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10 – Waste Processing 10 – Waste Processing
10.1 Overview and objectives of waste processing
10.1 Overview and objectives of waste processing
techniques
techniques
10.2 Waste sorting
10.2 Waste sorting
10.3 Composting
10.3 Composting
10.4 Reuse and recycling
10.4 Reuse and recycling
10.5 Mechanical and Biological treatment
10.5 Mechanical and Biological treatment
10.6 Incineration
10.6 Incineration
10.7 Land filling
10.7 Land filling
Outline Outline
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10.1 Overview and objectives of
10.1 Overview and objectives of
waste processing techniques
waste processing techniques
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Objectives
• to reduce the hazardous nature of the waste
• to separate the waste into its individual components, some or all of which can then be put to further use/treatment
• to reduce the amount of waste which has to be finally sent for disposal
• to transform the waste into a useful material
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Waste
Waste
reception
reception mediate mediate Inter-Inter- TreatmentTreatment
storage
storage
Storage
Storage DisposalDisposal
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Waste processing techniques
• Biological treatments and some mechanical-biological treatments
• Physico-chemical treatments
• Treatments applied to waste in order to enable the recycling/regeneration of materials
• Treatments applied to turn a waste into a material that can be used as a fuel in different industrial sectors
• End-of-pipe techniques used in waste treatment installations for the abatement of emissions
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10.2 Waste sorting
10.2 Waste sorting
10.2 Waste sorting
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kerbside collection schemes kerbside collection schemes
• Automatically separated in materials recovery facilities Automatically separated in materials recovery facilities • Mechanical - Biological treatment systemsMechanical - Biological treatment systems
Process by which waste is separated into
Process by which waste is separated into
different elements
different elements
10.2 Waste sorting
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Biodegradable waste components
Biodegradable waste components
• Green waste Green waste • Kitchen waste Kitchen waste • PaperPaper
Other recyclable components
Other recyclable components
• PlasticsPlastics • Glass Glass
• Metals (ferrous and non-ferrous) Metals (ferrous and non-ferrous) • Co-mingled recyclablesCo-mingled recyclables
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Kerbside collection of recyclable resources
Kerbside collection of recyclable resources
Purer waste streams
Purer waste streams
Higher market value
Higher market value
10.2 Waste sorting
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Completely environmentally friendly
Completely environmentally friendly
Global warming
Global warming
through exhaust
through exhaust
emissions
emissions
Increased number of
Increased number of
waste collection
waste collection
vehicles on the
vehicles on the
road
road
Kerbside collection of recyclable resources
Kerbside collection of recyclable resources
?
?
BUT BUT
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10.3 Waste composting
10.3 Waste composting
10.3 Composting
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Atoms and molecules Atoms and molecules
Living systems consist of atoms and Living systems consist of atoms and
molecules (at the Angstrőm level): molecules (at the Angstrőm level): • Carbon (C), Carbon (C),
• Hydrogen (H), Hydrogen (H), • Oxygen (O), Oxygen (O), • Nitrogen (N), Nitrogen (N),
• Phosphorus (P), Phosphorus (P), • Sulphur (S), …..Sulphur (S), …..
Groups of atoms make up living and Groups of atoms make up living and
non-living materials non-living materials
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Example living materials:
human being, animals, plants, trees human being, animals, plants, trees
Example non-living materials: Example non-living materials:
bricks, metal, stone, oxygen, water bricks, metal, stone, oxygen, water
Photosynthetic systems obtain their energy from the sun Photosynthetic systems obtain their energy from the sun
CO
CO22 + nutrients + sunlight energy + nutrients + sunlight energy organic mater organic mater Non-photosynthetic systems degrade energy-rich Non-photosynthetic systems degrade energy-rich
molecules for their growth molecules for their growth
10.3 Composting
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Organic matter such as sugar: C
Organic matter such as sugar: C66HH1212OO66
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Aerobic decomposition of biodegradable
organic matter, producing compost
Performed primarily by facultative and obligate aerobic bacteria, yeasts and fungi, helped in the cooler initial and ending phases by a number of larger organisms, and other families representing ants, nematodes and oligochaete worms
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Compost pile
Compost pile
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10.3 Composting
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Organisms decomposing organic matter
Organisms decomposing organic matter
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down completely under the action of microorganisms down completely under the action of microorganisms into carbon dioxide, water and biomass
into carbon dioxide, water and biomass
