International
Journal
of Environmental
Science and
Development
(TJESD)
Vol. 4, No. 3, June 2013
ISSN:2010-0264
Chief Editoe Mr. Saji Baby
TFICSIT
WWW.IACSIT.ORGIngnationalAssociation of Comprrter Science aod Information Technology kess
Instruction
of contribution
Aims and Scopes
International
Environmental
Science
andDevelopment (iiESD) is an international academic
journal which gains a foothold in Singapore, Asia and opens
to
the world.It
aimsto
promote theintegration
of
environmentalscience
anddevelopment, The focus is
to
publish papers onstate-of-the-art
environmentalscience
anddevelopment. Submitted papers will be reviewed
by
technical committeesof
the Joumal
andAssociation. The audience includes researchers, managers and operators for intelligent engineering
and systems as well as designers and developers. Topic include, but are not limited to:
.
Environmentalrestoration
and
ecologicalengineering: Habitat reconstruction. Biodiverslty conservation, Deforestation, Wetlands, Landscape
degradation
and
restoration,Ground
water remed iation, Soil deconta minatlon, Eco-technology, Bio-engineering.
Wastewater and sludge treatment: Nutrients removal, Suspendedand fixed
film
biological processes, Anaerobic treatment, Process model ing Sludge treatment and reuse, Fateof
hazardoussubstances,
Industrial
wastewater treatment, Advancesin
biological, physicaland
chemicalprocesses,
On
site
and small
scale systems, Storm-water management'
Air
pollutionand control:
Emission sources,Atmospheric modeling and numerical predictlon,
Interaction
between
pollutants,
Controttechnologies, Air emisslon trading
Find more topics but not limited in the website:
http://www.Uesd.org
Manuscrlpt Submission
Hard copy submissions
can
not be
accepted.All
submitted artlclesshould
repoft
original,previously unpublished
research
results,experimental
or
theoretical,
and
will
bepeer-reviewed.
Paper Review
All published joumal papers are refereed by the
international competent resea rche rs a nd sclentists.
Therefore,
a
full
double-
blind
internatlonal refereeing process is used in whlch:http://www.ijesd.org
-Papers are sent to reviewers for their peer review pr0cess.
-The
reviewers'
recommendations determinewhether
a
paperwill be
accepted/
acceptedsubject to change
/
subjectto
resubmission with significant changes/
rejected.All
papers are refereed, andthe
Editor-in-Chiefreserves the right to refuse any typescript, whether
on
invitation
or
.otherwise,and
to
makesuggestions
and/or
modifications
beforepublication.
Initial
Paper SubmissionProspective authors are kindly invited to submit full
text papers including results, tables, figures and
references. Full
text
papers (.doc,.rft,
.ps, .pdfl will be accepted only by electronic submission or E-mail: ijesd@vip.163.com. All submitted articlesshould
report original,
previously unpublishedresearch
results,
experimentalor
theoretical. Articles submitted to the UESD should meet thesecriteria and must not be under consideration for publication elsewhere. Manuscripts should follow
the
styleof
the UESD and are subjectto
both review and editing.Final Paper Submission
Each final full text paper (.doc, .pdfl along with the corresponding
signed
copyrighttransfer
form should be submitted by E-mail: ijesd@vip.163.com.Su bmission
Instructions
When submitting papers for potential publication in the UESD, please submlt an original editable ftle in
one of the (.doc, .pdf) style files, Altfigures, images,
tables, etc,, should be embedded into the original
file. Defailed instructions on preparing papers for
submission can be found in the Template paper and
Copyright Transfer Form. Further information on
the
scopeof the
IIESDis
also available uponenquiry of prospective authors. Authors accept the terms of Honor Code and Plagiarism Statement for
Paper Submlssion, and that the paper is original research contribution with the references properly cited in the manuscript.
Page Ghalges
Upon acceptance of
a
manuscript for publication,the author
or
his/her institution or oompany canpublish
the
paper after reglstration. Extra hardcopy
of
Joumalcan be
purchasedupon
thepayment of 100 USD, and we will post the journal to you free of charge.
