LAMPIRAN A PERHITUNGAN NERACA MASSA

LAMPIRAN A LAMPIRAN A

PERHITUNGAN NERACA MASSA PERHITUNGAN NERACA MASSA

Tabel B.1 Basis Pehitungan Tabel B.1 Basis Pehitungan K

Ke et te er ra an ng ga an n N Ni il la ai i

K

Kaappaassiittaas s

P

Prroodduukkssi i

t

toonn//ttaahhuunn

H

Haarri i

K

Keerrjja a

D

Daallaam m

S

Seettaahhuun n

3

33300..000 h0 h

a

arrii

J

Jaam m

K

Keerrjja a

D

Daallaam m

S

Seehhaarri i

2

244..0000

j

jaamm

K

Kaappaassiittaas s

P

Prroodduukkssi i

P

Peerrjjaam m

k

kgg//jjaamm

Data Berat Molekul Masing-masing Komponen : Data Berat Molekul Masing-masing Komponen :

Tabel B.2 Berat Molekul Komponen Bahan Baku Tabel B.2 Berat Molekul Komponen Bahan Baku SSeennyyaaw waa M Moolleekkuull

BM

BM Titik Titik Didih Didih Konsentrasi Konsentrasi ((kkgg//kkm mooll)) ((ººC C)) ((% %))

 Acetic Acid 

 Acetic Acid     6 60 0..0 05 5 1 11 18 8..1 10 0 1 10 0..7 70 0 2-Cyclopentanone

2-Cyclopentanone    8 84 4..0 09 9 1 15 50 0..0 00 0 5 5..6 60 0  Phenol 

 Phenol     9 94 4..1 11 1 1 18 81 1..7 70 0 8 8..6 60 0 Octanoic Acid 

Octanoic Acid     1 14 44 4..2 21 1 2 23 39 9..7 70 0 1 10 0..5 50 0 1,2-Benzenediol 

1,2-Benzenediol     1 11 10 0..1 11 1 2 24 45 5..5 50 0 5 5..5 50 0 benzaldehyde

benzaldehyde    1 10 06 6..0 02 2 1 17 78 8..1 10 0 4 4..5 50 0 Capric Acid 

Capric Acid     1 17 72 2..2 26 6 2 26 69 9..0 00 0 1 10 0..5 50 0  Lauric Acid 

 Lauric Acid     2 20 00 0..0 07 7 2 29 98 8..9 90 0 3 32 2..0 00 0  Myristic Acid 

 Myristic Acid     2 22 28 8..1 18 8 2 25 50 0..5 50 0 7 7..4 40 0

 Hexadecanoic Acid 

 Hexadecanoic Acid 

   2 25 56 6..1 19 9 3 35 52 2..0 00 0 4 4..7 70 0

Tabel B.3 Berat Molekul Hidrogen Tabel B.3 Berat Molekul Hidrogen

SSeennyyaaw waa M Moolleekkuull BM BM Titik Titik Didih Didih ((kkgg//kkm mooll)) ((ººC C))

 Hidrogen

 Hidrogen    2 2..0 01 1 --2 25 52 2..2 27 7

Tabel B.4 Berat Molekul Komponen Produk  Tabel B.4 Berat Molekul Komponen Produk 

BM

BM Titik Titik Didih Didih

C C²²HH⁴⁴OO²² C C⁵⁵HH⁸⁸OO C C⁶⁶HH⁶⁶OO C

C⁸⁸HH¹⁶¹⁶OO²² C

C⁶⁶HH⁶⁶OO²² C C⁷⁷HH⁶⁶OO C

C1010HH2020OO22

C

C¹²¹²HH²⁴²⁴OO²² C

C¹⁴¹⁴HH²⁸²⁸OO²² C

C¹⁶¹⁶HH³²³²OO²²

H H22

((kkgg//kkm mooll)) ((ººC C))

 Methane

 Methane    1 16 6..0 04 4 --1 16 61 1..5 50 0 Cyclopentane

Cyclopentane    7 70 0..1 10 0 4 49 9..0 00 0  Benzene

 Benzene    7 78 8..1 11 1 8 80 0..1 10 0

1-Octene

1-Octene    1 11 12 2..2 21 1 9 98 8..3 38 8 cyclohexane

cyclohexane    8 84 4..1 16 6 8 81 1..0 00 0 toluene

toluene    9 92 2..1 14 4 1 11 10 0..6 60 0

 Decane

 Decane    1 14 42 2..5 58 8 1 17 74 4..1 10 0  Dodecene

 Dodecene    1 17 70 0..5 57 7 2 21 16 6..2 20 0 Tetradecene

Tetradecene    1 19 98 8..4 49 9 2 25 53 3..6 60 0  Hexadecene

 Hexadecene    2 22 26 6..6 66 6 2 28 86 6..8 80 0 Water 

Water     1 18 8..0 00 0 1 10 00 0..0 00 0

Carbon Monoxide

Carbon Monoxide

   COCO

   2 28 8..0 01 1 --1 19 91 1..5 50 0

A.1 MIX TEE A.1 MIX TEE

Mencampurkan Crude Bio - Oil dengan Hidrogen Mencampurkan Crude Bio - Oil dengan Hidrogen

F1 F1

 Mix T

 Mix Tee 1ee 1

F3 F3 F2

F2

Bahan Baku Bio Oil

Bahan Baku Bio Oil= = 1 17 74 48 81 14 4..0 00 0 Hidrogen

Hidrogen    = = 6 64 46 68 8..1 12 2

Tabel B.5 Neraca Massa Mix Tee 1 Tabel B.5 Neraca Massa Mix Tee 1 K

Koom mppoonneenn F Foorrm muullaa M Maassuuk k ((kkgg//jjaam m)) K Keelluuaar r ((K Kgg//jjaam m)) F

