LAMPIRAN BAHAN
PVDF
Super P
LAMPIRAN ALAT
Neraca digital
Beaker Glass
Cawan
Penjepit dan Spatula
Oven
Hot Plate dan Magnetic Stirrer
Doctor Blade
Oven Vakum
Kaca Preparat
Holder
LAMPIRAN SAMPEL
Slurry (Lumpur)
Lembaran Katoda LiMn
2O
4LAMPIRAN ALAT KARAKTERISASI
XRD
Optical Microscop (OM)
Lampiran Perhitungan Massa LMO
Komposisi 85:10:5
Massa Al foil ukuran 4x4 cm = 0,07 gr
Massa Al foil ukuran coin cell = 0,0063 gr
Jari-jari dari coin cell = 0,725 cm
Luas coin cell = 1,65 cm
Kode Sampel
2
Massa setelah dipress (4x4 cm) (gr)
Massa coin cell (gr)
85T1
0,15
0,0114
85T2
0,17
0,0178
85T3
0,18
0,0194
Kode Sampel ukuran 4x4 cm
LMO dalam laminate (gr/cm
2)
LMO elektroda coin cell w(gr)
85T1
0,0068
16
= 0,00725
Komposisi 90:7:3
Massa Al foil ukuran 4x4 cm = 0,07 gr
Massa Al foil ukuran coin cell = 0,0063 gr
Jari-jari dari coin cell = 0,725 cm
Luas coin cell = 1,65 cm
Kode Sampel
2
Massa setelah dipress (4x4 cm) (gr)
Massa coin cell (gr)
85T1
0,10
0,0105
85T2
0,13
0,0122
Kode Sampel ukuran 4x4 cm
LMO dalam laminate (gr/cm
2)
LMO elektroda coin cell w(gr)
85T1
0,027
16
= 0,0016875
0,00378
85T2
0,054
16
= 0,003375
0,00531
85T3
0,108
16
= 0,00675
LAMPIRAN GRAFIK KAPASITAS DISCHARGE BATERAI
Analysis Results
General Information
Analysis date 2015/04/23 18:24:45
Sample name LMO Measurement date 2015/04/23 15:16:46
File name LMO.ras Operator Ibrahim Purawiardi
Comment
Measurement conditions
X-Ray 40 kV , 30 mA Scan speed / Duration time 3.0000 deg/min
Goniometer SmartLab(In-plane) Step width 0.0100 deg
Attachment RxRy Scan axis Theta/2-Theta
Filter Cu_K-beta Scan range 10.0000 - 90.0000 deg
CBO selection slit BB Incident slit 1/2deg
Diffrected beam mono. None Length limiting slit 10.0mm
Detector SC-70 Receiving slit #1 1/2deg
Qualitative analysis results
Phase name Formula Figure of merit Phase reg. detail DB card number
Graphite-2H, syn C 0.310 ICDD (PDF-4+ 2013 RDB) 00-056-0160
Lithium Manganese Oxide Li Mn2 O4 1.393 ICDD (PDF-4+ 2013 RDB) 04-016-2988
Phase name Formula Space group Phase reg. detail DB card number
Graphite-2H, syn C 194 : P63/mmc ICDD (PDF-4+ 2013 00-056-0160
Peak list
No. 2-theta(deg) d(ang.) Height(counts) FWHM(deg) Int. I(counts deg) Int. W(deg) Asym. factor
1 18.9259 4.68523 6.060307 0.225891 6.398392 1.055787 1.58624
2 23.908(4) 3.7189(6) 114(11) 0.185(15) 30.6(12) 0.27(4) 3.0(9)
3 26.5121(18) 3.3593(2) 12383(111) 0.1834(13) 2974(9) 0.240(3) 2.10(10)
4 27.535(10) 3.2368(11) 113(11) 0.12(2) 23.9(12) 0.21(3) 2.2(12)
5 36.4832 2.46082 11.943339 0.225891 4.530867 0.379363 1.58624
Structure parameters
Data set name Phase Name Element x y z Occupancy Temperature fact
LMO Graphite-2H, syn C 0.000000 0.000000 0.250000 1.000 0.000
LMO Graphite-2H, syn C 0.333333 0.666667 0.250000 1.000 0.000
LMO Lithium Manganese Li 0.125000 0.125000 0.125000 1.000 0.500
LMO Lithium Manganese Mn 0.500000 0.500000 0.500000 1.000 0.500
LMO Lithium Manganese O 0.244000 0.244000 0.244000 1.000 0.500
Data set name Rwp Rp Re S Chi^2 Maximum shift/e.s.
Lattice constants
Angular correction
Analysis results
Data set name a(A) b(A) c(A) alpha(deg) beta(deg) gamma(deg)
LMO 2.4613(10) 2.4613(10) 6.7173(5) 90.000000 90.000000 120.000000
LMO 8.223(6) 8.223(6) 8.223(6) 90.000000 90.000000 90.000000
Phase name a(A) b(A) c(A) alpha(deg) beta(deg) gamma(deg) V(A^3)
Graphite-2H, syn 2.4613(10) 2.4613(10) 6.7173(5) 90.000000 90.000000 120.000000 35.24(2)
Lithium Manganese 8.223(6) 8.223(6) 8.223(6) 90.000000 90.000000 90.000000 556.1(7)
Crystal structure analysis results
Phase name
Indexing
Formula Figure of merit Phase reg. detail DB card number
Graphite-2H, syn C 0.310 ICDD (PDF-4+ 2013 RDB) 00-056-0160
Lithium Manganese Oxide Li Mn2 O4 1.393 ICDD (PDF-4+ 2013 RDB) 04-016-2988
Quantitative analysis results
Phase name Content(%)
- Graphite-2H, syn 92.1(16)
- Lithium Manganese Oxide 7.9(5)
Phase name
Lattice information
a(A) b(A) c(A) alpha(deg) beta(deg) gamma(deg) V(A^3)
Graphite-2H, syn 2.4613(10) 2.4613(10) 6.7173(5) 90.000000 90.000000 120.000000 35.24(2)
Lithium Manganese 8.223(6) 8.223(6) 8.223(6) 90.000000 90.000000 90.000000 556.1(7)
Phase name Space group Z Z' Calc. density(g/cm^3)
Graphite-2H, syn 194 : P63/mmc 4 0.167 2.262
Lithium Manganese Oxide 227 : Fd-3m,choice-2 8 0.042 4.484
Structure determination
Measurement range: 10.0000-90.0000deg Refinement range: 10.0000-90.0000deg (1.09 A), Rwp = 13.30% S = 1.3873
Refinement
Phase name Atomic coords # of indep. reflns
Graphite-2H, syn Fractional coords 11