Find more information, please visit:
l
Editor in Ghief
Mr. SaJi BabY
Principal Envlronmental Scientist
GEO (Environmental Consultation
Servlces), Kuwalt
Editorial Board
Prof. Arbin Ebrahlm, Tuskegee
Univercity, USA
Prof, Agarwal Ankur, Florida Atlantic
Univerclty
Prof. Nasro Min Allah, COMSATS I nstitute of Information Tech nology
Prof. Capanni Niccolo, Robert Gordon
University
Prof. Arvlnder Kaur. Guru Gobind
Singh Indnprastha UniversiA
Prof. Takayama TsuYoshl, Iwate
Prcffrunl
UnivercltY, JanPnProf. Nashat Mansour, Lebanese American UniversitY
Prof. Dehmer Matthlas, Technixhe Univercibt Darmstadt
Prof. Chih-Ming Kung, Shih Chien
Univercity
Prof. Omranl Hichem, ComPlegne
U niversity of Tedt
nolqy
Prof. Mitsuo Yoshida. Tokyo Institute of Tedrnology, Japan
Prof. Baoqing Wang, Nankal Univercity,
Chlna
Prof. Chlhhao Fan, Ming Cltl Unlverslty
of Technology, Talwan
Dr. Yunardi, Chemial Engineering
Department, Syiah Kuala UnivercitY,
Indonsla
Dr. Hamed Nircumand, Faculty of civil
engineering, Uriiversltl Teknologi
Malaysla
Dr. Pere Espelt Lleonart, Tedrnical
Universi| of Catalonla, SPain
Submission
information
Papers should be submitted to our Paper Submission E-mail:
ijesd@vip.163.con1
And should be prepared in accordance with the Author Guide:
httpJ/www.flesd.org
Subscriptions and Delivery
IJESD is published in print versions. The journal covers the frontier issues
in
the environmental science and development. Printed copiesof
thejournal are distributed to accredited universities and govemment libraries.
Print version: Interested librarians
of
the
accredited universities andgovernment libraries are welcome to apply for the free subscription and
delivery of the joumal, by sending us an email (Uesd@vlp-l63-com) with
their institution name, address, contact phoneffax number, email address,
contact person and his/her position. After our stalf has verified this information, our journal will be delivered to your libraries with no charge
(note: the number of our journal's free print version is limited).
Online version: Interested librarians and envlronmental sc[entists are also
welcome to read the free online version of the joumal, by sending us an
email (ijesd@vip.163.com) with their institution name, addrcss, contact
phone/fax number, email addrcss, contact person and his/her position.
After our staff has processed this notiflcation, one can simply set up a link to ourJournal's web page. Then, you and your users can read the journal online fteely.
All
the
papersin
the journal are available freely with online full-textcontent and permanent worldwide web link. The abstracts will be irdexed
and available at major academlc databases.
Gall
for International
Editorial
Board Membens andRevlerens
Envlronmental engineers and scienUsts are welcome to ioan the UESD as
the
membercof
the
lnternatlonal editorial boardor
as
reviewers.Intercsted persons can send us an emall, along with thelr curriculum Mtae
(CV) to e-mall : ijesd@vip.lGl.com,
Bimonthly
ISSN:2010-0264
Sublect Category: Environmental Science and Development
Published by: International Association of Computer Sclence and
Information Technology Press (IACSIT Press)
rternational
Journal
of
Environmental
Science
and Development
CONTENTS
lume
4,
Number
3,
June
2013
:cts of the Composition and the Preparation Methods on Oil Sorption Capacity of Recycled Rayon
*e-KapokMixtures (RRWK)
Sorbent..
...,...-.246
Chaowalit Senanuralatarhtl, Panaddn Khongsrichatoen, Darathip Pejprom, SupawaruTantayanon, and
ha Khaodhiar
Environmental Norms and Climate Change Perceptions Influence Mitigation Behaviour?: Thailand as a
re
Study...
..-...251Suthirat Kittipongvises and Takashi Mino
ponse of Different Strains of Enterococcus faccalis to UV Inactivation after Freezing. . -
.
. - . .255W Gao andA.
Wiams
dy on Characteristics of LeakageAccident of Hazardous Chemicals and Their
Rescue.
...258Quanmin Bu, Weining Cai and Xing Tong
nulation of sfream Flow for Upper Lam Takongsub-Watershed Using swAT
Model.
...,...261Netnapa Pongpetch and Pongthep Suwanwaree
icontinuous Galerkin Method for ffreAir Pollution
Model.
..-...264XijianVang and Lite Zhao
alysis ofAccess to Clean Development Mechanism Landfill Projects through a Multi-Agent Model... 268 Silvia Cruz and Sbnia Paulino
lmate Change and Grormdwater: Vulnerability, Adaptation and Mitigation Opportunities in [ndia...272 KhajwiaAnupam and Kanae Shinjirc
Eporse of Scutellarin Content to Heavy Metals tn Ertgerun
Breviscapus
.. . .. . , ....277Huabin Xiong, Changqm Duan, Xnriang A, and Minghong Chen
ansport, Energy Conservation and Energy Efficiency in Buildings Explored as Situations of Opportunity for
ty
Transformation...-...