F 11 F F 22 F F 33

 Acetic Acid 

 Acetic Acid      18705.10 18705.10    0 0..0 00 0 1 18 87 70 05 5..1 10 0 2-Cyclopentanone

2-Cyclopentanone     9789.58 9789.58    0 0..0 00 0 9 97 78 89 9..5 58 8  Phenol 

 Phenol      15034.00 15034.00    0 0..0 00 0 1 15 50 03 34 4..0 00 0 Octanoic Acid 

Octanoic Acid      18355.47 18355.47    0 0..0 00 0 1 18 83 35 55 5..4 47 7 1,2-Benzenediol 

1,2-Benzenediol      9614.77 9614.77    0 0..0 00 0 9 96 61 14 4..7 77 7 benzaldehyde

benzaldehyde

  7866.63

  7866.63

   0 0..0 00 0 7 78 86 66 6..6 63 3 Capric Acid 

Capric Acid      18355.47 18355.47    0 0..0 00 0 1 18 83 35 55 5..4 47 7

CH

CH⁴⁴ C C55HH1010

C C⁶⁶HH⁶⁶ C C⁸⁸HH¹⁶¹⁶ C C⁶⁶HH¹²¹² C C⁷⁷HH⁸⁸ C C¹⁰¹⁰HH²²²² C C¹²¹²HH²⁶²⁶ C C¹⁴¹⁴HH³⁰³⁰ C C¹⁶¹⁶HH³⁴³⁴ H H22OO

C C22HH44OO22

C C⁵⁵HH⁸⁸OO C C66HH66OO C

C⁸⁸HH¹⁶¹⁶OO²² C

C⁶⁶HH⁶⁶OO²² C C77HH⁶⁶OO C

C¹⁰¹⁰HH²⁰²⁰OO²²

 Lauric Acid 

 Lauric Acid      55940.48 55940.48    0 0..0 00 0 5 55 59 94 40 0..4 48 8  Myristic Acid 

 Myristic Acid      12936.24 12936.24    0 0..0 00 0 1 12 29 93 36 6..2 24 4  Hexadecanoic Acid 

 Hexadecanoic Acid      8216.26 8216.26    0 0..0 00 0 8 82 21 16 6..2 26 6  Hidrogen

 Hidrogen     0.00 0.00     6 64 46 68 8..1 12 2 6 64 46 68 8..1 12 2

Total 

Total 

117744881144..0000 66446688..1122 118811228822..1122

F input

F input

= =

F output F output 

F

F22 + + F F44    ^{+ +} = = F5 F5

1

17 74 48 81 14 4..0 00 0 + + 6 64 46 68 8..1 12 2 = = 1 18 81 12 28 82 2..1 12 2 1

18 81 12 28 82 2..1 12 2 = = 1 18 81 12 28 82 2..1 12 2

A.2 REAKTOR 1 A.2 REAKTOR 1

Fungsi : Untuk mencampur Bio Oil dengan Hidrogen Fungsi : Untuk mencampur Bio Oil dengan Hidrogen

Reaktor I Reaktor I F

F3 3 F F4 4

Gambar B.1 Aliran Proses Pada Reaktor Gambar B.1 Aliran Proses Pada Reaktor

Reaksi yang terjadi di dalam pencampur : Reaksi yang terjadi di dalam pencampur : I.

I.

_(l)(l)

   + +

   (g)(g)

   → →

_(g)(g)

   + +

   ^COCO (g)(g)    ++    (l)(l)

II.

II.

(l)

(l)

   + + 2 2

   ^(g)(g)

   → →

(l)

(l)

   + +

   ^(l)(l)

III.

III.

_(l)(l)

   + +

   (g)(g)

   → →

_(l)(l)

   + +

   (l)(l)

IV

IV..

_(l)(l)

   + + 2 2

   (g)(g)

   → →

_(l)(l)

   + + 2 2

^H2OH2O (l)(l)

V

V.. _(l)(l)

   + + 5 5

   (g)(g)

   → →

_(l)(l)

   + + 2 2

   (l)(l)

VI.

VI.

   (l)(l)

   + + 2 2

   (g)(g)

   → →

_(g)(g)

   + +

   (l)(l)

II. . K Koonnvveerrssi i R Reeaakkssi i :: 9955% %

=

= 0 0..9 95 5

=

= 1 18 87 70 05 5..1 10 0 k kg g//jjaam m = = 3 31 11 1..4 49 9

  _{kmol/jam  kmol/jam}

=

= 0 0..9 95 5 x x 3 31 11 1..4 49 9

  kmol/jam   kmol/jam

=

= 2 29 95 5..9 92 2

  _{kmol/jam  kmol/jam} C

C¹²¹²HH²⁴²⁴OO²² C

C¹⁴¹⁴HH²⁸²⁸OO²² C

C¹⁶¹⁶HH³²³²OO²² H

H²²

C

C²²HH⁴⁴OO²²    HH²²    CHCH44    HH²²OO C

C55HH88O O HH22    CC55HH1010    HH22OO C

C⁶⁶HH⁶⁶O O HH²²    CC⁶⁶HH⁶⁶    HH²²OO C

C⁸⁸HH¹⁶¹⁶OO²²    HH²²    CC⁸⁸HH¹⁶¹⁶ C

C⁶⁶HH⁶⁶OO²²    HH²²    CC⁶⁶HH¹²¹²    HH²²OO C

C77HH⁶⁶O O HH²²    CC⁷⁷HH⁸⁸    HH²²OO

X X

_CC22HH44OO22

 N  N

_CC22HH⁴⁴OO²²

r  r 

1 1

Rx:

