Performance of Repetitive type of Biogas Desulfurizer Made From Steel Chips Waste.

(1)

,irat::2NsJ

?.

i

i:ai

97R:(A2-11',16

-06:7

'

:.-,

.r;€

t--

(2)

2"d

Sustai

lntemalional

Conli|cncc

on

rrebF

lecLrrclocY

t)c\.cl{)Dnrenl

(rcs

r

r))

Brli.

October'

PROCEEDI}.IGS

t0l

t),^\',\\1 LlNl\'Fll!t

r(rl1

"Dr

tc!,'ftuX Su':t,ttnal'h

1,,

lt u'logv

(3)

;,P.OCI] DINCS

sci.!rifi(

(onuir!.(1

l,,oi

I

Nx\i,

Red

ia(unr\ia'lr('<'ntrl"d3Nr:t

ItotSariql'(Pr.:

.d.4\vorld

lter.\rabl. Encrgr)

Pnii

rt,iKu.chli(alioobulNxtonrLUr\cbny,S.d[(or.a]

Iha

Bunh lilrrirM

(UnLvivcBily olwalloncon!,

A!$El;)

rrol

Jac ky.o Lnn(Chorbul Na!o.?l Unn€sny, Sou(ltKora)

P'ol Htr Ru,hur iHuangh. UDivc^ryolsciercennd T<hnolo,ey, Cl',o1)

rrol: Monbscr

Dcudr

(s.ur!i

vall.r

UDtrcrsny.Eg?t)

Pr.i A€\indcraur,bd (LJrv.r!,\ orNc!

so

hwals,Auimhi)

Pmr Tlori

cd

Tin? \:ndh,r(LnL)r Ltr

ltrrr'sny,

Indoncsh)

r'.r l\1.d.,\li K.tiq

s

(tjdi\{r

U.LveAn!,I'ldoneni) r.'rLY.lml.Dena)

Lt !u

cof-! rloi (llo ch,11,nh

c

l)r

r,1[1

slii

rr (Ud.]yarx (i'n\.r$ry.Irdoncs;a)

Dr

\\ .,.J! An.nm(lrdrrrn

L

r{'rr,rd.ndiia)

l,

I)

rl

PrL\trDrru

\'

(r'ii.ij.i

i, (i'tr!.'aty.

lndoncsn)

.i

I

r\rn'y.

rrd.rcir)

I

nr$i.!r{xl(

.nLEnce.'t

S!.r!,nrl)1.

.rltrd.-r!

D.vek)p'ncnr

t\,

I i

lI r!

St

dr

i,rtbl e

k.h'!

olotr

(4)

NIECHANICAI-'}CI\ET'R!N(;

t\l dl

(

)

I

Fur\

I'll)

RJrio

Cin

(rlld of

01)

C.nriu.0:l\ \/I'rhlc

lirtsmisri.

Irt

0l

0D

ljo)

(tD

ll0)

(rD r

ri)

MI

OD

2

t]2)

\i

r."

lD

lri

Th.

\r,'rh.d olirlrfc

tu

rbe' 1nd rlrcturation:l

ot.rrl.r fl

rh.

,.n.ui

NnJ nccuLicn..

dirriburirN

olrlre crem and

Enr\rLl'

Nnd|.s.rnrachine

.

tri'.,i,.r.

.il

F

n'rl'r'L

"rP'.r

'

r-ri

r' n,i dAlr'

rium

inn.

Srudt

A r)_s,!.1

Fooi

Serits

lrnn!

nfun Ma.lrire

a.iiiu::tr,,r

\rr.l.r*

Hi,al:.rs o! \\Ic1il!g

Al!r!q!r:r

\1C

io!l

",,h\\.id..t

tur

Nl.lrl

lred

Gs (Mlcl

lnd

Tu.s!.n

l'1e'1Grs

d

Crea'i-M{nulrdudrg

Fro(6

For Sman venical

Axn

\vind

lu'r.r

bl"d<

Srul!

PhFaland

Nltchrn,cal Pmpcdr6

olVcAckl

Maknal'i

*aj,"

roLr"y.rsr""

r"

ca

CfD !s AidingTool ro

l''!dict

Airflov 3nd Tlrcmral Perlonn.ncc

ol

lluildr

gs.

Ca:r

Study:

AnooN

ta(c

and

Tlr'nnxl

le

h rn

rr' r',l

.

o' I nn

^r)ufAr"ir\'

Lrl.d

.f.lrcnri.rl

!.arrrnls

on

rlr

rcnsilc

steDsrir:n,l

Il3nnni|ilil\

ol

F|c'

nrulb$ j_ fiher r.inlirccd Pl A

rornNnt!'

