Pembuatan serbuk jahe. Pembuatan serbuk jahe tunggal. Pembuatan serbuk jahe campuran. Analisis. Analisis Statistika

Lampiran 1 Diagram Alir Kerja Penelitian

Keterangan: JM = Jahe Merah, JG = Jahe Gajah, JE = Jahe Emprit, L = Lengkuas Pembuatan serbuk jahe

Pembuatan serbuk jahe campuran Pembuatan serbuk jahe tunggal 95% JM + 5% L 95% JM + 5% JE 95% JM + 5% JG Analisis Penentuan Konsentrasi 6-, 8-, 10-gingerol dan 6-shogaol menggunakan

KCKT Analisis menggunakan FTIR Analisis Statistika PLSDA PCA

Lampiran 2 Spektrum FTIR seluruh sampel

Lampiran 3 Kromatogram dan Hasil Pengukuran KCKT Larutan Standar

Retention Time Area Area % Height Height %

3.46 13244 0.15 835 0.21 4.547 82812 0.93 1849 0.46 4.643 13552 0.15 1769 0.44 5.993 167414 1.88 2576 0.64 6.703 118629 1.33 2637 0.66 6.853 34382 0.39 2600 0.65 7.143 42009 0.47 2562 0.64 7.51 147191 1.65 2704 0.67 8.397 36461 0.41 1782 0.44 8.76 31590 0.35 1540 0.38 9.133 10491 0.12 1266 0.31 9.28 10022 0.11 1176 0.29 9.847 214274 2.41 7595 1.89 10.903 44194 0.5 1299 0.32 12.14 1632010 18.33 56799 14.13 13.247 370 0 61 0.02 13.547 482 0.01 64 0.02 13.627 220 0 51 0.01 13.987 165 0 36 0.01 14.233 469 0.01 55 0.01 14.47 561 0.01 49 0.01 14.727 611 0.01 54 0.01 15.107 1868 0.02 101 0.03 15.337 714 0.01 96 0.02 15.427 266 0 59 0.01 15.517 212 0 59 0.01 16.16 3861 0.04 195 0.05 16.23 1275 0.01 174 0.04 16.403 487 0.01 120 0.03 16.54 386 0 57 0.01 17.143 1657 0.02 103 0.03 17.253 686 0.01 70 0.02 17.993 382 0 48 0.01

Lampiran 3 Kromatogram dan Hasil Pengukuran KCKT Larutan Standar (Lanjutan) 18.48 310 0 49 0.01 18.62 396 0 61 0.02 18.863 358 0 57 0.01 19.07 244 0 54 0.01 19.75 1227 0.01 54 0.01 19.81 86 0 43 0.01 19.96 164 0 45 0.01 20.973 71658 0.8 3404 0.85 21.48 217 0 68 0.02 22.63 886802 9.96 45256 11.25 24.13 1943362 21.82 98076 24.39 25.173 1156 0.01 185 0.05 25.5 2259 0.03 160 0.04 26.193 17084 0.19 780 0.19 26.673 71 0 31 0.01 26.787 353 0 59 0.01 26.917 185 0 76 0.02 26.947 189 0 59 0.01 27.047 317 0 65 0.02 27.177 189 0 46 0.01 27.327 157 0 38 0.01 27.437 346 0 53 0.01 27.727 970 0.01 81 0.02 28.263 86744 0.97 4628 1.15 28.947 4849 0.05 291 0.07 29.563 1529485 17.17 79533 19.78 30.623 14416 0.16 791 0.2 31.053 58009 0.65 1215 0.3 31.873 5884 0.07 543 0.14 32.107 3123 0.04 497 0.12 32.997 93003 1.04 2511 0.62 33.13 15393 0.17 2496 0.62 33.263 28603 0.32 2484 0.62 33.6 102834 1.15 2911 0.72 34.477 5333 0.06 354 0.09 35.11 4475 0.05 259 0.06 35.2 1423 0.02 259 0.06 35.477 12353 0.14 458 0.11 35.993 2890 0.03 188 0.05 36.403 54 0 29 0.01 36.863 4389 0.05 250 0.06 36.92 1028 0.01 216 0.05 37.183 3225 0.04 284 0.07