Rx:    + +    → →    + +

   ^COCO    ++

M

M    _{3 31 11 1..4 49 92 21 1 3 32 21 17 7..9 96 69 92 2 0 0..0 00 00 00 0 0 0..0 00 00 00 0 0 0..0 00 00 00 0} R 

R     2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5

SS    1 15 5..5 57 74 46 6 2 29 92 22 2..0 05 51 17 7 2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5 2 29 95 5..9 91 17 75 5 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 1 15 5..5 57 7 k km mo oll//jjaam m = = 9 93 35 5..2 25 5 k kg g//jjaam m

=

= 2 29 92 22 2..0 05 5 k km mo oll//jjaam m = = 5 58 87 73 3..3 32 2 k kg g//jjaam m

=

= 2 29 95 5..9 92 2 k km mo oll//jjaam m = = 4 47 74 46 6..5 52 2 k kg g//jjaam m

CO

CO

   = = 2 29 95 5..9 92 2 k km mo oll//jjaam m = = 8 82 28 89 9..6 64 4 k kg g//jjaam m

=

= 2 29 95 5..9 92 2 k km mo oll//jjaam m = = 5 53 32 26 6..5 51 1 k kg g//jjaam m

IIII. . K Koonnvveerrssi R i Reeaakkssi i :: 9955% %

=

= 0 0..9 95 5

=

= 9 97 78 89 9..5 58 8 k kg g//jjaam m = = 1 11 16 6..4 42 2

  _{kmol/jam  kmol/jam}

=

= 0 0..9 95 5 x x 1 11 16 6..4 42 2

  _{kmol/jam  kmol/jam}

=

= 1 11 10 0..6 60 0

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    _{1 11 16 6..4 42 2 2 29 92 22 2..0 05 5 0 0..0 00 0 0 0..0 00 0} R 

R     1 11 10 0..6 60 0 2 22 21 1..1 19 9 1 11 10 0..6 60 0 1 11 10 0..6 60 0

SS    5 5..8 82 2 2 27 70 00 0..8 86 6 1 11 10 0..6 60 0 1 11 10 0..6 60 0 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 5 5..8 82 2 k km mo oll//jjaam m = = 4 48 89 9..4 48 8 k kg g//jjaam m

=

= 2 27 70 00 0..8 86 6 k km mo oll//jjaam m = = 7 75 56 66 60 0..0 09 9 k kg g//jjaam m

=

= 1 11 10 0..6 60 0 k km mo oll//jjaam m = = 7 77 75 52 2..8 83 3 k kg g//jjaam m

=

= 1 11 10 0..6 60 0 k km mo oll//jjaam m = = 1 19 99 90 0..7 74 4 k kg g//jjaam m

II

III. I. Ko Konv nver ersi si Re Reak aksi si :: 97 97% %

=

= 0 0..9 97 7

=

= 1 15 50 03 34 4..0 00 0 k kg g//jjaam m = = 1 15 59 9..7 75 5

  _{kmol/jam  kmol/jam}

=

= 0 0..9 97 7 x x 1 15 59 9..7 75 5

  kmol/jam   kmol/jam

=

= 1 15 54 4..9 96 6

  _{kmol/jam  kmol/jam} C

C²²HH⁴⁴OO²²    HH²²    CHCH⁴⁴    HH²²OO

C C²²HH⁴⁴OO²²

H H22

CH CH⁴⁴

H H²²OO

X X

_CC55HH88OO

 N  N

_CC55HH88OO

r  r 

₁₁

C

C⁵⁵HH⁸⁸O O 2H2H²²    CC⁵⁵HH¹⁰¹⁰    HH²²OO

C C⁵⁵HH⁶⁶OO 3H 3H22

C C⁵⁵HH¹⁰¹⁰ H H²²OO

X X

_CC66HH66OO

 N  N

_CC66HH⁶⁶OO

r  r 

1 1

Rx:

Rx:    + +    → →    + +

M

M    _{1 15 59 9..7 75 5 2 27 70 00 0..8 86 6 0 0..0 00 0 0 0..0 00 0} R 

R     1 15 54 4..9 96 6 1 15 54 4..9 96 6 1 15 54 4..9 96 6 1 15 54 4..9 96 6

SS    4 4..7 79 9 2 25 54 45 5..9 90 0 1 15 54 4..9 96 6 1 15 54 4..9 96 6 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 4 4..7 79 9 k km mo oll//jjaam m = = 4 45 51 1..0 02 2 k kg g//jjaam m

=

= 2 25 54 45 5..9 90 0 k km mo oll//jjaam m = = 5 51 11 17 7..2 26 6 k kg g//jjaam m

=

= 1 15 54 4..9 96 6 k km mo oll//jjaam m = = 1 12 21 10 03 3..6 68 8 k kg g//jjaam m

=

= 1 15 54 4..9 96 6 k km mo oll//jjaam m = = 2 27 78 89 9..2 22 2 k kg g//jjaam m

IV

IV. K . Kon onve vers rsi R i Rea eaks ksi : i : 10 100% 0%

=

= 1 1..0 00 0

=

= 1 18 83 35 55 5..4 47 7 k kg g//jjaam m = = 1 12 27 7..2 28 8

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 0 x x 1 12 27 7..2 28 8

  _{kmol/jam  kmol/jam}

=

= 1 12 27 7..2 28 8

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    _{1 12 27 7..2 28 8 2 25 54 45 5..9 90 0 0 0..0 00 0 0 0..0 00 0} R 

R     1 12 27 7..2 28 8 2 25 54 4..5 57 7 1 12 27 7..2 28 8 2 25 54 4..5 57 7

SS    0 0..0 00 0 2 22 29 91 1..3 34 4 1 12 27 7..2 28 8 2 25 54 4..5 57 7 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 2 22 29 91 1..3 34 4 k km mo oll//jjaam m = = 4 46 60 05 5..5 58 8 k kg g//jjaam m