I

r.

r\\scnnnrq

I'ne{ijlfrn

fl

Tlnee Nhcels

B'.!cl€

Crrf

(lt)

\II

\'1

rl

v

2l

\1Jl

i!{

,0

\1 Sl

('

Ff IO

--

-ftrfordanec ol Repenuve lyp. oa Biogas Desul turi7f,r lllade rlD

ll0)

frofl Sreel

CtipsN.

rjolodrc]

r:n!

Nr

D

i{

6l

I inc

^Icr\urcinlrr

Nlcr|od rr Pt

\

\l

l0l

l.rLLl. And lDprcl sr,€ngtlr

ol

tslmboo I'ibcr

ltci'rlo'..d

FN\l

(inn|dil€r

A\'\lr

rxtnt

\lrl."rll

Fo' Abo!€

K

cc Pro{h.u.

(5)

NI

l0 (lD

ll0)

of

llcpciitirc

typc

ofBiog:'s Destrlfu.izc'

M.ile

lronr

Stccl Chips Wasie

tldiy lrh

a

NriG,\R

:,t \l'dc\l

(IPTAI

(,\',

Dcrn Ngrkan Xeiul

I\nF lLC'\R,\l

.h4!d,lht4dj@ad

lbdEtr:

lhis rts.arch d.\clop.J Etcnri\e

rtpr

oi

bi3rs

desullnri-r

br

url'/ng

\i!e

rcl

chits tum

n€kl

lo.rin-!

Proc.ss ot

tuniie

lhe:nnerling

Ftes\

\$

(trdrctetl on

relchit!

prior con,t:crnr.! ro y eld

r hillcr

lhe purpose

olrnn

lins

\rs

ro:li,.i',dc

rhc

drdual sr.ers

b

\.

rs

b

l.r

tlroY

dtrron to oJcuri'r ordcrroobhrf

tr

r.\rd.

.1;rcsdual

rrcss .liDrinrrdd.

tlt

st.lc\in\

is

l{sr

hle

r,

corllj.dnig as a biller Tlr.

rl

r.r

inq Frocc*

sascrmcd oLr b-\ bunrlfg rlre r.on chrp ar 900(Cl Dunng$c annealir-!

fl...sr

dle mo

rli!l

dd

Nith o\teen

!)

Iorn i

on.iid.

(|cror) inJ il dunng oxidario. diere is

I

\rcr

uPor

rl

drairhc

$.

iron bogore fe(Oll)r {i1l tE

lbmtd

BorholFerorand Iic((lllr.

rr.

rercfve

biljslnd

therelore Jblc r! eli!rinrts 1he HrS conraninanr iosido thc bio-qas

Iti.r.suhlron

de process

ol

il.sulphuiarlon is p'e.lpirarion

of sulfur

(S) in the

rom ol

li.isr

in rhe iurlace

orn..Lchips \hich

sill

r.duce rhd perfomance

ol

desulfun?€r Ihe rllcctivirv

ol

desultuizer rhcd is rc..vsr by rca.ritrs nre

rqsr

in $e

e.re

Iimc wirh O: rnd

ll

o. rh.rcior.

d€ desullui,s.aD be u5ed rePdnilely

Ke!

\ods

hydrt,g. nrllid.. \an€.

n

i

.h N. I uming pruc.ss. bioga

I.INl

RODLCIION

Jhis

\rrli r

!odriNitrg

lor.!r

ilihll

\orL

lnidJlri.

:1)ll)

As

r:lr.nrdi\e

Lr

rhe

FD!\ibl.

.tr.,g]. rlre

unli^loir

01 hio33s

llurld

be _Pfttnorcdespeciall' lllr tre

d*.lopng

.otrDlnri drc tr) lnnpltrn\

$d

lo$

co! ol

irr5hlldnr

A

i'nprove'neDr 1.r h.ter ptu.css

ihorldriorLl\r\\nrrJu.tlorrhco0ri'n,.rcn,lr,\ssellkm\\nrharhv{h):entullldc

lll:S)

rL1\r\i ldniJ nr ih. ho!rs

ind:t rrillt

ln rhe Lle!tL)tin! county

fi.

bro-!ns di!ensr

t.

n!i

r)

rrl(.,!

\irlr

roiPn.r{

t)

radr.t

q

.hdri,n .{l rh. H'S

c.fl.nrni$r

Snnn'.r'1lre

ligrn.i

i,

rl,.

