INTRODUCTION TO HARDMETALS
1.02 Fundamentals and General Applications of Hardmetals 1.03 Microstructure and Morphology of Hardmetals
1.01.8 Conclusion
Cemented carbides remain a growing market. There has been a continuous expansion in the consumption, from an annual world total of 10 ton in 1930 to about 50,000 ton in 2008. As the world’s economics grow, cemented carbides will play their part in the progress of technology.
New technologies and new materials will demand new tooling solutions, and cemented carbide tools will provide a cost-effective option due to their attractive properties. Modern recycling technologies and a more efficient collection system of scrap material will contribute in this regard, driven by both the price and the need to maintain and save natural resources. In the long term, recycling will inevitably become the key strategic factor for sustained economic growth, and the respective recycling strategies of cemented carbides are in the line.
So, after a period of almost 90 years, cemented carbides have developed from a temporary solution in industry (as a substitute for diamond in wire drawing in the lighting industry) to a very successful and almost irreplaceable material for the manufacturing industry (Schubert et al., 2010).
The authors of this chapter consider it as being very remarkable that from the very beginning of the hard- metals the optimal combination of WC and Co was chosen. Even by 2013, 90 years later, there is no better combination of hard carbide and metallic binder in sight.
History of Hardmetals 25
References
Aronsson, B. (2005).The origins and growth of cemented carbide(2nd revised ed.). Uppsala: Sandvik.
Baumhauer, H. (1922). DRP 443.911 Patent owner: Patent Treuhand Gesellschaft für elektrische Glühbirnen m.b.H., Berlin Inventor: Dr Heinrich Baumhauer in Berlin, Charlottenburg Title: Procedure for the fabrication of pieces and tools, especially drawing dies issue of letters patent: March 19, 1922.
Brookes, K. J. A. (1995). Half a century of hard metals.Metal Powder Report, 22–28.
Brookes, K. J. A. (1996).The world directory and handbook of hard metals(6th ed.). International Carbide Data.
Campbell, J. E., Powell, C. F., Nowicky, D. H., & Gonser, B. W. (1948). The vapour-phase deposition of refractory materials; I. General conditions and apparatus.Journal of the Electrochemical Society, 96, 318.
Derjagin, B. W., Spitsyn, B. V., Builov, L. L., Klochkov, A. A., Gorodetskii, A. E., & Smol’yaninov, A. V. (1976). Synthesis of diamond on non-diamond substrates.Doklady Akademii Nauk SSSR, 231, 333–335.
Exner, H. E., & Gurland, J. (1970). A guide to the literature on tungsten carbide-cobalt alloys.Powder Metallurgy International, 59–63, 104–105, 147.
Fang, Z. Z. (2013). Guest editor: Special Section: Recent advances of functionally graded hard materials.International Journal of Refractory Metals and Hard Materials, 36, 1–75.
Fernandez, C. M., & Senos, A. M. R. (2011). Cemented carbide phase diagrams: a review.International Journal of Refractory Metals and Hard Materials, 29, 405–418.
Fister, D. (1970). About the influence of carbon deficit of the hard material phase on the properties of TiC-VC(TaC, NbC)-Mo2C-Ni hard metals and about the coating of hardmetal plates with TiN.
Fuchs, G., Kopietz, A. (1917). DRP 30 77 64. Metallegierung.
Fuchs, G., Kopietz, A. (1918). DRP 31 00 41. Metallegierung.
German, R. M. (2005).A-Z of powder metallurgy. Oxford, UK: Elsevier Advances Techology.
Hobein, D. (1986). The reconstruction of the WIDIA-factory in Essen 1945–1949 (in German).Technikgeschichte, 53(4).
Huppmann, W. J. (2006). The historical roots of the powder metallurgical industry in Germany (in German). InPulvermetallurgie in Wissenschaft und Praxis, 22.
Hagen: Fachverband Pulvermetallurgie.
Jenssen, W., Schroeter, K. (1925). US Pat. 1.551.333. Tool and die, Kennametal:http://www.kennametal.com.
Kieffer, R., & Benesovsky, F. (1965).Hartmetalle. Wien: Springer Verlag.
Kieffer, R., Mariacher, H., Schoff, H. (1971). DE 195 96 90: Überzugsschicht, auf Hartmetallteilen für die spanende and spanlose Formgebung und Verfahren zu ihrer Herstellung [Coating on hard metal parts for the shaping, with continuous and discontinuous chip formation and procedures to their fabrication].