=

= 1 12 27 7..2 28 8 k km mo oll//jjaam m = = 1 14 42 28 82 2..4 42 2 k kg g//jjaam m

=

= 2 25 54 4..5 57 7 k km mo oll//jjaam m = = 4 45 58 82 2..1 19 9 k kg g//jjaam m

V

V. . K Koonnvveerrssi i R Reeaakkssi i :: 110000 ^{% %}

=

= 1 1..0 00 0

=

= 9 96 61 14 4..7 77 k 7 kg g//jjaam = m = 8 87 7..3 32 2

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 00 0 x x 8 87 7..3 32 2

  _{kmol/jam  kmol/jam}

=

= 8 87 7..3 32 2

  kmol/jam   kmol/jam C

C66HH66O O HH22    CC66HH66    HH22OO

C C⁶⁶HH⁶⁶OO

H H²² C C⁶⁶HH⁶⁶

H H²²OO

X X

_{CC88HH1616OO22}

 N  N

_CC88HH¹⁶¹⁶OO²²

r  r 

₁₁

C

C⁸⁸HH¹⁶¹⁶OO²²    2H2H²²    CC⁸⁸HH¹⁶¹⁶    2H2H²²OO

C

C⁸⁸HH¹⁶¹⁶OO²² 2H 2H²² C C⁸⁸HH¹⁶¹⁶ 2H 2H²²OO

X X

_CC66HH66OO22

 N  N

_CC66HH66OO22

r 

r 

₁₁

Rx:

Rx:    + +    → →    + +

M

M    _{8 87 7..3 32 2 2 22 29 91 1..3 34 4 0 0..0 00 0 0 0..0 00 0} R 

R     8 87 7..3 32 2 4 43 36 6..6 60 0 8 87 7..3 32 2 1 17 74 4..6 64 4

SS    0 0..0 00 0 1 18 85 54 4..7 74 4 8 87 7..3 32 2 1 17 74 4..6 64 4 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 1 18 85 54 4..7 74 4 k km mo oll//jjaam m = = 3 37 72 28 8..0 02 2 k kg g//jjaam m

=

= 8 87 7..3 32 2 k km mo oll//jjaam m = = 7 73 34 48 8..8 82 2 k kg g//jjaam m

=

= 1 17 74 4..6 64 4 k km mo oll//jjaam m = = 3 31 14 43 3..5 51 1 k kg g//jjaam m

VI

VI. . Ko Konv nver ersi si Re Reak aksi si :: 97 97% %

=

= 0 0..9 97 7

=

= 7 78 86 66 6..6 63 k 3 kg g//jjaam = m = 7 74 4..2 20 0

  _{kmol/jam  kmol/jam}

=

= 0 0..9 97 7 x x 7 74 4..2 20 0

  _{kmol/jam  kmol/jam}

=

= 7 71 1..9 97 7

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    7 74 4..2 20 0 1 18 85 54 4..7 74 4 0 0..0 00 0 0 0..0 00 0

R 

R     7 71 1..9 97 7 1 14 43 3..9 95 5 7 71 1..9 97 7 7 71 1..9 97 7

SS    ^{2 2..2 23 3 1 17 71 10 0..7 79 9 7 71 1..9 97 7 7 71 1..9 97 7}

Komponen Setelah Bereaksi : Komponen Setelah Bereaksi :

=

= 2 2..2 23 3 k km mo oll//jjaam m = = 2 23 36 6..0 00 0 k kg g//jjaam m

=

= 1 17 71 10 0..7 79 9 k km mo oll//jjaam m = = 3 34 43 38 8..6 69 9 k kg g//jjaam m

=

= 7 71 1..9 97 7 k km mo oll//jjaam m = = 6 66 63 31 1..6 64 4 k kg g//jjaam m

=

= 7 71 1..9 97 7 k km mo oll//jjaam m = = 1 12 29 95 5..5 52 2 k kg g//jjaam m

Tabel B.6 Neraca Massa Reaktor 1 Tabel B.6 Neraca Massa Reaktor 1 Komponen

Komponen ^{Formula Formula}

 ^{Input Input Output Output} 

kkgg//jjaam m kkgg//jjaam m

 Acetic Acid 

 Acetic Acid     1 18 87 70 05 5..1 10 0 9 93 35 5..2 25 5 2-Cyclopentanone

2-Cyclopentanone    9 97 78 89 9..5 58 8 4 48 89 9..4 48 8  Phenol 

 Phenol     1 15 50 03 34 4..0 00 0 4 45 51 1..0 02 2 Octanoic Acid 

Octanoic Acid     1 18 83 35 55 5..4 47 7 0 0..0 00 0 1,2-Benzenediol 

1,2-Benzenediol     9 96 61 14 4..7 77 7 0 0..0 00 0

C

C⁶⁶HH⁶⁶OO²²    5H5H²²    CC⁶⁶HH¹²¹²    2H2H²²OO

C C⁶⁶HH⁶⁶OO²²

5H 5H²² C C⁶⁶HH¹²¹² 2H 2H²²OO

X X

_CC77HH⁶⁶OO

 N  N

_CC77HH66OO

r  r 

₁₁

C

C⁷⁷HH⁶⁶O O 2H2H²²    CC⁷⁷HH⁸⁸    HH²²OO

C C77HH66OO

2H 2H²² C C⁷⁷HH⁸⁸

H H²²OO

C C²²HH⁴⁴OO²² C C⁵⁵HH⁸⁸OO C C⁶⁶HH⁶⁶OO C

C⁸⁸HH¹⁶¹⁶OO²² C

C66HH66OO22

benzaldehyde

benzaldehyde    7 78 86 66 6..6 63 3 2 23 36 6..0 00 0 Capric Acid 

Capric Acid     1 18 83 35 55 5..4 47 7 1 18 83 35 55 5..4 47 7  Lauric Acid 

 Lauric Acid     5 55 59 94 40 0..4 48 8 5 55 59 94 40 0..4 48 8  Myristic Acid 

 Myristic Acid     1 12 29 93 36 6..2 24 4 1 12 29 93 36 6..2 24 4  Hexadecanoic Acid 