,ic'rL.+,i

cotror

y

r

.!rfnd.J

\rnh

..

p.nenr

lnr

lihe.og

rhc HrS

R,ir.ri

r.lirr

1l,.

r(,..r\

qtrile

!.irlrliii.Ll

rnil rlilli.uh 10 b.

i'npl!nr$r.d

, Je!.loting .otr

n.r

ilr!j,.:,.

nna.le

r.

hr

ni,

gij

r

Ll

!.

₎

..

kItrc

t.

ncrt! rhtr.oriftle rhe novt

s d.fi.rrd

r r

rh.lr!

I \

nrlrc.scr.us

Fifhlrn

d0.ro e\incnreol

rh.ll:S

nrllr

Biu-!.s is

iirli.In!!.

r us.d

!

l

lndl lor

tl,.

i

trirl(nnbrnioo

cr-line

Lr.hd,ictrl

_{Sene'Ior to.}

innr

!r

lh.,nnhuiF, !lI.,br'

riLl

hIJLI!r,.dcrnJ

r

luNriotr

.t

Lllrrxnr

.l

11,.

srllLr.

rLllJiL

(io|.r.l. t\ctsi\e!!rni.i\llo.c!rrliointtupriol.rhrtrrrj_{.nrr

I[.

p,i tr

Fl

:.rl

ofrlns reserrch ]s

h,l€rcnT no,'licrt.d

!onrponenr in rhc bLdstrs

Jilcn.r

:)i.nr

rrrii

Ll,. HrS co.rxirinanr

ni{

I

h!

!\.!l

r.ntrntrclv lnor orLy on. hDlc

u\cl

Lhe

n)rn

rt

rtrt

\iL

b.

tr\.d

i!

Lrl usrD: rriL Td

!n

r

l.hin\

rrt{r

rrnc

lor lhe

nmD:

_f

rtrcs

ol!(iqndt

rrqh4ne

t\raff.Ef4

e

(6)

Iig I

is drc sasre rhe iron chipsohai.cd tron

'..ydc

rhis lbD

chips.,6ic

r" beconE biogas

ihc rdr'

in! nrulcn

rila

\hortLlkd

pmnrr

rLo'n rhe HrS cu, J,n,nJr, _(Ni

EXPT

J

'\

dr d

hprhh)

Erd,,J4v.r,','nr,,,,'en.nr

Hsinrhelevctof/

Iri,Jrustr'bd'mmrch"'t.\!oqkn.,n,,.rn,bioeLjorrraerqua.,.,otco,nbu{ioo

J

r rrhncruon

pdr!

in

rh.\ombrron

!ta1cr

arod;, rmpondnr;3{r,

.heH.s96

isl,rmful

dnd penonared _a6_riat_shourdbe mirinize ns exisre;ce _{in rhc}

bi.oi{

2. I,I'I'[R/TTTJRE STUDY

ri l\J'.!

{lt'h iH(r .,.tut,

roundd,co

Jn

nd ir

rh.

,'-

"tcd

rhrdtugcn.d,i..,.t..i,

ioel.

Jndd.4dt\d\.,..4\m.rc!.!.

!.

n

tr'npr.,n'e,dt

rhed,

.o\.n,d.o,I'c.,,

.m,nr

_n

t;n:,co,i",ppi. n

_ro,

r

fi'.1

ol

mtmal

c.mbunjon engine

(ibboos.

_{r9?8r Smith,}_2OOl,

wi.ci6rer,

_2002:

thc r.suh olcombu ion oflhc

lns

ur coDhtD ItrS ir a srlau _and_sufunr

..ro$e

lo mcrdls The I{2S coDr.rr rhd rcxrh 100 ppm c.n cause dearh i

lic.

5.(a)

l.)?r)

Ortrr

{urcc

ak6 infom lhar r1r

H.S

conlahimr _w,ll_rcduce_rh(l

(7)

ji

_rlic

iIillrhon

n, r!lnd,

rl(

l.n)!is

D)

tr .d

ll'(

'bl.i

t J.

\i!tr,]'J

'

r,

re\u'., h.Jtrb'.ri,

iL

l!u'.J LrLLlt!

_'

r.'

cr JrLl rriD.s

h.L

rd\cr

_-lcden{iof

n

r[n

gr

nrorli

elirnrxlcd or inhatr\.r. 1008. Nnrdhii. 2012)

a.r{rrns"rnn

lhc

t:or.

Borh

oi

(hr\ reaclnio

&sulphurizr,

oi

pmc.sscs as

2Feiotl)i

:tl,S

Jlersr+6Hral

Ferq+

jH.s

rfersr+lHro

Nh ch rlre tlrS

n

ol\.d

\ill

Iitld

tht

nn phur oride

lhir

.

