Pembuatan Nanosilikon Dari Pasir Alam Kecamatan Tanjung Tiram Kabupaten Asahan Secara Magnesiotermik Dengan Penambahan Natrium Klorida Sebagai Penyerap Kalor

(1)

(2)

(3)

(4)

Meas. data:SwdSiO2/Data 1 BG data:SwdSiO2/Data 1 Calc. data:SwdSiO2/Data 1

2-theta (deg)

Inte

Lampiran 3. Difraktogram Silika Hasil Isolasi dari Pasir Alam

General information

Analysis date 2015/02/09 13:32:53

Sample name SiO2 Measurement date 2015/02/09 10:44:33

File name SwdSiO2.ras Operator administrator

Comment

(5)

Lampiran 4. Puncak Difraktogram Silikat Hasil Isolasi dari Pasir Alam

Peak

No. 2-theta(deg) d(ang.) Height(coun

ts)

FWHM(deg) Int.

I(counts deg)

Int. W(deg)

Asym. factor

1 5.7(3) 15.5(7) 20(4) 1.3(2) 27(7) 1.4(6) 0.60(17)

31 65.694(6) 1.42017(11

) 59(8) 0.135(11) 11.2(7) 0.19(4) 2.9(6)

32 67.812(8) 1.38088(14

) 194(14) 0.194(9) 45.9(13) 0.24(2) 3.0(7)

33 68.265(7) 1.37280(13

) 237(15) 0.179(8) 52.5(15) 0.22(2) 2.5(5)

34 69.428(11) 1.35262(19

) 69(8) 0.132(15) 12.8(11) 0.19(4) 0.8(2)

35 73.37(5) 1.2893(7) 18(4) 0.29(6) 7.5(11) 0.43(16) 1.2(6)

36 74.206(5) 1.27691(8) 232(15) 0.121(5) 33.2(10) 0.143(14) 0.68(12)

37 75.694(5) 1.25547(6) 279(17) 0.133(5) 53.2(9) 0.191(15) 1.23(19)

(6)

Lampiran 5. Hasil Analisa Kuantitatif Silikat Hasil Isolasi dari

PasirAlam

General information

Analysis date 2015/02/09 13:33:37

Sample name SiO2 Measurement date 2015/02/09 10:44:33

File name SwdSiO2.ras Operator administrator

Comment

Qualitative analysis results

Phase name Formula Figure of merit Phase reg. detail DB card

number

Quartz Si O2 1.082 User (COD) 5000035

Albite, calcian, ordered

( Na , Ca ) Al ( Si , Al

)3 O8 1.379

ICDD

(PDF-2/Release 2012 RDB)

00-041-1480

Weight ratio

Phase name Content(%)

Quartz 72.5(11)

Albite, calcian, ordered 27.5(8)

Measurement profile

SwdSiO2

0 20 40 60 80 100

Quartz Albite, calcian, ordered Unknown Wt(%)

Meas. data:SwdSiO2/Data 1

Inte

2-theta (deg)

20 30 40 50 60 70

Quartz, Si O2, 5000035

(7)

Lampiran 6. Difraktogram Nanosilikon Hasil Reaksi Pada Suhu 800°C selama

6 jam ( Hasil Pencuucian HCl 2N)

General information

Analysis date 2015/03/31 12:49:27

Sample name Measurement date 2015/03/2

3 11:18:50

File name Tahap1.txt Operator

Comment

Measurement profile

Peak list

No. 2-theta(deg) d(ang.) Height(coun

ts)

FWHM(d eg)

Int. I(counts deg)

Int. W(deg)

Asym. factor

1 21.73(4) 4.086(7) 59(8) 0.38(5) 40.6(19) 0.68(12) 1.2(6)

Meas. data:Tahap1/Data 1 BG data:Tahap1/Data 1 Calc. data:Tahap1/Data 1

2-theta (deg)

Intensity (counts)

20 40 60 80

(8)

Lampiran 7. Hasil Analisa Kuantitatif Nanosilikon Hasil Reaksi Pada Suhu

800°C selama 6 jam ( Hasil Pencuucian HCl 2N)

General information

Analysis date 2015/03/31 12:49:57

11:18:50

Comment

Qualitative analysis results

Phase name Formula Figure of merit Phase reg. detail DB card

number

Silicon Si 0.418 User (COD) 9013102

Olivine Mg2 O4 Si 1.191 User (COD) 9001096

Periclase, syn Mg O 1.194 ICDD (PDF-2/Release

2012 RDB) 00-045-0946

cristobalite-beta high Si O2 0.982 ICDD (PDF-2/Release

2012 RDB) 01-071-6246

Graphite C 0.898 User (COD) 9000046

Weight ratio

Tahap1

- Silicon 26.0(2)

- Olivine 37(7)

- Periclase, syn 19.7(8)

- cristobalite-beta high 3.61(17)

- Graphite 14.0(3)

Measurement profil

Tahap1 Periclas..., syn(%) cristoba... high(%) Graphite(%)

Meas. data:Tahap1/Data 1

Intensity (counts)

0 500 1000 1500

2-theta (deg)

20 40 60 80

(9)

Lampiran 8. Difraktogram Nanosilikon Hasil Reaksi Pada Suhu 800°C selama

6 jam ( Hasil Pencucian HCl 2N dan CH

3

COOH 25%)

General information

Analysis date 2015/03/31 12:37:29

3 11:49:55

Comment

Measurement profile

Peak list

No.