 Hexadecanoic Acid     8 82 21 16 6..2 26 6 8 82 21 16 6..2 26 6  Hidrogen

 Hidrogen    6 64 46 68 8..1 12 2 3 34 43 38 8..6 69 9  Methane

 Methane    0 0..0 00 0 4 47 74 46 6..5 52 2 Cyclopentane

Cyclopentane    0 0..0 00 0 7 77 75 52 2..8 83 3  Benzene

 Benzene    0 0..0 00 0 1 12 21 10 03 3..6 68 8 1-Octene

1-Octene    0 0..0 00 0 1 14 42 28 82 2..4 42 2 cyclohexane

cyclohexane    0 0..0 00 0 7 73 34 48 8..8 82 2 toluene

toluene    0 0..0 00 0 6 66 63 31 1..6 64 4  Decane

 Decane    0 0..0 00 0 0 0..0 00 0

 Dodecene

 Dodecene    0 0..0 00 0 0 0..0 00 0

Tetradecene

Tetradecene    0 0..0 00 0 0 0..0 00 0

 Hexadecene

 Hexadecene    0 0..0 00 0 0 0..0 00 0

Water 

Water     0 0..0 00 0 1 19 91 12 27 7..6 69 9 Carbon Monoxide

Carbon Monoxide

   COCO

   0 0..0 00 0 8 82 28 89 9..6 64 4

Total

Total 181282.12 181282.12 181282.12 181282.12 A.3 REAKTOR 2

A.3 REAKTOR 2

Fungsi : Untuk mencampur Bio Oil dengan Hidrogen Fungsi : Untuk mencampur Bio Oil dengan Hidrogen

Reaktor II Reaktor II

Gambar B.1 Aliran Proses Pada Reaktor Gambar B.1 Aliran Proses Pada Reaktor

I.

I.

_(l)(l)

   + +

   (g)(g)

   → →

_(g)(g)

   + +

   ^COCO (g)(g)    ++    (l)(l)

II.

II.

_(l)(l)

   + +

   22    (g)(g)

   → →

_(l)(l)

   + +

   (l)(l)

III.

III.

_(l)(l)

   + +

   22    (g)(g)

   → →

_(l)(l)

   + +

   22    (l)(l)

VI.

VI.

   (l)(l)

   + +

   22    (g)(g)

   → →

_(g)(g)

   + +

   (l)(l)

VII

VII

_(l)(l)

   + +

   33    (g)(g)

   → →

_(l)(l)

   + +

   22    (l)(l)

VIII.

VIII.

   ^(l)(l)

   + +

   ^{33    (g)(g)}

   → →

(l)

(l)

   + +

   ^{22    (l)(l)}

IX

IX

   (l)(l)

   + +

   33    (g)(g)

   → →

_(l)(l)

   + +

   22    (l)(l)

C C77HH66OO C

C¹⁰¹⁰HH²⁰²⁰OO²² C

C¹²¹²HH²⁴²⁴OO²² C

C¹⁴¹⁴HH²⁸²⁸OO²² C

C¹⁶¹⁶HH³²³²OO²² H

H²² CH CH⁴⁴ C C⁵⁵HH1010

C C⁶⁶HH⁶⁶ C C⁸⁸HH¹⁶¹⁶ C C66HH1212

C C⁷⁷HH⁸⁸ C C¹⁰¹⁰HH²²²² C C¹²¹²HH²⁶²⁶ C C¹⁴¹⁴HH3030

C C¹⁶¹⁶HH³⁴³⁴ H H²²OO

F

F

⁴⁴

   F F

⁵⁵

C

C²²HH⁴⁴OO²²    HH²²    CHCH44    HH²²OO C

C⁵⁵HH⁸⁸O O HH²²    CC⁵⁵HH1010    HH²²OO C

C⁶⁶HH⁶⁶O O HH²²    CC⁶⁶HH⁶⁶    HH²²OO C

C77HH⁶⁶O O HH²²    CC⁷⁷HH⁸⁸    HH²²OO C

C¹⁰¹⁰HH²⁰²⁰OO²²    HH²²    CC¹⁰¹⁰HH²²²²    HH²²OO C

C1212HH2424OO22    HH22    CC1212HH2626    HH22OO C

C¹⁴¹⁴HH²⁸²⁸OO²²    HH²²    CC¹⁴¹⁴HH3030    HH²²OO

X.

X.