Td rhe h'lni.rD oild b.conre rc,d

ii

(

n

0scd in the

(Crll'>) lhcLc ioir

t,

d\oid rhe

nrn

_lecrNrJ by

HiS-ir

l€asr l,a\c ro

redlc. ,

rhc

sl!.

llreublsin. daD

lr89 ,n Nindhia.20l2, H:S

n

po$ible

r.

td!.c

b!

consid.r to

ll,S

will Eacr

b

lhe bos notr ote (

[e(Olln)

or

ton

oxrdc.f

is sinrilar and rccolnize rs rhc rvny

lLr.lmimre

tlrs

bv dry

$itrcn iD lh. Fquaridn (l)axJ

(l)

(2)

IlE

r.\

r

l,on] rhc plocss

cl

dcsulphurizatio

h

cquardn

(ll.rd

(:l

is preciPibtion

i'nohdr

ls ',

llrc

lom of

Fe2Sl

in

lhe s0rla..

ol

nccl chiDs

*hich

sill

r€drce

dom.i ,r -rlpil,/.Ior lorccorflr' r'. tr\"ru

'ltu"nor

nroe<

;.,.. ' .' .

LrqLrnrroor'/d

r

b)

"

r

"

l\'le \'

lrhc

Jmcr

neqih

;dH

()..,-,

-!FloI',u"rl.

clenenLrr

"aJc'blern

o"rSF'n1Jr

':008)

Fe2Sl'roll6ti2o

-)

rIelOH)3 +6S

I1leelc

ref'ol

n'llurrhenwasclcanedbvno$itrswarerinroih.d.nrlndzer

3. F,XPT,RIN'I

fNTAL

A6 iDftnn.d d orr

i'iital

$ork (NniJhii.20l2) th€ e\NriDenrrl

\r\

{dd.d

bJ r.lecting ihe

s6re ol

n.c!.hirs

Onl\ rplal 3nd

l.n!

qpes ot chrPs

\!cc

s.lcr.J

Lhtxnd.a!ingptucss

q .o

ucrtJ nr

rf.

fum.cc

b)

huni'rg

$e

chits ur 900"C

\

rh \lo$lr- coolins The

oxidarior pr.csss NN

!l!o

h.ppetr dunng process

ot dncali g

!!

vL.ld F€rOr and also

Fe(Oll),.

l:j!.

1 is rhe app.rrmcc 01 rhc clrips afier rnncaling a d

o\idlrior

_nroc6s.The

Esuh

lio r

procers

ol

.dnerlin.! is

$.

non .hips

$nholt

rcllul $'s'

due ro

trning

pro..r\ rh.r.lo c

lroilbl.I.

bc

r.

rf.clsd

d

bill.i

lhc si7s.1

tr.h |r

icr

$6

I

cm of

diclidls \nh

6.nolliiitier.

r.d

rhc

\F'Lhtus

j0 grarn

8\hn\n

iI

li!

1

Tle."nlr"rr!

1,u....

"r

$ndurrd

by

using.Jll.dricil

J'c.rrd

(!rLprdcd bv using

iyoo,'li:

1-*;

r-r

nthf.

lh.r.

\€rc

l0billd$r\Ptu'

ed;r rh\

6€r.ch sith

dal

seilll.iri0:rxo,,\ir'$rrJai.l,rllttr\ctscrirrrlrc!iteflhi.gi'

ii.

thcbioe.srhen

td

lld\c,l

ir nia

tl,. r,iler

\ith r1(.1r

rb.utO

l

Llrerrhou

lhisllltr!

'Jt

trtrnrlerageoi

dt

rlo",",.,i

rl.

U,,r".,,r.n

lor

.

hous.hald lhc |Ln:rs

c.or.

t.rioi

bebrc aM

di$

nrsiii

d,r h,lL(

rlrr

\!rsLlertrt.,l

dd

nieasn'cd

btusii!

-!x'riri'/.rbdes'ribedin

r'g.it"t

i,"-"^,,.'"".,"'1,tr'.\.rtuhrnslon.rprorrnr

Ld!.rhn)gai

rlrd llow

torrh rhe b,iL.r

Tl,.r,11'mn,enrotrhe!Ar'3sconduciedhiLFri-!\n!iienr'r'rNcanbd

lrbo\nd

Fi{ jtl)r 1\i \ih tr :011i

(tr

(8)

lier

l00lir.A

olbiosas pasirs desul tun zer, rhc ptucetsot

l''

_{rccolcry s.sco.ducred}by

lur dicdcsulJi'r^rri

b

rhe warer wnh bubblins an

i.

order rercrion nrcqurrion

(l)

ro

ecu.

