . , h a r e m a r f n i i p o k s o rt k e p s a r a c e s i s a s ir e t k a r a k l i s a h i r a D g n a b m o l e g n a g n a li b i a y n u p m e m g n a y m u rt k e p s h e l o r e p i d i m g n a y irp dengan bliangan gelombang pada spekrtum .) 1 7 9 1 ( n e g i n a l F i r a d r a d n a t s A 4 t il o e z

1 0 1 . 2 l e b a T Datarasioptiaserapan inframerahpada t emperatu rpemanasang le 07 o_{Cdengan vairas iperbandinganvolume} reaktan20/80 ,40/60 ,50/50 ,60/40dan80/20 n a g n i d n a b r e P e m u l o V h a r e m a r f n I n a p a r e S a ti P o i s a R n a b r o s b A ) n a p a r e S ( n a g n a li B g n a b m o l e G 0 5 6 - 05 0 m c ( - )1 n a b r o s b A ) n a p a r e S ( GBellioamngbaanng 0 0 5 - 04 2 m c ( - )1 n a b r o s b A ) n a p a r e S ( 0 8 / 0 2 560,11 1,3756 457,14 1,0237 1,3439 0 6 / 0 4 558,82 0,7716 457,14 0,4704 1,6402 0 5 / 0 5 555,23 1,2434 471,05 0,8752 1,4207 0 4 / 0 6 558,82 0,6611 465,71 0,4182 1,5811 0 2 / 0 8 558,82 0,6651 468,42 0,4204 1,5820 . 3 l e b a T Datarasioptiaserapan inframerahpada t emperatu rpemanasang le 08 o_{Cdengan vairas iperbandinganvolume} reaktan20/80 ,40/60,50/50 ,60/40dan80/20 n a g n i d n a b r e P e m u l o V h a r e m a r f n I n a p a r e S a ti P o i s a R n a b r o s b A ) n a p a r e S ( n a g n a li B g n a b m o l e G 0 5 6 - 05 0 m c ( - )1 n a b r o s b A ) n a p a r e S ( GBellioamngbaanng 0 0 5 - 04 2 m c ( - )1 n a b r o s b A ) n a p a r e S ( 0 8 / 0 2 554,59 0,5387 460,53 0,3881 1,3880 0 6 / 0 4 560,11 0,7261 457,14 0,4345 1,6710 0 5 / 0 5 564,70 0,8847 473,68 0,5186 1,7061 0 4 / 0 6 556,18 0,7560 468,42 0,4449 1,6992 0 2 / 0 8 557,14 0,2129 457,89 0,2646 0,8047 k u t n U vairas iperbandingan volume reaktan (20/80 , 6 , 0 5 / 0 5 , 0 6 / 0 4 0/40dan80/20 )padat emperaturpemanasan l e g 70o_{C muncu lserapanpadabliangangelombang1011} -m c 5 0 0 1 -1_{yangmenyatakanadanyarentangasimetir sdar i} O T n a t a k i 4tertahedral ,serapanpada bliangan gelombang 1 1 , 0 6 5 -555,23 cm-1 _{yang menyatakan adanya vibras i} a d a p n a p a r e s , ti l o e z a k g n a r e k l a r d e h il o p a d n a g n i c n i c 5 0 , 1 7 4 g n a b m o l e g n a g n a li b -457,14cm-1_{yangmenyatakan} O T n a t a k i k u k e t i s a r b i v a y n a d a 4dan munculnya serapan 0 2 4 g n a b m o l e g n a g n a li b a d a p -300cm-1_{yangmenyatakan} ir o p a y n a d a -poirt erbukadar izeolti .Serapanpadabliangan i s a ir a v a d a p n a k u m e ti d a g u j p ir i m g n a y g n a b m o l e g n a s a n a m e p r u t a r e p m e t ge l 80o_{C . Perbandingan hasi l} p a d a p s i s e t n i s l i s a h k u d o r p m a r g o rt k e p s erbandingan r u t a r e p m e t n a d 0 4 / 0 6 n a d 0 5 / 0 5 n a t k a e r e m u l o v n a s a n a m e p ge l80oC dengan spekrtogram standa rdar i a l F nigen( 1971) ,dtiunjukkanpadaGamba r3 .Dar iGamba r a d a p s i s e t n i s l i s a h m u rt k e p s a w h a b t a h il i d t a p a d 3 h i b e l 0 4 / 0 6 n a t k a e r e m u l o v n a g n i d n a b r e p miirpdanl ebih k u t n u m u rt k e p s l i s a h n a g n e d n a k g n i d n a b i d m a j a t t a p a d a k a m , 0 5 / 0 5 n a t k a e r e m u l o v n a g n i d n a b r e p m u ir t a n ( n a t k a e r e m u l o v n a g n i d n a b r e p a w h a b n a k l u p m i s i d r u t a r e p m e t a d a p 0 4 / 0 6 ) t a n i m u l a m u ir t a n n a d t a k il i s n a s a n a m e p ge l80o_{C ,merupakan hasi lspekrtum yang} . A 4 t il o e z k u t n u k i a b r e t . 3 r a b m a G Spekrtogrami nframerahprodukhaslis intesi s f r a d n a t s n a d lanigen( 1971) s i s e t n i s l i s a h k u d o r p , t u j n a l h i b e l i s a s ir e t k a r a k k u t n U r u t a r e p m e t a d a p 0 4 / 0 6 n a t k a e r e m u l o v n a g n i d n a b r e p a d a p n a s a n a m e p ge l 80o_{C dianailsa dengan menggunakan} r a n i s r e t e m o t k a r fi d -X.

