Xi
in figure 7,
which
is of a crystalbetween
crossed nicols restingon
the pinacoid a (100), the broad flat face.The
colors of a typicalexample
are indicated on the drawing.Thisstructureisnot
due
to twinningbutisdue
rather todifference in composition resultingin varying birefringence.The
variationisprobably inthe
amount
of the iron-epidote molecule,thisbeinggreat- est intheend
sectorsand
graduallydecreasingfrom
centertooutside in all sectors.The
extinction is parallel to the sides of the crystalsand
the axial plane across the length, this tabular face being nearly perpendicular to the obtuse bisectrix.The
crystalsvary
in color, in ordinarylight,fi'om colorless to pale greenish yellowwith noticeable pleochroism, the color being distrib-uted in the
same
pattern as the bire- fringence. This coloris visible in theend
sectors of the thicker crystalsand
in the inner tips of the side sectors.The
epidote is biaxial, negative(
—
), with2V
large.The
indicesvary
with the zoning.One
crystal gave, at the outer edges of the side ^ sectors,which
is the portion of mini-mum
birefringenceand
probably ofminimum
index,«=
1.748, j3= 1.754.This is typical "hour-glass struc- '^
ture,"
which
is describedby
Iddings-*as follows:
Differences in the molecular attractions 2^
in different directions in a crystal also show
"themselvesintheconstitution ofsomemixed crystals or crystals of isomorphous com- pounds. Itappears asthough certain mole-
culesintheisomorphous serieshavea greatertendency to attach themselves in onedirectionthan another;that isthey are more strongly attracted to certain faces of the mixed crystal than to others. The crystal then differs in com- position insegments builtup oflayers parallel to such faces, which
may
show themselvesin differences ofcolor or refraction. In some minerals the segments are pyramidal withthe apexesofthe pyramidstowardthe centerofthe crj-stal,and the bases atthesurface. Insections ofsuchcrystalsthe reversedpyramids sometimes suggestthe shape of an hour-glass, hence the term hour-glass struc- ture. Thecommonest examplesofsuchstructure arefoundin augite in certain basaltic rocks.
While
allofthe epidoteof thisshearzoneand
thatofthespecimens collectedby
Merrilland Wherry
are of thispeculiar type,the epidote ofthe miarolitic cavitiesand
that associated with the axinitewere
Fig.8.—Epidote. Projection of"hour GLASS" CRYSTALS ON ft(010) SHOWING OPTICAL ORIENTATION.
'*J P.Iddings. RockMinerals,p. 72,NewYork,1906.
60 PROCEEDINGS
OFTHE NATIONAL MUSEUIM.
Vol.not of this type.
A few
hour-glass epidotes were seen, however, entangled with theamphibole
of bluish smearson
cracks in albitic pegmatite (see p. 53).Paragenetically the epidote is
contemporaneous
with chlorite, asbestiformamphibole and
alsowith the earliest prehnite,indicating that its formation covered a considerable period.Angles of crystals of "hour-glass" epidote. Measured with elongation (6 axis) vertical.
CRYSTAL1.
Form.
ART.2.
PETROLOGY AT
GOOSECREEK SHANNON. 61 South
of the central part of the quarry face an apKte dikefrom
2 cm. to.3 cm. wide is cut
by
laterseams
filled with diopsideand where
these diopsideseams widen
they have a central layer of pur-plish-gray axinite. In places the axinite
seams
containminute
vugs linedwith acutewedge-shaped
ax- inite cr^^stals of purplish-browncolor.
The
centralportionofthese vugs is filled with cottony white hornblendewhich
containsembed- ded
perfect crystals of axiniteand
a fewlong prismaticcrystals of epi- dote.One
suchaxinite-lined cav- itywas
filled withawhite mineral which,when examined
microscopi- cally,was
foundtocontainnumer-
ous included colorlesshornblendefibers. This white mineral
which
is biaxial, positivewith
2V
small,r>v
pronounced, has a perfect cleavage perpendicular to the acute bisectrixand
is doubtless apophyllite. Itsrefractive index,i3is1.538.
The
axinite crystalwhich was measured was
one of the perfect individuals suspended on horn- blende fibers. It has theform and
habitshown
in figure 9and gave
the followingmeasurements
:
Fig.9.—Axinite. Showing common h.\bit of CRYSTALS FROMQOOSE CREEK. ORTHOGRAPHIC ANDCLINOGRAPHIC PROJECTION ON C(010)"
Measurementsofaxinite froyn Goose Creek.
Form.
62 PEOCEEDINGS
OPTHE NATIONAL MUSEUM.
VOL. 66.The
faces of the crystals are all lustrousand
brilliant but the prismatic planes are striated verticallyand somewhat rounded by
oscillation.
The
optical properties of this axinite are: biaxial, negative (—
),2V medium
large,r<v
moderate,a=
1.673, /3= 1.680,7=1.684,
7—
a =.011. In the granular portion of the taxiniteseam
chalcopyrite. apparently con- temporaneous, is intergrown with theaxinite.Paragenetically the axinite is placed as con-
temporaneous
with chalcopyrite, epidote,and
hornblende,and
earlier than apophyllite.a yn
Fig.10.—Prehnite.Typeicrys- tal. Orthographic crystal drawings.
bril-
The
scarcity of quartz is rather a nota-i)le feature of the
Goose
Creek assemblage of vein minerals. This mineral, socommon
elsewhere in association with zeolites in trap-
pean
rocks,was
seen onlyoncein allthe spec- imens collected. In this instanceitoccurred ascombs
ofprismatic crystalgrown
outfrom
either wall of a vein.
The
crystals restedupon
a layer of chlorite.The
individual quartz crystals average 2 millimeters longby
1 millimeter thickand
are transparent, colorless,and
liant.
They have
thecommon
habit,hexagonal prism terminated
by
a symmetrical hexagonal pyramid.The
veinbetween
the quartzcombs
isfilled with coarse granular datolite w^hich preserves
molds
of the quartz crystalswhen
they arebroken
out.The
wholevein averages about 1 cen- timeter wide.A
singlesmall cubeofgalena
was
seeninthechloriteunder- lying the quartz. Parageneticallythe quartz is laterthan chlorite
and
fi«-h
-prehnite, type 2crystalelon-\.i.L\j K.^Kj.i.i,LMu io
GATED ON THE 6 AXIS SHOWING CRYSTAL
galena
and
older than datolite. habitandstriation ofc (ood.Prehnite is the
most abundant
of the vein mineralsand
occurs in a variety offorms.In the lot ofmaterial collected
from
this locality in 1915by Doc-
tors Merrill
and Wherry,
the prehnite exhibits theordinaryform, pale greencolumnar
crusts with botryoidal to ill-definedcockscomb
surface. This prehnite rests