...282Aleh Kliatslco and PerLwtdqvist
sessment of Groundwater Potential Risk byAgricultural Activities, in North
Italy...
...286Ye Zhao, Marina De Maio, and Enrico Suozzi
n a Field Investigation and Open Data Analysis to Identifr Diff.rsion Sources of Radioactive Substance...29l
t
Kaaunari Ishidalrantification
on...,..
Method on Conversion of Gasoline to Biogas Fueled Sin Generator..
Tjolarda Gde Tirta Nindhia,
I
Wayan Surata, I- KetAri
WardanaCompaction Characteristics of Lateritic Soil-Stabilized Municipat Solid Waste Bottom
Sediment.
...304
' A. Y Abdulfutah, ,S. G Kiru, and:T A. AdedokunFictitious spokesperson to Enhance corporate Environmental
Image
...307Xiuqiang Pan and Yu-Ming Fei
Automatic Multi-Objective Calibration of a Rainfall RunoffModel for the Fitzroy Basin, eueensland,
Australia...
...311Md. ShariJ'Imam lbneAmhi Mohammad Masud Kamal Khan,Ivlohammad Golam Rasut, Raj H.Sharma,
and FatemaAlqam
Influence ofNozzle Pressure on Perforrnance and Emission in Compression Ignition Engine Rrmning on
DistilledWastePlasticOil(DwPO)...
...316Chumsunti Santaweesuk and Adun Janyalertadun
PolicyDesigEandknplementationlssuesofRegulatingGteenhouseGasEmissionsinChina..,...--....321
Xiangsheng Dou, Jingjing Xie, and Zenglongye
Alterations ofAcetylcholinesteraseActivity andAntioxidant Capacity of Zebrafish Brain andMuscle Exposed
to Sublethal Level of
Cadmium
...327
Abeer Ghazie A. Al-Smtafi and Yunjun yan
Cu and Cd induced C5rtotoxicity Involving Lipid Peroxidation and Sulfhydryl Com*ounds in the Hyperaocumulator and Nonaccumulator varieties of coumelina
communis
. . . . .. , . . . ..33 I
HaiouWang
Synthesis and Properties of FegO+Nanoparticles by Co-precipitation Method to Removal procion Dye.,...336
Poedji Loekiawati Hariani, Muhammad Faizal, Ridwan, Morsi, and Dedi Setiahdidaya
Identification of Contamination Sources and TDS Coucentration in Groundwatet of Second Biggest Crty
of
pakistan.
...-...141
M. M- Akhtar and Zhongfun Thng
Numerical Modelling for
tre
Extnerne Flood Event in the Fitzroy Basrn, euee,nsland, Australia. , . . , . . ., . . . . , .,.346Md' Sharif Imam lbne
Amfi
Mohanmad Masud Kqrnal Khan MohanmadGolan
Rasul, Raj H- Sharma,International Journal ofEnvironmentar science and Development, I/ol- 4, No. 3, June 20rS
Method on conversion of
Gasoline to
Biogas
Fueled.
Single Cylinder of Four stroke
Engine
of
Electric
Generator
Tiokorda Gde Tirta Nindhia, I Wayan Surata, I Ketut Adi Atrnika, Dewa Ngakan Ketut putra Negara,
and
Ari
Wardanabsaact---The Gasoline fueled single cylinder generator ne are well established and available in the market with
onable pricg in the other hand the biogas fueled engine for Fic gener&tor is not well established yet in the markel The ias energ:f is e""y to produce thercfore the price for the ;as is very much cheaper than the gasoline. The purpose of research is to lind conversion method from gasoline to
gas ftrelled of
tte
siugle cylinder four stroke engtne oftric
generator. For this purpose the biogas should bepaded to the level of zero lmpurities of hydrogen sulfide E2S,
ier @2O) and reducing up to zero level of CO2 impurities. ! carburetor of the gasoline engine was replaced
ud
ollyrponent of
lte
mixer of the fuel ard air were used. The rke of the biogas fueled should be completed with valve thatr bc opened automatically by vacuum of tte suction stuoke of engine and compression rafion of the engine should be
reased undl reach 9:1
of
compression ratio. With this rversion method the englne ofthe electric getrerator used for s researchis
run well and possible to reach maximum paclty that can be achieved by using gasoline previously.Inda Terms-lonversion, gasoling biogas, slngle cylinder,
r stroke engine, elecfic generator.