Ihc perronnh.€ or dcsulluriztion alrer

l"

rccolery ltrcD w.s evallarcd bv neddring rhc

HrS

.onr.ntlior

helore and rlrer pNinS rhc JcsutturiTcr To

en$c

rhdr rhe denrtfunzd

c.n be us.d

r.0.riri!.l\

2'i

ccdrery was

c.rdud.d

rgdrn

rtirr

pasrn! I()(l

liler.fbiogd

rnd

teie{lxgi

I

ns _{o.rLmanccaRerrscdadcsLlnriTer} to. r rc nc\r t00

tnrr.tt

o!a. ftc

r.srll

is

!i,.inr.Lln,

_{rhc Sraph}_foranrlyze

.1. _{RESrir_}

[,\ND

_DISCUSSTON

,\

J!sni\ctuiulrisobrrinedinrhisrerarchrb[nriteposrb]ero,

rh.Nrneot{eel

_chipsro

b.

uscd xs

i

l.nrlplru'i2xrion ol biogas reperirn€l)- l.i.!ue

6

sltre!,iptrotxbitirrol

r

d.nrLlitrlz.r !1

i'rrirl

_Frfonna.ccricrlassrng 100lire.

ni btr,$s

lnnial\

(tje _desutiunrd

lrL

i

l. ,'

e

oufLirntrds'Jor t-J...,

,..0,.t ,nrt,*.

ao"d

r0% _{3nc'rsc rr ruriiy.borr:100 |nerofbjogas}

(.)

(b)

Fr3fe 5 (a) Poiabb HrS

sr.i.

yd. (h)volun(

rd{

(9)

FrlondDce

ol

desuh'nzer arrer lrtEcovery is p.o*nled in

Iig

7

the

lErlbmcc

N

significandy ro e.ch 90% andjusr a iinle

da€de

unlil E.ch 35o/o atier passing r00 al

biqas

Finally rhc Esuh lrom 2'd

Rolery

is depicEd iD Figure S. The

p€rfo;dce

&$ltui/-

-'i1'n.

red e ro Ea!h ooeo Md g'adrd'l)

de.re.*

.9

ro red!h

aourJ'0oo

(10)

Fisu. 6 The p€nnmamc urd6urfu

5.

CONCLUSION

ft

cd

b€

onclud.d

lh:r

rhe d6ulfuii2er rhar

is d€v.loFd

in

rhis

resdch

is

succa$tully

!o Edlce

H,S impuriry

in

rhe bioeis Ep.rirively.

rhis is ncer

ds

fun2er can b€ ue

ml

only one tine

6

d6ultunu r tt'al _{avaitabte in the}_mdker

bur can be ued Fp€div€ly.

€

ACKNOWLEDGEMENT

Thisrese.rch was suproned financiallr br' rbe minisrryofndional cducarion of lh€ Republi

of

lndo.c\ia rluurgh dnder

lonmq

nuhbr,

r2)Sp,H/pUDir.t

rdbn

_{ll_.10t2 uod(}

Scn€nc oaNrtjotul Srratesic Rcsercb

cnnt

_lHibahSkin Sbategis NasiohatJ

REFERENCES

rreublein. D.,dan Srcinhau*r, A..2008. Biog,s

rron

W.st. and

Ren*ibre

R6onrce5, Wiley-VCII Verlae CmbH & KCaA- Federal RcNblic of

Cem.ry.

GibboDs.

J

ll.

1978- fnergy

froh

Bioloeiot Proc.sses,Mccas Hilt. tnc.New

yo

.

Nitrdiia. T C.T.2012, R.noval of H_l drosen _Sulfide(B2S) Conhhinant _in_aiosls_by

Urilizing Solid W.ste Sr..l Chins

lron

Th. Pmc6s ofTurning.Ihe 27dl

lnrenarionalConleFnce on Solid warc T(hnotoAy and Manrsenrem Mdnh

rl-14.2012 Philrdelphia. PA U.S A

Polpm*n. C . I t89,

Orgrni.

Nrste fiec) cting. John Wiley & _SonsLd, _C,€ar_Rrnain

snnh,

J

w,

Meffe. S.,

walron

P

s.

rnd Ellenor,

D

T. R"

_2001._Hydrosen_Suttid.

.emovrl?ro(e\r. US P,kn No DLlT

l-0

M68

(11)

h.srcr,

L

L..McMullin_Nl J..lluDr,J K..2002,ll€'no\ing llydrogen sulfidc

tr.n

A Grseoni

Mirlure

Using

t'crric

Ions Bondcd 1o Calcin.d Diatonrjle, IJS

pier

No 6.500,217.