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TABLE OF CONTENTS

CERTIFICATION . . . . . . . ii

ABSTRACT . . . . . . . iv

ACKNOWLEDGEMENT . . . . . . . v

CHAPTER 1: INTRODUCTION . . . . . 1

1.1 Background of Study . . . . 1 1.2 Problem Statement . . . . 2 1.3 Objectives and Scope of Study . . . 3

CHAPTER 2: LITERATURE REVIEW . . . . 4

2.1 Steam Cracking Furnace . . . . 4 2.2 Ethylene Cracking . . . . 5 2.3 Radiant Coil Material . . . . 6 2.4 Model Equation . . . . 7 2.5 Heat Transfer in Firebox . . . . 8

2.6 API 573 . . . . . . 8

2.7 Asymmetric Flow and Temperature Field . 9

2.8 CFD Model . . . . . 10

2.9 Remark on Symmetry Condition . . 11 2.10 Grid Independence . . . . 11

CHAPTER 3: METHODOLOGY . . . . . 12

3.1 Execution Chart . . . . . 12 3.2 Milestone and Project Planning . . . 13 3.3 Temperature Data Gathering . . . 14 3.4 Furnace Modeling and Simulation . . 15

3.5 Calculation . . . . . 17

3.6 Boundary Condition Settings . . . 18

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CHAPTER 4: RESULTS AND DISCUSSION . . . 19 4.1 Furnace Data at Normal Operation . . 19 4.2 Furnace Detail Dimension . . . 19 4.3 Simulation Results . . . . 20 4.4 Temperature Data Gathering (Plant Operation) 24 4.8 Error Analysis . . . . . 24

CHAPTER 5: CONCLUSIONS AND RECOMMENDATIONS . . 27

5.1 Conclusions . . . . . 27 5.2 Recommendations . . . . . 28

REFERENCES . . . . . . . . 29

APPENDICES . . . . . . . . 31

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LIST OF FIGURES

Figure 1 Schematic Diagram of Bent Tube Coil . . . 2

Figure 2 Schematic Diagram of an Industrial Process Furnace . . 5

Figure 3 Ethane Cracking Reactions . . . . . 5

Figure 4 Model Equations . . . . . . . 7

Figure 5 Peep Hole for Temperature Data Gathering. . . . 14

Figure 6 Infrared Pyrometer . . . . . . 15

Figure 7 Furnace (1/8) 3D Model in Gambit . . . . 15

Figure 8Meshing with size function . . . . . 16

Figure 9 Furnace Full Dimensions . . . . . . 19

Figure 10 Steady-State Iteration (3500) . . . . . 20

Figure 11 Steady-State Iteration (8000) . . . . . 20

Figure 12 Heat Distributions from Side View . . . . 21

Figure 13 Heat Distributions from Front View . . . . 22

Figure 14 Residuals Unsteady-State . . . . . 23

Figure 15 Mass Flow Rate Unsteady-State . . . . 23

Figure 16 Plot X-Y Graph . . . . . . . 25

Figure 17 Plot Z-Y Graph . . . . . . . 25

Figure 18 Flue Gas Velocity (Vertical Cross Section). . . . 32

Figure 19 Flue Gas Velocity (Horizontal Cross Section). . . . 33

Figure 20 Radiant Coil Section (4/2/1 Split) . . . . . 34

Figure 21 Temperature Point Location (Comparison). . . . 29

Figure 22 Sidewall Burner Thermography . . . . 36

Figure 23 Floor Burner Thermography . . . . . 37

Figure 24 Normal Data Operations (Ethane Cracking) . . . 38

Figure 25 Furance Process Operation Computer System . . . 39

Figure 26 Radiant Coil Position . . . . . . 40

Figure 27 Radiant Coil Bending Position . . . . . 40

Figure 28 Tubing Alignment (Shutdown) . . . . . 41

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Figure 29 Tubing Alignment (Operating) . . . . . 41

Figure 30 Tubing Support System . . . . . 42

Figure 31 Root Cause Investigation (RCI) . . . . 43

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LIST OF TABLES

Table 1 Material Properties Nickel-Chromium Alloy Steels . . . 6 Table 2 Tensile and Ductility for NiCr Alloy . . . . 6 Table 3 NiCr Specific Resistance and Maximum Operating Temperature. . 6 Table 4 Project Planning and Milestone FYP1 . . . . 13 Table 5 Project Planning and Milestone FYP2 . . . . 13 Table 6 Mass Flow Rate Convergence . . . . . 21

Table 7 Simulation Results . . . . . . . 33

Table 8 Temperature Data Gathering . . . . . 34

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NOMENCLATURE

m: Mass Flow Rate ρ: density

∆: differences/ changes DH: Hydraulic Diameter A: Cross sectional Area P: Perimeter of the Area k: Kinetic Reaction constant E: Activation Energy

BF: Boiler Feedwater HP: High Pressure

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