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Nonlinear programming for minimization of fresh water consumption in

multi contaminant mass exchanger network

R. Agustriyanto, A. Fatmawati, Y. Fransiscus

Surabaya Univ., Chemical Engineering Dept. Jl. Raya Kalirungkut, Surabaya 60292, Indonesia

tel. +62 312981158, e-mail: rudy.agustriyanto@ubaya.ac.id;

Abstract

This paper presents a formulation of water allocation problem (WAP) in order to minimize fresh water consumption in multi contaminant mass exchanger network. The approach is based on mass balance equation within the system being studied.

Keywords: Water allocation problem, optimization, mass exchanger network

I. Introduction

Pollution prevention is primarily stimulated by economics, legislation, liability concerns, and the enhanced environmental benefit of managing waste at source. Chemical process industries consume a huge amount of water. Consequently, wastewater streams from such industries which contain various contaminants may create environmental problem. The increasing cost of fresh water supply and wastewater treatment has encouraged process industries to minimize fresh water consumption and waste water generation. Water minimization techniques in the process design can simultaneously reduce overall fresh and waste water involved in the process. Hierarchy strategies that can be used to reduce waste within a process are as follows (Perry and Green, 1997; El-Halwagi, 1997):

• Source reduction

This include: modification of equipment, changes in process design and operation, reformulation and redesign of products, substitution of raw materials and use of green technology.

• Recycle / reuse

Typically this strategy involves separation technology to recover valuable materials such as solvents, metals, inorganic species and water.

• End-of pipe treatment

The application of chemical, biological and physical process to reduce waste toxicity and volume to meet environmental regulation.

• Ultimate disposal

Post process activities which handle waste such as deep well injection and off site shipment of hazardous material to waste management facilities.

Similar approaches are also proposed by Wang and Smith (1995) to minimize water consumption which in turn will reduce wastewater quantity. These approaches are:

• Process changes

This approach may reduce the quantity of overall process water required. For example: using air coolers instead of cooling towers.

• Re-use

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