LAMPIRAN 1
Perbandingan komposisi bahan LTO : PVDF : AB
LTO : PVDF : AB = 85% : 10% : 5%
Perhitungan Massa Bahan Li
4Ti
5O
12Persamaan Stokiometri :
Diketahui massa atom relative masing-masing unsur adalah :
Ar Li = 6,941
Ar O = 16
Ar H = 1,008
Ar Ti = 47,87
Maka berat molekuldari masing-masing bahan adalah :
Mr. LiOH.H
2O
= 41,9988 gr/mol
Mr. TiO
2= 79,997 gr/mol
Mr. Li
4Ti
5O
12= 459,9383 gr/mol
Massa LTO
= 10 gram
Menghitung jumlah mol Li
4Ti
5O
12
0,02174205
molMenghitung massa LiOH.H
2O
Perhitungan mol LiOH.H
2O
x
Perhitungan massa
Menghitung Massa TiO
2
Perhitungan mol TiO
2Mol TiO2
=
Mol TiO2
=
=
0,10871025
mol
Perhitungan massa TiO
2x
Mrmol x 79,997
LAMPIRAN 2
Menghitung Nilai Konduktivitas Sel Baterai
Dengan
Keterangan :
= konduktivitas sel baterai (1/
Ω
cm atau S/cm)
Re = hambatan elekronik (Ω)
Rct = hambatan transfer muatan (Ω)
A = luas permukaan persegi (cm
2)
= tebal lembaran (cm)
Z
total= penjumlahan dari hambatan elektronik dan hambatan transfer
muatan (Ω)
M-
1 (ketebalan 50 m)
Ω
Ω
=
M-2 (ketebalan 80
m)
Ω
a
b c
M-4 (ketebalan 120
m)
Ω
Ω
= 1,58
Menghitung Energy Density
(
)
M-1
(ketebalan 50 m)
M-2 (ketebalan
80 m)
M-4 (ketebalan
1β0 m)
Menghitung Power Density
(
)
M-1 (Ketebalan 50
m)
0,0017
M-2 (Ketebalan 80
m)
0,005
M-4 (Ketebalan 120
m)
0,0067
LAMPIRAN 3
Gambar Bahan
Serbuk LiOH.H
2O
Serbuk TiO
2Serbuk PVDF
Serbuk Karbon AB
Alat-alat Karakterisasi Penelitian
Alat Uji CV/CD (WBCS 3000)
LAMPIRAN 4
Analysis Results
General Information
Analysis date 2016/03/07 17:50:03
Sample name LTO Mia Measurement date
File name LTO Mia.ras Operator
Method Rietveld
Measurement profile
Intensity (count
s)
0 100 200 300 400 500
2-theta (deg)
Intensity (count
s)
20 40 60 80
Peak list
node1 17.48
Function name Shift axial displacement param0 -0.040801143214112399 Decay rate factor etaL0/mL0 1.36(19)
etaL1/mL1 0.36(7) Decay rate factor etaL0/mL0 0.27(10)
Structure parameters
LTO Mia Lithium Titanium Oxide Li 0.625000 0.6250 00
0.625 000
0.172 0.500 LTO Mia Lithium Titanium Oxide O 0.388100 0.3881
00
0.388 100
1.000 0.500 LTO Mia Lithium Titanium Oxide Li 0.000000 0.0000
00
0.000 000
1.000 0.500 LTO Mia Lithium Titanium Oxide Ti 0.625000 0.6250
00
LTO Mia 8.3572(4) 8.3572(4) 8.3572(4) 90.000000 90.000000 90.000000 LTO Mia 4.5909(5) 4.5909(5) 2.9579(4) 90.000000 90.000000 90.000000
Crystal structure analysis results
Indexing
Phase name Formula Figure of merit
Phase reg. detail DB card number
Lithium Titanium Oxide Li1.33 Ti1.66 O4 0.580 ICDD (PDF-4+ 2014 RDB) 04-009-5069 Rutile, syn Ti O2 0.520 ICDD (PDF-4+ 2014 RDB) 04-004-4338
Quantitative analysis results
Phase name Content(%)
- Lithium Titanium Oxide 77.3(10)
- Rutile, syn 22.7(6) Rutile, syn 4.5909(5) 4.5909(5) 2.957
9(4) Lithium Titanium Oxide 227 : Fd-3m,choice-1 8 0.042 3.469
Structure determination
Refinement
Measurement range: 10.0000-90.0000deg Refinement range: 10.0000-90.0000deg (1.09 A) Number of refined parameters: 41
Phase name Atomic cords # of indep. reflns
Lithium Titanium Oxide Fractional cords 19 Rutile, syn Fractional cords 20
Rwp = 38.45% S = 1.1692
LAMPIRAN 5
Sampel M-1
V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL
V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL
0.00E+00 5.00E+01 1.00E+02 1.50E+02 2.00E+02 2.50E+02 3.00E+02 3.50E+02 4.00E+02
0 50 100 150 200 250 300 350 400
X
Ħ
V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL
0.00E+00 2.00E+02 4.00E+02 6.00E+02 8.00E+02 1.00E+03 1.20E+03 1.40E+03
0 200 400 600 800 1,000 1,200 1,400
X
Ħ