Lampiran 3 Kromatogram dan Hasil Pengukuran KCKT Larutan Standar (Lanjutan) 38.52 106145 1.19 1665 0.41 39.583 7881 0.09 398 0.1 39.913 516 0.01 96 0.02 40.083 469 0.01 106 0.03 40.15 548 0.01 119 0.03 40.227 302 0 116 0.03 40.32 886 0.01 125 0.03 40.447 579 0.01 90 0.02 40.623 123 0 46 0.01 41.05 285 0 57 0.01 41.157 157 0 50 0.01 41.273 168 0 39 0.01 41.693 1086 0.01 86 0.02 41.817 490 0.01 103 0.03 41.873 260 0 81 0.02 41.947 420 0 70 0.02 42.1 375 0 49 0.01 43.24 98468 1.11 3442 0.86 43.603 65498 0.74 2651 0.66 44.013 46817 0.53 1981 0.49 44.56 42247 0.47 2075 0.52 44.78 39370 0.44 2028 0.5 45.413 191547 2.15 6034 1.5 46.093 21732 0.24 2537 0.63 46.39 41221 0.46 2612 0.65 46.96 100315 1.13 3443 0.86 47.087 25430 0.29 3463 0.86 47.187 22662 0.25 3443 0.86 47.337 60673 0.68 3494 0.87 48.357 398853 4.48 14331 3.56 49.383 66984 0.75 4853 1.21 49.837 177 0 35 0.01

Lampiran 4.Kromatogram, Hasil Pengukuran dan Perhitungan konsentrasi 6-, 8-, 10-gingerol dan 6-shogaol (a) Jahe Merah, (b) Jahe Gajah, (c) Jahe Emprit, (d) Lengkuas, (e) Jahe Merah + Jahe Gajah, (f) Jahe Merah + Jahe Emprit, (g) Jahe Merah + Lengkuas

(a)

(b)

(c)

Lampiran 4.Kromatogram, Hasil Pengukuran dan Perhitungan konsentrasi 6-, 8-, 10-gingerol dan 6-shogaol (a) Jahe Merah, (b) Jahe Gajah, (c) Jahe Emprit, (d) Lengkuas, (e) Jahe Merah + Jahe Gajah, (f) Jahe Merah + Jahe Emprit, (g) Jahe Merah + Lengkuas

(e)

(f)

Lampiran 5Tabulasi Pengukuran dan Perhitungan Konsentrasi 6-, 8-, 10-Gingerol dan 6-Shogaol Jahe Merah, Jahe Gajah, Jahe Emprit, Lengkuas, Jahe Merah + Jahe Gajah, Jahe Merah + Jahe Emprit dan Jahe Merah + Lengkuas

Waktu Retensin(menit) Luas Area Konsentrasi (µg/mL)

6-Gingerol 8-Gingerol 10-Gingerol 6-Shogaol 6-Gingerol 8-Gingerol 10-Gingerol 6-Shogaol 6-Gingerol 8-Gingerol 10-Gingerol 6-Shogaol Standard 12.14 24.13 29.563 22.63 1632010 1943362 1529485 886802 50 50 50 25 JE 12.463 24.3 29.693 22.817 1606700 971686 595094 462726 49.2245 25.0001 19.4540 13.0447 JG 12.537 24.313 29.713 22.817 662592 606250 305666 236631 20.2998 15.5979 9.9924 6.6709 JM 12.617 24.45 29.717 22.85 61458 110928 29565 81786 1.8828 2.8540 0.9665 2.3056 L 12.313 24.073 29.653 22.647 39558 247328 160087 112481 1.2119 6.3634 5.2333 3.1709 JM+JE 12.35 24.273 29.647 22.733 156309 107065 50375 68037 4.7888 2.7546 1.6467 1.9180 JM+JG 12.577 24.397 29.74 22.867 138953 108216 23552 65195 4.2571 2.7842 0.7699 1.8379 JM+L 12.667 24.42 29.733 22.887 46064 118017 33900 94734 1.4112 3.0364 1.1082 2.6706 Contoh perhitungan:

Konsentrasi 6-gingerol Jahe Emprit (JE)

= ×

Konsentrasi 6-gingerol =50 µ / × = 49.2245 µg/mL

O H O C H3 O O H H3C n O H O C H3 C H3 O O H O C H3 O H3C n

CH

₃

(CH

₂

)nCHO

Lampiran 6 Reaksi Degradasi Gingerol

+ Zingeron Gingerol (n = 4, 6, 8) Shogaol (n = 4, 6, 8)

n

6-shogaol

4

8-shogaol

6

10-shogaol

8

n

6-gingerol

4

8-gingerol

6

10-gingerol

8

Lampiran 7 Plot Proporsi 7 Komponen Utama Pertama PCA Spektrum Turunan Pertama Seluruh Sampel

