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Introduction

Retrieval of Chemical Abundances in Titan’s Upper Atmosphere

Abstract

We present an innovative retrieval method that corrects for the effect of pointing motion by forward modeling the Cassini/UVIS instrument response function with the pointing motion value obtained from the SPICE C kernel along the spectral dimension. A high-resolution star model and an instrument response simulator that includes the position of the point source on the detector are used for the analysis of the pointing motion.

Introduction

The steering motion is introduced by the spacecraft's attitude control system, which frequently fires thrusters during occultation observations (Chiang et al. 1993). The Markov Chain Monte-Carlo (MCMC) method (Foreman-Mackey et al. 2013) is used as a parameter search tool.

Compensating for pointing motion

The spatial dimension lies along the length of the 5 pixels, with the spectral dimension perpendicular to it. The position of the star image on the slit along the spectral dimension as a function of the jet tangent height in Titan's atmosphere during T52 is shown in Figure 2.1b.

Methodology

The motion of the star image along the spectral dimension, however, must be modeled for data analysis, which is the focus of this work. Temperature differences between the measurement temperature and the ambient conditions in Titan's atmosphere may contribute to this.

Figure 2.1b as the green path. The reference spectrum of the star (I 0 ) is constructed by  averaging the spectra when the ray tangent height is greater than 1500 km above Titan’s  surface, where extinction by Titan’s atmosphere is negligible, and the poin
Figure 2.1b as the green path. The reference spectrum of the star (I 0 ) is constructed by averaging the spectra when the ray tangent height is greater than 1500 km above Titan’s surface, where extinction by Titan’s atmosphere is negligible, and the poin

Synthetic spectrum analysis

The bounds are adjusted by 2 orders of magnitude after every 2000 steps if necessary according to the PDF of the parameter and the convergence criterion. Probability density functions (PDFs, blue solid lines) of the logarithm of LOS abundances obtained from the synthetic spectrum (red line in Figure 2.2).

Figure 2.3. Probability density functions (PDFs, blue solid lines) of the logarithm of  LOS  abundances  retrieved  from  the  synthetic  spectrum  (red  line  in  Figure  2.2)
Figure 2.3. Probability density functions (PDFs, blue solid lines) of the logarithm of LOS abundances retrieved from the synthetic spectrum (red line in Figure 2.2)

Results and discussion

All the major hydrocarbons except C2H6 remain well constrained down to 400 km where absorption saturates. Three species (C2H6, C2N2 and C6N2) are excluded as their LOS occurrences are not well constrained over most of the altitude range considered.

Figure 2.5. Vertical profiles of the logarithm of LOS abundances retrieved from T52  occultation observations
Figure 2.5. Vertical profiles of the logarithm of LOS abundances retrieved from T52 occultation observations

Conclusions

Number density profiles corresponding to well-bounded number densities and positive upper bounds are shown in Figure 2.6. Since the number densities at each height are calculated with contributions from the well- and poorly-constrained LOS abundances, the number densities have larger relative uncertainties and smaller range of heights where they are well-constrained. Other minor species (Figures 2.6e-2.6h) are well constrained in at least some of the altitude range considered, and thus may provide constraints on Titan's atmospheric chemistry.

Appendix

Vertical profiles of the free parameters: (a) fractal dimension, (b) monomer radius, (c) number of monomers in each aggregate, and (d) total number density, and two derived quantities: (e) total effective radius, and (f ) total mass density assuming a material density of 1g/cm-3 in the retrievals under scenarios of monodispersed fractal aggregates constrained using all observations (green) and forward scattering only (blue). Results of the profiles of the four free parameters (Df, rm, Nm, na) are compared with the observations in Figures 3.3 and 3.4. The first two principal components, PC1 (blue) and PC2 (green), of the scaled reflectance spectrum time series.

Figure 2.S1. (a) Simulated photon count spectra from the T52 occultation at 754 km ray  tangent height with pointing motion values along the spectral dimension of 0 (blue), -0.5  (red) and +0.5 (green) mrad
Figure 2.S1. (a) Simulated photon count spectra from the T52 occultation at 754 km ray tangent height with pointing motion values along the spectral dimension of 0 (blue), -0.5 (red) and +0.5 (green) mrad

A Bimodal Distribution of Haze in Pluto's Atmosphere

Abstract

We present a joint retrieval of Pluto's haze morphology and distribution in the lower 50 km of its atmosphere, using observations from multiple instruments aboard the New Horizons spacecraft. Haze in Pluto's atmosphere is one of the most distinctive features seen during New Horizons' historic flyby in 2015. This result successfully addresses the disagreement between the instruments, and provides important constraints on local haze production and gas condensation in Pluto's atmosphere.

