by
Bapan Pramanik
Department of Chemistry
Indian Institute of Technology Guwahati Guwahati, Assam, 781039
India
A Thesis Submitted in Partial Fulfillment of the Requirements for the degree of
Doctor of Philosophy In
Chemistry
IIT Guwahati, March 2019
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To
My Parents and Sister…
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Contents
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Abstract
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Acknowledgements
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List of Abbreviations
NIR
Φ
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B-H FP TLC EDA DETA TETA PBS HEPES Tris TAE MOPS Ct-DNA ITC Ka
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Chapter 1
Introduction
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Chapter 2
Solvochromism and Efficient Base Sensing by a Viologen-Perylenediimide Conjugate
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N
ET abs em f
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C)
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Chapter 3
A Perylenediimide-Peptide Conjugate for Self- Assembly Assisted Tandem Sensing of Pd 2+ and CN -
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Efficient Detection of Histone by a DNA- Naphthalenediimide Hybrid
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acalculated for 1 g mL-1 of NDI in presence of 10 g mL-1 of DNA; bTm of DNA = 64.5 °C
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A
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Chapter 5
Picric Acid Detection at Femtogram Level by a Short Peptide Gelator
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B) D)
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NMR, Mass Spectra, and Chromatogram of the Synthesized Compounds
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Figure1 1H NMR spectrum of 2.A.
Figure 2 ESI-Ms spectrum of 2.A.
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Figure 3 1H NMR spectrum of 2.B.
Figure 4 ESI-Ms spectrum of 2.B.
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Figure 5 1H NMR spectrum of 2.C.
Figure 6 ESI-Ms spectrum of 2.C.
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Figure 7 1H NMR spectrum of 2.1.
Figure 8
NMR spectrum of 2.1
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Figure 9 ESI-Ms spectrum of 2.1.
Figure 10 1H NMR spectrum of 2.2.
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Figure 11 ESI-Ms spectrum of 2.2.
Figure 12 1H NMR spectrum of 2.3.
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Figure 13 ESI-Ms spectrum of 2.3.
Figure 14 1H NMR spectrum of 3.A.
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Figure 15 ESI-Ms spectrum of 3.A.
Figure 16 ESI-Ms spectrum of 3.B.
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Figure 17 1H NMR spectrum of 3.C.
Figure 18 ESI-MS spectrum of 3.C.
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Figure 19 ESI-Ms spectrum of 3.D.
Figure 20 1H NMR spectrum of 3.1.
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Figure 21 ESI-Ms spectrum of 3.1.
Figure 22 ESI-Ms spectrum of 3.1.
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Figure 23 1H NMR spectrum of 4.1A.
Figure 24 ESI-Ms spectrum of 4.1A.
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Figure 25 1H NMR spectrum of 4.2A.
Figure 26 ESI-Ms spectrum of 4.2A.
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Figure 27 1H NMR spectrum of 4.3A.
Figure 28 ESI-Ms spectrum of 4.3A.
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Figure 29 1H NMR spectrum of 4.1B.
Figure 30 ESI-Ms spectrum of 4.1B.
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Figure 31 1H NMR spectrum of 4.2B.
Figure 32 ESI-Ms spectrum of 4.2B.
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Figure 33 1H NMR spectrum of 4.3B.
Figure 34 ESI-Ms spectrum of 4.3B.
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Figure 35 1H NMR spectrum of 4.4A.
Figure 36 ESI-Ms spectrum of 4.4A.
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Figure 37 1H NMR spectrum of 4.1.
Figure 38 ESI-Ms spectrum of 4.1.
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Figure 39 1H NMR spectrum of 4.2.
Figure 40 ESI-Ms spectrum of 4.2.
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Figure 41 ESI-Ms spectrum of 4.2.
Figure 42 1H NMR spectrum of 4.3.
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Figure 43 ESI-Ms spectrum of 4.3.
Figure 44 1H NMR spectrum of 4.4.
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Figure 45 ESI-Ms spectrum of 4.4.
Figure 46 1H NMR spectrum of 4.5.
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Figure 47 ESI-Ms spectrum of 4.5.
Figure 48 1H NMR spectrum of 5.1.
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Figure 49 13C NMR spectrum of 5.1.
Figure 50 ESI-Ms spectrum of 5.1.
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Figure 51 HPLC chromatogram of 5.1.
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References
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List of Publications
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