Lampiran 9 Tabel Score PCA 7 Komponen Utama Spektrum Turunan Pertama Seluruh Sampel PC-1 PC-2 PC-3 PC-4 PC-5 PC-6 PC-7 L -5.76473 -6.56572 0.064774 -0.57134 -0.19883 1.379412 -0.85716 L -6.84404 -5.38843 -0.5475 0.460827 -0.23967 1.883559 0.927168 L -6.83359 -5.39207 -0.53651 0.462959 -0.21365 1.863892 0.929066 L -4.41868 -2.68416 0.256398 -1.15654 0.477947 -1.7711 1.487321 L -4.20345 -4.88167 0.196198 -3.066 0.766587 -0.97716 0.191093 L -4.17165 -4.85848 0.196909 -3.04233 0.748241 -0.97164 0.184353 L -8.2816 -3.63061 0.310286 3.254243 -0.63821 -1.29452 0.403954 L -8.24449 -3.62677 0.311684 3.251083 -0.63855 -1.28896 0.396374 L -7.92324 -5.92887 -0.03527 0.202764 0.058694 -0.19958 -1.31628 L -7.93944 -5.92859 -0.05779 0.162186 0.085871 -0.2475 -1.23007 JM -4.43388 2.005976 0.015283 -0.03249 0.174111 -0.04838 -0.13828 JM -4.74516 2.131232 0.077579 0.139674 0.192617 -0.31834 -0.2473 JM -4.41696 2.01016 0.105892 -0.02489 0.157998 -0.16342 -0.17538 JM -4.8272 2.175438 0.143852 0.225662 0.069256 -0.3268 -0.32618 JM -4.831 2.183281 0.134778 0.219548 0.083911 -0.32596 -0.30171 JM -4.82489 2.069178 0.170549 0.143865 0.167324 -0.43345 -0.22041 JM -4.82675 2.072264 0.166833 0.139125 0.170797 -0.43513 -0.20929 JM -4.55808 2.059133 0.109881 0.010132 0.182607 -0.13813 -0.16092 JM -4.57624 2.073965 0.099296 0.006334 0.204569 -0.1414 -0.13169 JM -4.55938 2.064067 0.104696 0.007251 0.191057 -0.14025 -0.14908 JG -4.38317 1.800225 0.065079 -0.10125 0.024022 -0.00056 0.024164 JG -4.36114 1.796887 0.051977 -0.11215 0.033826 0.009475 0.055044 JG -4.37074 1.803354 0.060612 -0.10535 0.02764 -0.00067 0.032427 JG -4.13817 1.703008 -0.01861 -0.16344 -0.03763 0.258144 0.169421 JG -4.13735 1.703454 -0.01815 -0.1634 -0.03781 0.256642 0.168454 JG -3.76268 1.841987 -0.00247 -0.2574 -0.04335 0.432455 0.161373 JG -3.75321 1.838693 -0.0106 -0.26283 -0.0345 0.438167 0.182671 JG -4.13799 2.108371 0.015798 -0.06807 -0.00425 0.127194 -0.04438 JG -4.12791 2.104743 0.009945 -0.07221 0.000181 0.132475 -0.03002 JG -4.13183 2.107321 0.013072 -0.06917 -0.00183 0.128917 -0.0387 JE -4.18953 1.8695 0.065593 -0.03946 0.08096 0.227753 -0.01545 JE -4.19347 1.874672 0.062045 -0.03943 0.093994 0.22662 -0.00199 JE -4.28299 1.943728 0.083071 -0.09134 0.112322 0.192301 0.030496 JE -4.29812 1.956125 0.070313 -0.09393 0.143293 0.192354 0.0698 JE -4.27855 1.943075 0.079694 -0.09359 0.119791 0.192517 0.04182 JE -4.23098 1.930144 0.10757 -0.12077 0.075422 0.268577 -0.00496 JE -4.22066 1.924865 0.108333 -0.11985 0.075553 0.268791 -0.00769 JE -3.68392 1.809964 0.001023 -0.32242 -0.03225 0.408709 0.149694 JE -3.68296 1.809386 0.003407 -0.3217 -0.03136 0.408401 0.150323 JE -3.68467 1.810464 0.006017 -0.31889 -0.02959 0.405411 0.145954 JM+JE 5.796762 -0.22049 0.680713 -0.20558 -0.94564 -0.0642 0.236903