I.
INrnonucrroNThe progress of utilization biogas as a fuel for elecbic
is found not as good
Ity in manufucturing
I become a problem nt yield in high price ofthe engine. Other problem is caused y the biogas qualities that vary among the region that make
I dilEcult to upgrade in to the standard state for fueled
the
Among all impurities in the biogas, the CO2, tI2S and
rater should be eliminated in order possible to be used as
irel of the engine. Some of the methods can be summarized u written bellow as a reference to be decided uthich method
rill
be adopted and developed.Dot:
ro.zzogDrsD.2ol3.v4.358
3ooH2S is removed in the first stage of biogas purification.
Two techniques are applied that are removal of I{zS during
digestion and removal of H2S after digestion [2].
For the method ofremoval H2S during digestion, there are two types that are widely practiced narrrely by air-oxygen dosing to the biogas and addition of iron chloride into the
digester. Air-orygen dosing to the biogas system is based on the biological aerobic oxidation of IIzS to elemental sulfir by microorganisms [2]. Sulfide oxidizing microorganisms are
autotrophic and use COz from the biogas to cover their
carbon need. For the method of addition of iron chloride into
the digester, the iron cbloride can be penetrated directly into
the digester or tfuough the influentmixing tank. tt reacts u,ith
the H2S thatpresent in the biogas to fomr particles of FeS [2]. There are many methods of removal oftl2S after digestion,
adsorption using iron oxide
or
hydroxidefor
example. Hydrogen sulfide reacts easily with iron oxideor
iron hydroxide and forms iron sulfide. The other technique isabsorption
with
liquids that can be either physical orchemical. Chemical absorption involves dissolving the
component followed by a chernical reaction
of
the tracecomlronent and the solvent whereas physical absorption
involves dissolving the
face
componentin
the solven!Physical absorption removes I{zS by absorption in water or
an organic solvent. The most corrtmon solvent
is
water scnrbbing, although the growths of microorganisms in the packing occur. Single pass absorption and regenerativeabsorption are two t5pes of water absorption processes that cornmonly used
for
the
upgradingof
biogas_ The disadvantage is a high coosurnption ofwater is needed, therefor regeneration process should be promoted [2].
H2S can be separated from the gas by leading
fte
gasthrough a semi penneable meryrbrane (membrane se.paration
technique). H2S able pass tlrough the membrane but not ClIe.
The important compon€nt is a micro porous hydrophobic
membrane that able to separating fte gas from liquid phase. The molecules from the gas stueam, flowing in one direction,
difffuse tbrough the membrane and will be absorbed on the other side by the liquid, flowing in counter current. For this purpose NaOH can be used as the absorbent Hquid t2l.
The method that is similar to the technique where air-O2
was added to the digestion is biological filter.
It
is use specific bacteria that are able to oxidize HzS. Before entering the filterbd air
is added to the biogas. The H2S is absorbedin the liquid phase, made up from gas oondensate and liquid
from effluent slurry separation. After absorption, I{2S is
oxidized by the bacteria, growing on the filterbed_ The IIzS
lnlernational Jourildl of Enirounental Scietlce and Developmenl, fol. 4, .No. i, June 201i
l
l
liquid of tlre filter. Other benefit of Biological filtration is
applied
in
several installationsfbr
rernoving odorsit
ischeaper than chemical clcarriug and possible
to
refiloveammonia from the biogas. It is reporled also FI2S can also be removed by using activated carbon [2].
As mentioned previously beside II3S, the CO2 gas should also eliminate for the purpose of upgrading biogas tbr fueled
Lhe spark ignition engine. Sevcral teclniques are introduced here that was obtained from literature sfudy iu order proper
decision could be obtaincd.
Physical and chentical CO2absorplion. The CO2 and CHa
are separated by using absorbent. Water can be used as
physical absorbent. CO2 is separated from the biogas by
reacting u,ith water at high pressure. Biogas is entered fi'om
the bottorn of vertical column. Water is fed at the top of the
column to achieve a gas-liquid counter flow [2],
Pressure swing adsorption (PSA)
or
vacuum swingadsorption (VS"{). PSA and VSA use a coluuul filled with a
molecular sieve (silica gel, alumina- activated carbon or
zeolile), for adsorption of the gases CO2 and letting ClIa pass
through. The molecules are adsorbed loosely in tlre cavities
of the molecular sieve [2]
Membrane separation
is
basedon the
selectivcpermeability prcperty of membranes. Two basic systems
exisf gas-gas separationrtth a gas phase at both sides ofthe
membrane and gasJiquid absorption separation with a liquid
absorbing the diffused molecules. Multiple stages may be
required due to irnperfect separation that would increase the methane loss. This problem can be overcome by recirculation
Q).
