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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1

Chapter 8 Solutions

8.1

Solutions

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2

Solutions: Solute and Solvent

Solutions

 are homogeneous

mixtures of two or more substances

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 4

Examples of Solutions

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 5

Identify the solute in each of the following solutions: A. 2 g sugar (1) and 100 mL water (2)

B. 60.0 mL of ethyl alcohol (1) and 30.0 mL of methyl alcohol (2)

C. 55.0 mL water (1) and 1.50 g NaCl (2) D. Air: 200 mL O2 (1) and 800 mL N2 (2)

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6

Identify the solute in each of the following solutions: A. sugar (1)

B. methyl alcohol (2) C. NaCl (2)

D. O2 (1)

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7

Water

Water

 is the most common solvent

 is a polar molecule

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc.

Combinations of Solutes and

Solvents in Solutions

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 9

 are hydrated in solution by many H2O molecules

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10

When NaCl(s) dissolves in water, the reaction can be written as

H2O

NaCl(s) Na+(aq) + Cl- (aq)

solid separation of ions

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 11

Solid LiCl is added to water. It dissolves because: A. The Li+ ions are attracted to the

1) oxygen atom () of water. 2) hydrogen atom ( +) of water.

B. The Cl– ions are attracted to the 1) oxygen atom () of water. 2) hydrogen atom ( +) of water.

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 12

Solid LiCl is added to water. It dissolves because: A. The Li+ ions are attracted to the

1) oxygen atom () of water.

B. The Cl– ions are attracted to the 2) hydrogen atom ( +) of water.

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 13

Two substances form a solution

 when there is an attraction between the particles of the solute and solvent

 when a polar solvent (such as water) dissolves polar solutes (such as sugar) and/or ionic solutes (such as NaCl)

 when a nonpolar solvent such as hexane (C6H14) dissolves nonpolar solutes such as oil or grease

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 14

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 15

Like Dissolves Like

Solvents Solutes

Water (polar) Ni(NO3)2

CH2Cl2 (nonpolar) (polar)

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 16

Will each of the following solutes dissolve in water? Why or why not?

1) Na2SO4

2) gasoline (nonpolar) 3) I2

4) HCl

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 17

Will each of the following solutes dissolve in water? Why or why not?

1) Na2SO4 Yes. The solute is ionic. 2) gasoline No. The solute is nonpolar. 3) I2 No. The solute is nonpolar. 4) HCl Yes. The solute is polar.

Most polar and ionic solutes dissolve in water because water is a polar solvent.

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