Klink, J., & Weidenfeld, H. (1951).Mitteilungen der fried. Krupp WIDIA-Fabrik, Essen (News of the..)
Kolaska, H. (1992).Pulvermetallurgie der hartmetalle. Hagen: Fachverband Pulvermetallurgie (Powder metallurgy of hard metals).
Kolaska, H. (2007). Hard metal–yesterday, today and tomorrow (in German). Metall 12/2007, 825–832.
Kolaska, H., & Ettmayer, P. (in press). Geschichte der hartmetalle (History of Hard Metals).
Konstanty, J. (2005).Powder metallurgy diamond tools. Amsterdam, Boston: Elsevier.
Lengauer, W. (2012). Hard metals and cermets; actual tendencies of development (in German); contribution to the planned book of Kolaska and Ettmayer.
Lohmann, Voigtländer. (1914). Metall-fabrikationsges, m.b.H., Essen, DRP 286.184: procedure for the fabrication of pieces of tungsten–and molybdenum carbides of varying size (in German).
Lux, B., Funk, B., Schachner, H., Triquet, C. (1974). US Pat. 3.836.392. Process for increasing the resistance to wear of the surface of cemented carbide parts subject to wear.
Lux, B., & Haubner, R. (1989). Low pressure synthesis of superhard coatings. In H. Bildstein, & H. M. Ortner (Eds.),Proceedings of the 12th Int. Plansee Seminar ’89(Vol. 3). Innsbruck: Tyrolia (C2).
Mari, D. (2001).Cermets and hard metals, encyclopedia of materials: science and technology. Elsevier Science Ltd.
Moers, K. (1931). I. Methods for the preparation of pure high-melting carbides, nitrides and borides and a description of a few of their properties. II.
The preparation of pure carbides, nitrides and borides by the method of growth and a description of a few of their properties.Zeitschrift fu¨r anorganische und allgemeine Chemie, 198, 243–261.
Muenster, A., & Ruppert, W. (1953). Thermodynamics of some reactions of titanium tetrachloride.Zeitschrift fu¨r Elektrochemie, 57(7), 558–564.
Novikov, N.V. (2008). Modern hard metals, collection of proceedings, Kiev, ISBN 978-966-02-4718-5.
Ortner, H. M. (1997). The influence of trace elements on the properties of hard metals, Vol. IV of the European concerted action COST 503: Powder metallurgy –powder based materials of the European Commission. T. Valente (Ed.),Directorate – General, Science, Research and Development, Brussels.
Ortner, H. M. (2005). Trials and tribulations in editing the IJ RMHM for 13 years (1991–2004).International Journal of Refractory Metals and Hard Materials, 23, 3–16.
Ortner, H. M. (2009). The International Journal of Refractory Metals and Hard Materials–present state, future and retrospective view.International Journal of Refractory Metals and Hard Materials, 27, 513–519.
Petzow, G., Claussen, N., & Exner, H. E. (1968). Structure and properties of cermets.Zeitschrift fu¨r Metallkunde, 59, 170–179.
Plansee Group. (2010).http://www.plansee-group.com/history_ENG_HTML.htm.
Riedel, R. (Ed.). (2000).Handbook of ceramic hard materials. Weinheim: Wiley-VCH.
Rix, E. F. G., Dix, G. E. (1969). DBP 1 521166:Verfahren zum Herstellen von U¨berzu¨gen auf Hartmetallko¨rpern[Procedure for the fabrication of coatings on hard metals].
Rudy, E. (1973). Boundary phase stability and critical phenomena in higher order solid solution systems.Journal of the Less Common Metals, 33, 43–70.
Rudy, E. (1976). US 3971656. Spinodal carbonitride alloys for tool and wear applications.
Ruppert, W., Schwendler, G. (1956). DBP 1 165 377:Verfahren zur Herstellung von Titankarbidu¨berzu¨gen durch Gasplattieren.
Ruppert, W., Schwendler, G. (1957). US Pat. 2, 962. 399. Process for deposition of titanium carbide coatings, Sandvik:http://www.hardmaterials.sandvik.com/
sandvik/0130/Internet/SEO3459.NSF.
Schade, P. (2010a). Guest editor of special issue. Selected papers of the 17th Int. Plansee Seminar 2009 in Reutte, Austria: Tungsten and molybdenum.