   (l)(l)

   + +

   33    (g)(g)

   → →

_(l)(l)

   + +

   22    (l)(l)

II. . K Koonnvveerrssi i R Reeaakkssi i :: 9955% %

=

= 0 0..9 95 5

=

= 9 93 35 5..2 25 5 k kg g//jjaam = m = 1 15 5..5 57 7

  _{kmol/jam  kmol/jam}

=

= 0 0..9 95 5 x x 1 15 5..5 57 7

  _{kmol/jam  kmol/jam}

=

= 1 14 4..8 80 0

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

   ^COCO    ++

M

M    _{1 15 5..5 57 7 1 17 71 10 0..7 79 9 0 0..0 00 0 0 0..0 00 0 0 0..0 00 0} R 

R     1 14 4..8 80 0 1 14 4..8 80 0 1 14 4..8 80 0 1 14 4..8 80 0 1 14 4..8 80 0

SS    0 0..7 78 8 1 16 69 95 5..9 99 9 1 14 4..8 80 0 1 14 4..8 80 0 1 14 4..8 80 0 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..7 78 8 k km mo oll//jjaam m = = 4 46 6..7 76 6 k kg g//jjaam m

=

= 1 16 69 95 5..9 99 9 k km mo oll//jjaam m = = 3 34 40 08 8..9 95 5 k kg g//jjaam m

=

= 1 14 4..8 80 0 k km mo oll//jjaam m = = 2 23 37 7..3 33 3 k kg g//jjaam m

CO

CO

   = = 1 14 4..8 80 0 k km mo oll//jjaam m = = 4 41 14 4..4 48 8 k kg g//jjaam m

=

= 1 14 4..8 80 0 k km mo oll//jjaam m = = 2 26 66 6..3 33 3 k kg g//jjaam m

IIII. . K Koonnvveerrssi R i Reeaakkssi i :: 9955% %

=

= 0 0..9 95 5

=

= 4 48 89 9..4 48 8 k kg g//jjaam m = = 5 5..8 82 2

  _{kmol/jam  kmol/jam}

=

= 0 0..9 95 5 x x 5 5..8 82 2

  kmol/jam   kmol/jam

=

= 5 5..5 53 3

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    _{5 5..8 82 2 1 16 69 95 5..9 99 9 0 0..0 00 0 0 0..0 00 0} R 

R     5 5..5 53 3 1 11 1..0 06 6 5 5..5 53 3 5 5..5 53 3

SS    0 0..2 29 9 1 16 68 84 4..9 93 3 5 5..5 53 3 5 5..5 53 3 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..2 29 9 k km mo oll//jjaam m = = 2 24 4..4 47 7 k kg g//jjaam m

=

= 1 16 68 84 4..9 93 3 k km mo oll//jjaam m = = 3 33 38 86 6..7 72 2 k kg g//jjaam m

=

= 5 5..5 53 3 k km mo oll//jjaam m = = 3 38 87 7..6 64 4 k kg g//jjaam m

C

C¹⁶¹⁶HH³²³²OO²²    HH²²    CC¹⁶¹⁶HH³⁴³⁴    HH²²OO

X X

_CC22HH44OO22

 N  N

_CC22HH⁴⁴OO²²

r  r 

₁₁

C

C²²HH⁴⁴OO²²    HH²²    CHCH⁴⁴    HH²²OO

C C²²HH⁴⁴OO²²

H H²² CH CH⁴⁴

H H²²OO

X X

_CC55HH88OO

 N  N

_CC55HH88OO

r  r 

1 1

C

C55HH88O O 2H2H22    CC55HH1010    HH22OO

C C⁵⁵HH⁶⁶OO

2H 2H22

C C⁵⁵HH¹⁰¹⁰

=

= 5 5..5 53 3 k km mo oll//jjaam m = = 9 99 9..5 54 4 k kg g//jjaam m

II

III. I. Ko Konv nver ersi si Re Reak aksi si :: 97 97% %

=

= 0 0..9 97 7

=

= 4 45 51 1..0 02 2 k kg g//jjaam m = = 4 4..7 79 9

  _{kmol/jam  kmol/jam}

=

= 0 0..9 97 7 x x 4 4..7 79 9

  _{kmol/jam  kmol/jam}

=

= 4 4..6 65 5

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    _{4 4..7 79 9 1 16 68 84 4..9 93 3 0 0..0 00 0 0 0..0 00 0} R 

R     4 4..6 65 5 4 4..6 65 5 4 4..6 65 5 4 4..6 65 5

SS    0 0..1 14 4 1 16 68 80 0..2 29 9 4 4..6 65 5 4 4..6 65 5 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..1 14 4 k km mo oll//jjaam m = = 1 13 3..5 53 3 k kg g//jjaam m

=

= 1 16 68 80 0..2 29 9 k km mo oll//jjaam m = = 3 33 37 77 7..3 37 7 k kg g//jjaam m

=

= 4 4..6 65 5 k km mo oll//jjaam m = = 3 36 63 3..1 11 1 k kg g//jjaam m

=

= 4 4..6 65 5 k km mo oll//jjaam m = = 8 83 3..6 68 8 k kg g//jjaam m

VI

VI. . Ko Konv nver ersi si Re Reak aksi si :: 97 97% %

=

= 0 0..9 97 7

=

= 2 23 36 6..0 00 0 k kg g//jjaam m = = 2 2..2 23 3

  _{kmol/jam  kmol/jam}

=

= 0 0..9 97 7 x x 2 2..2 23 3

  _{kmol/jam  kmol/jam}

=

= 2 2..1 16 6

  kmol/jam   kmol/jam

Rx:

Rx:    + +    → →    + +

M

M    _{2 2..2 23 3 1 16 68 80 0..2 29 9 0 0..0 00 0 0 0..0 00 0} R 

R     2 2..1 16 6 4 4..3 32 2 2 2..1 16 6 2 2..1 16 6

SS    0 0..0 07 7 1 16 67 75 5..9 97 7 2 2..1 16 6 2 2..1 16 6 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 07 7 k km mo oll//jjaam m = = 7 7..0 08 8 k kg g//jjaam m

=

= 1 16 67 75 5..9 97 7 k km mo oll//jjaam m = = 3 33 36 68 8..6 69 9 k kg g//jjaam m

=

= 2 2..1 16 6 k km mo oll//jjaam m = = 1 19 98 8..9 95 5 k kg g//jjaam m

=

= 2 2..1 16 6 k km mo oll//jjaam m = = 3 38 8..8 87 7 k kg g//jjaam m

H

H²²OO

X X

_CC66HH66OO

 N  N

_CC66HH⁶⁶OO

r  r 

₁₁

C

C66HH66O O HH22    CC66HH66    HH22OO

C C⁶⁶HH⁶⁶OO

H H22

C C⁶⁶HH⁶⁶

H H²²OO

X X

_CC77HH66OO

 N  N

_CC77HH66OO

r  r 

₁₁

C

C⁷⁷HH⁶⁶O O 2H2H²²    CC⁷⁷HH⁸⁸    HH²²OO

C C⁷⁷HH⁶⁶OO

2H 2H²² C C77HH88

H H²²OO

VII.