Cryogenic sepa.ration. Since CI{4, COz
and
otherimpurities
liquef
in different temperahrre or pressure, it ispossible to obtain methane by cooling and compressing the
biogas. The liquidCOa is also a solvent separating remaining
impurities from the Cas l2l.
Biological methane erurichment- Specific methanogens using only CO2 ati a carbon source andH2 as an energy source.
The
selection between mesophilicard
thermophilicoperation temperatures is typically based on whether the
completion of reaction or the rale of reaotion is of primary
concern. Thermophilic methanogens
exhibit
rapidmethanogenesis,
while
mesophilic bacteriagive
morecomplete conversion of the available CO2lzl.
Removal
of
C02 and HzStom
biogasby
aqueoussolutions in a packed column can be done by using sodium
hydroxide (NaOH), calcium hydroxide (Ca(OH)2) and
mono+thsnolamiae
(MEA)
as liquid
solvent. Liquidsolvents were circulated tbrough the column, coatacting the biogas in couutercument flow. Test results indicated similar
absorption patterns between the cheurical solvents used.
Chemical absorption by solvents in apacked column was an
effective tecbnique for removing CO2 over a short operation
time, but their absorptioa capability declined rapidly with time. Ca(OH)z aDpared. to become satuated more rapidly
than the other solvents[3].
Untreated or raw bioga.s is usually saturated with water and the absolute wat€r quantity depends on the temperature. The
lower the temperature, the lower the water content in the raw
biogas. The removal methods for water are genorally based
on physical scparation
of
condensed wateror
chemicaldryiltg [2].
Physic,al drying metltod.s. The simplest way of removino
excess water vapor is through rcfiigeration.
to
achiev" towei dew points flre gas has to be compressed before cooling andthen later expanded to the desired pressur-e. The lower t1..
deu,point, the higher presslue is needcd to be applied. T1. condensed water droplets are entrapped and removed. |1a
physical drying methods prcvent wator contact tvitfi dor,r'nstreanr equiprnent like compressors, pipes, activated
carbon beds and other parts of thc process. In this u,ay,
corrosion is prevented [2].
Chemical &ying metltods. Thesc techniques ale usrrally
applied at elevated pressures. At atmospheric pressure only a small amount of water is removed by the absorption aq{ adsorption tcchniques. Adsorption using alumina or zeolites
molecular sieves is the most corrlmon technique [2].
Beside ius difticulty for fueled the engine. biogas has
advantages as alternative energy since easy to produce er.en
from municipal waste [a]. This make that the effort to use
biogas
to
fueledthe
engine should be promoted andsupported as what happened
in
thc developed counu-y.Recendy the biogas
is
possibleto
usefor
driven airconditioaing system [5], and more even at the sub toopical
r€gion, the used ofbiogas was provotr well for combined heat
and powered (C[IP) for establishing electricity and heating
during winter
[6].
Further more The results show thatimplementation of a biogas-based CHP plant result in an
electricity powerproduction, Reduced system costs provide a
profltability, CO2 emission reductions [7].
The
benefrt ofbiogas instead
for
providing eleckicity demandis
alsopossible for heat production reducing the odor, reducing
greenhouse efTect and more erren can producing fertilizer tbr
agriculture.
lt
was calculatcd that from about 7595d/day
methane ga-s could be obtained about 77.4 MWh of electicity [8]. This conclusion can be use to ensure the effort of providirg electricity from biogas should be continued and encouraged
[8]-There is an improvement in trermal efEciency and power
ouQut of a biogas fuetled spark ignition engine with very
lean mixtures and a hydrogen concsrtration of 15% [9]. But
utilization and aprplication and implementation
offtis
idea isfar &om easy especially in the developing word particularly
in providing hydrogen for this
purpose-The engine fueled with mixture of biogas and city gas rr'as
"Leady developed [10] and reported runwell, brr the argine
perforrnance during using singte fueled biogas was not
reported yet in this reporl The used of city gas should be
questioned because will need more cost to providc csperially
forthe farm in rural area.
The purpose of this research is to develop method for
conversion fiom gasoline to biogas fueled small engine to run
the elechic generator to reach the performance of gasoline
fireled engine to gen€rate electricity u,hich is reliably to be
ir4plemented
in
the developing wodd-. The small fueledgasoline engine was from the specification that easily to be
found and widely available in the market
of
developin$ country,International Journal of Envirorunenlal Science and Detelopmenl, Yrtl. 4, No. 3, June 2013
[I.