International Journal of Refractory Metals and Hard Materials, 28(6).
Schade, P. (2010b). 100 years of doped tungsten wire, as above, 648–660.
Schedler, W. (1988).Hartmetall fu¨r den Praktiker[Hard metal for the practitioner]. Düsseldorf: VDI-Verlag GmbH.
Schröter, K. (1923). DRP 420.689: sintered hard metal alloy and procedure for its fabrication. Inventor: Karl Schroeter in Berlin-Lichtenberg. Patent owner:
Patent-Treuhand-Gesellschaft für Elektrische Glühlampen, mbH, Berlin issue of letters patent: March 30, 1923.
Schröter, K., Agte, C., Moers, K. Wolff, H. DE 622.347 (1931) and US Pat. 2.015.536 (1932/35).Verfahren zur Herstellung von Hartmetall-Legierungen fu¨r Arbeitsgera¨te und Werkzeuge aus Wolframkarbid und einem zusa¨tzlichen Hilfsmetall[Procedure for the fabrication of hard metal alloys for working vessels and, tools made of tungsten carbide and an additional metal].
Schubert, W.-D., Lassner, E., & Boehlke, W. (June 2010).Cemented carbides – a success story, in Tungsten, Int. Tungsten Industry Association (ITIA).
Schuhmacher, G. (1969).Wendeschneidplatten aus Hartmetall mit Titankarbidschicht(Inserts made of hardmetal with a titanium carbide coating) TZ Prakt.
Metallbearb, 63, 275–278.
Schwarzkopf, P. (1955).Geschichten aus Molybda¨nemark(Vol. 1). Füssen, Germany: C.F. Wintersche Verlagshandlung.
Schwarzkopf, P. (1955).Geschichten aus Molybda¨nemark(Vol. 2). Austria: Bergland, Verlag Wien.
Schwarzkopf, W. M., (Ed.). (1971). Paul Schwarzkopf –Zur Erinnerung an Prof. Dr. Paul Schwarzkopf anläßliich des ersten Jaherstages seines Ablebens, Metallwerk Plansee AGaCo KG [in memory of Prof. Dr. Paul Schwarzkopf on the occasion of thefirst anniversary of his demise].
Schwarzkopf, M. (Friday, July 8, 2011).Plansee celebrates with records (in German). Tiroler Tageszeitung. Wirtschaft.
Schwarzkopf, P., Hirschl, I. (1931). US Pat. 1.925.910. Production of hard metal alloys, especially for tools.
Schwarzkopf, P., & Kieffer, R. (1960).Cemented carbides. New York: The Macmillan Co.
Seb, P. K. (1994). De Beers Monodite–a performance evaluation.Industrial Diamond Review, 54(560), 13–20, 1/94.
Skaupy, F. (1951). Memorandum about the development of hardmetal in the OSRAM-Studiengesellschaft, later named WIDIA from August 15, 1951 [personal information of W. Skaupy to H. Kolaska August 28, 1992].
Sundmann, B., Jansson, B., & Andersson, J. O. (1985).Calphad, 9.
Telle, R. (1997). Ceramics for high-tech applications, Vol. V of the European concerted action COST 503 (COST-subgroup hard materials): Powder metallurgy– powder based materials of the European Commission. In T. Valente (Ed.),Directorate – General, Science, Research and Development, Brussels.
Trent, E. M. (1991).Metal cutting(3rd ed.). Oxford, London: Butterworth-Heinemann Ltd.
Upadhyaya, G. S. (1998).Cemented tungsten carbides: Production, properties and testing. New Jersey, USA: Noyes.
van Arkel, A. E., & De Boer, J. H. (1925). Preparation of pure titanium, zirconium, hafnium and thorium metal.Zeitschrift fu¨r Anorganische und Allgemeine Chemie, 148, 345–350.
Weidenfeld, H. (October 1951).Heinrich Weidenfeld erza¨hlt (in German). Der Sinterling. Essen: Mitteilungen der Friedr.-Krupp WIDIA Fabrik.
Wiegand, H., & Ruppert, W. (1960). Some properties of the material combination, steel with titanium carbide coating. Metalloberfla¨che, 14(7), 193 (8) 229–235.
Wolff, H. (1941). Hardmetalltillverknigens utveckling, Teknisk Tidskrift, Arg 71, Häfte 52, 549–551.
History of Hardmetals 27