VII. Konv Konversi ersi Reak Reaksi : si : 100% 100%

=

= 1 1..0 00 0

=

= 1 18 83 35 55 5..4 47 7 k kg g//jjaam m = = 1 10 06 6..5 56 6

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 0 x x 1 10 06 6..5 56 6

  _{kmol/jam  kmol/jam}

=

= 1 10 06 6..5 56 6

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    _{1 10 06 6..5 56 6 1 16 67 75 5..9 97 7 0 0..0 00 0 0 0..0 00 0} R 

R     1 10 06 6..5 56 6 3 31 19 9..6 67 7 1 10 06 6..5 56 6 2 21 13 3..1 11 1

SS    0 0..0 00 0 1 13 35 56 6..3 30 0 1 10 06 6..5 56 6 2 21 13 3..1 11 1 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 1 13 35 56 6..3 30 0 k km mo oll//jjaam m = = 2 27 72 26 6..1 16 6 k kg g//jjaam m

=

= 1 10 06 6..5 56 6 k km mo oll//jjaam m = = 1 15 51 19 92 2..8 86 6 k kg g//jjaam m

=

= 2 21 13 3..1 11 1 k km mo oll//jjaam m = = 3 38 83 36 6..0 04 4 k kg g//jjaam m

VIII.

VIII. Konversi Konversi Reaksi Reaksi 100% 100%

=

= 1 1..0 00 0

=

= 5 55 59 94 40 0..4 48 8 k kg g//jjaam m = = 2 27 79 9..6 60 0

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 0 x x 2 27 79 9..6 60 0

  _{kmol/jam  kmol/jam}

=

= 2 27 79 9..6 60 0

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    2 27 79 9..6 60 0 1 13 35 56 6..3 30 0 0 0..0 00 0 0 0..0 00 0

R 

R     2 27 79 9..6 60 0 8 83 38 8..8 81 1 2 27 79 9..6 60 0 5 55 59 9..2 21 1

SS    0 0..0 00 0 5 51 17 7..4 48 8 2 27 79 9..6 60 0 5 55 59 9..2 21 1 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 5 51 17 7..4 48 8 k km mo oll//jjaam m = = 1 10 04 40 0..1 14 4 k kg g//jjaam m

=

= 2 27 79 9..6 60 0 k km mo oll//jjaam m = = 4 47 76 69 91 1..6 61 1 k kg g//jjaam m

=

= 5 55 59 9..2 21 1 k km mo oll//jjaam m = = 1 10 00 06 65 5..7 76 6 k kg g//jjaam m X

X

_{CC1010HH2020OO22}

 N  N

_CC1010HH²⁰²⁰OO²²

r  r 

₁₁

C

C¹⁰¹⁰HH²⁰²⁰OO²²    3H3H²²    CC¹⁰¹⁰HH²²²²    2H2H²²OO

C

C¹⁰¹⁰HH²⁰²⁰OO²² 3H 3H²² C C¹⁰¹⁰HH²²²²

2H 2H²²OO

X X

_{CC1212HH2424OO22}

 N  N

_{CC1212HH2424OO22}

r  r 

₁₁

C

C¹²¹²HH²⁴²⁴OO²²    3H3H²²    CC¹²¹²HH²⁶²⁶    2H2H²²OO

C

C1212HH2424OO22

3H 3H²² C C¹²¹²HH²⁶²⁶

2H 2H²²OO

IX

IX. K . Kon onve vers rsi R i Rea eaks ksi : i : 10 100% 0%

=

= 1 1..0 00 0

=

= 1 12 29 93 36 6..2 24 4 k kg g//jjaam m = = 5 56 6..6 69 9

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 0 x x 5 56 6..6 69 9

  _{kmol/jam  kmol/jam}

=

= 5 56 6..6 69 9

  _{kmol/jam  kmol/jam}

Rx:

Rx:    + +    → →    + +

M

M    5 56 6..6 69 9 5 51 17 7..4 48 8 0 0..0 00 0 0 0..0 00 0

R 

R     5 56 6..6 69 9 1 17 70 0..0 08 8 5 56 6..6 69 9 1 11 13 3..3 39 9

SS    ^{0 0..0 00 0 3 34 47 7..4 40 0 5 56 6..6 69 9 1 11 13 3..3 39 9}

Komponen Setelah Bereaksi : Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 3 34 47 7..4 40 0 k km mo oll//jjaam m = = 6 69 98 8..2 28 8 k kg g//jjaam m

=

= 5 56 6..6 69 9 k km mo oll//jjaam m = = 1 11 12 25 53 3..0 02 2 k kg g//jjaam m

=

= 1 11 13 3..3 39 9 k km mo oll//jjaam m = = 2 20 04 40 0..9 95 5 k kg g//jjaam m

X.