2-theta(deg)

d(ang.) Height(count

s)

FWHM(de g)

Int. I(counts deg)

Int. W(deg)

Asym. factor

1 21.8103 4.07168 54(7) 0.36(4) 30.846905 0.57(8) 3.6(6)

18 56.1117 1.63777 382(20) 0.208(10) 104.28947

7

2-theta (deg)

Intensity (counts)

20 40 60 80

(10)

Lampiran 9. Hasil Analisa Kuantitatif Nanosilikon Hasil Reaksi Pada Suhu

800°C selama 6 jam ( Hasil Pencucian HCl 2N dan CH

3

COOH

25%)

General information

Analysis date 2015/03/31 12:38:04

3 11:49:55

Comment

Qualitative analysis results

Phase name Formula Figure of merit Phase reg.

detail

DB card number

gamma-Mg2 ( Si O4 ) Mg2 ( Si O4 ) 1.108 ICDD

(PDF-2/Release

01-077-8453

Periclase, syn Mg O 0.754 ICDD

(PDF-2/Release

01-071-9574

Stishovite Si O2 1.310 ICDD

(PDF-2/Release

01-077-8643

Weight ratio

Tahap2

- Silicon 59.625079

- gamma-Mg2 ( Si O4 ) 19.485073

- Periclase, syn 11.583128

- Stishovite 9.306720

- Unknown

Measurement profile

Tahap2

gamma-Mg... O4 )(%)

Periclas..., syn(%)

Stishovite(%)

Unknown(%)

Intensity (counts)

0 500 1000 1500

2-theta (deg)

20 40 60 80

Silicon, Si, 2104748

gamma-Mg2 ( Si O4 ), Mg2 ( Si O4 ), 01-077-8453 Periclase, syn, Mg O, 01-071-9574

(11)

Lampiran 10. Difraktogram Nanosilikon Hasil Reaksi Pada Suhu 800°C selama

6 jam ( Hasil Pencucian CH

3

COOH 25% dan HF 4,8%)

General information

Analysis date 2015/03/31 12:57:30

3 11:35:03

Comment

Measurement profile

Peak list

No. 2-theta(deg) d(ang.) Height(count

s)

FWHM(de g)

Int. I(counts deg)

Int. W(deg)

Asym. factor

1 15.233(15) 5.812(6) 95(10) 0.16(2) 28.3(16) 0.30(5) 1.0(4)

2-theta (deg)

Intensity (counts)

(12)

Lampiran 11. Hasil Analisa Kuantitatif Nanosilikon Hasil Reaksi Pada Suhu

800°C selama 6 jam ( Hasil Pencucian CH

3

COOH 25% dan HF

4,8%)

General information

Analysis date 2015/03/31 12:57:57

11:35:03

Comment

Qualitative analysis results

Phase name Formula Figure of merit Phase reg. detail DB card number

Stishovite, syn Si O2 1.379 ICDD

(PDF-2/Release 2012

01-076-2979

Silicon Oxide Si O2 1.606 ICDD

(PDF-2/Release 2012

01-075-3170

Ringwoodite Mg2 O4 Si 1.521 User (COD) 9000269

Periclase Mg O 1.098 User (COD) 9006801

Weight ratio

Tahap3

Measurement profile

Tahap3

Stishovi..., syn(%)

Silicon Oxide(%)

Ringwoodite(%)

Periclase(%)

Intensity (counts)

0 500 1000

2-theta (deg)

20 40 60 80

Silicon, Si, 2104748

(13)

Lampiran 12. Difraktogram Nanosilikon Hasil Reaksi Pada Suhu 800°C selama

7 jam

General information

Analysis date 2015/03/31 13:00:01

Sample name NANO_RUNNINGII Measurement date 2015/03/19 10:06:56

File name NANO_SILIKA

RUNNINGII.ras

Operator administrator

Measurement profile

Peak list

No.

2-theta(deg)

d(ang.) Height(count

s)

FWHM(deg )

Int. I(counts deg)

Int. W(deg)

Asym. factor

1 15.336(7) 5.773(3) 477(22) 0.215(7) 143(3) 0.30(2) 1.7(3)

Meas. data:NANO_SILIKA RUNNINGII/Data 1

BG data:NANO_SILIKA RUNNINGII/Data 1 Calc. data:NANO_SILIKA RUNNINGII/Data 1

2-theta (deg)

Intensity (counts)

20 40 60 80

(14)

Lampiran 13. Hasil Analisa Kuantitatif Nanosilikon Hasil Reaksi Pada Suhu

800°C selama 7 jam

General information

Analysis date 2015/03/31 13:05:10

Sample name NANO_RUNNINGII Measurement

date

2015/03/19 10:06:56

File name NANO_SILIKA

RUNNINGII.ras

Operator administrator

Comment

Qualitative analysis results

Phase name Formula Figure of merit Phase reg. detail DB card number

Periclase Mg O 0.984 User (COD) 9013225

perovskite (Mg, Si) HP, syn, magnesium

Mg Si O3 1.474 ICDD (PDF-2/Release

2012 RDB)

01-080-0568

silicon dioxide Si O2 1.467 ICDD (PDF-2/Release

2012 RDB)

01-070-5689

Quartz O2 Si 1.635 User (COD) 9010146

Weight ratio

Silicon 29(6)

Periclase 7(4)

perovskite (Mg, Si) HP, syn, magnesium

catena-13(5)

silicon dioxide 43(4)

Quartz 8.0(18)

Measurement profile

NANO_SILIKA RUNNINGII

0 50 100