Lampiran 9 Tabel Score PCA 7 Komponen Utama Spektrum Turunan Pertama Seluruh Sampel (Lanjutan) JM+JE 6.314261 -0.26092 0.883077 -0.10045 -0.86436 -0.12024 -0.36947 JM+JE 5.689626 -0.23625 1.312381 -0.33322 -0.98585 0.01036 0.335656 JM+JE 6.210654 -0.29045 1.584627 -0.26682 -1.07123 -0.07097 -0.38027 JM+JE 5.689639 -0.23625 1.312384 -0.33322 -0.98584 0.010357 0.335647 JM+JE 6.210653 -0.29045 1.584627 -0.26682 -1.07123 -0.07097 -0.38027 JM+JE 5.689628 -0.23626 1.312386 -0.33323 -0.98584 0.010344 0.335562 JM+JE 6.210653 -0.29045 1.584629 -0.26683 -1.07123 -0.07099 -0.38028 JM+JE 5.689624 -0.23626 1.312379 -0.33323 -0.98585 0.010363 0.335623 JM+JE 6.210653 -0.29046 1.58463 -0.26682 -1.07124 -0.07097 -0.3803 JM+JG 6.396153 -0.32789 0.79997 0.099726 -0.18779 -0.069 0.120713 JM+JG 6.123127 -0.12307 0.368537 -0.25972 -0.96651 -0.15087 0.002085 JM+JG 5.820811 -0.18189 -3.23839 0.095515 -0.04003 -0.13151 -0.03825 JM+JG 5.469415 -0.00069 -3.35531 -0.32277 -0.69882 -0.07715 -0.05168 JM+JG 5.82081 -0.18189 -3.2384 0.095513 -0.04002 -0.13152 -0.03828 JM+JG 5.820803 -0.18202 -3.23844 0.095493 -0.04002 -0.13154 -0.03928 JM+JG 5.820811 -0.18177 -3.23838 0.095523 -0.04 -0.13152 -0.03737 JM+JG 5.820813 -0.18191 -3.23839 0.095515 -0.04004 -0.1315 -0.03841 JM+JG 5.820814 -0.1819 -3.2384 0.095522 -0.04004 -0.13149 -0.03833 JM+JG 5.82081 -0.18201 -3.23844 0.09558 -0.04008 -0.13147 -0.03891 JM+L 7.665997 -0.57517 0.999168 0.546273 1.198967 0.133011 0.002875 JM+L 5.833963 -0.14948 0.669777 -0.25152 -0.95616 -0.0314 0.18901 JM+L 7.666023 -0.57517 0.999174 0.546277 1.198976 0.133006 0.002874 JM+L 7.665997 -0.57517 0.999168 0.546272 1.198966 0.13301 0.002875 JM+L 7.665997 -0.57517 0.999168 0.546273 1.198966 0.133011 0.002874 JM+L 7.665996 -0.57517 0.999168 0.546273 1.198967 0.133011 0.002875 JM+L 7.665997 -0.57517 0.999168 0.546273 1.198966 0.133011 0.002875 JM+L 7.665994 -0.57517 0.999167 0.546272 1.198965 0.133011 0.002875 JM+L 7.66599 -0.57517 0.999167 0.546271 1.198965 0.133012 0.002874 JM+L 7.665997 -0.57517 0.999168 0.546273 1.198967 0.133011 0.002875