X. K Kon onve verrsi si R Rea eaks ksi : i : 10 100% 0%

=

= 1 1..0 00 0

=

= 8 82 21 16 6..2 26 k 6 kg g//jjaam = m = 3 32 2..0 07 7

  _{kmol/jam  kmol/jam}

=

= 1 1..0 00 0 x x 3 32 2..0 07 7

  _{kmol/jam  kmol/jam}

=

= 3 32 2..0 07 7

  _{kmol/jam  kmol/jam}

Rx:

Rx:

   + +

   → →

   + +

M

M    _{3 32 2..0 07 7 3 34 47 7..4 40 0 0 0..0 00 0 0 0..0 00 0} R 

R     3 32 2..0 07 7 9 96 6..2 21 1 3 32 2..0 07 7 6 64 4..1 14 4

SS    0 0..0 00 0 2 25 51 1..1 19 9 3 32 2..0 07 7 6 64 4..1 14 4 Komponen Setelah Bereaksi :

Komponen Setelah Bereaksi :

=

= 0 0..0 00 0 k km mo oll//jjaam m = = 0 0..0 00 0 k kg g//jjaam m

=

= 2 25 51 1..1 19 9 k km mo oll//jjaam m = = 5 50 04 4..8 89 9 k kg g//jjaam m

=

= 3 32 2..0 07 7 k km mo oll//jjaam m = = 7 72 26 69 9..3 30 0 k kg g//jjaam m

=

= 6 64 4..1 14 4 k km mo oll//jjaam m = = 1 11 15 54 4..5 55 5 k kg g//jjaam m

T

Tabel B.7 Neraca abel B.7 Neraca Massa Reaktor II Massa Reaktor II

X X

_CC1414HH²⁸²⁸OO²²

 N  N

_{CC1414HH2828OO22}

r  r 

₁₁

C

C¹⁴¹⁴HH²⁸²⁸OO²²    3H3H²²    CC¹⁴¹⁴HH³⁰³⁰    2H2H²²OO

C

C¹⁴¹⁴HH²⁸²⁸OO²² 3H 3H²² C C¹⁴¹⁴HH³⁰³⁰

2H 2H²²OO

X X

_{CC1616HH3232OO22}

 N  N

_{CC1616HH3232OO22}

r  r 

₁₁

C

C1616HH3232OO22    3H3H22    CC1616HH3434    2H2H22OO

C

C¹⁶¹⁶HH³²³²OO²² 3H 3H22

C C¹⁶¹⁶HH³⁴³⁴

2H 2H²²OO

K

Koom mppoonneenn F Foorrm muullaa

 ^{Input Input Output Output} 

kkgg//jjaam m kkgg//jjaam m

 Acetic acid 

 Acetic acid 

    935.25 935.25

   _46.7646.76

2-Cyclopentanone

2-Cyclopentanone     489.48 489.48

   _24.4724.47  Phenol 

 Phenol 

    451.02 451.02

   _13.5313.53

Octanoic Acid 

Octanoic Acid 

    0.00 0.00

   _0.000.00

1,2-Benzenediol 

1,2-Benzenediol 

    0.00 0.00

   _0.000.00

benzaldehyde

benzaldehyde

    236.00 236.00

   _7.087.08

Capric Acid 

Capric Acid 

    18355.47 18355.47

   _0.000.00  Lauric Acid 

 Lauric Acid 

    55940.48 55940.48

   _0.000.00  Myristic Acid 

 Myristic Acid 

    12936.24 12936.24

   _0.000.00  Hexadecanoic Acid 

 Hexadecanoic Acid 

    8216.26 8216.26

   _0.000.00

 Hidrogen

 Hidrogen     3438.69 3438.69

   _504.89504.89

 Methane

 Methane     4746.52 4746.52

   _{4983.844983.84}

Cyclopentane

Cyclopentane     7752.83 7752.83

   _{8140.478140.47}

 Benzene

 Benzene

  12103.68

  12103.68

  12466.79   12466.79

1-Octene

1-Octene     14282.42 14282.42

   _{14282.4214282.42}

cyclohexane

cyclohexane     7348.82 7348.82

   _{7348.827348.82}

toluene

toluene    6 66 63 31 1..6 64 4 6 66 63 38 8..7 72 2  Decane

 Decane    0 0..0 00 0 1 15 51 19 92 2..8 86 6  Dodecene

 Dodecene    0 0..0 00 0 4 47 76 69 91 1..6 61 1 Tetradecene

Tetradecene    0 0..0 00 0 1 11 12 25 53 3..0 02 2  Hexadecene

 Hexadecene    0 0..0 00 0 7 72 26 69 9..3 30 0 Water 

Water     1 19 91 12 27 7..6 69 9 3 36 67 71 13 3..4 41 1

Carbon Monoxide

Carbon Monoxide    COCO

   8 82 28 89 9..6 64 4 8 87 70 04 4..1 12 2

T

Toottaal l 118811228822..112 2 118811228822..1122

A.4

A.4 SEPARA SEPARATOR  TOR 

Fungsi : Fungsi :

Separator Separator

C C²²HH⁴⁴OO²² C C⁵⁵HH⁸⁸OO C C⁶⁶HH⁶⁶OO C

C⁸⁸HH¹⁶¹⁶OO²² C

C⁶⁶HH⁶⁶OO²² C C77HH⁶⁶OO C

C1010HH2020OO22

C

C¹²¹²HH²⁴²⁴OO²² C

C¹⁴¹⁴HH²⁸²⁸OO²² C

C¹⁶¹⁶HH³²³²OO²² H

H²² CH CH⁴⁴ C C⁵⁵HH1010

C C66HH66

C C⁸⁸HH¹⁶¹⁶ C C⁶⁶HH¹²¹² C C⁷⁷HH⁸⁸ C C¹⁰¹⁰HH²²²² C C1212HH2626

C C¹⁴¹⁴HH3030

C C¹⁶¹⁶HH³⁴³⁴ H H²²OO

F F

⁶⁶

F

F

⁵⁵

   F F

⁷⁷