Introduction

Observations of nebular particles obtained by the Multispectral Visible Imaging Camera (MVIC, Reuter et al. 2008) at optical wavelengths present a bluish color, indicating small particle radii compared to the observation wavelength (Gladstone et al. 2016). However, there is a disagreement between the UV-extinction and scattering phase functions at visible wavelengths obtained by the LOng-Range Reconnaissance Imager (LORRI, Cheng et al. 2008), so no solution has been found that can explain both sets observations (Cheng et al. 2017). In addition to observations with these three instruments, infrared (IR) spectra of nebula particles in a forward scattering configuration were obtained with the Linear Etalon Imaging Spectral Array (LEISA, Reuter et al. 2008, Grundy et al. 2018), which were not evaluated. .

Observations and data processing

  • Alice
  • LORRI
  • LEISA
  • MVIC

I/F profiles in images taken at various mean phase angles from 19.5° to 169.0° were reported by Cheng et al. 2017) to analyze the property of haze particles. Here we fit four I/F profiles from Cheng et al. 2017) with the highest resolution in this work, covering phase angles from backward to forward scattering. Despite its primary purpose of mapping the surface geology and composition, LEISA obtained an observation of Pluto's haze at a forward scattering geometry with a phase angle of 169° (Grundy et al. 2018).

Figure  3.1.  Comparison  between  observations  obtained  by  instruments  onboard  New  Horizons spacecraft (shaded areas) and model results with 1-σ uncertainties under the  scenario of a bimodal distribution of haze particles (solid lines with error ba
Figure 3.1. Comparison between observations obtained by instruments onboard New Horizons spacecraft (shaded areas) and model results with 1-σ uncertainties under the scenario of a bimodal distribution of haze particles (solid lines with error ba

Methodology

  • Aggregate morphology
  • Scattering models
  • Retrieving algorithm
  • Surface reflection

We use the distribution model described by Tomasko et al. 2008) to estimate the phase function and particle cross sections of the parametrized fractal aggregate. The Python package emcee (Foreman-Mackey et al. 2013) is used to implement the parameter search algorithm. We use the Hierarchical Equal Area IzoLatitude Pixelization (HEALPix; Górski et al. 2005 ) method to discretize Pluto's surface for the reflectance calculation.

Results

  • Monodispersed fractal aggregates
  • Monodispersed fractal aggregates and surface reflection
  • Bimodal distribution

Best-fit results are marked as solid lines, while those derived from probability density functions (PDFs) with 1-σ uncertainty are shown as shaded areas. The results show that the assumption of monodisperse fractal aggregates cannot fit all observations: it underestimates the backscatter (Figures 3.4a and 3.4b) due to the phase functions dominated by the forward distribution of the fractal aggregates. Haze particles are two-dimensional ~1μm aggregates with ~20nm monomers at most heights (Figure 3.3b and 3.3e).

Figure 3.3. Vertical profiles of the free parameters: (a) fractal dimension, (b) monomer  radius, (c) number of monomers in each aggregate, and (d) aggregate number density,  and  two  derived  quantities:  (e)  aggregate  effective  radius,  and  (f)  tot
Figure 3.3. Vertical profiles of the free parameters: (a) fractal dimension, (b) monomer radius, (c) number of monomers in each aggregate, and (d) aggregate number density, and two derived quantities: (e) aggregate effective radius, and (f) tot

Discussion

Our results break the degeneracy between bimodal and power-law distributions of haze particles proposed by Kutsop et al. in review), which used only MVIC observations. Due to the low temperature, C2 species can condense/stick onto haze particles through gas/solid phase change (Wong et al. 2017) or gas-haze incorporation (Luspay-Kuti et al. 2017). While the contribution of Pluto's surface reflectance is negligible on the observed I/F above Pluto's limb, the detected haze optical properties can help improve the constraints on Pluto's surface albedo (e.g. Buratti et al. 2017).

Summary

Constraints on the composition of Pluto's surface can be greatly improved if the influence of the aerosols is removed. The bimodal distribution consists of a population of ~1μm two-dimensional aggregates with ~20nm monomers and a population of ~80nm particles. Surface reflectance makes negligible contributions to haze brightness above the limb, but other surface-related mechanisms can affect haze brightness in the lower 15 km of the atmosphere.

Appendix

  • Abel transform of noisy data
  • MVIC data processing
  • Test of scenarios

Land and ocean are attached to the Earth's surface and appear periodically in the light curve time series. In contrast, PC1 contributes the most variation to k. a) Time series of the first principal component, PC1 (blue points). Spectrally dependent single-point light curves of Earth were analyzed as observations of a surrogate exoplanet.

