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CH - 10

December - Examination 2015 B.Sc. (Third Year) Examination

Organic Chemistry Paper - CH - 10

Time : 3 Hours ] [ Max. Marks :- 50

Note : The question paper is divided into three sections A, B and C. Write answers as per the given instructions.

ZmoQ> : àíZnÌ "A' "~' Am¡a "g' VrZ IÊS>m| ‘| {d^m{OV h¡& à˶oH$ IÊS> Ho$

{ZX}emZwgma àíZm| Ho$ CÎma Xr{OE&

Section - A 10 x 1 = 10

(Very short Answer Questions)

Note : Answer all questions. As per the nature of the question you delimit answer in one word, one sentence or maximum up to 30 words. Each question carries 1 marks.

(IÊS> - A) (A{V bKw CÎma dmbo àíZ)

ZmoQ> : g^r àíZmo§ Ho$ CÎma Xr{OE& Amn AnZo CÎma H$mo àíZmZwgma EH$

eãX, EH$ dm³¶ ¶m A{YH$V‘ 30 eãXmo§ ‘o§ n[agr{‘V H$s{OE&

à˶oH$ àíZ 1 A§H$ H$m h¡&

628

CH - 10 /300 / 4 (1) (P.T.O.)

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628

CH - 10 /300 / 4 (2) (Contd.)

1) (i) How many signal are obtained in the NMR spectrum of ethanol.

EWoZmb Ho$ NMR ñno³Q´>‘ ‘| {H$VZo {g½Zb àmßV hmoVo h¢?

(ii) Write the Zwitter ion structure of amino acid.

Eo‘moZmo Aåb H$s {OdQ²>a Am¶Z g§aMZm {b{IE&

(iii) Write the full name and structure of a DNA molecule.

DNA AUw H$m nyam Zm‘ d g§aMZm {b{IE&

(iv) What do you understand by reducing and non reducing sugars?

AnMm¶H$ VW AZAnMm¶H$ eH©$am go Amn ³¶m g‘PVo h¢?

(v) Why the α-hydrogen atoms of Ketones are acidic?

H$sQ>moZ Ho$ α - hmBS´>moOZ na‘mUw Aåbr¶ ³¶m| hmoVo h¢?

(vi) What happens when pyroll react with H2Pt?

³¶m hmoVm h¡ O~ {namob H2Pt go {H«$¶m H$aVm h¡?

(vii) What is the difference between quinoline and Isoquinoline?

p³dZmobrZ d AmBgmop³dZmobrZ ‘| ³¶m A§Va h¡?

(viii) Write IUPAC name of pyridine.

{narS>rZ H$m IUPAC Zm‘ {b{IE&

(ix) What is meant by sulphonation?

gë’$moZrH$aU go ³¶m VmËn¶© h¡?

(x) What is Grignard’s reagent?

[J«Ý¶ma A[^H$‘©H$ {H$go H$hVo h¡?

(3)

CH - 10 /300 / 4 (3) (P.T.O.) 628

Section - B 4 x 5 = 20

(Short Answer type Questions)

Note : Answer any 4 questions. Each answer should not exceed 200 words. Each question carries 5 marks.

(IÊS> - ~) (bKw CÎmadmbo àíZ)

ZmoQ> : {H$Ýhr§ Mma àíZmo§ Ho$ CÎma Xr{OE& Amn AnZo CÎma H$mo A{YH$V‘

200 eãXmo§ ‘| n[agr{‘V H$s{O¶o& à˶oH$ àíZ 5 A§H$m| H$m h¡&

2) What is the principle of PMR Spectroscopy?

PMR ñnoñQ´>moñH$monr H$m {gÕm§V ³¶m h¡?

3) Give the synthesis and use of sulphonamide.

gë’$moZ¡‘mB‹S> H$m g§íbofU Ed§ Cn¶moJ Xr{OE&

4) Explain that thiophene is more stable then furan?

g‘PmBE {H$ â¶ya¡Z H$s Anojm Wm¶mo’$sZ A{YH$ ñWm¶r h¡?

5) Describe two methods of synthesis of pyridine.

{n[aS>rZ Ho$ g§íbofU H$s Xmo {d{Y¶m| H$m dU©Z H$s{OE&

6) Write short notes on classification of Carbohydrates and Haworth projection formula.

H$m~m}hmBS´>oQ>mo H$m dJuH$aU Am¡a hmdW© àjonU gyÌ na {Q>ßnUr {b{IE&

7) How amino acid can be prepared by Gabriel Pthalimide synthesis?

J«¡{~¶b W¡br‘mBS> g§íbofU go Eo‘rZmo Aåb {H$g àH$ma go ~Zm¶o Om gH$Vo h¢?

8) What are fats and oils? What is difference in them?

dgm d Vob ³¶m h¡? BZ‘| ³¶m AÝVa h¡?

9) Write short note on natural rubber.

àmH¥${VH$ a~a na g§{jßV {Q>ßnUr {b{IE&

(4)

628

CH - 10 /300 / 4 (4)

Section - C 2 x 10 = 20

(Long Answer Questions)

Note : Answer any 2 questions. You have to delimit your each answer maximum up to 500 words. Each question carries 10 marks.

(IÊS> - g) (XrK© CÎmar¶ àíZ)

ZmoQ> : {H$Ýhr§ Xmo àíZmo§ Ho$ CÎma Xr{OE& Amn AnZo CÎma H$mo A{YH$V‘

500 eãXmo§ ‘| n[agr{‘V H$s{O¶o& à˶oH$ àíZ 10 A§H$m| H$m h¡&

10) What do you mean by Polymerization? What are the types of Polymerization? Describe in brief.

~hþbH$sH$aU go Amn ³¶m g‘PVo h¡§? ~hþbH$sH$aU {H$VZo àH$ma Ho$ hmoVo h¡§ g§jon ‘| dU©Z H$amo?

11) What are soaps? Discuss with diagrams the modern methods of its manufacturing.

gm~wZ {H$go H$hVo h¡? BgHo$ {Z‘m©U H$s AmYw{ZH$ {d{Y¶m| H$m g{MÌ dU©Z H$s{OE&

12) Explain in detail the composition and constitution of proteins and polypeptides.

àmQ>rZm§o Ed§ nm{bnoßQ>mBS>mo Ho$ g§KQ>Z Ed§ g§aMZm na {dñVma go {ddoMZm H$s{OE&

13) Describe two methods of synthesis of Furan? Discuss the aromatic character of furan.

â¶ya¡Z Ho$ g§íbofU H$s Xmo {d{Y¶m| H$m dU©Z H$s{OE& â¶ya¡Z H$s Eoamo‘¡{Q>H$

àH¥${V H$s {ddoMZm H$s{OE&

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