Lampiran 10 Tabel Score PCA 7 Komponen Utama Spektrum Turunan Kedua Seluruh Sampel PC-1 PC-2 PC-3 PC-4 PC-5 PC-6 PC-7 L -1.69678 -4.97256 -0.19418 0.359953 0.820509 -0.62834 0.125205 L -3.0101 -4.64929 0.211776 -0.07049 -0.54663 0.022425 2.555012 L -2.98876 -4.66797 0.156889 -0.3203 -0.61307 -0.02333 2.487501 L -2.02329 -2.30934 -0.03597 0.051487 0.151215 0.137821 -0.49974 L -2.13376 -4.66645 -0.26916 0.31967 1.427101 -1.3227 -0.97142 L -2.15832 -4.70992 -0.23387 0.448437 1.49492 -1.28403 -1.01749 L -3.5364 -2.16067 -0.76194 -0.68735 -1.67428 2.233093 -0.72959 L -3.52715 -2.14462 -0.72758 -0.55327 -1.66618 2.234009 -0.74852 L -3.2585 -4.7022 -0.45402 -0.2794 -0.2654 0.219446 -0.7118 L -3.70335 -5.06165 -0.65284 -0.56119 -0.22984 0.04668 -1.15304 JM -2.87746 1.308424 -0.12077 -0.1679 0.197236 -0.01178 0.004367 JM -3.10321 1.395166 -0.18342 -0.04817 -0.06749 -0.02874 -0.1436 JM -2.9993 1.350257 -0.15528 0.101603 -0.10172 -0.16204 -0.10049 JM -3.47642 1.522513 -0.30061 -0.11164 -0.22255 0.073826 -0.22607 JM -3.49352 1.50443 -0.30349 -0.21437 -0.08873 0.163545 -0.18888 JM -3.12839 1.300636 -0.25681 0.00287 -0.1884 -0.01955 -0.19435 JM -3.15523 1.303052 -0.24069 0.007666 -0.10554 0.032131 -0.18023 JM -3.02672 1.353782 -0.19415 -0.09591 0.063984 -0.02358 -0.04687 JM -3.06887 1.350854 -0.17791 -0.1338 0.223513 0.085704 -0.01088 JM -3.0415 1.349489 -0.18697 -0.11341 0.121364 0.016404 -0.03519 JG -3.00519 1.28704 -0.10454 0.063775 0.04539 -0.10082 -0.00642 JG -3.04881 1.280348 -0.12913 -0.07724 0.169605 -0.01472 0.033091 JG -3.0246 1.300132 -0.05547 0.178155 0.135322 -0.04871 0.003758 JG -2.90864 1.249681 -0.05751 -0.19494 0.271394 -0.03012 0.123201 JG -2.90563 1.251441 -0.06055 -0.19135 0.253971 -0.04325 0.121331 JG -2.53639 1.328407 0.032214 0.162759 0.159407 -0.23049 0.17813 JG -2.56478 1.322819 0.037137 0.094956 0.261137 -0.16739 0.19851 JG -2.73272 1.448601 -0.01023 0.151735 0.009209 -0.17016 0.039669 JG -2.73942 1.438026 -0.02305 0.069696 0.045402 -0.14644 0.051315 JG -2.72713 1.440832 -0.03057 0.081286 -0.00972 -0.18195 0.042216 JE -2.70517 1.27454 -0.04651 0.195504 0.012412 -0.2095 0.103602 JE -2.71402 1.264227 -0.08655 0.05628 0.004801 -0.21385 0.111116 JE -2.83012 1.261487 -0.15492 -0.18394 0.15965 -0.09463 0.10339 JE -2.89717 1.264094 -0.18031 -0.33811 0.291002 -0.00933 0.143782 JE -2.83989 1.263679 -0.14471 -0.16334 0.206149 -0.06519 0.116081 JE -2.75112 1.265551 -0.10667 -0.0744 0.080969 -0.19535 0.08662 JE -2.7179 1.253852 -0.12535 -0.10798 0.005469 -0.24302 0.075642 JE -2.60703 1.307771 -0.00721 0.151393 0.11592 -0.3193 0.186533 JE -2.59258 1.300637 -0.03196 0.097193 0.08668 -0.33643 0.190188 JE -2.56921 1.29527 -0.03043 0.10145 0.046385 -0.36617 0.179294 JM+JE 4.125209 -0.01357 -0.73902 -0.12431 0.039939 0.268353 0.00893