EXPTXTUENTAL'l'he selected engine for this pulpose was 4-stroke gasoline engine, air-cooled, and inclined single cylinder. The displacement is l96cc, the compression ration of the engine was increased from 8.5:1 to reach around 9:1. The ignition system was non contact transistor ignition (TCI).
The biogas obtained from digester was desulfurized by
using annealed and compacted steel waste chips from the
waste of turning process in. The detail of processing can be
access
in our
previous report [11]. The annealed andcompacted billet used for this research is presented in Fig. I, and detail schematic of conversion method from gasoline to biogas fueled electric generator engine can be seen in the Fig.
7
Fig. l. Anneafed and compacted billct ofsteel waste chips as desulfurizer
?6
Fig. 2. Schematic of conversion method ftom gasoline to biogas fueled
clecdric generator eugine. l. Digester, 2. Desulfurizer, 3. First bag ofgas holder, 4. l,ow pressure compressor, 5. CO: elimioation" 6. Second bag of
gas holder,7. Dehumidifrer, E- High pressure ofcompressor, 9. Biogas container, 10. vacuumpowered val;:,#,"JJ -*", 12. Biogas and Air
To ensure that the biogas is free from H2S impurities, the
II2S contents
in
the biogas was checked before and afterpassing the desulfurizer. [f the HzS still found in the biogas the addition ofbillet of annealed and compacted desulfurizer
should be done. The biogas with free impurities of IIzS was flowed to entering the first bag
of
gas holder. The lowpressure of compressor was used to pump the biogas from
the first bag of gas holder to entering the component of COz
removal which was contain with solution of lo%o NaOH in
water (H2O). The biogas was collected afterward
in
the second bagof
gas holder and after thatit
was ready to entering the process of dehumidification to ensure that thebiooas free from water content. From this point the biogas was ready to be compressed in to the biogas container until
reach about
4
MPaxl0-t. The valve whichwill
open byvacuum mechanism of the intake manifold was installed to
arrange the flow of the biogas. With this valve the gas will
flow in to the intake of the manifold and
will
stopif
the engine not running. The biogas then was continued to flow into the mixer part.
This mixer component is part
of
the carburetor in thegasoline fueled engine but the carburetion cup was replaced and only mixer part was remain. Together with biogas, the air
was flowed in to the mixer, and directed in to the intake valve
of the combustion chambcr.
It
should be noted here that during starting the engine, the flow rate of the biogas was letmaximum and reduce the rate gradually until the engine start rururing, and the rate of air flow in to the mixer was adjusted
until the engine run stable.
III.
R-ESULTANDDISCUSSIONBy using desulfurizer the biogas can be upgraded to zero content of H2S impurities that lead to avoid increasing acidity
tl
1l of
the
lubricant thereforethe
corrosionin
the combustion chamber canbe
avoided. Previously the existence of HzS in the biogas was overcome by increasing frequency of engine oil change which iswill
increase theoperating cost [12]. Other urgent thing that makc H2S should
be eliminated due to H2S is a toxic gas [2]. [n this report the used of annealed and compacted billet of steel waste chips
was found successful in elimination of HzS impurity. The
steel which is main content is iron (Fe) transformed to both
iron oxide (FezOr) and iron hydroxide (Fe2(OH)3) during
annealing process.
Iron
oxide and iron hydroxide wasrecognized easy to react with H2S and form iron sulfide as
reaction in Equation 1 atd2 bellow [2]:
Fe2O3+3H2S-+Fe2S3+3H2O
(l)
2Fe(OH)3+3HzS+FezSr+6HzO
(2)It
is should be noted that the reaction in Eq. 1 and 2 arevery sensitive to water [2] therefore dryit g process of this
type of desulfirizer during maintenance is obligatory. The p(rcess of desulfurization in this research was conducted at early prbcess that is after the biogas come out from the digester The main reason
is to
protect the gas pumP, compressor and storage tank from corrosion since it is knownH2S is very corrosive to metal [2] especially steel.
The elimination
of
the COz impurities by flowing the biogas in to the solution of l0o/o NaOH in water (tIzO) wasfound easier that the method proposed by by Chien et al- [13]
and also Tippayawong and Thanompongchart,
[3].