2 0 1 . 4 . 3 Karakteirsas iMenggunakanDfiraktomete rSina rX e m u l o v n a g n i d n a b r e p k u t n u s i s e t n i s k u d o r p a s il a n a l i s a H a d a p 0 4 / 0 6 t a n i m u l a m u ir t a n n a d t a k il i s m u ir t a n n a s a n a m e p r u t a r e p m e t ge l 80o_{C dengan menggunakan} fi d raktograms ina rX ,dtiunjukkanpadaGamba r4. . 4 r a b m a G Poladfiraks izeoil thasi lsintesi sperbandingan r u t a r e p m e t a d a p 0 4 / 0 6 n a t k a e r e m u l o v pemanasang le 08 oC . n a it il e n e p i r a d s i s e t n i s l i s a h n a r a n e b e k i j u g n e m k u t n U i s k a r fi d a l o p n a k g n i d n a b m e m a r a c n a g n e d n a k u k a li d , i n i A 4 t il o e z r a d n a t s i s k a r fi d a l o p n a g n e d s i s e t n i s l i s a h t il o e z , 2 9 9 1 , t a r u M i r a d dalam Akbar , 1996) , terilha tpada . 5 r a b m a G . 5 r a b m a G Poladifraksis tanda rzeoil t4Adar iMura t r a d n a t s i a g a b e s ( ) 2 9 9 1 (

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a y n a d a t a h il r e t , m a r g o t k a r fi d n a g n i d n a b r e p i r a D a l o p n a g n e d s i s e t n i s l i s a h k u d o r p i s k a r fi d a l o p n a p ir i m e k a l o p k u t n U . ) 2 9 9 1 ( t a r u M i r a d A 4 t il o e z r a d n a t s i s k a r fi d e p a d a p s i s e t n i s l i s a h i s k a r fi d rbandingan volume reaktan = θ 2 t u d u s h a r e a d a d a p i g g n it r e t k a c n u p 3 t a p a d r e t 0 4 / 0 6 n a d 6 2 , 3 ; 1 7 , 3 = ) Å ( d i a li n a tr e s , 5 1 , 0 3 n a d 9 2 , 7 2 ; 0 2 , 4 2 t a r u M i r a d A 4 t il o e z r a d n a t s i s k a r fi d a l o p k u t n u n a D . 6 9 , 2 g n it r e t k a c n u p 3 n a k t a p a d i d , ) 4 9 9 1 ( t r e b m I n a d ) 2 9 9 1 ( g i i a li n a tr e s , 0 2 , 0 3 n a d 0 2 , 7 2 ; 0 2 , 4 2 = θ 2 t u d u s h a r e a d a d a p i a li n a w h a b i u h a t e k i d t a p a D . 9 9 , 2 n a d 8 2 , 3 ; 1 7 , 3 = ) Å ( d ( d i a li n n a d θ 2 t u d u s Å ) untuk perbandingan volume n a s a n a m e p r u t a r e p m e t a d a p 0 4 / 0 6 n a t k a e r ge l80o_{Champi r} a d θ 2 t u d u s i a li n n a g n e d a m a s nd(Å )standar ,maka dapa t i n i n a it il e n e p a d a p s i s e t n i s l i s a h t il o e z a w h a b n a k l u p m i s i d . A 4 t il o e z n a k a p u r e m

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