Lampiran 10 Tabel Score PCA 7 Komponen Utama Spektrum Turunan Kedua Seluruh Sampel (Lanjutan) JM+JE 3.415915 -0.08396 -0.07007 0.898044 -1.17364 -0.76175 -0.2599 JM+JE 3.725315 0.008964 -0.78087 1.291589 1.518796 1.353577 0.259327 JM+JE 3.353934 -0.08306 -0.43384 2.314536 -1.27249 -0.52913 -0.11129 JM+JE 3.725316 0.008937 -0.78082 1.291579 1.518763 1.353607 0.259316 JM+JE 3.353903 -0.08306 -0.43387 2.314532 -1.27248 -0.52914 -0.11125 JM+JE 3.72529 0.009073 -0.78125 1.291843 1.51902 1.353348 0.258516 JM+JE 3.353964 -0.08288 -0.43382 2.314616 -1.27235 -0.52914 -0.1115 JM+JE 3.725474 0.008917 -0.78051 1.29151 1.519109 1.353902 0.259701 JM+JE 3.35386 -0.08317 -0.43423 2.314708 -1.27254 -0.52921 -0.11108 JM+JG 3.747081 -0.08015 -0.52382 -0.70858 0.045869 0.005446 0.051792 JM+JG 3.556756 0.038462 0.188277 1.099882 0.129778 0.117548 0.006819 JM+JG 2.584185 -0.14875 2.973223 -0.27536 0.001475 0.163353 -0.11541 JM+JG 2.850135 -0.0948 3.623846 -0.3985 -0.10531 -0.03445 -0.17361 JM+JG 2.584248 -0.1487 2.973646 -0.27553 0.001644 0.163436 -0.11608 JM+JG 2.584271 -0.14938 2.97491 -0.27673 0.002774 0.163151 -0.12317 JM+JG 2.584605 -0.14763 2.975033 -0.27532 0.001529 0.164274 -0.11285 JM+JG 2.584051 -0.14904 2.972361 -0.27521 0.001254 0.163055 -0.11516 JM+JG 2.584179 -0.14912 2.973738 -0.27562 0.001213 0.163745 -0.11444 JM+JG 2.584213 -0.15123 2.977115 -0.2764 -0.00117 0.167136 -0.11342 JM+L 4.940369 0.14027 -1.11502 -1.16895 -0.0952 -0.31278 0.060608 JM+L 6.25878 0.519202 -2.00726 -0.7478 -0.15502 0.1998 -0.25565 JM+L 4.940595 0.14032 -1.11515 -1.16904 -0.09519 -0.3128 0.060602 JM+L 4.9404 0.14028 -1.11504 -1.16898 -0.09519 -0.31278 0.060604 JM+L 4.940375 0.140272 -1.11502 -1.16896 -0.09519 -0.31278 0.060605 JM+L 4.940433 0.140285 -1.11505 -1.16899 -0.09519 -0.31278 0.060607 JM+L 4.940378 0.140274 -1.11503 -1.16896 -0.09519 -0.31278 0.060607 JM+L 4.940407 0.140277 -1.11504 -1.16898 -0.09519 -0.31278 0.060604 JM+L 4.940465 0.140291 -1.11508 -1.16898 -0.09519 -0.31279 0.060603 JM+L 4.940411 0.140279 -1.11507 -1.16899 -0.09519 -0.31279 0.060603

Lampiran 11 Plot Proporsi 7 Komponen Utama Pertama PCA Spektrum Normal Seluruh Sampel

Lampiran 13 Tabel Score PCA 7 Komponen Utama Pertama Spektrum Normal Seluruh Sampel PC-1 PC-2 PC-3 PC-4 PC-5 PC-6 PC-7 L -9.36025 2.920959 -2.83472 0.569424 -0.6837 0.225679 0.311908 L -10.064 3.917585 -2.13708 0.267573 -0.49116 0.437731 0.098299 L -10.0629 3.943455 -2.10722 0.28773 -0.4976 0.441087 0.099414 L -8.1589 1.772889 -0.54001 0.820703 0.973414 -1.01213 -0.59032 L -9.06435 2.529928 -1.41436 1.293293 1.920375 -0.29985 0.33204 L -9.03452 2.609228 -1.36843 1.304001 1.938301 -0.28197 0.329443 L -9.62269 2.377942 -2.27848 -0.21672 -1.16091 -0.09644 -0.54514 L -9.55458 2.441317 -2.21291 -0.19521 -1.15634 -0.07879 -0.54335 L -10.9897 3.149585 -2.36305 -0.31044 -0.1243 0.220181 -0.01491 L -11.0734 3.528721 -2.25002 -0.3171 -0.11081 0.216772 -0.04126 JM -4.97225 -1.12932 1.169631 -0.29086 0.419166 0.350577 -0.47045 JM -4.08307 -0.70073 1.626187 -0.04833 0.194283 0.221473 -0.19144 JM -3.79399 -0.7877 1.734016 0.03356 0.316491 0.35931 -0.12645 JM -3.31773 -0.61472 1.406049 0.027896 -0.33938 -0.14388 0.186175 JM -3.31817 -0.63672 1.410811 0.02462 -0.33604 -0.15269 0.190346 JM -3.09406 -0.56854 1.535122 0.137139 -0.0761 0.138493 0.215013 JM -3.08259 -0.56429 1.550724 0.135621 -0.06805 0.139874 0.216006 JM -3.09058 -0.39433 1.839699 0.137956 -0.0508 0.095463 0.16803 JM -3.10483 -0.42919 1.83285 0.132629 -0.05415 0.077709 0.172167 JM -3.09488 -0.42271 1.83983 0.139381 -0.04967 0.089069 0.170783 JG -3.99036 -1.30725 0.443245 -0.08448 -0.61219 -0.41381 0.154994 JG -3.98855 -1.33434 0.453304 -0.08715 -0.60832 -0.42537 0.159357 JG -3.96373 -1.31425 0.475908 -0.07686 -0.60095 -0.40762 0.156947 JG -4.35097 -0.65673 1.028401 -0.15511 -0.37461 -0.32339 -0.00973 JG -4.34122 -0.65491 1.036862 -0.15163 -0.37053 -0.31767 -0.00884 JG -3.63942 -0.06011 2.261517 -0.03443 0.493204 0.439227 -0.09402 JG -3.64515 -0.08411 2.260266 -0.03892 0.492883 0.426183 -0.08978 JG -3.97718 -0.6674 2.037154 -0.1935 0.296568 0.191199 -0.23145 JG -3.98193 -0.68236 2.04211 -0.19543 0.297323 0.182832 -0.23018 JG -3.96005 -0.65852 2.061687 -0.1907 0.306193 0.197671 -0.23193 JE -3.61279 -0.4345 1.656626 0.124073 -0.09222 0.073722 0.05107 JE -3.60974 -0.45122 1.663232 0.126387 -0.09013 0.07106 0.052554 JE -3.57284 -1.16058 0.94784 0.048121 -0.49227 -0.29037 0.212933 JE -3.59601 -1.19987 0.932099 0.042676 -0.50328 -0.3154 0.216032 JE -3.56102 -1.16166 0.961193 0.05147 -0.48932 -0.29084 0.214157 JE -3.50112 -1.27792 0.793472 0.018384 -0.57205 -0.30388 0.283964 JE -3.50251 -1.28853 0.794639 0.024721 -0.57733 -0.30758 0.283948 JE -4.17821 -0.919 1.683337 -0.09679 0.299458 0.159345 -0.2587 JE -4.1913 -0.93699 1.677249 -0.09479 0.29669 0.155054 -0.25933 JE -4.20732 -0.95658 1.664947 -0.08819 0.289779 0.153105 -0.2613