• A A compostablecompostable material biodegrades substantially material biodegrades substantially under composting conditions, into carbon dioxide, under composting conditions, into carbon dioxide, methane, water and compost biomass
methane, water and compost biomass
• A A compost-compatiblecompost-compatible material does not have to be material does not have to be compostable or even biodegradable, is generally inert compostable or even biodegradable, is generally inert and is present in compost at relatively low levels
and is present in compost at relatively low levels
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C : N ratio
C : N ratio
Carbon
Carbon e.g.e.g. in the form of cellulose which the bacteria need in the form of cellulose which the bacteria need for their energy (dry, straw-type material, such as
for their energy (dry, straw-type material, such as cereal straws, leaves, sawdust, wood chips, paper, cereal straws, leaves, sawdust, wood chips, paper, cardboard)
cardboard)
Nitrogen in the form of protein, which provides nutrients for Nitrogen in the form of protein, which provides nutrients for
the energy exchanges (green plant material such as the energy exchanges (green plant material such as
crop residues, hay, grass clippings, weeds, manure of crop residues, hay, grass clippings, weeds, manure of
poultry, herbivorous animals such as horses, cows and poultry, herbivorous animals such as horses, cows and
llamas; fruit and vegetable trimmings) llamas; fruit and vegetable trimmings)
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Active
Active
• exothermic action of the bacteria as they decompose exothermic action of the bacteria as they decompose the organic matter
the organic matter
• close to ideal conditions close to ideal conditions
Passive
Passive
• level of physical intervention is kept to a minimumlevel of physical intervention is kept to a minimum • more common type of composting in most domestic more common type of composting in most domestic
garden compost bins garden compost bins
10.3 Composting
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Home composting
Home composting
range of techniques, from extremely passive (throw range of techniques, from extremely passive (throw everything in a pile and leave it for a year or two) to everything in a pile and leave it for a year or two) to
extremely active (monitor the temperature, turn the pile extremely active (monitor the temperature, turn the pile
regularly, adjust the ingredients over time). regularly, adjust the ingredients over time).
Industrial composting
Industrial composting
waste management alternative to landfills, along with other waste management alternative to landfills, along with other advanced waste processing systems
advanced waste processing systems
combined with mechanical sorting of mixed waste streams combined with mechanical sorting of mixed waste streams is called mechanical biological treatment
is called mechanical biological treatment
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Materials Recovery Facility (MRF)
Materials Recovery Facility (MRF)
Specialized plant that receives, separates and prepares Specialized plant that receives, separates and prepares
recyclable materials for marketing to end-user recyclable materials for marketing to end-user manufacturers.
manufacturers.
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Clean
:accepts recyclable materials that have been collected in comingled wastes from kerbside collection
separated at source from municipal solid waste generated by either residential or commercial sources
Dirty:
accepts a mixed solid waste stream and then proceeds to separate out designated recyclable materials
through a combination of manual and mechanical sorting
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Facts and figures Facts and figures
• Landfills are used for less than 10% of all waste. Dutch Landfills are used for less than 10% of all waste. Dutch household waste recycling averages to 60% (2006).
household waste recycling averages to 60% (2006). • Compost (2003): Compost (2003): The separately gathered organic The separately gathered organic
fraction is 50% of household waste, or 1500 fraction is 50% of household waste, or 1500
kilotonnes. This is processed to 600 kilotonnes of kilotonnes. This is processed to 600 kilotonnes of compost
compost
• Paper (2005): Paper (2005): In the Netherlands the recycled amount In the Netherlands the recycled amount in 2005 was up to 2.5 million tonnes, which is 75% of in 2005 was up to 2.5 million tonnes, which is 75% of annual consumption.
annual consumption.
Recycling in The Netherlands
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10.5
10.5
Mechanical and Biological
Mechanical and Biological
Treatment
Treatment
10.5 Mechanical and Biological Treatment
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uses living micro-organisms to decompose organic wastes uses living micro-organisms to decompose organic wastes
into water, CO
into water, CO22 and simple inorganics or into simpler and simple inorganics or into simpler
organics such as aldehydes and acids organics such as aldehydes and acids
Biological treatment
Biological treatment
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Several biological treatments
Several biological treatments
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Activated sludge:
Activated sludge:
Decomposes organic wastes in water Decomposes organic wastes in water
by exposing waste to biological by exposing waste to biological
growth. Water is recycled and growth. Water is recycled and aerated to facilitate biological aerated to facilitate biological
action and a sludge is generated. action and a sludge is generated.
