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Dr. SK MOHAMMAD AZIZ

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

Dr. SK MOHAMMAD AZIZ

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(3)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(4)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(5)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(6)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(7)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(8)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

(10)

COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

Hinsberg Thiophene Synthesis: The synthesis of thiophene carboxylic acids from 1,2‐diketones and dialkyl thiodiacetate (i.e., thiodiglycolate) via an intermediate of δ‐lactone in the presence of sodium or potassium alkoxide is referred to as the Hinsberg reaction. Experimental evidence shows that both diester and half acid, half ester thiophene derivatives also form in this reaction. This reaction has been extended to 1,4‐diketones. The formed thiophene derivatives are oxidized to sulfone derivatives by perbenzoic acid.

This reaction has been applied to synthesize thiophene derivatives as well as

furan, selenophene, and pyrrole derivatives.

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

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COMPILED AND CIRCULATED BY DR. SK MOHAMMAD AZIZ,

ASSISTANT PROFESSOR, DEPARTMENT OF CHEMISTRY, NARAJOLE RAJ COLLEGE

CHEMISTRY: SEM-V, PAPER- C12T: ORGANIC CHEMISTRY-IV, HETEROCYCLIC COMPOUNDS 1

THANK TOU

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