Byreducing the water content in the biogas up to zero level
affect in easy starting of the
engine-The use of the bag gas holder of the biogas was useful
during compressing of the biogas in to the gas container
because this is make easy to be observed whether biogas
available or not during compression. The bag gas holder can be made from plastic bag and this is actually from the balloon
of tube tlpe of digester [14]. Other t1rye of digester such as
fixed dome digester
[4]
was formd not suitable duringcompression gas because we can not observe the availability
of the biogas. Mean while floating cover digester [14] was
found increasing water content in the biogas during suction for the prupose of compressiou in to ttre biogas container.
The silica that was used for dehumidifrer in ttris research
International Journal ofEtnironmental Science and Developnlent, Vol. 4, No. 3, June 2013
was found working well to eliminate the water content in the
biogas. This process was known as drying process by adsorption dryer
[2].
The silica grain providedin
thisresearch was adsorbing the water and the grain joint together in the form ofsolid tubular. The solid silica can be crashed to become grain and heating for regeneration.
The compression ration in this research was increased step
by step from 8.5:l until yield condition in which the engine
was easy
to
start running andrun
stable. The final compression ration was9:l
which reached minimumcompression ratio for the biogas fueled spark ignition engine
tlsl.
The conversion methods that is developed in this research
was successful to run the electric generator engine that previously fueled by gasoline to be converted by using biogas.
The engine run stable and can produce electricity. The maximum RPM (revolution per minutes) that can be obtained
by using biogas was found can reach the maximum RPM
obtained by using gasoline fuel which is around 3600 RPM.
IV.
Cottct usroNThe conversion from gasoline to biogas fueled engine can
be achieved by desulfurizing of the biogas at the firs step
continued
with
eliminationof
CO, inpurity and thendehumidification and put the gas in to the bag of gas holder.
The biogas afterward should be compressed in to the gas container for easy mixing process with orygen from the air. The carburetion componentwas replaced and only mixerpart of the fuel is used and before entering the mixer, the valve controlled by vacuum
of
suction strokeof
the piston isinstalled to control the flow
of
the biogas during on-ofprocess ofthe engine. During starting process, the biogas is
let to flow in maximum flow rate and reduce the rate until
engine startrunning. The process is folloured by adjusting the air flow in to the mixer until the engine nrn stable.
AcKNowLEDGEIvtENT
The authors wish
to
thank the Minisryof
National Education and Cultureof
The republicof
Indonesia forfinancial support under scheme of competitive research grant (skim penelitian hibah bersaing) for the year of2013 granted through Udayana University, Jimbaran, Bali, Indonesia
REFERENCES
tU F. Oscio and J. C. Torres, 'Biogas purffication ft,om anacrobic
digestion in a wastevrater tseatnent plant for biofuel productioq"
Reaerwbk Energ, vol. A, pp- 2l@-2171, March 2(X)9.
l2l E. Ryckebosch. M. Drorillon, and IL Vervaercn, 'Techoiqucs for Transformation bf Biogas To Biomethane," Biomass ond Bioenergt, vol. 35, pp. 1631.1645, March 201 l.
t3l N. Tippayawong and P, Thaoompongcha6'Biogas Quality Upgnde
by Simultaneous Removal of COe and tIzS in A Packed Column Rear,W," Eaerg4 vol. 35, pp.453l-4535,lv{ay 2010.
[4] N. Kuwahara, i,L D. Berq md S. V. Bajay, iEnergy Supply from
Mruricipal Waste: The Potensial of Biogas-fuelcd Buses in Brazil""
Renewoble Enetgr. vol. 16, pp. 1000-1fi)3, Ianuary 1999.
15] D. Damrongsk and N. Tippayawing,'Experimental investigation of an
automotive air+onditioning sl,rstem driven by a small biogas engiog"
Applid Ihennal Engiaeering, vol. 30, pp. 4fi)-405, September 2010. t6] R. P. L M. Raven and IC H. GrcgerserL "Biogas plants in Denmark:
succqsses End setbacls," Renewable and Susuinable Energt Reviews,
vol. ll, pp. I l6-132, Doernber 2fi)7
t7l S. Amiri, D. sson, "Simulation 1ntr
introduction of gas system," Reney,able
Energt,vol.49
t8l P. Scfccdpri Elecrricitv
Requirements I Benefit ii Sample Dairy Reneu'ahle
Enetgt Research, vol. 2, no. 3, pp. 384-387, }v|.zy 2012.