Table 3.S1. List of MVIC observations
Table 3.S1. List of MVIC observations

Earth as an Exoplanet: A Two-dimensional Alien Map

Abstract

Resolving spatially-varying exoplanet characteristics from single-point light curves is essential for determining whether Earth-like worlds contain geological features and/or climate systems that affect habitability. We present the first two-dimensional (2D) surface map of the Earth, reconstructed from light curve observations without any assumptions of its spectral properties. This study serves as a baseline for reconstructing the surface features of Earth-like exoplanets in the future.

Introduction

Land/ocean changes and cloud patterns were recently extracted from the Earth's light curves using two years of observations of the Earth's bright side from the Deep Space Climate Observatory (DSCOVR, Jiang et al. 2018). Spatial maps of hot Jupiter atmosphere have been compiled (e.g. Knutson et al. 2007, Louden & Wheatley 2015). Using two-day single-point light curves from NASA's EPOXI mission, Cowan et al. 2009) presented the first detected longitudinal surface map of the Earth's surface.

Observations and labels

In summary, using the EPIC observations collected in 2016 and 2017 and the concurrent viewing geometry, we obtain a time series consisting of 10-point reflectance spectra with two Figure 4.1. b) Earth land/ocean map for the same scenario as (a), using the GSHHG database (Wessel et al. 1996). The mean value and variance of the reflectance in each channel are shown in Figure 4.1d; obviously there is a considerable difference between the channels. In the following analysis, we normalize the time series of reflectance spectra to obtain zero mean and unit standard deviations, since the singular value decomposition (SVD) presented in Section 4.4 is sensitive to scaling between the dimensions of the dataset.

Time series analysis

The order of variance accounted for by PCs depends on the contribution of land and cloud fractions to the variance of the time series. The interpretation of the first two PCs is also supported by their time series (Figure 4.3). The regularization parameter, λ, is 10-3 for the construction of this map (see Appendix 3.7.2 for further details). b) Global land/ocean map of Earth.

Figure  4.2.  (a)  Singular  values  of  the  principal  components  (PCs,  red)  and  their  importance to land (blue) and cloud (green) fractions
Figure 4.2. (a) Singular values of the principal components (PCs, red) and their importance to land (blue) and cloud (green) fractions

Discussion

If these materials can be constrained by reflectance spectra, their fractions can be deduced from the size of the corresponding PC. Once the surface information is extracted from the light curves, the exoplanet surface map can be recovered from the observational geometry without making any spectral assumptions. Glares, features that are small on the surface but contribute significantly to the spectrum, can also affect the quality of the resulting map.

Summary

Their contributions to light curves are simulated and estimated in Lustig-Yaeger et al. 2018), and observational evidence in DSCOVR/EPIC images is presented by Li et al. In this work, the effect of glint is assumed to be on the "mean ocean" and is removed when the light curves are scaled.

Appendix

  • Gradient Boosted Regression Trees
  • Surface map construction
  • Surface map uncertainty

One of the advantages of decision trees is that they can evaluate the feature importance (computers in this work). The uncertainty values ​​are in the order of ~10% of the pixel values ​​in the recovered map (Figure 4.4a), suggesting a good quality of Earth surface map reconstruction. Above all, observations of the atmosphere of Pluto provide constraints on a cold version of prebiotic-like atmosphere.

Figure 4.S2. (a) Recovered land fraction map using synthetic observations, produced by  averaging  the  ground  truth  of  the  land/ocean  map  given  the  viewing  geometry
Figure 4.S2. (a) Recovered land fraction map using synthetic observations, produced by averaging the ground truth of the land/ocean map given the viewing geometry

Conclusions and Future Directions

Evolution of Earth’s atmosphere

Photochemistry in Titan’s atmosphere

Titan’s atmosphere

Photon count spectra

Probability density functions of synthetic data

Probability density functions of observations

Vertical profiles of LOS abundances

Vertical profiles of number densities

Illustration of fractal aggregate morphology

Free parameter profiles of monodispersed aggregates

Observations and the monodispersed aggregate model

I/F of secondary scattering

Free parameter profiles of bimodal distribution

Contributions of fractal aggregates and spheres

Local scattering intensity of 80nm particles

Singular values and correlation

PC time series and power spectra

Retrieved 2-D map of the Earth

Gambar

Figure  1.2.  Photochemical  scheme  in  Titan’s  atmosphere.  Taken  from  Atreya  et  al
Table 2.1. Stellar occultation during T52.
Figure 2.1b as the green path. The reference spectrum of the star (I 0 ) is constructed by  averaging the spectra when the ray tangent height is greater than 1500 km above Titan’s  surface, where extinction by Titan’s atmosphere is negligible, and the poin
Figure 2.2. (a) Photon count spectra of the T52 occultation at 754 km ray tangent height  showing the observed spectrum (blue), the best fit simulated model spectrum (green)  and the synthetic spectrum  (red), which includes  artificially introduced noise
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