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Synthesis of a New DPTYEAP Ligand and Its Complexes with Their Assessments on Physical Properties, Antioxidant, and Biological Potential to Treat Breast Cancer

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(1)

Abbas Fadhil Yasir and Hayder Obaid Jamel

2-aminothiazol

N N S

N HO DPTYEAP refluxed for 8 h

Application Antioxidant Anticancer

Fig S1. Graphical abstract

Fig S2. FTIR spectra of the synthesized ligand (DPTYEAP)

Fig S3. FTIR spectra of the Ni(II) complex

(2)

Abbas Fadhil Yasir and Hayder Obaid Jamel

Fig S4. FTIR spectra of the Cu(II) complex

Fig S5. FTIR spectra of the Ag(I) complex

Fig S6. FTIR spectra of the Pt(IV) complex

(3)

Abbas Fadhil Yasir and Hayder Obaid Jamel

Fig S7. Electronic spectra of the synthesized ligand (DPTYEAP)

Fig S8. Shows the absorption peaks of each of the Ni(II) complexes

Fig S9. Shows the absorption peaks of each of the Cu(II) complexes

(4)

Abbas Fadhil Yasir and Hayder Obaid Jamel

Fig S11. Shows the absorption peaks of each of the Pt(IV) complexes

Fig S12. Shows the XRD patterns for ligand (DPTYEAP) and Ni(II) complexes

(5)

Abbas Fadhil Yasir and Hayder Obaid Jamel

Fig S13. Shows the XRD patterns for the Cu(II), Ag(I) and Pt(IV) complexes

Fig S14. IC50 for (DPTYEAP) ligand of cancer cell line (MCF-7) and natural cell line (WRL68)

Fig S15. IC50 for the Pt(IV) complex in the cancer cell line (MCF-7) and natural cell line (WRL68)

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