Lampiran 13 Tabel Score PCA 7 Komponen Utama Pertama Spektrum Normal Seluruh Sampel (Lanjutan) JM+JE 3.188579 -0.97748 -1.76736 -1.06506 0.344021 -0.05341 0.010399 JM+JE 5.244026 0.368592 -0.58789 -0.74691 0.274714 0.064002 0.127512 JM+JE 3.094776 -1.12352 -1.82305 -1.03659 0.328722 -0.03434 0.034018 JM+JE 5.148839 0.222618 -0.64223 -0.71992 0.255652 0.081987 0.153878 JM+JE 2.999438 -1.27092 -1.87903 -0.99958 0.321965 -0.0253 0.035076 JM+JE 5.0535 0.075218 -0.69821 -0.68291 0.248894 0.09102 0.154936 JM+JE 2.904102 -1.41832 -1.935 -0.96257 0.315208 -0.01627 0.036135 JM+JE 4.958162 -0.07218 -0.75418 -0.6459 0.242135 0.100053 0.155993 JM+JE 2.808765 -1.56572 -1.99098 -0.92555 0.308451 -0.00724 0.037193 JM+JE 4.862829 -0.21958 -0.81016 -0.60889 0.235382 0.109088 0.157053 JM+JG 9.076515 2.327451 0.32573 -0.80685 0.211396 -0.31665 -0.08217 JM+JG 1.20925 -1.97903 -1.81944 -0.66947 0.266715 0.235935 0.291922 JM+JG 8.296484 1.164419 -0.0961 -0.41907 0.185235 -0.31726 -0.24689 JM+JG 0.435897 -3.14692 -2.25623 -0.33861 0.218292 0.284565 0.229814 JM+JG 7.53628 -0.01091 -0.54245 -0.12393 0.131351 -0.24523 -0.23845 JM+JG 6.728512 -1.25988 -1.01674 0.189668 0.074124 -0.16867 -0.22947 JM+JG 6.776034 -1.18616 -0.98881 0.171234 0.077428 -0.17323 -0.23004 JM+JG 4.84076 -4.17842 -2.12511 0.922562 -0.05969 0.010181 -0.20853 JM+JG 4.578429 -4.584 -2.27914 1.024408 -0.07829 0.035036 -0.20562 JM+JG 4.08058 -5.35379 -2.57145 1.217685 -0.11355 0.082224 -0.20008 JM+L 14.37251 5.147904 1.641312 -0.16139 -0.09116 -0.10256 -0.01105 JM+L 3.702267 -0.71809 -1.51288 -1.02241 0.325553 -0.07919 0.044763 JM+L 14.04698 4.644616 1.450181 -0.03501 -0.11423 -0.07171 -0.00743 JM+L 11.28268 0.370799 -0.17286 1.038192 -0.31016 0.190208 0.023246 JM+L 13.72145 4.141326 1.259049 0.091375 -0.13731 -0.04087 -0.00382 JM+L 10.95715 -0.13249 -0.36399 1.164573 -0.33324 0.221052 0.026859 JM+L 13.39593 3.638038 1.067919 0.217756 -0.16038 -0.01002 -0.00021 JM+L 10.63162 -0.63578 -0.55512 1.290954 -0.35631 0.251896 0.030472 JM+L 13.0704 3.134748 0.876787 0.344137 -0.18345 0.02082 0.003405 JM+L 10.30609 -1.13907 -0.74626 1.417335 -0.37938 0.28274 0.034085