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Aerated lagoons:
Aerated lagoons:
Large lagoons containing high concentrations of Large lagoons containing high concentrations of
micro-organisms. The lagoon is aerated to encourage bacterial organisms. The lagoon is aerated to encourage bacterial
growth and decomposition of waste. growth and decomposition of waste.
10.5 Mechanical and Biological Treatment
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Composting:
Composting:
‘
‘Engineered’ mounds of waste are built to encourage the Engineered’ mounds of waste are built to encourage the
biological breakdown of organic solids, producing a humic biological breakdown of organic solids, producing a humic
substance valuable as soil conditioner substance valuable as soil conditioner
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Aerobic digestion:
Aerobic digestion:
Reduction of the organic content of waste. Applied to solid Reduction of the organic content of waste. Applied to solid
waste, non-continuous waste waters, bioremediation waste, non-continuous waste waters, bioremediation
and to sludge and soil contaminated with oil and to sludge and soil contaminated with oil
Anaerobic digestion:
Anaerobic digestion:
Decomposes organic matter in closed vessels in the Decomposes organic matter in closed vessels in the absence of air. Uses two forms of bacteria: absence of air. Uses two forms of bacteria:
acid-forming and methane- acid-forming. Applied to solid-liquid forming and methane- forming. Applied to solid-liquid
wastes, highly contaminated waste waters (e.g. wastes, highly contaminated waste waters (e.g.
chlorinated compounds), bioremediation and in the chlorinated compounds), bioremediation and in the
production of biogas to be used as a fuel. production of biogas to be used as a fuel.
10.5 Mechanical and Biological Treatment
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Form of waste processing facility that combines a sorting Form of waste processing facility that combines a sorting
facility with a form of biological treatment such as facility with a form of biological treatment such as composting or anaerobic digestion
composting or anaerobic digestion
Mechanical Biological Treatment
Mechanical Biological Treatment
Typical mechanical elements: factory style conveyors, Typical mechanical elements: factory style conveyors,
industrial magnets, eddy current separators, trommels, industrial magnets, eddy current separators, trommels,
shredders and other tailor made systems shredders and other tailor made systems
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10.6
Incineration
Incineration
10.6 Incineration
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Waste treatment technology that involves the combustion Waste treatment technology that involves the combustion
of organic materials and/or substances, "thermal of organic materials and/or substances, "thermal
treatment". treatment".
Converts the waste into ash, flue gases, particulates, and Converts the waste into ash, flue gases, particulates, and
heat, which can in turn be used to generate electricity. heat, which can in turn be used to generate electricity.
Flue gases are cleaned for pollutants (particulate matter, Flue gases are cleaned for pollutants (particulate matter,
heavy metals, dioxins, furans, sulphur dioxide, and heavy metals, dioxins, furans, sulphur dioxide, and
hydrochloric acid
hydrochloric acid) ) before they are dispersed in the before they are dispersed in the atmosphere
atmosphere
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•
moving grate
moving grate
•
fixed grate
fixed grate
•
rotary-kiln
rotary-kiln
•
fluidised bed
fluidised bed
Types of incinerator plant design
Types of incinerator plant design
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• Dioxin and furansDioxin and furans • Carbon dioxideCarbon dioxide
• Other emissions, including sulphur dioxide, Other emissions, including sulphur dioxide,
hydrochloric acid, heavy metals and fine particles hydrochloric acid, heavy metals and fine particles
Gaseous emissions
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filters filters
• Acid gas / basic scrubbersAcid gas / basic scrubbers • Dry desulfurisationDry desulfurisation
• Catalytic reduction (SCR) or selective non-catalytic Catalytic reduction (SCR) or selective non-catalytic reduction (SNCR)
reduction (SNCR)
• Adsorbtion on active carbon powderAdsorbtion on active carbon powder
Flue gas cleaning
Flue gas cleaning
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• Fly ash and bottom ashFly ash and bottom ash
• Fly ash constitutes more of a potential health hazardFly ash constitutes more of a potential health hazard • High concentrations of heavy metals such as lead, High concentrations of heavy metals such as lead,
cadmium, copper and zinc as well as small amounts of cadmium, copper and zinc as well as small amounts of dioxins and furans
dioxins and furans
Solid outputs
Solid outputs
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Flue gas cleaning
Flue gas cleaning
NEUTREC® flue gas cleaning process (from www.neutrec.com)
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10.7 Landfilling
10.7 Landfilling
10.7 Landfilling
10.7 Landfilling
The presentation on landfilling is
The presentation on landfilling is
provided in chapters 18, 19 and 20