t9l E. Porpatham, A. Ramesb, and B. Nagalingarn "Effect of hyftogen addition on the pcrformance ofa biogas fuelled spark ignition engine,"
Imenntional Jounnl of Hydrogen Energt, vol. 32, pp. 2057-2065,
October 2007
[I0] Y. Yamasaki, M. Kanno. Y. Suzuki, and S. Kaneko, *Development of
an engine control system using city gas and biogas fucl mixture," vo1 101, pp. 465-474, January 2013
I l] T. c. T. Nindhia, "Removal of Hydrogen Sulfide (H2S) contaminant in
Biogas by Utilizing Solid Waste Steel Chips from The Proccss of
Tuming," in Proc. Twenbt-sevenlh Inlernational Confet'ence on Solid Waste Technologt and Management, Philadelphia, PA U.S.A., 2012,
March 1l-14. pp259-264
[2] J. Huanga, and R J. Crookesb, "Assessment ofsimulated biogas as a
fuel for the spark ignition engine," Fuel, vol.77, no. 15, pp. I 793--1 801, June 1998
[3] Y. K. Chieq Y. C. Sheng, T. H. Tzu, D. Le, K. H. Ling, and S.L. Chih
'Ability of A Mutatrt Strain of The Microalga Chlorella sp. To Caprure Carbon Dioxide for Biogas Upgradiog," Applied Energ4 vol- 93, pp. 176-1E3, January 2012.
[l41 T. Bond and M. R. Ternpleton, "History and future of domestic biogas
plants in the developing world," Ezergtfor Sustainable Developnrcnl,
vol. 15, pp. 347-354, October 201 l.
I 15] E. Porpatharq A Rarnesb, and B. Nagaliogas\ "Etrect of compression
ratio on the performance and combustion of a biogas fuelled spark
ignition enginq" Fuel, vol. 95, pp. 247 -256,November 201 l.
Tjokorda Gde Tirta Nindhla Was bom in Denpasar,
Bali, Indonesia ou Jaruary l6'n, 1972. Received
Doctor Degree in Mechanical Engioeering from Gadjah Mada University (UGM) YogyakartE, Indooesia on August 2003, with major field ofstudy
was Material Engineering.
He participated in various interuational research
collaboration such as with Muroran Institute of
Technolory Japan (20M), Toyohashi University of Technolory Japan
(2006), Leoben Mining University Austria (2008-2009), Technical University of Vienna Austria (2010) aod Recently with Institute Chemical
techrolory ofPrague Czech Republic (2012-now). His cunentjob is as Full gineering at Departueot of Mechanical
Udayana University, Jimbaran, Bali,
Indonesia IIis research interst covering subjects such as, biomaterial, waste
recyclq failure analyses, ceramic, metallutgy, compositg renewable eoergy, and environmcntal friendly runufactrring.
Prof Nindhia is a member of JICA Alumi, ASEA-LTNINET alumni, and
<[so member of association of Indonesian Nanotechnolory. Prof Nindhia
receivedbest rcsearcher award in 1997 from Udayua University the place
where he is wo*ing aod again in 2012 received both 3o1tssearch6 as.ard
from Engineering Faculty of Udayana University and fiom Udayana
Uliversity.
I Weyan Surrt! was bom in Nusa fenida, Bali Indonesia on July 5, 1958. Received Doctor Degree in tte field of Ergonomic from Udayana Univesity itr 20 I I . His research inrerest very nuch rclatcd in process of rnaoufacure. His Currqt job is researcher and lectucr at Departuent of Mcchaoical Eagineering; Engineering Facult5r, Udayana University, Jimbaran, Bali,
Indonesia
I Ketut Adi Atnlka was bom in Negara" Bali, Indonesia on May t8, I 969.
Received Master degree in mechanical engineering From Iostiote
Technotory ofSepuluh November. Surabay4 Indonesia- His Currentjob is
researcher and lectrer at Departmeot of Mechznical Engineering,
Engineering Faoulty, Udayana Univetsity, Jimbaran, Bali Indonesia
Dena Ngakan Ketut Putrr Ncgara was bom in Payanga4 Bali. Indooesia onJune 13, 19?1. Received M.Sc fromUniversity of Bradfon( uK in 2001
in Manufacnriog Systems Engineering and Managerrent. His Curreot job
is resealcher and lcctrrer at Department of Mechaaical rngineerin&
Engineering Faculty, Udayana Univesity, Jimbamo, Bali,
Indonesia-AdWerdana was born in Kupang,Indonesia onNovember I, 1985. Heis in the final stage io finishing his undergraduarc course at Departnent of
Mechaoical Engh€ering, Engineering Fsculty, Udayana University,
Jimbaran" Bali, Indonesia