Lampiran 14 Tabel Score PCA 7 Komponen Utama Pertama Spektrum Normal JE, JG dan JM PC-1 PC-2 PC-3 PC-4 PC-5 PC-6 PC-7 JM -0.0172 1.54176 -0.22929 -0.3864 -0.02905 -0.07421 -0.08031 JM 0.373957 0.428497 -0.10518 -0.23043 0.1033 -0.07403 -0.01139 JM 0.526925 0.20833 -0.34967 -0.15588 -0.01223 0.004334 -0.00873 JM -0.08879 -0.56157 0.115833 -0.06014 0.068542 -0.14929 0.077053 JM -0.09649 -0.55734 0.103345 -0.04253 0.076647 -0.14621 0.069129 JM 0.247748 -0.71121 -0.15713 -0.13861 -0.12744 -0.06302 0.02088 JM 0.265312 -0.72066 -0.1608 -0.1324 -0.12433 -0.06231 0.018254 JM 0.531567 -0.73828 -0.02376 -0.06592 0.055851 0.005325 -0.0006 JM 0.503176 -0.7204 -0.0347 -0.04633 0.068938 0.010717 -0.01205 JM 0.517479 -0.72956 -0.04186 -0.05057 0.063226 0.010332 -0.0064 JG -1.3157 0.178317 0.057798 -0.008 -0.10568 -0.04799 0.031401 JG -1.32236 0.181315 0.041695 0.01638 -0.09371 -0.04347 0.020709 JG -1.2867 0.156292 0.034275 0.012533 -0.09942 -0.04549 0.027287 JG -0.50379 0.449236 0.576654 -0.05862 0.044701 0.007489 -0.00392 JG -0.49261 0.440275 0.570221 -0.0573 0.04254 0.007162 -0.00322 JG 1.329947 -0.07396 0.247411 0.034368 -0.21305 0.065784 -0.0231 JG 1.313606 -0.06513 0.239253 0.050508 -0.20354 0.070626 -0.03358 JG 0.73588 0.367357 -0.00988 0.267869 0.050008 -0.12162 -0.03449 JG 0.730174 0.37397 -0.01558 0.281007 0.058716 -0.11812 -0.04063 JG 0.764704 0.351909 -0.01596 0.275364 0.05231 -0.12059 -0.03605 JE 0.330709 -0.22811 0.139277 -0.14586 0.099299 0.130187 -0.01588 JE 0.328477 -0.22791 0.125345 -0.13295 0.105032 0.133441 -0.02161 JE -0.78792 -0.23221 -0.10514 0.064591 0.056376 0.078343 -0.03563 JE -0.83096 -0.20703 -0.11068 0.083811 0.072792 0.085403 -0.04823 JE -0.77724 -0.24278 -0.11176 0.071886 0.061486 0.081934 -0.0387 JE -0.98542 -0.30467 -0.15438 0.135037 -0.05648 0.029995 -0.049 JE -0.99295 -0.30379 -0.1616 0.141071 -0.05025 0.033628 -0.04886 JE 0.350305 0.634112 -0.14664 0.088494 0.008266 0.101092 0.095023 JE 0.334859 0.648539 -0.15424 0.09371 0.012853 0.104077 0.094864 JE 0.313302 0.66471 -0.16285 0.095333 0.014301 0.10649 0.097781

Lampiran 15 Predict Vs Reference PLSDA Spektrum Turunan Kedua Seluruh Sampel (Lanjutan)

Lampiran 16 Predict Vs Reference PLSDA Spektrum Turunan Kedua Sampel JE, JG dan JM (Lanjutan)

Lampiran 17 Predict Vs Reference PLSDA Spektrum Turunan Kedua Sampel JM+JE, JM+JG dan JM+L (Lanjutan)