39
. . , . . , . . , . .
, -
, -
, -
. -
[1, 2].
- [1].
-
, -
. -
,
- .
, , -
[2],
-
, -
.
- - n, C –
, , -
[1]:
n n n C
C
n n! exp 1
1
0
, (1) –
.
- ,
.
, -
-
- - [2].
,
- - ,
-
. -
( )
[1, 2].
: z
r X z z L
Y , ; (2)
dV r d z z K
Y
V , , (3)
X, Y – -
; KV – -
;z – -
; r – ; –
;V – ;L – -
.
: Y
X dV k
d
st , (4)
kst– .
(1), (2) :
. ln 0
,
, 0 ,
2 2
2 2
z X z r L z z D
X
z r Y z z D
Y
(5)
-
ln 1
, V KV
z r K
z
D , (6)
– [2]:
40
2007. 2
k L
st . (7), -
f V
V K Ldf
K 1f
. (8) -
0
1 1
Y Y 1 f K ds
0
1 1
1 exp 1
1
z V Y
Y Y f K ds
J
0
0
1 exp 1 .
1
z st
V Y
X k f K ds
J
(9)= 1 -
[2].
z V Y
ds J K
Y f Y
0 0
1 1
z V Y
st
K ds
J f X k
0
0 . (10)
: 1:
0
1 1
exp f K ds
J
H V Y
0 0 0
1 1 1
exp Y
X ds k
K J f
st H
V Y
; (11) = 1:
0
ds J K
f
HV Y
0 0 0
1
1 Y
X ds k
J K
f
H stV Y
. (12) n
-
, -
: 1:
1 0 1 0
1 1 exp
1 1 exp
ds K J f
ds K J f
n
i H
i V Y
n
i H
i V Y
i i
0
1
0Y X k
st; (13) = 1:
n
i H
i V Y
n
i H
i V Y
i i
ds K J f
ds K J f
1 0 1 0
1 1 1
. (14)
- - n
:
1 0 1 0
1 1 exp
1 1 exp
ds K J f
ds K J f
n
i H
i V Y
n
i H
i V Y
i i
0
1
0Y X k
st. (15) - [3],
RS, -
- HS - .
:
a D RS aD 4
2 ln , (16)
41
S S
S a H
hR H
J h
j 2
2
exp 2
2 . (17)
,
: HS, -
, -
, -
- .
-
, -
[1, 2].
-
a d d I a
i
exp 4 4
0 0
min . (18)
d0
a ( , -
).
a d0
- I imin - .
- - :
1:
1 1 1
exp
1 1 1
exp
S S
H H
K G F
H H
K G F
; (19)
= 1:
1 1
1
S S
H H
GK F
H H
GK F
. (20)
F – ;G – -
.
-
[4], -
:
h h
h , (21) N
h 1 HS
, (22)
1 ln 1 1
N 1 , (23)
h* – -
( -
).
, -
,
, -
, -
.
- .
1 2 3 4 5 6 7 8
0,25 0,50 0,75 1,00 1,25 1,50 1,75 2,00 a
d0
I imin
(12)
42
2007. 2
1. . -
. .: , 1969. . 622.
2.Brener A.M., Bolgov N.P., Sokolov N.M., Tarat E.Ya.
The application of random walk methods to the modelling of liquid distribution on the regular shelf packing // Theor. Found.
of Chem. Eng. 1981. V. 15(1). P. 62-67.
3.Brener A.M. Adaptation of random walk methods to the modelling of liquid distribution in packed columns // Advances in Fluid Mechanics, IV. Southampton, Boston: WIT Press, 2002.
P. 291-300.
4. ., ., . . .:
, 1982. C. 696.
i -
i .
i .
.
Summary
The new approach to modelling the liquid distribution influence on the heat and mass transfer intensity in the gas- liquid chemical reactors has been carried out. The expressions obtained can be applied to the design of reactors with allowance for the scaling phenomena.
513.83
. . 3.03.07 .
. . , . .
- ,
-
, . . .
- -
, -
. . [1, 2] ( . [3, c. 27]
-
). , -
-
L n , -
L
, -
:
0 0
0
u
Lu
, L u1 0u1 u0, ...,1
0 S S
S
u u
u
L
. (1)-
[4, c.179] N f,
m -
0 )
( A E
mf
– -
; – -
), -
,
, f
N -
, .
N -
- ,
f
if
f
0,
1, ,
, ,(1)
0
,
0
f
Af Af
1f
1f
0, ... ,1 i i
i
f f
Af
.(1)
, ,
-
. . [5].
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. , ,